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11.发明授权Multiphase lubricant concentrates for use in water based systems in the field of exploratory soil drilling 失效多相润滑剂浓缩物用于探索性土壤钻井领域的水基系统公开(公告)号：US06211119B1
公开(公告)日：2001-04-03
申请号：US09308399
申请日：1999-06-01
IPC分类号： C09K702
CPC分类号： C10M173/00 , C09K8/26 , C09K8/36 , C10M2201/02 , C10M2203/00 , C10M2203/02 , C10M2203/022 , C10M2203/024 , C10M2203/04 , C10M2207/021 , C10M2207/022 , C10M2207/04 , C10M2207/046 , C10M2207/08 , C10M2207/126 , C10M2207/281 , C10M2207/282 , C10M2207/283 , C10M2207/286 , C10M2207/287 , C10M2207/288 , C10M2207/289 , C10M2207/32 , C10M2209/102 , C10M2209/103 , C10M2209/104 , C10M2209/105 , C10M2209/107 , C10M2209/108 , C10M2209/109 , C10M2209/12 , C10M2211/00 , C10M2211/06 , C10M2215/00 , C10M2215/042 , C10M2215/062 , C10M2215/08 , C10M2215/082 , C10M2215/086 , C10M2215/10 , C10M2215/12 , C10M2215/122 , C10M2215/202 , C10M2215/28 , C10M2217/00 , C10M2217/02 , C10M2217/04 , C10M2217/044 , C10M2219/02 , C10M2219/022 , C10M2219/024 , C10M2223/02 , C10M2223/04 , C10M2223/041 , C10M2223/042 , C10M2223/049 , C10M2223/06 , C10M2223/061 , C10M2223/065 , C10M2223/10 , C10M2229/02 , C10M2229/04 , C10M2229/041 , C10M2229/042 , C10M2229/043 , C10M2229/044 , C10M2229/045 , C10M2229/046 , C10M2229/047 , C10M2229/048 , C10M2229/05 , C10M2229/051 , C10M2229/052 , C10M2229/053 , C10M2229/054 , C10N2240/00 , C10N2240/22 , C10N2240/30 , C10N2240/50 , C10N2240/52 , C10N2240/54 , C10N2240/56 , C10N2240/58 , C10N2240/60 , C10N2240/66 , C10N2250/02 , C10N2270/02
摘要： The invention relates to multiphase lubricant concentrates with improved properties for use in aqueous fluids for geological exploration by drilling which contain organic lubricating components which are solid and/or liquid at room temperature (O phase) together with emulsifiers finely dispersed in a continuous aqueous phase (W phase). These concentrates are characterized in that the system of O phase/W phase and emulsifiers has a phase inversion temperature (PIT) above room temperature and has been produced by heating the multiphase system to temperatures equal to or above the PIT and subsequent cooling to temperatures below the PIT. The present invention also relates to the use of the multiphase lubricant concentrates as an additive in water-based fluids for use in geological exploration by drilling and for the subsequent treatment of the resulting boreholes.
摘要翻译： 本发明涉及具有改进性能的多相润滑剂浓缩物，其用于通过钻井进行地质勘探的含水流体，其包含在室温（O相）下固体和/或液体的有机润滑组分以及细分散在连续水相中的乳化剂（ W相）。 这些浓缩物的特征在于，O相/ W相和乳化剂的体系具有高于室温的相转化温度（PIT），并且通过将多相体系加热至等于或高于PIT的温度并随后冷却至低于 PIT。本发明还涉及多相润滑剂浓缩物作为添加剂在水基流体中的用途，用于通过钻孔进行地质勘探和随后处理所得到的钻孔。
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公开(公告)号：US5348938A
公开(公告)日：1994-09-20
申请号：US54462
申请日：1993-04-28
摘要： The use is described ofa) mono- and/or polyfunctional alcohols of natural and/or synthetic origin which are at least largely water-insoluble and are fluid and pumpable in the temperature range of 0.degree. to 5.degree. C.,or ofb) solutions, fluid and pumpable in the given temperature range, in ecologically-acceptable water-insoluble oils, of at least largely water-insoluble mono- and/or polyfunctional alcohols of natural and/or synthetic origin,as the continuous oil phase of drilling fluids, which exist as W/O-emulsions, have a dispersed aqueous phase and preferably have further usual additives in the alcohol-containing oil phase, and which are suitable for the environment-friendly development of, e.g., petroleum and natural gas deposits. Drilling fluids of the above type are also described, which are characterized in that they contain as the continuous oil phase, or dissolved in ecologically-acceptable water-insoluble oils, an additive of at least largely water-insoluble mono- and/or polyfunctional alcohols, the oil phase in each case being fluid and pumpable in the temperature range of 0.degree. to 5.degree. C. and having flash points above 80.degree. C.
摘要翻译： PCT No.PCT / EP90 / 00499 Sec。 371日期1991年10月7日 102（e）日期1991年10月7日PCT 1990年3月29日PCT PCT。 出版物WO90 / 12070 日期为1990年10月18日。使用描述了a）天然和/或合成来源的单和/或多官能醇，其至少在很大程度上不溶于水并且在0℃至5℃的温度范围内是可流动和可泵送的 或者b）在生态上可接受的水不溶性油中的至少大部分天然和/或合成来源的水不溶性单和/或多官能醇的在给定温度范围内的溶液，流体和可泵送的溶液， 作为以W / O乳液形式存在的钻井液的连续油相，具有分散的水相，优选在含醇油相中具有其他通常的添加剂，适用于环境友好的开发，例如 ，石油天然气矿床。 还描述了上述类型的钻井液，其特征在于它们包含作为连续油相或溶解在生态上可接受的水不溶性油中，至少主要是水不溶性单和/或多官能醇的添加剂 每种情况下的油相在0℃至5℃的温度范围内是可流动的并可泵送，闪点高于80℃。
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13.发明授权Use of selected ester oils in water-based drilling fluids of the O/W emulsion type and corresponding drilling fluids with improved ecological acceptability 失效在O / W乳液型水相钻井液和相应的钻井液中使用选定的酯油，具有改善的生态可接受性
公开(公告)号：US5318956A
公开(公告)日：1994-06-07
申请号：US055409
申请日：1993-04-29
CPC分类号： C09K8/26
摘要： The use is disclosed of water-dispersible esters, which are fluid or at least plastically deformable at working temperature and have flash points of at least 80.degree. C., from saturated and/or unsaturated carboxylic acids with up to 36 carbon atoms and mono- and/or polyhydric alcohols, as at least the main constituent of the dispersed oil phase of water-based O/W-emulsion drilling fluids which are suitable for the environmentally friendly development of geological formations and which contain, if desired, insoluble, finely particulate weighting agents for the formation of water-based O/W-emulsion drilling muds and/or further additives, such as emulsifiers, fluid-loss additives, wetting agents, alkali reserves and/or auxiliary substances for the inhibition of drilled rock of high water-sensitivity.
摘要翻译： 公开了水分散性酯，其是在工作温度下为流体或至少可塑性变形的具有至多80℃的闪点的水分散性酯，其具有至多36个碳原子的饱和和/或不饱和羧酸， 和/或多元醇作为至少是水性O / W乳液钻井液的分散油相的主要成分，其适用于地质构造的环境友好型开发，并且如果需要，其含有不溶性的细颗粒 用于形成水基O / W乳液钻井泥浆的增重剂和/或其它添加剂，例如乳化剂，流体损失添加剂，润湿剂，碱储备和/或用于抑制高水钻岩的辅助物质 -灵敏度。
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公开(公告)号：US5318954A
公开(公告)日：1994-06-07
申请号：US84783
申请日：1993-06-29
摘要： The invention describes the use of selected esters, fluid at room temperature and with flash points above 80.degree. C., of C.sub.1-5 -monocarboxylic acids and mon- and/or polyfunctional alcohols as the oil phase, or a component of the oil phase of invert drilling muds which are suitable for environment-friendly development of petroleum or natural gas deposits and contain in a continuous oil phase a dispersed aqueous phase together with emulsifiers, weighting agents, fluid-loss additives and preferably further conventional additives. In a further embodiment the invention relates to invert drilling fluids of the type described, which are characterized in that the oil phase contains esters from C.sub.1-5 -monocarboxylic acids with mono- and/or polyfunctional alcohols preferably in admixture with other components from the class of ecologically acceptable compounds.
摘要翻译： 本发明描述了在室温下和高于80℃的闪点的选择的酯，作为油相的C1-5-一元羧酸和单和/或多官能醇或油相的组分的用途 适用于石油或天然气沉积环境友好型开发的钻井泥浆，并在连续油相中与乳化剂，增重剂，流体损失添加剂以及优选的其它常规添加剂一起含有分散的水相。 在另一个实施方案中，本发明涉及所述类型的反相钻井液，其特征在于油相含有来自C 1-5 - 一元羧酸的酯与单和/或多官能醇优选与来自该类的其它组分混合 的生态可接受的化合物。
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公开(公告)号：US5252554A
公开(公告)日：1993-10-12
申请号：US825431
申请日：1992-01-21
申请人： Heinz Mueller , Claus-Peter Herold , Stephan von Tapavicza , Douglas J. Grimes , Jean-Marc Braun , Stuart P. T. Smith
发明人： Heinz Mueller , Claus-Peter Herold , Stephan von Tapavicza , Douglas J. Grimes , Jean-Marc Braun , Stuart P. T. Smith
CPC分类号： C09K8/34
摘要： Invert emulsion muds for drilling of gas and oil, which are environmentally safe, and which contain:A. a continuous oil phase composed predominantly of at least one monocarboxylic acid ester of a C.sub.2 C.sub.12 monofunctional alkanol wherein the monocarboxylic acid contains from 12 to 16 carbon atoms and is aliphatically saturated,B. a disperse aqueous phase,C. at least one emulsifier,D. at least one weighting agent,E. at least one fluid loss additive, andF. a mild alkaline reserve.
摘要翻译： 反转用于钻井气体和油的乳液泥浆，其是环境安全的，并且其包含：A.主要由至少一种C2C12单官能链烷醇的单羧酸酯组成的连续油相，其中所述一元羧酸含有12至16个碳原子 并且是脂肪饱和的，B.分散水相，C.至少一种乳化剂，D.至少一种加重剂，E.至少一种流体损失添加剂，F.一种温和的碱性储备。
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16.发明授权Aqueous swellable compositions of guar gum and guar gum derivatives in oleophilic liquids and their use 失效瓜尔胶和瓜尔胶衍生物在亲油液体中的水溶胀性组合物及其用途公开(公告)号：US06180572B2
公开(公告)日：2001-01-30
申请号：US09091313
申请日：1998-12-28
IPC分类号： E21B2106
摘要： The invention relates to the use of oil-soluble oleophilic organic liquid phases—flowable at temperatures of 0 to 10° C.—from the classes of corresponding monocarboxylic and/or polycarboxylic acid esters, carbonic acid esters, fatty alcohols and their oligoalkoxides and/or ethers as the at least predominant part of the liquid phase in storage-stable homogeneous mixtures with guar and/or water-soluble guar derivatives for their use in water-based borehole servicing fluids.
摘要翻译： 本发明涉及使用在0至10℃温度下可流动的油溶性亲油有机液相 - 来自相应的单羧酸和/或多元羧酸酯，碳酸酯，脂肪醇及其低聚烷氧基化物和/ 或醚作为储存稳定的均匀混合物中液相的至少主要部分，其具有瓜尔胶和/或水溶性瓜尔胶衍生物，用于其在水基井眼维修流体中。
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17.发明授权Mineral additives for setting and/or controlling the rheological properties and gel structure of aqueous liquid phases and the use of such additives 失效用于设定和/或控制水性液相的流变性质和凝胶结构的矿物添加剂以及这些添加剂的使用
公开(公告)号：US5663122A
公开(公告)日：1997-09-02
申请号：US374556
申请日：1995-01-27
IPC分类号： C09K8/05 , C09K8/16 , C09K8/32 , C10M125/10 , C10M125/26 , C10M173/02 , C09K7/02 , B01J13/00 , C09K7/04 , C09K7/06
CPC分类号： C09K8/32 , C09K8/05 , C09K8/16 , C10M125/10 , C10M125/26 , C10M173/02 , C10M2201/02 , C10M2201/062 , C10M2201/087 , C10M2201/10 , C10M2201/102 , C10M2201/103 , C10M2201/105 , C10N2240/40 , C10N2240/401 , C10N2250/02
摘要： The invention concerns the use of mixed hydroxydes of bivalent and trivalent metals with a three-dimensional spaced-lattice structure of the garnet type to control the thixotropic thickening of aqueous preparations, using swellable clays and/or other swellable layer-silicate compounds of natural and/or synthetic origin as visosity-increasing agents. The preferred garnet-type mixed hydroxydes are catoites of the basic structure Ca.sub.3 Al.sub.2 (OH).sub.12 a minor proportion of whose OH units can be exchanged for acid groups, in particular silicate groups.
摘要翻译： PCT No.PCT / EP93 / 01902 371日期：1995年1月27日 102（e）日期1995年1月27日PCT提交1993年7月19日PCT公布。 出版物WO94 / 02566 日期1994年2月3日本发明涉及使用石榴石类型的三维间隔晶格结构的二价和三价金属的混合氢氧化物来控制水性制剂的触变增稠，使用可溶胀粘土和/或其它可溶胀层 - 天然和/或合成来源的硅酸盐化合物作为增粘剂。 优选的石榴石型混合氢氧化物是碱式结构Ca 3 Al 2（OH）12的一种较小比例的OH单元可以交换酸基团，特别是硅酸盐基团。
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公开(公告)号：US5461028A
公开(公告)日：1995-10-24
申请号：US955738
申请日：1992-12-07
摘要： Described is the use of oleophilic monomeric and/or oligomeric diesters of carbonic acid with the same or different oil-soluble and ecologically compatible mono-functional and optionally polyfunctional alcohols as a component of oil-based or water-based drilling fluids and other fluid drill-hole treatment agents. The invention in one embodiment comprises oil-based fluids, and particularly inverted fluids of the W/O type, which in the continuous phase at least in part contain oleophilic carbonic acid diesters. In a further important embodiment the invention relates to water-based emulsion fluids which in the dispersed oil phase at least in part contain said oleophilic carbonic acid diesters. The invention further comprises drill-hole treatment agents, and especially drilling fluids of the above-mentioned types, the continuous or dispersed oil phases of which, respectively, consist of oleophilic carbonic acid disasters or contain said ester type in admixture with other ecologically compatible oil mixing components. Preferred mixing components for a use in combination which the carbonic acid diesters are appropriate carboxylic acid ester oils, oleophilic alcohols and/or oleophilic ethers.
摘要翻译： PCT No.PCT / EP91 / 01001 Sec。 371日期：1992年12月7日 102（e）日期1992年12月7日PCT 1991年5月29日PCT PCT。 WO91 / 18958 PCT出版物 日期为1991年12月12日。描述了使用具有相同或不同的油溶性和生态相容性的单官能和任选多官能醇作为油基或水溶性组分的碳酸的亲油单体和/或低聚二酯， 基础钻井液和其他流体钻孔处理剂。 本发明在一个实施方案中包括油基流体，特别是W / O型的倒置流体，其在连续相中至少部分含有亲油性碳酸二酯。 在另一重要实施方案中，本发明涉及在分散油相中至少部分含有所述亲油性碳酸二酯的水基乳液。 本发明还包括钻孔处理剂，特别是上述类型的钻井液，连续或分散的油相分别由亲油性碳酸性灾害组成或含有所述酯型与其它生态相容的油混合 混合组分。 用于组合使用的优选的混合组分，其中碳酸二酯是合适的羧酸酯油，亲油醇和/或亲油醚。
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19.发明授权Aqueous resin preparations and a process for stabilizing rock and plugging cavities 失效水泥树脂的制备和稳定岩石和填埋场的工艺
公开(公告)号：US5199823A
公开(公告)日：1993-04-06
申请号：US761902
申请日：1991-11-06
CPC分类号： C08J3/03 , C09K17/40 , C09K17/48 , C09K8/5086 , C08J2361/20
摘要： The invention relates to aqueous preparations of acid-catalyzed melamine resins and/or urea-formaldehyde condensates which contain an addition of zeolite NaA and/or hydroxysodalite to increase their usefulness. The preparations in question are particularly suitable for use in the stabilization of rock and/or plugging of cavities, for example in tunneling and mining. Accordingly, the invention also relates to a process for stabilizing rock, for example in tunneling and mining, by injection of corresponding preparations together with an acidic catalyst.
摘要翻译： PCT No.PCT / EP90 / 00353 Sec。 371日期1991年11月6日 102（e）日期1991年11月6日PCT 1990年3月3日PCT公布。 WO90 / 10780 PCT出版物 日本1990年9月20日。本发明涉及酸催化的三聚氰胺树脂和/或脲 - 甲醛缩合物的含水制剂，其含有添加沸石NaA和/或羟基方钠矿以提高其有用性。 所讨论的制剂特别适合用于稳定岩石和/或堵塞空腔，例如在隧道掘进和采矿中。 因此，本发明还涉及通过与酸性催化剂一起注入相应的制剂来稳定岩石的方法，例如隧道掘进和开采。
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20.发明授权Use of selected fatty alcohols and their mixtures with carboxylic acid esters as lubricant components in water-based drilling fluid systems for soil exploration 失效选择的脂肪醇及其与羧酸酯的混合物作为用于土壤勘探的水基钻井液体系中的润滑剂组分公开(公告)号：US06716799B1
公开(公告)日：2004-04-06
申请号：US09308400
申请日：1999-06-01
IPC分类号： C09K702
摘要： The invention relates to the use of linear and/or branched fatty alcohols containing at least 12 carbon atoms in the molecule and/or to the use of mixtures of such fatty alcohols with carboxylic acid esters as a lubricating additive in water-based drilling fluids for their use in geological exploration by drilling. The fatty-alcohol-based lubricants or lubricant systems are particularly suitable for use in water-based alkali metal silicate drilling muds which are known to be distinguished by comparatively high pH values. The additives according to the invention combine their lubricating effect with a foam-suppressing effect, i.e. prevent unwanted foaming.
摘要翻译： 本发明涉及在分子中含有至少12个碳原子的直链和/或支链脂肪醇的用途和/或在水基钻井液中使用这种脂肪醇与羧酸酯作为润滑添加剂的混合物 它们在钻探地质勘探中的应用。 基于脂肪醇的润滑剂或润滑剂系统特别适用于已知通过较高pH值区分的水基碱金属硅酸盐钻井泥浆。 根据本发明的添加剂将其润滑效果与泡沫抑制效果相结合，即防止不希望的起泡。
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