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公开(公告)号：US06844460B2
公开(公告)日：2005-01-18
申请号：US10336437
申请日：2003-01-03
申请人： Binh Thanh Nguyen
发明人： Binh Thanh Nguyen
CPC分类号： C07F7/1892
摘要： Mercaptoalkylalkyldialkoxysilane compositions are prepared by reacting an alkoxysilane containing an unsaturated organic group, with a sulfur containing organic acid, in the presence of a peroxide catalyst. This step produces a thiol ester. In the next step, methanolysis of the thiol ester is carried out in the presence of a basic catalyst. The resulting product is a mercaptoalkylalkyldialkoxysilane composition such as mercaptoethylmethyldimethoxysilane, mercaptomethylmethyldiethoxysilane, mercaptopropylmethyldiethoxysilane, or mercaptopropylmethyldimethoxysilane. Carrying out the first step of the reaction at least in part in the presence of air obtains maximum efficiency.
摘要翻译： 巯基烷基烷基二烷氧基硅烷组合物通过使含有不饱和有机基团的烷氧基硅烷与含硫有机酸在过氧化物催化剂存在下反应来制备。 该步骤产生硫醇酯。 在下一步骤中，硫醇酯的甲醇分解在碱性催化剂的存在下进行。 所得产物为巯基乙基甲基二甲氧基硅烷，巯基乙基甲基二乙氧基硅烷，巯基丙基甲基二乙氧基硅烷或巯基丙基甲基二甲氧基硅烷等巯基烷基二烷氧基硅烷组合物。 至少部分在空气存在下进行反应的第一步可以获得最大的效率。
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公开(公告)号：US5872274A
公开(公告)日：1999-02-16
申请号：US96324
申请日：1998-06-11
CPC分类号： C07F7/122
摘要： A method for the preparation of tertiary-hydrocarbylsilyl compounds. The method comprises contacting a mixture comprising diethylene glycol dibutyl ether, and a Grignard reagent described by formula RMgX with a silicon compound described by formula R.sup.1.sub.a SiX.sub.4-a, where R is a tertiary-hydrocarbyl group comprising four to about 20 carbon atoms, each R.sup.1 is an independently selected substituted or unsubstituted monovalent hydrocarbon group comprising one to about 20 carbon atoms, each X is an independently selected halogen atom, and a is an integer with a value of zero to three, in the presence of an effective amount of a copper compound catalyst. The present invention provides a method for making sterically hindered organosilicon intermediates useful in the pharmaceutical industry.
摘要翻译： 一种制备叔烃基甲硅烷基化合物的方法。 该方法包括使包含二甘醇二丁基醚的混合物和式RMgX所述的格利雅试剂与式R1aSiX4-a所述的硅化合物接触，其中R是包含4至约20个碳原子的叔烃基，每个R 1是 独立选择的取代或未取代的包含1至约20个碳原子的单价烃基，每个X是独立选择的卤素原子，a是在有效量的铜化合物存在下，a是0至3的整数 催化剂。 本发明提供一种制备用于制药工业的空间位阻有机硅中间体的方法。
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13.发明授权Polysilane—polysilazane copolymers and methods for their preparation and use 失效聚硅烷 - 聚硅氮烷共聚物及其制备和使用方法公开(公告)号：US08658284B2
公开(公告)日：2014-02-25
申请号：US13504579
申请日：2010-10-25
申请人： Wei Chen , Eric Scott Moyer , Binh Thanh Nguyen , Sheng Wang , Mark A. Wanous , Xiaobing Zhou
发明人： Wei Chen , Eric Scott Moyer , Binh Thanh Nguyen , Sheng Wang , Mark A. Wanous , Xiaobing Zhou
CPC分类号： C08G77/62 , C09D183/16 , Y10T428/31663
摘要： A polysilane-polysilazane copolymer contains a polysilane unit of formula (I), and a polysilazane unit of formula (II), where each R1 and each R2 are each independently selected from H, Si, and N atoms, R3 is selected from H, Si, or C atoms, a≧1, b≧1, and a quantity (a+b)≧2. The polysilane-polysilazane copolymer may be formulated in a composition with a solvent. The polysilane-polysilazane copolymer may be used in PMD and STI applications for trench filling, where the trenches have widths of 100 nm or less and aspect ratios of at least (6). The polysilane-polysilazane copolymer can be prepared by amination of a perchloro polysilane having (2) or more silicon atoms per molecule with a primary amine.
摘要翻译： 聚硅烷 - 聚硅氮烷共聚物含有式（I）的聚硅烷单元和式（II）的聚硅氮烷单元，其中每个R 1和R 2各自独立地选自H，Si和N原子，R 3选自H， Si或C原子，a> = 1，b> = 1，数量（a + b）> = 2。 聚硅烷 - 聚硅氮烷共聚物可以配制成具有溶剂的组合物。 聚硅烷 - 聚硅氮烷共聚物可用于PMD和STI应用于沟槽填充，其中沟槽具有100nm或更小的宽度和至少（6）的纵横比。 聚硅烷 - 聚硅氮烷共聚物可以通过每分子具有（2）个或更多个硅原子的氨氯化聚酰胺与伯胺胺化制备。
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14.发明申请Polysilane - Polysilazane Copolymers And Methods For Their Preparation And Use 失效聚硅烷 - 聚硅氮烷共聚物及其制备和使用方法公开(公告)号：US20120214006A1
公开(公告)日：2012-08-23
申请号：US13504579
申请日：2010-10-25
申请人： Wei Chen , Eric Scott Moyer , Binh Thanh Nguyen , Sheng Wang , Mark A. Wanous , Xiaobing Zhou
发明人： Wei Chen , Eric Scott Moyer , Binh Thanh Nguyen , Sheng Wang , Mark A. Wanous , Xiaobing Zhou
IPC分类号： C08G77/62 , B05D5/12 , B32B9/00 , C09D183/16
CPC分类号： C08G77/62 , C09D183/16 , Y10T428/31663
摘要： A polysilane−polysilazane copolymer contains a polysilane unit of formula (I), and a polysilazane unit of formula (II), where each R1 and each R2 are each independently selected from H, Si, and N atoms, R3 is selected from H, Si, or C atoms, a≧1, b≧1, and a quantity (a+b)≧2. The polysilane−polysilazane copolymer may be formulated in a composition with a solvent. The polysilane-polysilazane copolymer may be used in PMD and STI applications for trench filling, where the trenches have widths of 100 nm or less and aspect ratios of at least (6). The polysilane−polysilazane copolymer can be prepared by amination of a perchloro polysilane having (2) or more silicon atoms per molecule with a primary amine.
摘要翻译： 聚硅烷 - 聚硅氮烷共聚物含有式（I）的聚硅烷单元和式（II）的聚硅氮烷单元，其中每个R 1和R 2各自独立地选自H，Si和N原子，R 3选自H， Si或C原子，a≥1，b≥1，数量（a + b）≥2。 聚硅烷 - 聚硅氮烷共聚物可以配制成具有溶剂的组合物。 聚硅烷 - 聚硅氮烷共聚物可用于PMD和STI应用于沟槽填充，其中沟槽具有100nm或更小的宽度和至少（6）的纵横比。 聚硅烷 - 聚硅氮烷共聚物可以通过每分子具有（2）个或更多个硅原子的氨氯化聚酰胺与伯胺胺化制备。
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公开(公告)号：US06713644B1
公开(公告)日：2004-03-30
申请号：US10264881
申请日：2002-10-03
申请人： Binh Thanh Nguyen
发明人： Binh Thanh Nguyen
IPC分类号： C07F708
CPC分类号： C07F7/0829
摘要： Chloropropylsilanes are prepared via hydrosilation of olefinic halides with organosilicon hydrides, in the presence of neat platinum free copper containing catalysts. Organosilicon hydrides such as triethylsilane, olefinic halides such as allyl chloride, and catalysts such as copper acetate, copper chloride, copper sulphate, copper hydroxide, copper nitrate, and copper cyanide, can be used in the process.
摘要翻译： 氯化丙基硅烷通过烯化卤化物与有机硅氢化合物在存在纯铂游离铜的催化剂存在下制备。 可以使用有机硅氢化物如三乙基硅烷，烯丙基卤化物如烯丙基氯，以及催化剂如乙酸铜，氯化铜，硫酸铜，氢氧化铜，硝酸铜和氰化铜。
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16.发明授权
公开(公告)号：US5914421A
公开(公告)日：1999-06-22
申请号：US108625
申请日：1998-07-01
CPC分类号： C07F7/20
摘要： A method of preparing an alkoxysilane having reduced halide content. The method comprises contacting a mixture comprising an alkoxysilane and residual halide with a mixture comprising about 1.5 to 15 moles of an alkyl alcohol per mole of residual halide, the alkyl alcohol comprising 1 to about 4 carbon atoms and about 0.1 to 5 moles of an orthoformate per mole of residual halide, to form a mixture comprising additional alkoxysilane and lower boiling species, and separating the lower boiling species and the alkoxysilane. Remaining residual halide may be contacted alkali metal to further reduce the halide content. Alkoxysilanes are useful as catalyst modifiers to manufacture polypropylene.
摘要翻译： 制备卤化物含量降低的烷氧基硅烷的方法。 该方法包括将包含烷氧基硅烷和残余卤化物的混合物与每摩尔残余卤化物包含约1.5至15摩尔烷基醇的混合物，包含1至约4个碳原子的烷基醇和约0.1至5摩尔的原甲酸酯 形成含有另外的烷氧基硅烷和低沸点物质的混合物，并分离低沸点物质和烷氧基硅烷。 剩余的残余卤化物可以与碱金属接触以进一步降低卤化物含量。 烷氧基硅烷可用作制备聚丙烯的催化剂改性剂。
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公开(公告)号：US5880304A
公开(公告)日：1999-03-09
申请号：US813025
申请日：1997-03-06
CPC分类号： C07F7/184 , C07F7/083 , C07F7/12 , C07F7/127 , C07F7/1892
摘要： Organosilicon aldehydes and ketones are prepared by a method in which an organosilicon compound containing ozonide functionality is first formed by exposing an organosilicon compound containing unsaturation to ozone. The organosilicon compound containing ozonide functionality is then reduced to the corresponding organosilicon aldehyde or ketone with a reducing agent. One preferred reducing agent is a combination of zinc and acetic acid. Complete conversion of the ozonide to the carbonyl (.dbd.C.dbd.O) compound is obtained when the ozonide containing the reducing agent is heated briefly to about 30.degree. C.
摘要翻译： 有机硅醛和酮通过一种方法制备，其中首先通过将含有不饱和键的有机硅化合物暴露于臭氧而形成含有臭氧化物官能度的有机硅化合物。 然后将含有臭氧化物官能团的有机硅化合物用还原剂还原成相应的有机硅醛或酮。 一种优选的还原剂是锌和乙酸的组合。 当将含有还原剂的臭氧化物短暂加热至约30℃时，可以将臭氧化物完全转化为羰基（= C = O）化合物。
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公开(公告)号：US5756796A
公开(公告)日：1998-05-26
申请号：US861311
申请日：1997-05-19
CPC分类号： C07F7/0827
摘要： A method for preparation of alkenylsilanes comprising contacting magnesium metal with a mixture comprising diethylene glycol dibutyl ether, an alkenyl halide, and a halosilane at a temperature within a range of about 5.degree. C. to 200.degree. C. The method provides a high yield of alkenylsilane product that is easily recoverable and also provides for high ratios of alkenylsilane to diethylene glycol dibutyl ether.
摘要翻译： 一种制备烯基硅烷的方法，包括使镁金属与包含二甘醇二丁基醚，链烯基卤化物和卤代硅烷的混合物在约5℃至200℃的温度范围内接触。该方法提供了高产率 烯基硅烷产物易于回收，并且还提供了高比例的烯基硅烷与二甘醇二丁醚。
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19.发明申请Method of Making Phenyl-Containing Chlorosilanes with Aliphatic or Cycloparaffinic Hydrocarbon Solvents 审中-公开制备含有苯基的氯硅烷与脂族或环烷烃溶剂的方法公开(公告)号：US20080139834A1
公开(公告)日：2008-06-12
申请号：US11883151
申请日：2006-01-25
IPC分类号： C07F7/16
CPC分类号： C07F7/122
摘要： Phenylmethyldichlorosilanes and diphenylmethylchlorosilanes are prepared by a Grignard process involving the step of contacting a phenyl Grignard reagent, an ether solvent, a trichlorosilane, and an aliphatic or cycloparaffinic hydrocarbon coupling solvent; in a mole ratio of the ether solvent to the phenyl Grignard reagent is 2 to 5, the mole ratio of the trichlorosilane to the phenyl Grignard reagent is 0.1 to 10, and the mole ratio of the aliphatic or cycloparaffinic hydrocarbon coupling solvent to the phenyl Grignard reagent is 3 to 7. Preferred reactants include phenylmagnesium chloride as the phenyl Grignard reagent; diethyl ether as solvent; n-heptane as the aliphatic hydrocarbon coupling solvent, or cyclohexane as the cycloparaffinic hydrocarbon coupling solvent; and methyltrichlorosilane.
摘要翻译： 苯甲基二氯硅烷和二苯基甲基氯硅烷通过格氏方法制备，该方法包括使格利雅试剂，醚溶剂，三氯硅烷和脂族或环烷烃偶联溶剂接触的步骤; 醚溶剂与苯基格氏试剂的摩尔比为2至5，三氯硅烷与苯基格氏试剂的摩尔比为0.1至10，脂族或环烷烃耦合溶剂与苯基格利雅的摩尔比 试剂为3至7.优选的反应物包括苯基氯化镁作为苯基格氏试剂; 乙醚为溶剂; 正庚烷作为脂族烃偶联溶剂，或环己烷作为环烷烃耦合溶剂; 和甲基三氯硅烷。
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公开(公告)号：US07351847B2
公开(公告)日：2008-04-01
申请号：US10585155
申请日：2004-12-17
申请人： Binh Thanh Nguyen
发明人： Binh Thanh Nguyen
摘要： Three improved Grignard processes are used for preparing phenyl-containing chlorosilane products wherein the yield of diphenylchlorosilanes as a product is maximized, while the yield of phenylchlorosilanes as a product is minimized. In one embodiment, the process involves contacting a phenyl Grignard reagent, an ether solvent, an aromatic halogenated coupling solvent and a trichlorosilane. In another embodiment, the process involves contacting a phenyl Grignard reagent, an ether solvent, an aromatic halogenated coupling solvent, a trichlorosilane, and a phenylchlorosilane. In yet another embodiment, the process involves contacting a phenyl Grignard reagent, an ether solvent, an aromatic halogenated coupling solvent, and a phenylchlorosilane. In each embodiment, the reactants are present in particular mole ratios of the components.
摘要翻译： 三种改进的Grignard方法用于制备苯基氯硅烷产物，其中作为产物的二苯基氯硅烷的产率最大化，而作为产物的苯基氯硅烷的产率最小化。 在一个实施方案中，该方法包括使苯基格氏试剂，醚溶剂，芳族卤化偶联溶剂和三氯硅烷接触。 在另一个实施方案中，该方法包括使苯基格氏试剂，醚溶剂，芳族卤化偶合溶剂，三氯硅烷和苯基氯硅烷接触。 在另一个实施方案中，该方法包括使苯基格氏试剂，醚溶剂，芳族卤代偶联溶剂和苯基氯硅烷接触。 在每个实施方案中，反应物以组分的特定摩尔比存在。
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