摘要:
A Ce—Zr mixed oxide is employed as an oxygen storage component for a lean-NOx catalyst, and catalytic precious metal atoms are placed at and/or between crystal lattice points of the mixed oxide. This structure prevents the sintering of the precious metal and accelerates movement of oxygen ions in each of crystallites of the Ce—Zr mixed oxide to increase the oxygen storage/release amount of the mixed oxide, which enhances the NOx removal performance of the catalyst.
摘要:
An exhaust gas purification catalyst comprises an oxygen storage component constituted by a mixed oxide containing cerium and zirconium, and a catalytic metal and a NOx storage component are carried on the oxygen storage component. The oxygen storage component is in the form of porous secondary particles in each of which primary particles of an average particle size of less than 10 nm cohere to form fine pores inside each said secondary particle.
摘要:
The present invention is intended to ensure the improvement in catalytic performance of an exhaust gas catalytic converter, which is an essential performance thereof, ensure the thermal resistance thereof and downsize the converter, i.e., improve the arrangeability thereof. The exhaust gas catalytic converter has an upstream catalyst and a downstream catalyst which are arranged in upstream and downstream sides of an engine exhaust passage through which exhaust gas flows. Each of the upstream catalyst and the downstream catalyst contains an oxygen storage component. The oxygen storage component in the upstream catalyst has a structure in which Rh atoms are placed at or between crystal lattice points of a mixed oxide containing Ce and Zr and has a larger amount of oxygen storage than the oxygen storage component in the downstream catalyst under the same temperature conditions.
摘要:
There are provided NOx trap catalyst to trap and release NOx based on air-fuel ratio, first fuel supply means for supplying gasoline, second fuel supply means for supplying hydrogen, engine operation detecting means for detecting engine operating condition, fuel ratio changing means for changing the ratio of gasoline and hydrogen, NOx release determining means for determining whether it is required for the NOx to be released based on a state of the trapped NOx, NOx releasing means for releasing the NOx trapped by making the air-fuel ratio rich when the NOx releasing requirement is determined, gasoline ratio increasing means for increasing the ratio of gasoline when NOx releasing requirement is determined and the air-fuel-ratio rich control is executed. Accordingly, improper vibrations or noises can be restrained from occurring when the rich air-fuel-ratio control is executed to release the trapped NOx from the NOx trap catalyst.
摘要:
A Ce—Zr mixed oxide is employed as an oxygen storage component for a lean-NOx catalyst, and catalytic precious metal atoms are placed at and/or between crystal lattice points of the mixed oxide. This structure prevents the sintering of the precious metal and accelerates movement of oxygen ions in each of crystallites of the Ce—Zr mixed oxide to increase the oxygen storage/release amount of the mixed oxide, which enhances the NOx removal performance of the catalyst.
摘要:
The present invention relates to an exhaust gas purification catalytic material containing: (a) a mixed oxide containing Ce and Zr for storing and releasing oxygen; and (b) a precious metal catalyst made of one or more kinds of precious metals. The precious metal catalyst comprises a first precious metal catalyst component placed between atoms, at crystal lattice points and/or at oxygen defect sites of the mixed oxide and a second precious metal catalyst component loaded on the surface of the mixed oxide, thereby improving the thermal resistance, oxygen storage capacity and exhaust gas conversion performance of the catalytic material.
摘要:
An exhaust gas purifying device of the present invention comprises NOx trap catalyst including NOx trap material, catalytic metal and O2 storage material, NOx sensor, section for releasing NOx when NOx absorbed amount of the NOx trap catalyst reaches a specified amount, section for determining diagnosis conditions of the NOx trap catalyst, section for detecting termination of O2 release from the O2 storage material, and section for diagnosing O2 storage capacity according to output value (NO1) of the NOx sensor during a term from beginning of the oxygen concentration lowering by the NOx release section until termination of the O2 release and for diagnosing NOx reduction capacity of the catalytic metal according to output value (NO2) of the NOx sensor after termination of O2 release, wherein a speed of lowering oxygen concentration during the diagnosis is set so as to be slower than that during non-diagnosis.
摘要翻译:本发明的排气净化装置包括NOx捕集催化剂,其包括NOx捕集材料,催化金属和O 2储存材料,NOx传感器,当NOx捕集催化剂的NOx吸收量达到规定量时释放NOx的部分,用于确定诊断的部分 NO x捕集催化剂的条件,用于检测从O 2储存材料中释放的O2的终止的部分,以及根据由氧浓度降低开始的期间的NOx传感器的输出值(NO1)来诊断O 2存储容量的部分 NOx释放部分,直到O2释放结束,并且根据在O 2释放结束之后的NOx传感器的输出值(NO2)来诊断催化金属的NOx还原能力,其中将诊断期间将氧浓度降低的速度设定为 比非诊断时要慢。
摘要:
Disclosed is an exhaust gas purifying catalyst, which comprises an oxygen absorbing material having a catalytic noble metal arranged at a lattice position or an interlattice position of a crystal structure of a composite oxide containing Ce and Zr, which is capable of sufficiently exhibiting a catalytic function even if a ZrO2 mass ratio is out of the range of 20 to 30 mass % or 65 to 90 mass %. Specifically, in an exhaust gas purifying catalyst formed with a catalyst layer including a cerium-zirconium (CeZr) composite oxide, the composite oxide contains ceria (CeO2) and zirconia (ZrO2) in such a manner that a mass ratio of ceria to a total mass of ceria and zirconia falls within the range of 36 to 64 mass %. Further, the composite oxide contains, in the form of an oxide, a rare-earth metal other than cerium (Ce), in the range of 3 to 20 mass % with respect to a total mass of the composite oxide.
摘要:
There are provided NOx trap catalyst to trap and release NOx based on air-fuel ratio, first fuel supply means for supplying gasoline, second fuel supply means for supplying hydrogen, engine operation detecting means for detecting engine operating condition, fuel ratio changing means for changing the ratio of gasoline and hydrogen, NOx release determining means for determining whether it is required for the NOx to be released based on a state of the trapped NOx, NOx releasing means for releasing the NOx trapped by making the air-fuel ratio rich when the NOx releasing requirement is determined, gasoline ratio increasing means for increasing the ratio of gasoline when NOx releasing requirement is determined and the air-fuel-ratio rich control is executed. Accordingly, improper vibrations or noises can be restrained from occurring when the rich air-fuel-ratio control is executed to release the trapped NOx from the NOx trap catalyst.
摘要:
An upstream catalyst and a downstream catalyst are disposed in an exhaust passage of an engine. The downstream catalyst contains in the same catalyst layer thereof. Rh-doped CeZrNd mixed oxide particles on which Rh is supported and active alumina particles on which Pt is supported. The upstream catalyst is a three-way catalyst containing an oxygen storage component having a lower oxygen storage capacity than the Rh-doped CeZrNd mixed oxide.