公开(公告)号：US06271317B1

公开(公告)日：2001-08-07

申请号：US09441179

申请日：1999-11-15

申请人： Adel Farhan Halasa ,  Shingo Futamura ,  Wen-Liang Hsu ,  Barry Allen Matrana

发明人： Adel Farhan Halasa ,  Shingo Futamura ,  Wen-Liang Hsu ,  Barry Allen Matrana

IPC分类号： C08F830

CPC分类号： C08C19/44 ,  C08F236/04 ,  C08F297/023 ,  C08F297/044 ,  C08F297/046 ,  C08F4/48

摘要： Tire rubbers which are prepared by anionic polymerization are frequently coupled with a suitable coupling agent, such as a tin halide, to improve desired properties. It has been unexpectedly found that greatly improved properties for tire rubbers, such as lower hysteresis, can be attained by asymmetrically coupling the rubber. This invention more specifically discloses an asymmetrical tin-coupled rubbery polymer which is particularly valuable for use in manufacturing tire tread compounds, said asymmetrical tin-coupled rubbery polymer being comprised of a tin atom having at least three polydiene arms covalently bonded thereto, wherein at least one of said polydiene arms has a number average molecular weight of less than about 40,000, wherein at least one of said polydiene arms has a number average molecular weight of at least about 80,000, and wherein the ratio of the weight average molecular weight to the number average molecular weight of the asymmetrical tin-coupled rubbery polymer is within the range of about 2 to about 2.5.

摘要翻译： 通过阴离子聚合制备的轮胎橡胶通常与合适的偶合剂如卤化锡偶联，以改善所需的性能。 已经意外地发现，通过不对称地连接橡胶，可以获得轮胎橡胶的较大改善的性能，例如较低的滞后。 本发明更具体地公开了一种非对称锡 - 偶联橡胶状聚合物，其特别有价值用于制造轮胎胎面胶料，所述不对称锡 - 偶联橡胶状聚合物由具有共价键合至少三个聚二烯臂的锡原子组成，其中至少 所述聚二烯臂之一具有小于约40,000的数均分子量，其中所述聚二烯臂中的至少一个具有至少约80,000的数均分子量，并且其中重均分子量与数 不对称锡 - 偶联橡胶状聚合物的平均分子量在约2至约2.5的范围内。

公开(公告)号：US5616655A

公开(公告)日：1997-04-01

申请号：US526183

申请日：1995-09-11

申请人： Richard M. D'Sidocky ,  David J. Zanzig ,  Shingo Futamura

发明人： Richard M. D'Sidocky ,  David J. Zanzig ,  Shingo Futamura

IPC分类号： B60C1/00 ,  C08C19/20 ,  C08F8/00 ,  C08K3/00 ,  C08K3/30 ,  C08K3/36 ,  C08K5/00 ,  C08K5/548 ,  C08K5/57 ,  C08L9/00 ,  C08L9/06 ,  C08C19/25

CPC分类号： C08K3/30 ,  C08K5/548

摘要： A method is disclosed for processing a rubber composition comprising thermomechanically mixing at a rubber temperature in a range of 140.degree. C. to 190.degree. C. for a mixing time of 1 to 20 minutes(i) 100 parts by weight of at least one sulfur vulcanizable elastomer selected from conjugated diene homopolymers and copolymers, natural rubber and copolymers of at least one conjugated diene and aromatic vinyl compound;(ii) 10 to 250 phr of particulate precipitated silica;(iii) 0.01 to 1.0 parts by weight per weight of said silica of an organosilicon compound; and(iv) 0.05 to 10 phr of sodium thiosulfate pentahydrate.Addition of the sodium thiosulfate pentahydrate to sulfur vulcanizable rubber, silica and sulfur containing organosilicon compound decreases the mixing/processing time without sacrificing end product properties.

摘要翻译： 公开了一种用于加工橡胶组合物的方法，该橡胶组合物在140℃至190℃的橡胶温度下热机械混合，混合时间为1至20分钟（i）100重量份的至少一种硫 选自共轭二烯均聚物和共聚物的可硫化弹性体，天然橡胶和至少一种共轭二烯和芳族乙烯基化合物的共聚物; （ii）10至250phr微粒沉淀二氧化硅; （iii）0.01至1.0重量份的所述有机硅化合物二氧化硅; 和（iv）0.05至10phr硫代硫酸钠五水合物。 将硫代硫酸钠五水合物加入可硫化橡胶，二氧化硅和含硫有机硅化合物中，减少混合/处理时间，而不会牺牲最终产品性能。

公开(公告)号：US4107256A

公开(公告)日：1978-08-15

申请号：US788214

申请日：1977-04-18

申请人： Wendell R. Conrad ,  Shingo Futamura ,  Robert A. Hayes

发明人： Wendell R. Conrad ,  Shingo Futamura ,  Robert A. Hayes

IPC分类号： C08G18/00 ,  B29C41/00 ,  B29C41/04 ,  C08G18/08 ,  C08G18/72 ,  B29C5/04 ,  C08G18/82 ,  C08G18/83 ,  C08G18/86

CPC分类号： C08G18/0871 ,  B29C41/003 ,  B29C41/04 ,  B29K2075/00 ,  B29K2105/251

摘要： Polyurethanes having a fine particle size are prepared according to a suspension process wherein silicone surfactants are utilized and the polymerization is carried out under agitation in a nonaqueous and a nonsolvent system according to either a two step, or preferably a one step process. The produced suspension-type polyurethanes are generally powders or very small granules and, therefore, can be utilized directly for rotational or spin molding processes wherein they are cured through the use of specific curing agents. Additionally, generally any suspension polyurethanes having a plasticity value of at least 2,000 square mm. at 150.degree. C, can be cured in a rotational or spin molding operation utilizing specific curing agents and curing at a temperature below the decomposition temperature of the polyurethane, for example, below 250.degree. C.

摘要翻译： 根据悬浮法制备具有细粒度的聚氨酯，其中使用硅氧烷表面活性剂，并且根据两步或优选一步法在非水和非溶剂体系中搅拌下进行聚合。 生产的悬浮型聚氨酯通常是粉末或非常小的颗粒，因此可以直接用于旋转或旋转模塑方法，其中它们通过使用特定的固化剂固化。 另外，通常具有塑性值为至少2000平方毫米的任何悬浮聚氨酯。 在150℃下，可以使用特定的固化剂在旋转或旋转成型操作中固化，并在低于聚氨酯的分解温度的温度下固化，例如低于250℃。

公开(公告)号：US4071492A

公开(公告)日：1978-01-31

申请号：US674459

申请日：1976-04-07

申请人： Tristram Walker Bethea ,  Shingo Futamura

发明人： Tristram Walker Bethea ,  Shingo Futamura

IPC分类号： C08G18/00 ,  C08G18/10 ,  C08G18/32 ,  C08G18/48 ,  C08G18/65 ,  C08K5/12

CPC分类号： C08G18/4854 ,  C08G18/10

摘要： A polyurethane-urea elastomer is prepared by reacting a copolymer of propylene oxide and tetrahydrofuran having hydroxyl end groups with an organic polyisocyanate and the isocyanate-terminated polymer is then reacted with an aromatic diamine in either bulk or solution process.

摘要翻译： 通过使具有羟基端基的环氧丙烷和四氢呋喃的共聚物与有机多异氰酸酯反应制备聚氨酯 - 脲弹性体，然后将异氰酸酯封端的聚合物与本体或溶液方法中的芳族二胺反应。

公开(公告)号：US3937760A

公开(公告)日：1976-02-10

申请号：US464871

申请日：1974-04-29

申请人： William Max Cole ,  Shingo Futamura

发明人： William Max Cole ,  Shingo Futamura

IPC分类号： C08F297/04 ,  C08L9/02 ,  C08L9/06

CPC分类号： C08F297/04

摘要： The process disclosed herein involves the continuous preparation of a multiblock copolymer of two monomers or more such as butadiene and styrene, butadiene and isoprene, etc. This process comprises the alternate feeding of first one monomer stream and then another monomer stream differing in monomer composition from the first monomer stream, each stream of monomer being interrupted while the other stream of monomer is being fed continually into the polymerization system containing an anionic polymerization catalyst capable of polymerizing each of said monomers. A product stream is withdrawn from the polymerization system at the same rate as the total of the feed streams, thereby effecting a continual flow through the polymerization system. The rate of catalyst feed is controlled to give the desired molecular weight to the multiblock copolymer; the size of each block in the copolymer is controlled by the time of flow of the respective monomer and the concentration of monomer in the monomer feed; and the number of blocks is controlled by the number of alternating feed steps that are performed during the residence time in the polymerization system.

公开(公告)号：US07683115B2

公开(公告)日：2010-03-23

申请号：US12029038

申请日：2008-02-11

申请人： Wen-Liang Hsu ,  Leh-Yeh Hsu, legal representative ,  Kuo-Chih Hua ,  Shingo Futamura

发明人： Wen-Liang Hsu ,  Kuo-Chih Hua ,  Shingo Futamura

IPC分类号： B60C1/00 ,  C08K5/04

CPC分类号： C08K5/548 ,  B29B7/7495 ,  C08K3/22 ,  C08K3/36 ,  C08K9/06 ,  C08L9/06

摘要： This invention relates to the preparation of silica-containing rubber compositions which contain precipitated silica reinforcement and use of an oligomeric organomercaptosilane coupling agent containing a plurality of mercapto and silane moieties, and a minimal content, if any, of ethoxy groups and is thus substantially free of ethoxy groups. The interaction of the plurality of mercapto moieties, or groups, of such oligomeric organomercaptosilane with the diene-based elastomer can promote a significant viscosity build up of the uncured rubber composition in a preliminary non-productive mixing stage and therefore present significant rubber processing difficulties during the mixing of the rubber composition. A challenge is therefore presented for reducing such viscosity buildup for such uncured silica-containing rubber composition.

摘要翻译： 本发明涉及含有沉淀二氧化硅增强物和使用含有多个巯基和硅烷部分的低聚有机巯基硅烷偶联剂的含二氧化硅的橡胶组合物的制备，并且含有最小含量（如果有的话）为乙氧基，因此基本上不含 的乙氧基。 这种低聚有机体巯基的多个巯基或基团与二烯基弹性体的相互作用可以在预备的非生产性混合阶段中促进未固化的橡胶组合物的显着的粘度增加，因此在 橡胶组合物的混合。 因此提出了一种降低这种未固化的含二氧化硅的橡胶组合物的这种粘度累积的挑战。

公开(公告)号：US20090156769A1

公开(公告)日：2009-06-18

申请号：US11955453

申请日：2007-12-13

申请人： Adel Farhan Halasa ,  Wen-Liang Hsu ,  Leh-Yeh Hsu ,  Shingo Futamura ,  Joe Zhou ,  Chad Aaron Jasiunas

发明人： Adel Farhan Halasa ,  Wen-Liang Hsu ,  Leh-Yeh Hsu ,  Shingo Futamura ,  Joe Zhou ,  Chad Aaron Jasiunas

IPC分类号： C08F4/28 ,  C07C381/00 ,  C07F9/28 ,  C07F7/08 ,  C08F230/02 ,  C08F26/00 ,  C08F26/06

CPC分类号： C08F236/14 ,  C07C323/25 ,  C07F7/1804 ,  C07F9/5004 ,  C07F9/5031 ,  C08L19/006

摘要： Rubbery polymers can be formed having the general formula: R1R2N—(CH2)n—X—CH2—CHR3R4 wherein R1 and R2 are independently selected from a group consisting of alkyls, cycloalkyls, alkenyls, cycloalkenyls, aryls, phenyls, heterocycles, acyls, and silanes, or R1 in combination with R2 forms a heterocyclic ring; n is an integer from 1 to 20; X is selected from a group consisting of sulfur, a phosphorus moiety, and a silicon moiety; R3 and R4 are one of hydrogen, alkyls, alkenyls, and at least one of which includes reactive unsaturation such as an alkenyl group. Moreover, this invention discloses a process of making functionalized rubbery polymers from the functionalized monomers.

摘要翻译： 可以形成具有以下通式的橡胶状聚合物：<？in-line-formula description =“In-line formula”end =“lead”？> R1R2N-（CH2）nX-CH2-CHR3R4 <？in-line-formula description 其中R 1和R 2独立地选自烷基，环烷基，烯基，环烯基，芳基，苯基，杂环，酰基和硅烷，或R 1与 R2形成杂环; n为1〜20的整数， X选自硫，磷部分和硅部分; R3和R4是氢，烷基，烯基之一，并且其中至少一个包括反应性不饱和键如烯基。 此外，本发明公开了一种由官能化单体制备官能化橡胶聚合物的方法。

公开(公告)号：US20080194748A1

公开(公告)日：2008-08-14

申请号：US12029038

申请日：2008-02-11

申请人： Shingo Futamura

发明人： Shingo Futamura

IPC分类号： C08K3/18

CPC分类号： C08K5/548 ,  B29B7/7495 ,  C08K3/22 ,  C08K3/36 ,  C08K9/06 ,  C08L9/06

摘要： This invention relates to the preparation of silica-containing rubber compositions which contain precipitated silica reinforcement and use of an oligomeric organomercaptosilane coupling agent containing a plurality of mercapto and silane moieties, and a minimal content, if any, of ethoxy groups and is thus substantially free of ethoxy groups. The interaction of the plurality of mercapto moieties, or groups, of such oligomeric organomercaptosilane with the diene-based elastomer can promote a significant viscosity build up of the uncured rubber composition in a preliminary non-productive mixing stage and therefore present significant rubber processing difficulties during the mixing of the rubber composition. A challenge is therefore presented for reducing such viscosity buildup for such uncured silica-containing rubber composition.

摘要翻译： 本发明涉及含有沉淀二氧化硅增强物和使用含有多个巯基和硅烷部分的低聚有机巯基硅烷偶联剂的含二氧化硅的橡胶组合物的制备，并且含有最小含量（如果有的话）为乙氧基，因此基本上不含 的乙氧基。 这种低聚有机体巯基的多个巯基或基团与二烯基弹性体的相互作用可以在预备的非生产性混合阶段中促进未固化的橡胶组合物的显着的粘度增加，因此在 橡胶组合物的混合。 因此提出了一种降低这种未固化的含二氧化硅的橡胶组合物的这种粘度累积的挑战。

公开(公告)号：US20080066838A1

公开(公告)日：2008-03-20

申请号：US11517631

申请日：2006-09-08

申请人： Ping Zhang ,  Paul Harry Sandstrom ,  Joseph John Kulig ,  Shingo Futamura ,  Kenneth Allen Bates ,  Wen-Liang Hsu ,  Kuo-Chih Hua

发明人： Ping Zhang ,  Paul Harry Sandstrom ,  Joseph John Kulig ,  Shingo Futamura ,  Kenneth Allen Bates ,  Wen-Liang Hsu ,  Kuo-Chih Hua

IPC分类号： B60C11/00

CPC分类号： B60C1/0016 ,  C08K3/013 ,  C08K7/02 ,  C08L21/00 ,  C08L29/04 ,  C08L33/02 ,  C08L33/26 ,  C08L2666/04

摘要： This invention relates to a rubber composition which contains a dispersion of a particulate hydrophilic water absorbing polymer and tire with a tread thereof.

摘要翻译： 本发明涉及一种橡胶组合物，其含有颗粒状亲水性吸水聚合物和轮胎与其胎面的分散体。

公开(公告)号：US20070175557A1

公开(公告)日：2007-08-02

申请号：US11651133

申请日：2007-01-09

申请人： Aaron Scott Puhala ,  Rachel Rebekah Barnette ,  David Charles Poling ,  Eric John Marazzi ,  Kuo-Chih Hua ,  Shingo Futamura

发明人： Aaron Scott Puhala ,  Rachel Rebekah Barnette ,  David Charles Poling ,  Eric John Marazzi ,  Kuo-Chih Hua ,  Shingo Futamura

IPC分类号： B60C11/00

CPC分类号： B60C1/0016 ,  B60C11/005 ,  B60C11/0058 ,  B60C11/0066 ,  B60C11/14 ,  B60C2011/0025 ,  C08L9/00 ,  C08L9/06 ,  C08L19/006 ,  C08L2666/02

摘要： The invention relates to a tire having a circumferential tread of a cap/base configuration composed of an outer tread rubber cap layer with a running surface of the tread and an underlying tread rubber base layer, wherein said tread cap layer is composed of two longitudinal adjacent zones, namely a primary tread cap zone and a minor lateral outboard control element (zone). The primary tread cap zone and the lateral outboard tread cap element provide a significant gradation of cold dynamic storage moduli (G′) at −25° C. and hot tan delta values at 100° C., yet similar warm dynamic storage moduli (G′) at 60° C. The primary tread cap zone and lateral outboard control tread cap element are load bearing in the sense of extending from the running surface of the tread radially inward to the unitary (non-zoned) tread base rubber layer. The zoned rubber tread cap layer and unitary rubber tread base layer are an integral tread composite in a sense of being co-extruded. In one aspect of the invention, the primary tread cap zone rubber composition is silica-rich and the lateral, outboard element rubber composition is carbon black-rich and which furthermore provide a gradation of filler reinforcement content; provide a gradation of silica to carbon black ratio and provide a gradation of cis 1,4-polybutadiene rubber content.

摘要翻译： 本发明涉及一种轮胎，其具有由具有胎面的行进表面的外胎面橡胶帽层和下面的胎面橡胶基层组成的帽/底座构造的圆周胎面，其中所述胎冠盖层由两个纵向相邻 区域，即主胎面区域和小侧向外侧控制元件（区域）。 主要胎冠区域和侧向外侧胎面花纹块元件在-25℃下提供了显着的冷动态储存模量（G'）和100℃下的热tanδ值，而类似的热动态储存模量（G '）在60℃。主胎面区域和侧向外侧控制踏板元件是从胎面的行进表面径向向内延伸到整体（非分区）胎面基底橡胶层的意义上的承载轴承。 划分的橡胶胎冠层和整体橡胶胎面基层是共挤出的整体胎面复合材料。 在本发明的一个方面，一次胎面胎面橡胶组合物是二氧化硅富集的，并且外侧的外侧元件橡胶组合物是富含炭黑的，并且还提供填料增强含量的等级。 提供二氧化硅与炭黑的比例，并提供顺式1,4-聚丁二烯橡胶含量的等级。