公开(公告)号：US09423467B2

公开(公告)日：2016-08-23

申请号：US14128285

申请日：2012-06-28

Applicant: Raphael Salot ,  Philipp Achatz ,  Steve Martin ,  Sami Oukassi

Inventor： Raphael Salot ,  Philipp Achatz ,  Steve Martin ,  Sami Oukassi

IPC: G01R31/36 ,  H01M10/04 ,  H01M2/26 ,  H01M6/40 ,  H01M10/0525 ,  H01M10/0565 ,  H01M10/0585 ,  H01M10/48 ,  H01M10/42

CPC classification number: G01R31/3658 ,  H01M2/266 ,  H01M6/40 ,  H01M10/04 ,  H01M10/0436 ,  H01M10/0525 ,  H01M10/0565 ,  H01M10/0585 ,  H01M10/4207 ,  H01M10/4285 ,  H01M10/48 ,  H01M10/482 ,  Y02E60/122 ,  Y02P70/54

Abstract: The method of producing a device having batteries includes the following successive steps performed on a support substrate: providing a support substrate including a first electrically conducting layer forming a main surface, simultaneously forming a plurality of batteries on the first electrically conducting layer, testing operation of the plurality of batteries to discriminate between a first group of functional batteries and a second group of defective batteries, forming a second electrically conducting layer electrically insulated from the first electrically conducting layer, the second electrically conducting layer and the first electrically conducting layer being configured to connect only the functional batteries in parallel.

Abstract translation: 制造具有电池的器件的方法包括在支撑衬底上执行以下连续步骤：提供包括形成主表面的第一导电层的支撑衬底，同时在第一导电层上形成多个电池，测试操作 所述多个电池用于区分第一组功能电池和第二组有缺陷的电池，形成与所述第一导电层电绝缘的第二导电层，所述第二导电层和所述第一导电层被配置为 仅连接功能电池并联。

公开(公告)号：US09243332B2

公开(公告)日：2016-01-26

申请号：US12818607

申请日：2010-06-18

Applicant: Sami Oukassi ,  Lucie Le Van-Jodin ,  Raphael Salot

Inventor： Sami Oukassi ,  Lucie Le Van-Jodin ,  Raphael Salot

IPC: B01J19/08 ,  C23F4/00 ,  H01M10/052 ,  H01M10/058

CPC classification number: C23F4/00 ,  H01M10/052 ,  H01M10/058 ,  Y02E60/122

Abstract: The method for eliminating metallic lithium on a support comprises a plasma application step. The plasma is formed from a carbon source and an oxygen source with a power comprised between 50 and 400 W. It transforms the metallic lithium into lithium carbonate. The method then comprises a dissolution step of the lithium carbonate in an aqueous solution.

Abstract translation: 用于消除载体上的金属锂的方法包括等离子体施加步骤。 等离子体由碳源和氧源源于50至400W之间形成。它将金属锂转化为碳酸锂。 该方法然后包括碳酸锂在水溶液中的溶解步骤。

公开(公告)号：US20140248541A1

公开(公告)日：2014-09-04

申请号：US14117238

申请日：2012-06-15

Applicant: Sami Oukassi ,  Samir Guerroudj ,  Michaël Roffat

Inventor： Sami Oukassi ,  Samir Guerroudj ,  Michaël Roffat

IPC: H01M10/0562 ,  H01M10/052

CPC classification number: H01M10/052 ,  H01M6/185 ,  H01M6/187 ,  H01M6/40 ,  H01M10/0562 ,  H01M2300/0071 ,  H01M2300/0094

Abstract: At least one zone made of lithium-containing glass-ceramic material, in a solid electrolyte for a lithium battery, is formed from a lithium-containing ceramic material, advantageously in the form of a layer such as a thin film It is obtained by melting of at least a part of the lithium-containing ceramic material, followed by a recrystallization heat treatment. Melting is obtained by a laser beam irradiation operation, which enables fabrication of the solid electrolyte to be performed directly on a multilayer stack comprising certain active components of the lithium battery.

Abstract translation: 在锂电池用固体电解质中的含锂玻璃陶瓷材料制成的至少一个区域由含锂陶瓷材料形成，有利地为薄膜等形式通过熔融而得到 的至少一部分含锂陶瓷材料，然后进行再结晶热处理。 通过激光束照射操作获得熔融，其能够在包括锂电池的某些有源部件的多层堆叠中直接进行固体电解质的制造。

公开(公告)号：US20110311883A1

公开(公告)日：2011-12-22

申请号：US13203796

申请日：2010-03-04

Applicant: Sami Oukassi ,  Raphael Salot ,  Nicolas Dunoyer ,  Steve Martin

Inventor： Sami Oukassi ,  Raphael Salot ,  Nicolas Dunoyer ,  Steve Martin

IPC: H01M10/052 ,  H01M10/04 ,  H01M4/38 ,  H01M4/64 ,  H01M10/0562

CPC classification number: H01M6/18 ,  H01M6/186 ,  H01M6/187 ,  H01M6/40 ,  H01M10/0436 ,  H01M10/052 ,  H01M10/0562 ,  H01M10/0585 ,  H01M2300/0068

Abstract: The microbattery is formed by a stack of solid thin layers on a substrate which, starting from the substrate, successively comprises a first electrode, a solid electrolyte and a second electrode/current collector assembly. A first surface and a second surface of the electrolyte are respectively in contact with a main surface of the first electrode and a main surface of the second electrode/current collector assembly. The dimensions of the main surface of the first electrode are smaller than the dimensions of the main surface of said assembly, and the dimensions of the first surface of the solid electrolyte are smaller than the dimensions of the second surface of the solid electrolyte. The solid electrolyte is furthermore not in contact with the substrate.

Abstract translation: 微电池由衬底上的一堆固体薄层形成，其从衬底开始依次包括第一电极，固体电解质和第二电极/集电器组件。 电解质的第一表面和第二表面分别与第一电极的主表面和第二电极/集电器组件的主表面接触。 第一电极的主表面的尺寸小于所述组件的主表面的尺寸，并且固体电解质的第一表面的尺寸小于固体电解质的第二表面的尺寸。 此外，固体电解质不与基板接触。

公开(公告)号：US20100330401A1

公开(公告)日：2010-12-30

申请号：US12818708

申请日：2010-06-18

Applicant: Sami Oukassi ,  Frédéric Le Cras ,  Steve Martin ,  Raphaël Salot

Inventor： Sami Oukassi ,  Frédéric Le Cras ,  Steve Martin ,  Raphaël Salot

IPC: H01M10/44

CPC classification number: H01M4/0438 ,  H01M4/0445 ,  H01M4/0461 ,  H01M4/131 ,  H01M4/133 ,  H01M4/134 ,  H01M4/1395 ,  H01M4/38 ,  H01M4/382 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/587 ,  H01M6/40 ,  H01M10/0436 ,  H01M10/052 ,  H01M10/0562 ,  H01M2004/021 ,  H01M2300/0068

Abstract: The lithium-ion microbattery comprises a positive electrode having a first Li+ ion storage capacity and a first thickness made from a first lithium insertion material, an electrolyte and a negative electrode having a second storage capacity and a second thickness made from a second insertion material. The thicknesses are such that the ratio of the first storage capacity over the second storage capacity is greater than or equal to 10 and lower than or equal to 1000. During the first charging of the micro-battery, the Li+ ions are inserted in the negative electrode and completely saturate the second insertion material. When initial charging is continued, they form a metallic lithium layer between the electrolyte and the lithium-saturated negative electrode by electroplating. During the subsequent charging and discharging cycles, only the metallic lithium layer participates in transfer of lithium ions.

Abstract translation: 锂离子微电池包括具有第一Li +离子存储容量的正极和由第一锂插入材料制成的第一厚度，具有第二存储容量的电解质和负极以及由第二插入材料制成的第二厚度。 厚度使得第一存储容量与第二存储容量之比大于或等于10且小于或等于1000.在微电池的第一次充电期间，将Li +离子插入到负极 电极并使第二插入材料完全饱和。 当继续进行初始充电时，它们通过电镀在电解质和锂饱和负极之间形成金属锂层。 在随后的充放电循环中，只有金属锂层参与锂离子的转移。

公开(公告)号：US20100310758A1

公开(公告)日：2010-12-09

申请号：US12796922

申请日：2010-06-09

Applicant: Steve MARTIN ,  Nicolas Dunoyer ,  Sami Oukassi ,  Raphaël Salot

Inventor： Steve MARTIN ,  Nicolas Dunoyer ,  Sami Oukassi ,  Raphaël Salot

IPC: B05D5/12

CPC classification number: H01M6/40 ,  C23C14/042 ,  C23C14/541 ,  C23C16/042 ,  C23C16/52 ,  H01M6/18 ,  H01M6/185

Abstract: The microcomponent, for example a microbattery, comprising a stack with at least two superposed layers on a substrate, is made using a single steel mask able to expand under the effect of temperature. The mask comprises at least one off-centered opening. The mask being at a first temperature, a first layer is deposited through the opening of the mask. The mask being at a second temperature, higher than the first temperature, a second layer is deposited through the opening of the mask. Finally, the mask being at a third temperature, higher than the second temperature, a third layer is deposited through the opening of the mask.

Abstract translation: 微组件，例如微电池，其包括在衬底上具有至少两个叠置层的叠层，其使用能够在温度影响下膨胀的单个钢掩模制成。 面罩包括至少一个偏心开口。 掩模处于第一温度，第一层通过掩模的开口沉积。 掩模处于比第一温度高的第二温度下，通过掩模的开口沉积第二层。 最后，掩模处于高于第二温度的第三温度，通过掩模的开口沉积第三层。

公开(公告)号：US20090155685A1

公开(公告)日：2009-06-18

申请号：US12269486

申请日：2008-11-12

Applicant: Raphael Salot ,  Steve Martin ,  Sami Oukassi

Inventor： Raphael Salot ,  Steve Martin ,  Sami Oukassi

IPC: H01M2/08

CPC classification number: H01M8/028 ,  H01M2/0404 ,  H01M6/40 ,  H01M8/0286 ,  H01M10/0436 ,  H01M10/052 ,  H01M10/0585

Abstract: This lithium electrochemical device includes a stack of layers suitable for constituting a micro-battery deposited on a substrate and encapsulated using a protective cap sealed onto the substrate. It includes two collectors of the current generated by the micro-battery and at least one insulating layer inert as regards lithium. The collectors and the insulating layer or layers are deposited on the substrate. The protective cap is sealed onto the substrate using the layers constituting the current collectors and the insulating layer or layers. The cap has layers of the same nature, positioned in the same order in line with their respective layers deposited on the substrate, so that when the cap is sealed onto the substrate, the respective layers deposited on the cap and on the substrate come into contact with each other to provide the actual seal of the cap on the substrate.

Abstract translation: 该锂电化学装置包括适于构成沉积在基板上的微电池的层叠层，并使用密封在基板上的保护帽进行封装。 它包括由微电池产生的电流的两个集电极和关于锂的至少一个绝缘层是惰性的。 集电体和绝缘层被沉积在基板上。 使用构成集电体的层和绝缘层将保护盖密封在基板上。 盖具有相同性质的层，以与沉积在基底上的各自层相同的顺序定位，使得当盖被密封到基底上时，沉积在盖和基底上的相应层接触 彼此提供盖子在基板上的实际密封。

公开(公告)号：US09373831B2

公开(公告)日：2016-06-21

申请号：US14117500

申请日：2012-05-11

Applicant: Sami Oukassi ,  Raphael Salot

Inventor： Sami Oukassi ,  Raphael Salot

IPC: H01M10/052 ,  H01M2/26 ,  H01M2/20 ,  H01M10/04 ,  H01M10/0585 ,  H01G11/10 ,  H01G11/72 ,  H01G11/76

CPC classification number: H01M2/26 ,  H01G11/10 ,  H01G11/72 ,  H01G11/76 ,  H01M2/204 ,  H01M2/266 ,  H01M10/0436 ,  H01M10/052 ,  H01M10/0585 ,  Y02E60/122 ,  Y02E60/13 ,  Y02P70/54

Abstract: An electrical energy storage and/or generation device with an architecture including a stack of electrical storage and/or generation elements, such as microbatteries. An electrical connection is not made between the different stacked elements during manufacture, but subsequently with assistance of an electronic control unit to configure, in series and/or in parallel, all or a proportion of the elements, and to configure electrical outputs of the device, such as the electrical voltage or the storage capacity.

Abstract translation: 一种具有结构的电能存储和/或生成装置，其包括诸如微电池的电存储和/或发电元件的堆叠。 在制造期间不在不同的堆叠元件之间进行电连接，而是随后在电子控制单元的帮助下，串联和/或并联地配置全部或一部分元件，并且配置该装置的电输出 ，如电压或存储容量。

公开(公告)号：US09356313B2

公开(公告)日：2016-05-31

申请号：US14117238

申请日：2012-06-15

Applicant: Sami Oukassi ,  Samir Guerroudj ,  Michaël Roffat

Inventor： Sami Oukassi ,  Samir Guerroudj ,  Michaël Roffat

IPC: H01M10/0562 ,  H01M10/052 ,  H01M6/18 ,  H01M6/40

CPC classification number: H01M10/052 ,  H01M6/185 ,  H01M6/187 ,  H01M6/40 ,  H01M10/0562 ,  H01M2300/0071 ,  H01M2300/0094

Abstract: At least one zone made of lithium-containing glass-ceramic material, in a solid electrolyte for a lithium battery, is formed from a lithium-containing ceramic material, advantageously in the form of a layer such as a thin film. It is obtained by melting of at least a part of the lithium-containing ceramic material, followed by a recrystallization heat treatment. Melting is obtained by a laser beam irradiation operation, which enables fabrication of the solid electrolyte to be performed directly on a multilayer stack comprising certain active components of the lithium battery.

Abstract translation: 由含锂玻璃陶瓷材料制成的至少一个由锂电池用固体电解质构成的区域由含锂陶瓷材料形成，有利地是薄膜等层的形式。 通过熔化至少一部分含锂陶瓷材料，然后进行再结晶热处理而获得。 通过激光束照射操作获得熔融，其能够在包括锂电池的某些有源部件的多层堆叠中直接进行固体电解质的制造。

公开(公告)号：US08778532B2

公开(公告)日：2014-07-15

申请号：US12269486

申请日：2008-11-12

Applicant: Raphaël Salot ,  Steve Martin ,  Sami Oukassi

Inventor： Raphaël Salot ,  Steve Martin ,  Sami Oukassi

IPC: H01M2/08 ,  H01M2/02 ,  H01M8/02

CPC classification number: H01M8/028 ,  H01M2/0404 ,  H01M6/40 ,  H01M8/0286 ,  H01M10/0436 ,  H01M10/052 ,  H01M10/0585

Abstract: This lithium electrochemical device includes a stack of layers suitable for constituting a micro-battery deposited on a substrate and encapsulated using a protective cap sealed onto the substrate. It includes two collectors of the current generated by the micro-battery and at least one insulating layer inert as regards lithium. The collectors and the insulating layer or layers are deposited on the substrate. The protective cap is sealed onto the substrate using the layers constituting the current collectors and the insulating layer or layers. The cap has layers of the same nature, positioned in the same order in line with their respective layers deposited on the substrate, so that when the cap is sealed onto the substrate, the respective layers deposited on the cap and on the substrate come into contact with each other to provide the actual seal of the cap on the substrate.

Abstract translation: 该锂电化学装置包括适于构成沉积在基板上的微电池的层叠层，并使用密封在基板上的保护帽进行封装。 它包括由微电池产生的电流的两个集电极和关于锂的至少一个绝缘层是惰性的。 集电体和绝缘层被沉积在基板上。 使用构成集电体的层和绝缘层将保护盖密封在基板上。 盖具有相同性质的层，以与沉积在基底上的各自层相同的顺序定位，使得当盖被密封到基底上时，沉积在盖和基底上的相应层接触 彼此提供盖子在基板上的实际密封。