公开(公告)号：US20060141276A1

公开(公告)日：2006-06-29

申请号：US10561673

申请日：2004-06-23

申请人： Takashi Ito ,  Tsuneo Hagiwara

发明人： Takashi Ito ,  Tsuneo Hagiwara

IPC分类号： B32B27/00

CPC分类号： B29C64/135 ,  B33Y70/00 ,  Y10T428/24942 ,  Y10T428/254 ,  Y10T428/26 ,  Y10T428/31855

摘要： It is intended to provide an optical three-dimensional object as will be described below which has a high impact resistance and is superior in dimensional accuracy, mechanical properties such as tensile strength, and other properties such as water resistance, moisture resistance and heat resistance, and a method of producing the same. An optical three-dimensional object includes multiple cured resin layers containing at least cured resin layer that has a sea-island microstructure in which fine island components of a polymer differing from a cured resin constituting the sea component and have a particle diameter of 20 to 2,000 nm are dispersed in the sea component made of the cured polymer; and a method of producing this optical three-dimensional object by stereolithographic molding method with the use of a photo curable resin composition containing a homogeneous mixture of a curable resin component for forming the sea component with a component (preferably a polyalkylene ether compound) for forming the polymeric island components.

摘要翻译： 旨在提供具有高耐冲击性并且尺寸精度优异，拉伸强度等机械性能，耐水性，耐湿性，耐热性等其他性能的光学三维物体， 及其制造方法。 光学三维物体包括多个固化树脂层，其至少包含具有海岛微结构的固化树脂层，其中聚合物的细小岛成分与构成海成分的固化树脂不同，粒径为20至2,000 nm分散在由固化的聚合物制成的海组分中; 以及通过使用含有用于形成海成分的固化性树脂成分的均匀混合物与成分（优选为聚亚烷基醚化合物）形成的光固化性树脂组合物的立体成像法来制造该光学三维物体的方法 聚合物岛组分。

公开(公告)号：US4495343A

公开(公告)日：1985-01-22

申请号：US501395

申请日：1983-06-06

申请人： Kaoru Iwata ,  Tsuneo Hagiwara ,  Hiroshi Matsuzawa

发明人： Kaoru Iwata ,  Tsuneo Hagiwara ,  Hiroshi Matsuzawa

IPC分类号： G03F7/20 ,  C08F2/00 ,  C08F2/48 ,  C08F290/00 ,  C08F299/00 ,  C08F299/04 ,  C08G63/00 ,  C08G63/68 ,  C08G63/685 ,  C08L33/00 ,  C08L33/02 ,  C08L67/00 ,  C08L67/06 ,  C09D167/06 ,  G03F7/004 ,  G03F7/027 ,  G03F7/032 ,  G03F7/038 ,  G03F7/32 ,  C08G69/08 ,  C08G69/44

CPC分类号： G03F7/0388 ,  C08G63/6858 ,  G03F7/0384 ,  G03F7/325

摘要： A photocrosslinkable substantially linear polyester polymer having sensitivity to visible light is provided which contains at least 10 mole %, based on the entire polymer, of units derived from a phenylenebis(.alpha.-cyanobutadienecarboxylic acid) and has a reduced viscosity of at least 0.2 dl/g. A typical use of the polymer is in making printing plates.

摘要翻译： 提供了对可见光敏感的可光交联的基本上线性的聚酯聚合物，其含有至少10摩尔％（基于整个聚合物）衍生自亚苯基双（α-氰基丁二酸羧酸）的单元，并且具有至少0.2dl / G。 聚合物的典型用途是制造印刷版。

公开(公告)号：US08338074B2

公开(公告)日：2012-12-25

申请号：US10562098

申请日：2004-06-24

申请人： Takashi Ito ,  Tsuneo Hagiwara ,  Hideki Kimura ,  Masashi Date ,  Jiro Yamamoto

发明人： Takashi Ito ,  Tsuneo Hagiwara ,  Hideki Kimura ,  Masashi Date ,  Jiro Yamamoto

IPC分类号： G03F7/004 ,  G03F7/027 ,  G03F7/029 ,  C08G59/68

CPC分类号： C08G59/687 ,  B33Y70/00 ,  C08F2/50 ,  C08F2/56 ,  G03F7/0045 ,  G03F7/027 ,  G03F7/038

摘要： It is intended to provide the following resin composition for stereolithography which is superior in storage stability and aging stability during operation, shows no increase in viscosity upon prolonged storage, has a high light-curing sensitivity and, therefore, makes it possible to produce, upon photo irradiation, an object by stereolithography, which is superior in dimensional accuracy, fabricating accuracy, water resistance, moisture resistance and mechanical properties at a high fabricating speed and a high productivity. A resin composition for stereolithography which is an actinic radiation-curable resin composition containing a cationic-polymerizable organic compound, a radical-polymerizable organic compound, a photo cationic polymerization initiator and a photo radical polymerization initiator, in which the photo cationic polymerization initiator contains a compound represented by the following formula (I) and having a purity of 80% or higher: wherein M represents an antimony atom or a phosphorus atom; and the broken line between S+ and MF6− represents an ionic bond.

摘要翻译： 旨在提供以下用于立体光刻的树脂组合物，其在操作中的储存稳定性和老化稳定性优异，在长时间保存时不显示粘度增加，具有高的光固化灵敏度，因此可以在 照相照射，通过立体光刻法，在高制造速度和高生产率下尺寸精度，制造精度，耐水性，耐湿性和机械性能都优异。 一种用于立体光刻的树脂组合物，其是含有阳离子可聚合有机化合物，自由基可聚合有机化合物，光阳离子聚合引发剂和光自由基聚合引发剂的光化辐射固化树脂组合物，其中光阳离子聚合引发剂包含 由下式（I）表示的并且纯度为80％以上的化合物：其中M表示锑原子或磷原子; S +和MF6-之间的虚线表示离子键。

公开(公告)号：US07354643B2

公开(公告)日：2008-04-08

申请号：US10561673

申请日：2004-06-23

申请人： Takashi Ito ,  Tsuneo Hagiwara

发明人： Takashi Ito ,  Tsuneo Hagiwara

IPC分类号： B32B7/02 ,  B32B5/16 ,  B05D1/36 ,  B05D3/02

CPC分类号： B29C64/135 ,  B33Y70/00 ,  Y10T428/24942 ,  Y10T428/254 ,  Y10T428/26 ,  Y10T428/31855

摘要： It is intended to provide an optical three-dimensional object as will be described below which has a high impact resistance and is superior in dimensional accuracy, mechanical properties such as tensile strength, and other properties such as water resistance, moisture resistance and heat resistance, and a method of producing the same. An optical three-dimensional object includes multiple cured resin layers containing at least one cured resin layer that has a sea-island microstructure in which fine island components of a polymer differing from a cured resin constituting the sea component and have a particle diameter of 20 to 2,000 nm are dispersed in the sea component made of the cured polymer; and a method of producing this optical three-dimensional object by stereolithographic molding method with the use of a photo curable resin composition containing a homogeneous mixture of a curable resin component for forming the sea component with a component (preferably a polyalkylene ether compound) for forming the polymeric island components.

摘要翻译： 旨在提供具有高耐冲击性并且尺寸精度优异，拉伸强度等机械性能，耐水性，耐湿性，耐热性等其他性能的光学三维物体， 及其制造方法。 光学三维物体包括多个固化树脂层，其含有至少一个具有海岛微结构的固化树脂层，其中聚合物的细小岛成分与构成海成分的固化树脂不同，粒径为20〜 2,000nm分散在由固化的聚合物制成的海组分中; 以及通过使用含有用于形成海成分的固化性树脂成分的均匀混合物与成分（优选为聚亚烷基醚化合物）形成的光固化性树脂组合物的立体成像法制造该光学立体物的方法 聚合物岛组分。

公开(公告)号：US20070060682A1

公开(公告)日：2007-03-15

申请号：US10562098

申请日：2004-06-24

申请人： Takashi Ito ,  Tsuneo Hagiwara ,  Hideki Kimura ,  Masashi Date ,  Jiro Yamamoto

发明人： Takashi Ito ,  Tsuneo Hagiwara ,  Hideki Kimura ,  Masashi Date ,  Jiro Yamamoto

IPC分类号： C08C1/14

CPC分类号： C08G59/687 ,  B33Y70/00 ,  C08F2/50 ,  C08F2/56 ,  G03F7/0045 ,  G03F7/027 ,  G03F7/038

摘要： It is intended to provide the following resin composition for stereolithography which is superior in storage stability and aging stability during operation, shows no increase in viscosity upon prolonged storage, has a high light-curing sensitivity and, therefore, makes it possible to produce, upon photo irradiation, an object by stereolithography, which is superior in dimensional accuracy, fabricating accuracy, water resistance, moisture resistance and mechanical properties at a high fabricating speed and a high productivity. A resin composition for stereolithography which is an actinic radiation-curable resin composition containing a cationic-polymerizable organic compound, a radical-polymerizable organic compound, a photo cationic polymerization inhibitor and a photo radical polymerization inhibitor, in which the photo cationic polymerization inhibitor contains a compound represented by the following formula (I) and having a purity of 80% or higher: wherein M represents an antimony atom or a phosphorus atom; and the broken line between S+ and MF6− represents an ionic bond.

摘要翻译： 旨在提供以下用于立体光刻的树脂组合物，其在操作中的储存稳定性和老化稳定性优异，在长时间保存时不显示粘度增加，具有高的光固化灵敏度，因此可以在 照相照射，通过立体光刻法，在高制造速度和高生产率下尺寸精度，制造精度，耐水性，耐湿性和机械性能都优异。 一种用于立体光刻的树脂组合物，其是含有阳离子可聚合有机化合物，可自由基聚合的有机化合物，光阳离子聚合抑制剂和光自由基聚合抑制剂的光化辐射固化树脂组合物，其中光阳离子聚合抑制剂含有 由下式（I）表示的并且纯度为80％以上的化合物：其中M表示锑原子或磷原子; 并且S SUP + +和/或MF 6之间的虚线表示离子键。

公开(公告)号：US08361376B2

公开(公告)日：2013-01-29

申请号：US11993355

申请日：2006-06-15

申请人： Takashi Ito ,  Tsuneo Hagiwara

发明人： Takashi Ito ,  Tsuneo Hagiwara

IPC分类号： B29C35/08 ,  B29C41/02

CPC分类号： G03F7/0037 ,  B29C64/106 ,  B33Y10/00 ,  B33Y70/00 ,  C08L63/00 ,  C08L67/07 ,  Y10T428/24355 ,  Y10T428/24777 ,  C08L2666/18

摘要： An optical three-dimensional shaped item excelling in the smoothness of molding end face. There is provided a three-dimensional shaped item composed of, superimposed one upon another, multiple cured resin layers having a given configurational pattern formed by irradiating with actinic energy rays a molding face consisting of an actinic energy ray curable resin composition, wherein at least part of an uneven region of molding end face of the three-dimensional shaped item, the degree of unevenness thereof is reduced to smoothness by segregation of a component contained in the actinic energy ray curable resin composition and/or a substance derived from the component. Also, there is provided an actinic energy ray curable resin composition for the three-dimensional shaped item.

摘要翻译： 成型端面平滑度优异的光学立体成型件。 提供一种三维成形物品，它们由多个固化树脂层组成，具有通过用光化能射线照射由光化能量射线固化树脂组合物构成的成型面而形成的给定结构图案，其中至少部分 在三维成形品的成型端面的不均匀区域中，通过使光活性能量射线固化型树脂组合物中所含的成分和/或来自该成分的物质的偏析分离，其不均匀度降低到平滑度。 此外，提供了一种用于三维成形物品的光化学能量射线固化树脂组合物。

公开(公告)号：US5629066A

公开(公告)日：1997-05-13

申请号：US377032

申请日：1995-01-23

申请人： Utami Yonemura ,  Tsuneo Hagiwara

发明人： Utami Yonemura ,  Tsuneo Hagiwara

IPC分类号： B05D3/10 ,  B05D5/12 ,  C08J7/04 ,  G11B5/66

CPC分类号： C08J7/047 ,  B05D3/10 ,  B05D3/107 ,  B05D5/12 ,  B05D2201/00 ,  C08J2433/00 ,  C08J2483/00 ,  C08J2485/00 ,  Y10S428/90 ,  Y10T428/26 ,  Y10T428/265 ,  Y10T428/31507 ,  Y10T428/31551 ,  Y10T428/31663 ,  Y10T428/31786 ,  Y10T428/31797 ,  Y10T428/31855 ,  Y10T428/31935

摘要： A resin article comprising a shaped body of a synthetic resin having a surface, and a coated resin layer covering the surface of the shaped body, said coated resin layer being made of an amino group-containing polymer and/or a polymer containing (meth) acrylate of (iso)cyanuric acid as a constituent unit and having a top surface, wherein the top surface of the coated resin layer is chemically converted to have an anti-static property by chemical reaction with a quaternary compound-forming reagent. Alternatively, a resin article having stable anti-static properties may comprise a shaped body of a synthetic resin covered with an anti-static coating layer made of a reaction product of at least one of an amino group-containing alkoxy silane, an amino group-containing alkoxy titanium compund, or an oligomer thereof, with a quaternary compound-forming reagent.

摘要翻译： 一种树脂制品，包括具有表面的合成树脂的成形体和覆盖所述成形体的表面的涂覆的树脂层，所述涂覆的树脂层由含氨基的聚合物和/或含有（甲基） （iso）氰尿酸的丙烯酸酯作为构成单元，并且具有顶表面，其中涂覆的树脂层的顶表面通过化学反应被化学转化成具有抗季铵化合物形成试剂的抗静电性能。 或者，具有稳定抗静电性的树脂制品可以包括合成树脂的成形体，其被抗静电涂层覆盖，所述抗静电涂层由含氨基的烷氧基硅烷，氨基 - 含有烷氧基钛化合物或其低聚物与季铵化合物形成试剂。

公开(公告)号：US5384215A

公开(公告)日：1995-01-24

申请号：US50488

申请日：1993-05-13

申请人： Kazuhiko Sato ,  Tsuneo Hagiwara ,  Michio Yamaura

发明人： Kazuhiko Sato ,  Tsuneo Hagiwara ,  Michio Yamaura

IPC分类号： C08F34/00 ,  H01B1/12 ,  H01M4/1399 ,  H01M4/60

CPC分类号： H01M4/0466 ,  H01M4/0438 ,  H01M4/60 ,  H01M4/602 ,  H01M2004/028 ,  H01M2300/0025

摘要： A polypyrrole shaped material characterized in that when the polypyrrole shaped material is assembled into a tri-electrode cell comprising the polypyrrole shaped material as a positive electrode, platinum as a negative electrode, a lithium metal as a reference electrode and LiClO.sub.4 or LiBF.sub.4 as an electrolyte and said tri-electrode and cell are subjected to discharging at a current density of 10 mA/cm.sup.2 and controlled-potential charging at 3.6 V, (i) at the completion of the discharging, the concentration of chlorine or fluorine in the polypyrrole shaped material is 30% or below of that at the completion of the charging, and (ii) at the completion of the charging, the distribution of chlorine or fluorine in the thickness direction of the polypyrrole shaped material is 50% or less. This polypyrrole shaped material enables charging and discharging at high current densities and has large charging and discharging capacities, and can therefore be utilized as an electrode for secondary battery.

摘要翻译： PCT No.PCT / JP91 / 01559 Sec。 371日期：1993年5月13日 102（e）日期1993年5月13日PCT 1991年11月14日PCT PCT。 出版物WO92 / 09112 一种聚吡咯型材料，其特征在于，当聚吡咯形状材料组装成包含聚吡咯形材料作为正极的三电极电池，作为负极的铂，作为参比电极的锂金属和 LiClO 4或LiBF 4作为电解质，并且所述三电极和电池以10mA / cm 2的电流密度和3.6V的控制电位充电进行放电，（i）在放电完成时，氯的浓度或 聚吡咯形状材料中的氟为充电结束时的30％以下，（ii）充电结束时，聚吡咯形状材料的厚度方向上的氯或氟的分布为50％， 减。 该聚吡咯形状材料能够以高电流密度充电和放电，并且具有大的充电和放电容量，因此可以用作二次电池的电极。

公开(公告)号：US4400519A

公开(公告)日：1983-08-23

申请号：US118238

申请日：1980-02-04

申请人： Tsuneo Hagiwara ,  Akihiro Horike

发明人： Tsuneo Hagiwara ,  Akihiro Horike

IPC分类号： C08K5/00 ,  C07D207/404 ,  C07D207/44 ,  C07D207/452 ,  C07D209/48 ,  C07D211/88 ,  C07D221/14 ,  C07D233/78 ,  C07D251/34 ,  C07D403/12 ,  C08F2/50 ,  C08K5/34 ,  C08K5/3477 ,  C08L23/00 ,  C08L67/00 ,  C08L101/00 ,  G03F7/031 ,  C07D403/14

CPC分类号： C07D207/452 ,  C07C265/00 ,  C07D209/48 ,  C07D211/88 ,  C07D221/14 ,  C07D233/78 ,  C07D251/34 ,  C08F2/50 ,  G03F7/031

摘要： Benzil-di-(.beta.-succinimidoethyl)ketal of the following structural formula ##STR1## and novel benzil ketal derivatives thereof. The novel benzil ketal derivatives are characterized by having a structure in which a 5- or 6-membered cyclic imidecontaining group is bonded to each of the two oxygen atoms of ketal. Because these compounds have a high decomposition or sublimation temperature and the ability to initiate photopolymerization, they are useful as photopolymerization initiators in the production of photopolymerizable shaped articles from a molten blend of a photopolymerizable thermoplastic polymer composition.

摘要翻译： 苯并二 - （β-琥珀酰亚氨基乙基）缩酮，其具有以下结构式（IMAGE）及其新型苯偶酰缩酮衍生物。 新型苯偶酰缩酮衍生物的特征在于具有其中5或6元环亚氨基基团与缩酮的两个氧原子中的每一个键合的结构。 由于这些化合物具有高的分解或升华温度和引发光聚合的能力，因此它们可用作由可光聚合的热塑性聚合物组合物的熔融共混物生产可光聚合的成型制品中的光聚合引发剂。

公开(公告)号：US08293810B2

公开(公告)日：2012-10-23

申请号：US11212711

申请日：2005-08-29

申请人： Takashi Ito ,  Tsuneo Hagiwara ,  Toshiyuki Ozai ,  Takeshi Miyao

发明人： Takashi Ito ,  Tsuneo Hagiwara ,  Toshiyuki Ozai ,  Takeshi Miyao

IPC分类号： C08F283/12 ,  C08F2/50 ,  C08J3/28 ,  G03F7/031 ,  C08G77/04 ,  C08G77/20 ,  C08L83/07

CPC分类号： C08F283/12 ,  B33Y70/00 ,  C08L83/08 ,  C08L83/00

摘要： A resin composition suited for rapid prototyping is provided comprising (I) an actinic energy radiation-curable silicone composition, (II) an actinic energy radiation-sensitive polymerization initiator, and (III) an actinic energy radiation absorber. The resin composition experiences little viscosity buildup and maintains fluidity during long-term storage at elevated temperature, and is effective in rapid prototyping or shaping by stereolithography using any actinic energy radiation.

摘要翻译： 提供了适用于快速成型的树脂组合物，其包括（I）光化能辐射可固化硅氧烷组合物，（II）光化能辐射敏感聚合引发剂，和（III）光化能辐射吸收剂。 树脂组合物在高温下长时间储存​​期间几乎不产生粘度增加并保持流动性，并且通过使用任何光化能量辐射的立体光刻技术在快速成型或成型中是有效的。