公开(公告)号：US06210563B1

公开(公告)日：2001-04-03

申请号：US09222977

申请日：1998-12-30

申请人： Ying-Yen P. Tsao ,  Tracy J. Huang ,  Philip J. Angevine

发明人： Ying-Yen P. Tsao ,  Tracy J. Huang ,  Philip J. Angevine

IPC分类号： C10G35085

CPC分类号： C10G45/54 ,  C10G2400/04

摘要： A process is provided for selectively producing diesel fuel with increased cetane number from a hydrocarbon feedstock. The process includes contacting the feedstock with a catalyst which has a large pore crystalline molecular sieve material component having a faujasite structure and alpha acidity of less than 1, preferably about 0.3 or less. The catalyst also contains a dispersed Group VIII noble metal component which catalyzes the hydrogenation/hydrocracking of the aromatic and naphthenic species in the feedstock.

摘要翻译： 提供了一种从碳氢化合物原料选择性地生产具有增加的十六烷值的柴油燃料的方法。 该方法包括使原料与催化剂接触，所述催化剂具有大孔分子筛材料组分，其具有八面沸石结构和α酸度小于1，优选约0.3或更小。 催化剂还含有分散的VIII族贵金属组分，其催化原料中芳族和环烷烃物质的氢化/加氢裂化。

公开(公告)号：US4929576A

公开(公告)日：1990-05-29

申请号：US323178

申请日：1989-03-15

申请人： Ying-Yen P. Tsao ,  Roland von Ballmoos

发明人： Ying-Yen P. Tsao ,  Roland von Ballmoos

IPC分类号： B01J29/90

CPC分类号： B01J29/90

摘要： There is provided a process for redispersing agglomerated noble metals such as platinum over the surface of certain tetrahedral crystalline oxides containing oxides of aluminum and phosphorus. Examples of such crystalline oxides include aluminophosphate (i.e. AlPO.sub.4 s), silicoaluminophosphates (i.e. SAPOs), ELAPSOs, MeAPOs, FeAPOs, TiAPOs and FCAPOs. The agglomerated noble metals may be redispersed by containing the supported noble metal with a suitable treating agent such as a stream of gas comprising molecular chlorine.

摘要翻译： 提供了在含有铝和磷的氧化物的某些四面体结晶氧化物的表面上再分散附聚的贵金属如铂的方法。 这种结晶氧化物的实例包括磷酸铝（即AlPO 4），硅铝磷酸盐（即SAPO），ELAPSO，MeAPO，FeAPO，TiAPO和FCAPO。 聚结的贵金属可以通过用合适的处理剂（例如包含分子氯的气流）包含负载的贵金属来再分散。

公开(公告)号：US4882307A

公开(公告)日：1989-11-21

申请号：US092248

申请日：1987-09-02

申请人： Ying-Yen P. Tsao

发明人： Ying-Yen P. Tsao

IPC分类号： C07C15/067 ,  B01J29/068 ,  B01J29/44 ,  B01J29/67 ,  B01J29/74 ,  C07B61/00 ,  C07C1/00 ,  C07C4/18 ,  C07C5/13 ,  C07C15/00 ,  C07C67/00 ,  C10G45/64

CPC分类号： C10G45/64 ,  B01J29/7415

摘要： A process for preparing noble metal-containing zeolites having high noble metal dispersion comprises (a) contacting a zeolite material with a cationic noble metal complex; (b) calcining the resulting meterial in the presence of molecular oxygen at about 300.degree. to 375.degree. C. for a time sufficient to cause decomposition of said complex; (c) purging oxygen and water from the calcined material in an inert atmosphere at 200.degree. to 350.degree. C.; and (d) reducing the purged material with hydrogen at 200.degree. to 350.degree. C. for a time sufficient to reduce the cationic noble metal to highly dispersed free metal.

公开(公告)号：US4790928A

公开(公告)日：1988-12-13

申请号：US153395

申请日：1988-02-08

申请人： Clarence D. Chang ,  Nai Y. Chen ,  Stuart D. Hellring ,  Ying-Yen P. Tsao ,  Dennis E. Walsh

发明人： Clarence D. Chang ,  Nai Y. Chen ,  Stuart D. Hellring ,  Ying-Yen P. Tsao ,  Dennis E. Walsh

IPC分类号： B01J29/40 ,  C07C1/20 ,  C10G47/02 ,  C07C5/13 ,  C10G11/02

CPC分类号： B01J29/40 ,  C07C1/20 ,  B01J2229/26 ,  B01J2229/36 ,  B01J2229/42 ,  C07C2529/40

摘要： The acidity of a zeolite catalyst is reduced by calcination in an essentially water-free atmosphere at temperatures above 700.degree. C., preferably from 725.degree. to 800.degree. C., to reduce the alpha value to less than about 10 percent of its original value. The low acidity catalysts produced in this way may be used for conversions requiring low acidity, shape selective catalysis, including dewaxing. The calcined, low acidity catalysts exhibit improved dewaxing activity.

摘要翻译： 沸石催化剂的酸度通过在高于700℃，优选725℃至800℃的温度下在基本无水的气氛中煅烧而降低，以将α值降低到其原始值的约10％ 。 以这种方式生产的低酸性催化剂可用于需要低酸度，形状选择性催化（包括脱蜡）的转化。 煅烧的低酸度催化剂表现出改善的脱蜡活性。

公开(公告)号：US4532225A

公开(公告)日：1985-07-30

申请号：US639273

申请日：1984-08-09

申请人： Ying-Yen P. Tsao ,  Stephen S. Wong

发明人： Ying-Yen P. Tsao ,  Stephen S. Wong

IPC分类号： B01J29/064 ,  B01J29/076 ,  B01J29/10 ,  B01J29/28

CPC分类号： B01J29/064 ,  B01J29/076

摘要： A method of incorporating metals onto a crystalline aluminosilicate zeolite support comprises first depositing a metal which forms bonds with the zeolite and subsequently depositing a catalytically active metal into the zeolite which becomes associated with the first metal. The catalytically active metals may be introduced by decomposition of an organometallic complex which contains pi-electron donating ligands.

摘要翻译： 将金属掺入到结晶硅铝酸盐沸石载体上的方法包括首先沉积与沸石形成键的金属，随后将催化活性金属沉积到与第一金属相关的沸石中。 催化活性金属可以通过分解含有π-电子给体配体的有机金属络合物来引入。

公开(公告)号：US5481057A

公开(公告)日：1996-01-02

申请号：US217819

申请日：1994-03-25

申请人： Weldon K. Bell ,  Tracy J. Huang ,  Rudolph M. Lago ,  Ying-Yen P. Tsao ,  D. Duayne Whitehurst

发明人： Weldon K. Bell ,  Tracy J. Huang ,  Rudolph M. Lago ,  Ying-Yen P. Tsao ,  D. Duayne Whitehurst

IPC分类号： C07C2/58 ,  C10G57/00 ,  C07C4/06

CPC分类号： C07C2/58 ,  C10G57/005 ,  C07C2529/08

摘要： A process for catalytic cracking and C3/C4 olefin alkylation with phosphorus stabilized faujasite catalyst is disclosed. Catalytic cracking produces C3 and C4 olefins, which are alkylated using phosphorus stabilized and water activated cracking catalyst. Spent alkylation catalyst may be discharged into the FCC unit.

摘要翻译： 公开了一种用磷稳定化八面沸石催化剂进行催化裂化和C3 / C4烯烃烷基化的方法。 催化裂化产生C3和C4烯烃，它们使用磷稳定和水活化的裂化催化剂进行烷基化。 废烷基化催化剂可以排放到FCC装置中。

公开(公告)号：US5384296A

公开(公告)日：1995-01-24

申请号：US106668

申请日：1993-08-16

申请人： Ying-Yen P. Tsao

发明人： Ying-Yen P. Tsao

IPC分类号： B01J29/068 ,  B01J37/10 ,  B01J29/06

CPC分类号： B01J37/10 ,  B01J29/068 ,  B01J2229/36

摘要： A zeolite catalyst composition having increased resistance to agglomeration and/or migration of its noble metal component at high temperatures and a method for preparing the catalyst composition are disclosed. The zeolite catalyst composition contains non-framework multivalent alumina which is obtained by calcining the zeolite at a temperature of at least 600.degree. C. in moist air (10 to 100 torr water).

摘要翻译： 公开了一种沸石催化剂组合物，其在高温下具有增加的贵金属组分的附聚和/或迁移的能力，以及制备该催化剂组合物的方法。 沸石催化剂组合物含有非框架多价氧化铝，其通过在潮湿空气（10至100托的水）中在至少600℃的温度下煅烧沸石获得。

公开(公告)号：US5290534A

公开(公告)日：1994-03-01

申请号：US973510

申请日：1992-11-09

申请人： Ying-Yen P. Tsao

发明人： Ying-Yen P. Tsao

IPC分类号： B01J29/74 ,  C01B39/04 ,  C01B39/48 ,  C01B33/34 ,  B01J29/32

CPC分类号： C01B39/48 ,  B01J29/74 ,  C01B39/04

摘要： An improved method for removing organic residue from ZSM-18 which can be used during zeolite synthesis or with an as-synthesized ZSM-18. When used during synthesis, a minute amount of noble metal is incorporated into the ZSM-18. Alternatively, a noble metal-containing precursor is impregnated onto as-synthesized ZSM-18. Thereafter, ZSM-18 united with the noble metal is reduced in hydrogen at 200.degree. C. for about 1 hour. Next, ZSM-18 united with the noble metal is calcined at 300.degree. C. for 10-24 hours, and subsequently at 500.degree. C. for 1-3 hours thereby producing a ZSM-18 material that is free of organic residue.

摘要翻译： 一种用于从ZSM-18中除去有机残余物的改进方法，其可以在沸石合成期间或用合成的ZSM-18来使用。 当在合成时使用时，将少量的贵金属掺入到ZSM-18中。 或者，将含贵金属的前体浸渍到合成的ZSM-18上。 此后，与贵金属结合的ZSM-18在氢气中在200℃下还原约1小时。 接下来，将与贵金属结合的ZSM-18在300℃下煅烧10-24小时，然后在500℃下煅烧1-3小时，由此产生不含有机残余物的ZSM-18材料。

公开(公告)号：US4678764A

公开(公告)日：1987-07-07

申请号：US800581

申请日：1985-11-21

申请人： Quang N. Le ,  Ying-Yen P. Tsao ,  Stephen S. Wong

发明人： Quang N. Le ,  Ying-Yen P. Tsao ,  Stephen S. Wong

IPC分类号： B01J29/74 ,  B01J29/90 ,  B01J38/60 ,  B01J38/66 ,  B01J29/38 ,  B01J23/96

CPC分类号： B01J29/90 ,  B01J38/60 ,  B01J38/66 ,  B01J29/7415 ,  Y10S502/517

摘要： A method for reactivating noble metal-containing zeolites containing sulfur oxide poisoned noble metal such as oxygen regenerated platinum zeolite beta catalysts, by contacting the catalyst with an acidic aqueous solution having a pH below about 7. The solution contains a Bronsted acid compound having a dissociation constant ranging from about 1.times.10.sup.-14 to about 2.times.10.sup.-1.

摘要翻译： 通过使催化剂与pH低于约7的酸性水溶液接触，使含有硫氧化物中毒的贵金属如贵金属贵金属如氧再生的铂沸石β催化剂再生的方法。该溶液含有具有解离性的布朗斯台德酸化合物 常数范围为约1×10-14至约2×10 -1。

公开(公告)号：US4513098A

公开(公告)日：1985-04-23

申请号：US508407

申请日：1983-06-28

申请人： Ying-Yen P. Tsao

发明人： Ying-Yen P. Tsao

IPC分类号： B01J23/883 ,  B01J37/02 ,  B01J37/20 ,  C10G49/02 ,  B01J27/02 ,  B01J31/12 ,  C10G35/04 ,  C10G35/06

CPC分类号： C10G49/02 ,  B01J23/883 ,  B01J37/0203 ,  B01J37/0209 ,  B01J37/20

摘要： Certain organometallic precursors selectively interact with surface hydroxyl groups on an inorganic oxide support such as silica, alumina or silica-alumina or to provide a uniform distribution of metal complexes on the surfaces of said support. Subsequent reduction of the support results in a high dispersion of uncomplexed metal centers to which other organometallic precursors are subsequently attached. The substantially attached organometallic precursors may be reduced and/or sulfided to yield a highly active hydrogenation catalyst having a plurality of metal species in a highly dispersed distribution.

摘要翻译： 某些有机金属前体选择性地与无机氧化物载体如二氧化硅，氧化铝或二氧化硅 - 氧化铝上的表面羟基相互作用，或提供金属络合物在所述载体表面上的均匀分布。 随后的载体减少导致随后附着其它有机金属前体的未复合金属中心的高分散体。 基本上连接的有机金属前体可以被还原和/或硫化以产生具有高度分散分布的多种金属物质的高活性氢化催化剂。