Method of producing silica-based particles

    公开(公告)号:US10040943B2

    公开(公告)日:2018-08-07

    申请号:US11631357

    申请日:2004-07-08

    摘要: Hollow silica-based particles having cavities inside the outer shell having a low refractive index. The method of producing the silica-based particles comprises the following steps (a) and (b): (a) a step in which, when an aqueous silicate solution and/or an acidic silicic acid solution and an aqueous solution of an alkali-soluble inorganic compound are simultaneously added in an alkali aqueous solution to prepare a dispersion liquid of composite oxide particles, an electrolytic salt is added at the molar ratio of a mole number of the electrolytic salt (ME) versus that of SiO2 (MS) [(ME)/(MS)] in the range from 0.1 to 10, and (b) a step of furthermore adding an electrolytic salt, if necessary, to the dispersion liquid of composite oxide particles and then removing at least a portion of elements constituting the composite oxide other than silicon by adding an acid to prepare a dispersion liquid of silica-based particles.

    Transparent film-forming coating liquid, substrate with transparent film, and display device
    14.
    发明授权
    Transparent film-forming coating liquid, substrate with transparent film, and display device 有权
    透明成膜涂布液,带有透明膜的基板和显示装置

    公开(公告)号:US07625635B2

    公开(公告)日:2009-12-01

    申请号:US10556375

    申请日:2004-05-12

    CPC分类号: C09D1/00

    摘要: A transparent film-forming coating liquid is provided which is capable of forming a transparent film that is excellent not only in scratch resistance, film hardness, scratch strength and adhesion to a substrate but also in haze and anti-glare properties. Also provided is a display device having a front panel constituted of a substrate with such a transparent film applied thereto. The transparent film-forming coating liquid comprises inorganic oxide particle groups, in each of which 2 to 10 inorganic oxide particles on an average are linked in the form of a chain, and a polar solvent. In the transparent film-forming coating liquid, the inorganic oxide particles have an average particle diameter of 4 to 200 nm. The inorganic oxide particles are silica particles, and the silica particles are porous particles and/or hollow particles each having a cavity inside.

    摘要翻译: 提供一种能够形成透明膜的透明成膜涂布液,其不仅耐刮擦性,膜硬度,划痕强度和对基材的粘附性,而且在雾度和防眩性中也是优异的。 还提供了一种显示装置,其具有由施加有这种透明膜的基板构成的前面板。 透明成膜用涂布液包含无机氧化物粒子基团,其中平均为2〜10个无机氧化物粒子以链状的形式连结,并具有极性溶剂。 在透明成膜用涂布液中,无机氧化物粒子的平均粒径为4〜200nm。 无机氧化物粒子是二氧化硅粒子,二氧化硅粒子是内部有空洞的多孔粒子和/或中空粒子。

    Anti-glare film and liquid crystal display apparatus
    15.
    发明申请
    Anti-glare film and liquid crystal display apparatus 审中-公开
    防眩光胶片和液晶显示装置

    公开(公告)号:US20080057228A1

    公开(公告)日:2008-03-06

    申请号:US11896262

    申请日:2007-08-30

    摘要: An anti-glare film comprises an anti-glare layer, and a low-refraction-index layer formed on at least one surface thereof and comprising a low-refraction-index resin and a hollow silica particle. The film has an internal haze of 0 to 1%, a haze of 5 to 6.5%, a transmitted image clarity of 20 to 30%, and a reflected light of the film has a* of 0.5 to 1.3 and b* of −2.3 to −0.5. The particle may have a mean particle diameter of about 50 to 70 nm and a refraction index of about 1.2 to 1.25. The film may have an uneven surface, and the average inclination angle of the surface may be about 0.7 to 1°. The anti-glare layer may comprise plural polymers and have a domain formed by a phase separation, and a difference in refraction index between the polymers may be about 0 to 0.04.

    摘要翻译: 防眩光膜包括抗眩光层和在其至少一个表面上形成的低折射率层,并且包括低折射率树脂和中空二氧化硅颗粒。 膜的内部雾度为0〜1%,雾度为5〜6.5%,透射图像透明度为20〜30%,膜的反射光的*为0.5〜1.3,b *为-2.3 至-0.5。 颗粒的平均粒径可以为约50至70nm,折射率为约1.2至1.25。 该膜可能具有不平坦的表面,并且该表面的平均倾斜角可以为约0.7°至1°。 抗眩光层可以包含多个聚合物并且具有通过相分离形成的结构域,并且聚合物之间的折射率差可以为约0至0.04。

    Chain inorganic oxide fine particle groups
    16.
    发明授权
    Chain inorganic oxide fine particle groups 失效
    链无机氧化物微粒组

    公开(公告)号:US07309457B2

    公开(公告)日:2007-12-18

    申请号:US10981845

    申请日:2004-11-05

    IPC分类号: H01B1/00 H01B1/02 H01B1/08

    摘要: A chain antimony oxide fine particle group comprising antimony oxide fine particles which have an average particle diameter of 5 to 50 nm, are connected in the form of a chain and have an average connection number of 2 to 30 and preferably used for forming a hard coating film. The fine particle group can be prepared by a process comprising treating an alkali antimonate aqueous solution with a cation exchange resin to prepare an antimonic acid (gel) dispersion and then treating the dispersion with an anion exchange resin and/or adding a base to the dispersion. Also provided is a substrate with a film comprising a substrate and a hard coating film. The hard coating film includes a chain inorganic oxide fine particle group, in which inorganic oxide fine particles of 2 to 30 on the average are connected in the form of a chain, and a matrix. The inorganic oxide particles may be silica particles, silica-alumina particles being preferable, and porous particles and/or hollow particles having a cavity inside being more preferable.

    摘要翻译: 包含平均粒径为5〜50nm的氧化锑微粒的链状氧化锑微粒组以链状连接,平均连接数为2〜30,优选用于形成硬涂层 电影。 微粒子组可以通过以下方法制备,该方法包括用阳离子交换树脂处理碱式锑酸盐水溶液以制备锑酸(凝胶)分散体,然后用阴离子交换树脂处理分散体和/或向分散体中加入碱 。 还提供了具有包括基底和硬涂膜的薄膜的基底。 硬涂膜包括链状无机氧化物细粒子群,其中平均形式为2至30的无机氧化物细颗粒以链的形式连接,并且基质。 无机氧化物颗粒可以是二氧化硅颗粒,二氧化硅 - 氧化铝颗粒是优选的,并且更优选具有内部空腔的多孔颗粒和/或中空颗粒。

    Electrode catalyst fine particles, dispersion of the same, and process for producing the dispersion
    18.
    发明授权
    Electrode catalyst fine particles, dispersion of the same, and process for producing the dispersion 失效
    电极催化剂微粒,其分散体,以及分散体的制造方法

    公开(公告)号:US07479469B2

    公开(公告)日:2009-01-20

    申请号:US10966895

    申请日:2004-10-15

    摘要: Provided is a process for producing electrode catalyst fine particles capable of affording formed catalysts such as membranes excellent in uniformity and strength and also employable as catalyst to exhibit high catalytic activity over long periods because fine metal particles are highly distributed on carriers to make particle growth or the like less likely to occur. Electrode catalyst fine particles comprise fine particles which have an average particle diameter of 10 nm to 10 μm and in which fine metal particles are supported on carrier particles, wherein a potential difference (absolute value of (II) minus (I)) between a flow potential (I) of a water dispersion of the fine metal particles at 1 wt % concentration and a pH of 3 to 8 and a flow potential (II) of a water dispersion of the carrier particles at 1 wt % concentration and a pH of 4 to 10, is in the range of 10 to 3000 mV.

    摘要翻译: 提供一种能够提供均匀性和强度优异的成膜催化剂的电极催化剂微粒的制备方法,并且也可用作催化剂,以在长时间内表现出高催化活性,因为金属颗粒高度分布在载体上以使颗粒生长或 似乎不太可能发生。 电极催化剂微粒包含平均粒径为10nm〜10μm的微粒,载体颗粒上负载有金属微粒,其中电流差((II)减(I)的绝对值) 浓度为1重量%,pH为3〜8的细金属颗粒的水分散体的电位(I)和载体颗粒的水分散体的流动电位(II)为1重量%,pH为4 至10,在10至3000mV的范围内。

    Electrode catalyst fine particles, dispersion of the same, and process for producing the dispersion
    19.
    发明申请
    Electrode catalyst fine particles, dispersion of the same, and process for producing the dispersion 失效
    电极催化剂微粒,其分散体,以及分散体的制造方法

    公开(公告)号:US20050085379A1

    公开(公告)日:2005-04-21

    申请号:US10966895

    申请日:2004-10-15

    摘要: Provided is a process for producing electrode catalyst fine particles capable of affording formed catalysts such as membranes excellent in uniformity and strength and also employable as catalyst to exhibit high catalytic activity over long periods because fine metal particles are highly distributed on carriers to make particle growth or the like less likely to occur. Electrode catalyst fine particles comprise fine particles which have an average particle diameter of 10 nm to 10 μm and in which fine metal particles are supported on carrier particles, wherein a potential difference (absolute value of (II) minus (I)) between a flow potential (I) of a water dispersion of the fine metal particles at 1 wt % concentration and a pH of 3 to 8 and a flow potential (II) of a water dispersion of the carrier particles at 1 wt % concentration and a pH of 4 to 10, is in the range of 10 to 3000 mV.

    摘要翻译: 提供一种能够提供均匀性和强度优异的成膜催化剂的电极催化剂微粒的制备方法,并且也可用作催化剂,以在长时间内表现出高催化活性,因为金属颗粒高度分布在载体上以使颗粒生长或 似乎不太可能发生。 电极催化剂微粒包含平均粒径为10nm〜10μm的微粒,载体颗粒上负载有金属微粒,其中电流差((II)减(I)的绝对值) 浓度为1重量%,pH为3〜8的细金属颗粒的水分散体的电位(I)和载体颗粒的水分散体的流动电位(II)为1重量%,pH为4 至10,在10至3000mV的范围内。