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公开(公告)号：US07745652B2
公开(公告)日：2010-06-29
申请号：US12328868
申请日：2008-12-05
申请人： Zenon Lysenko , Bob R. Maughon , Jozef Bicerano , Kenneth A. Burdett , Christopher P. Christenson , Clark H. Cummins , Marvin L. Dettloff , Alan K. Schrock , P. J. Thomas , Richard D. Varjian , Jerry E. White , John Michael Maher
发明人： Zenon Lysenko , Bob R. Maughon , Jozef Bicerano , Kenneth A. Burdett , Christopher P. Christenson , Clark H. Cummins , Marvin L. Dettloff , Alan K. Schrock , P. J. Thomas , Richard D. Varjian , Jerry E. White , John Michael Maher
IPC分类号： C07C51/43
CPC分类号： C07D303/42 , C07C67/31 , C07C67/333 , C07C67/347 , C07C67/56 , C07C69/533 , C07C227/08 , C07C227/18 , C07C229/08 , Y02P20/125 , C07C69/716 , C07C69/675
摘要： Integrated processes of preparing industrial chemicals starting from seed oil feedstock compositions containing one or more unsaturated fatty acids or unsaturated fatty acid esters, which are essentially free of metathesis catalyst poisons, particularly hydroperoxides; metathesis of the feedstock composition with a lower olefin, such as ethylene, to form a reduced chain olefin, preferably, a reduced chain α-olefin, and a reduced chain unsaturated acid or ester, preferably, a reduced chain α,ω-unsaturated acid or ester. The reduced chain unsaturated acid or ester may be (trans)esterified to form a polyester polyolefin, which may be epoxidized to form a polyester polyepoxide. The reduced chain unsaturated acid or ester may be hydroformylated with reduction to produce an α,ω-hydroxy acid or α,ω-hydroxy ester, which may be (trans)esterified with a polyol to form an α,ω-polyester polyol. Alternatively, the reduced chain unsaturated acid or ester may be hydroformylated with reductive amination to produce an α,ω-amino acid or α,ω-amino ester, which may be (trans)esterified to form an α,ω-polyester polyamine.
摘要翻译： 从含有一种或多种不饱和脂肪酸或不饱和脂肪酸酯的种子油原料组合物制备工业化学品的综合方法，其基本上不含复分解催化剂毒物，特别是氢过氧化物; 原料组合物与低级烯烃如乙烯的复分解以形成还原链烯烃，优选还原链α-烯烃和还原链不饱和酸或酯，优选还原链α，ω-不饱和酸 或酯。 还原链不饱和酸或酯可以（反式）酯化以形成聚酯聚烯烃，其可以被环氧化以形成聚酯多环氧化物。 还原链不饱和酸或酯可以通过还原加氢甲酰化以产生α，ω-羟基酸或α，ω-羟基酯，其可以与多元醇反应形成α，ω-聚酯多元醇。 或者，还原链不饱和酸或酯可以通过还原胺化加氢甲酰化以产生α，ω-氨基酸或α，ω-氨基酯，其可以（反式）酯化形成α，ω-聚酯多胺。
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12.发明申请MONOVINYLIDENE AROMATIC POLYMERS CONTAINING NONFUNCTIONALIZED, NONMINERAL OIL 审中-公开含有非官能化的非金属油的单甲氧基芳族聚合物公开(公告)号：US20100298486A1
公开(公告)日：2010-11-25
申请号：US12439956
申请日：2007-09-11
CPC分类号： C08L53/02 , C08K5/103 , C08L51/04 , C08L55/02 , C08L2666/04 , C08L2666/24 , C08L2666/02
摘要： Monovinylidene aromatic polymers, e.g., general purpose polystyrene or high impact polystyrene, are plasticized with a nonfunctionalized, nonmineral oil, e.g., a vegetable oil such as canola oil, cottonseed oil or the like. The mixture of monovinylidene aromatic polymer and oil is typically and preferably free of any significant amount of functionalized nonmineral oil, and it typically contains at least 0.1 weight percent of the nonfunctionalized, nonmineral oil, alone or in combination with a mineral oil, based on the weight of the polymer. The nonmineral oil has an iodine value of less than 120, and a hydroxyl number of less than 20.
摘要翻译： 单亚乙烯基芳族聚合物，例如通用聚苯乙烯或高抗冲聚苯乙烯，用非官能化的非矿物油（例如植物油如卡诺拉油，棉籽油等）增塑。 单亚乙烯基芳族聚合物和油的混合物通常且优选不含任何显着量的官能化非矿物油，并且其通常包含至少0.1重量％的非官能化非矿物油，单独或与矿物油组合，基于 聚合物的重量。 非矿物油的碘值小于120，羟基数小于20。
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公开(公告)号：US06849666B2
公开(公告)日：2005-02-01
申请号：US10332310
申请日：2001-05-15
申请人： Hanno R. Van der Wal , Mark F. Sonnenschein , Alan K. Schrock , Francois Casati , Christopher P. Christenson , Zenon Lysenko , Jozef Bicerano , Fabio Aguirre , Sudhakar Balijepalli
发明人： Hanno R. Van der Wal , Mark F. Sonnenschein , Alan K. Schrock , Francois Casati , Christopher P. Christenson , Zenon Lysenko , Jozef Bicerano , Fabio Aguirre , Sudhakar Balijepalli
CPC分类号： C08G18/4841 , C08G18/10 , C08G18/4018 , C08G18/409 , C08G18/4266 , C08G18/4277 , C08G2101/0008 , C08G2101/005 , C08G2101/0083 , C08G2250/00 , C08G18/48
摘要： A process is disclosed for producing resilient polyurethane foams by foaming an organic polyisocyanate, an iso-cyanate-reactive compound and a fusible polymer. The improvement in the hardness of the foams is achieved without adversely affecting the other properties of the foams, such as tensile strength and elongation.
摘要翻译： 公开了通过使有机多异氰酸酯，异氰酸酯反应性化合物和易熔聚合物发泡来生产弹性聚氨酯泡沫体的方法。 实现泡沫塑料的硬度的改善，而不会不利地影响泡沫的其它性能，例如拉伸强度和伸长率。
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公开(公告)号：US20090143544A1
公开(公告)日：2009-06-04
申请号：US12328868
申请日：2008-12-05
申请人： Zenon Lysenko , Bob R. Maughon , Jozef Bicerano , Kenneth A. Burdett , Christopher P. Christenson , Clark H. Cummins , Marvin L. Dettloff , Alan K. Schrock , P. J. Thomas , Richard D. Varjian , Jerry E. White , John Michael Maher
发明人： Zenon Lysenko , Bob R. Maughon , Jozef Bicerano , Kenneth A. Burdett , Christopher P. Christenson , Clark H. Cummins , Marvin L. Dettloff , Alan K. Schrock , P. J. Thomas , Richard D. Varjian , Jerry E. White , John Michael Maher
IPC分类号： C08L63/08 , C07C51/43 , C07C59/42 , C07C31/18 , C07C215/00 , C08L79/02 , C08L67/04 , C07C229/00 , C07C69/732 , C07C1/00
CPC分类号： C07D303/42 , C07C67/31 , C07C67/333 , C07C67/347 , C07C67/56 , C07C69/533 , C07C227/08 , C07C227/18 , C07C229/08 , Y02P20/125 , C07C69/716 , C07C69/675
摘要： Integrated processes of preparing industrial chemicals starting from seed oil feedstock compositions containing one or more unsaturated fatty acids or unsaturated fatty acid esters, which are essentially free of metathesis catalyst poisons, particularly hydroperoxides; metathesis of the feedstock composition with a lower olefin, such as ethylene, to form a reduced chain olefin, preferably, a reduced chain α-olefin, and a reduced chain unsaturated acid or ester, preferably, a reduced chain α,ω-unsaturated acid or ester. The reduced chain unsaturated acid or ester may be (trans)esterified to form a polyester polyolefin, which may be epoxidized to form a polyester polyepoxide. The reduced chain unsaturated acid or ester may be hydroformylated with reduction to produce an α,ω-hydroxy acid or α,ω-hydroxy ester, which may be (trans)esterified with a polyol to form an α,ωpolyester polyol. Alternatively, the reduced chain unsaturated acid or ester may be hydroformylated with reductive amination to produce an α,ω-amino acid or α,ω-amino ester, which may be (trans)esterified to form an α,ω-polyester polyamine.
摘要翻译： 从含有一种或多种不饱和脂肪酸或不饱和脂肪酸酯的种子油原料组合物制备工业化学品的综合方法，其基本上不含复分解催化剂毒物，特别是氢过氧化物; 原料组合物与低级烯烃如乙烯的复分解以形成还原链烯烃，优选还原链的α-烯烃和还原链不饱和酸或酯，优选还原链的α，ω-不饱和酸 或酯。 还原链不饱和酸或酯可以（反式）酯化以形成聚酯聚烯烃，其可以被环氧化以形成聚酯多环氧化物。 还原链不饱和酸或酯可以通过还原加氢甲酰化以产生α，ω-羟基酸或α，ω-羟基酯，其可以与多元醇反应形成α，ω-聚酯多元醇。 或者，还原链不饱和酸或酯可以通过还原胺化加氢甲酰化以产生α，ω-氨基酸或α，ω-氨基酯，其可以（反式）酯化形成α，ω-聚酯多胺。
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15.发明申请POLYURETHANE FOAMS MADE FROM HYDROXYMETHYL-CONTAINING POLYESTER POLYOLS AND TERTIARY AMINE-CONTAINING POLYOLS 审中-公开含羟基甲基的聚酯多元醇和仲胺含多元醇的聚氨酯泡沫公开(公告)号：US20100010110A1
公开(公告)日：2010-01-14
申请号：US12440269
申请日：2007-09-18
IPC分类号： C08G18/18
CPC分类号： C08G18/36 , C08G18/482 , C08G18/485 , C08G18/5021 , C08G2101/005 , C08G2101/0083
摘要： Flexible polyurethane foams are prepared by reacting a polyisocyanate with a high equivalent weight polyol. At least a portion of the high equivalent weight polyol is a polyester containing hydroxymethyl groups. The high equivalent weight polyol further includes species containing tertiary amine groups. The presence of tertiary amine-containing polyols in the formulation leads to improvements in resiliency, tensile and/or tear strength.
摘要翻译： 柔性聚氨酯泡沫通过使多异氰酸酯与高当量多元醇反应制备。 高当量多元醇的至少一部分是含有羟甲基的聚酯。 高当量多元醇还包括含有叔胺基团的物质。 制剂中含叔胺的多元醇的存在导致弹性，拉伸和/或撕裂强度的改善。
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16.发明申请POLYURETHANE ELASTOMERS MADE USING MIXTURES OF ALIPHATIC DIOL CHAIN EXTENDER AND SECONDARY AMINE 有权聚氨酯弹性体制造使用混合二氧化钛链延伸剂和二次胺公开(公告)号：US20130253084A1
公开(公告)日：2013-09-26
申请号：US13990488
申请日：2011-11-16
申请人： Rajat Duggal , Nathan Wilmot , Richard Keaton , Alan K. Schrock
发明人： Rajat Duggal , Nathan Wilmot , Richard Keaton , Alan K. Schrock
CPC分类号： C08G18/08 , C08G18/10 , C08G18/12 , C08G18/14 , C08G18/222 , C08G18/2865 , C08G18/325 , C08G18/3271 , C08G18/3275 , C08G18/3278 , C08G18/3281 , C08G18/6523 , C08G18/6529 , C08G18/6535 , C08G18/6614 , C08G18/6618 , C08G18/6622 , C08G18/6648 , C08G18/6651 , C08G18/6655 , C08G18/6681 , C08G18/6685 , C08G18/6688
摘要： Polyurethane elastomers are formed by curing a reaction mixture containing at least one polyisocyanate at least one polyol, an aliphatic diol chain extender and a small amount of a secondary amino compound that may have none or one or more hydroxyl groups. The reaction is catalyzed with a metal catalyst. In certain embodiments, the catalyst is an organozirconium, organotitanium or tertiary amine-based catalyst. The presence of the secondary amine compound in those cases provides for a good surface appearance and good physical properties.
摘要翻译： 通过固化含有至少一种多异氰酸酯的反应混合物形成聚氨酯弹性体，至少一种多元醇，脂族二醇增链剂和少量可以没有一个或一个或多个羟基的仲氨基化合物。 该反应用金属催化剂催化。 在某些实施方案中，催化剂是有机锆，有机钛或叔胺类催化剂。 在这些情况下，仲胺化合物的存在提供良好的表面外观和良好的物理性能。
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17.发明授权公开(公告)号：US06911487B2
公开(公告)日：2005-06-28
申请号：US10015815
申请日：2001-11-02
IPC分类号： C08G18/10 , C08F257/02 , C08F265/04 , C08F279/02 , C08F283/00 , C08G18/00 , C08G18/08 , C08G18/12 , C08G18/28 , C08G18/40 , C08G18/48 , C08G18/66 , C08G18/67 , C08G18/75 , C09D175/04 , C08F2/16 , C08J3/00 , C08J5/18 , C08L75/04
CPC分类号： C08G18/758 , C08F257/02 , C08F265/04 , C08F279/02 , C08F283/006 , C08G18/0866 , C08G18/12 , C08G18/283 , C08G18/4018 , C08G18/4841 , C08G18/6674 , C08G18/672 , C08G2270/00 , Y10S525/902 , C08G18/305 , C08G18/302 , C08G18/3246
摘要： Dispersions of hybrid polyurethane particles are made using miniemulsion techniques. An isocyanate-terminated prepolymer and a monomer are mixed and dispersed in an aqueous phase to form a dispersion of droplets. All droplets are polymerized and chain-extended in one step to form hybrid particles containing a polyurethane and a polymer of the monomer. This process provides a simple method of making hybrid particles, in which particle size and the number of particles is controlled in the mixing step. The hybrid particles often have a core-shell morphology, with the polyurethane being concentrated in the shell and the polymer being concentrated in the center of the particle.
摘要翻译： 使用细乳液技术制备混合聚氨酯颗粒的分散体。 将异氰酸酯封端的预聚物和单体混合并分散在水相中以形成液滴的分散体。 所有液滴在一个步骤中聚合和链延伸以形成含有聚氨酯和单体聚合物的混合颗粒。 该方法提供了制备混合颗粒的简单方法，其中在混合步骤中控制颗粒尺寸和颗粒数量。 杂化颗粒通常具有核 - 壳形态，其中聚氨酯被集中在壳中，并且聚合物被浓缩在颗粒的中心。
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18.发明授权Polyurethane foams prepared from mechanically frothed polyurethane dispersions 有权由机械起泡的聚氨酯分散体制备的聚氨酯泡沫公开(公告)号：US06271276B1
公开(公告)日：2001-08-07
申请号：US09464113
申请日：1999-12-16
申请人： Michael Y. Gribble , Rick L. Tabor , James J. Jakubowski , Alan K. Schrock , Paulus C. J. M. Van Bellegem , James G. Kennedy
发明人： Michael Y. Gribble , Rick L. Tabor , James J. Jakubowski , Alan K. Schrock , Paulus C. J. M. Van Bellegem , James G. Kennedy
IPC分类号： C08J900
CPC分类号： C08J9/30 , C08G18/0866 , C08G18/12 , C08G18/283 , C08J2375/04 , D06N3/14 , D06N7/0073 , D06N7/0086 , D06N2203/041 , D06N2203/042 , D06N2203/047 , D06N2203/048 , D06N2203/068 , D06N2209/1685 , Y10T428/249976 , C08G18/3246
摘要： The present invention is polyurethane dispersion composition that can be mechanically frothed to yield a foam that has good resiliency. Frothed foams of the present invention can be useful in cushioned flooring applications such as attached cushion broadloom, carpet tiles, carpet underlay, or vinyl flooring. Frothed foams of the present invention can also be useful as coatings for various textiles and for diapers.
摘要翻译： 本发明是可以机械发泡以产生具有良好弹性的泡沫的聚氨酯分散体组合物。 本发明的起泡泡沫可用于缓冲地板应用，例如附着的缓冲宽幅布，地毯，地毯底层或乙烯基地板。 本发明的起泡沫也可用作各种纺织品和尿布的涂料。
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19.发明授权Process for the preparation of arylcyclobutene terminated condensation polymers 失效制备ARYLCYCLOBUTENE终止凝聚聚合物的方法
公开(公告)号：US5171824A
公开(公告)日：1992-12-15
申请号：US632868
申请日：1990-12-24
IPC分类号： C08G63/00 , C08G63/20 , C08G63/64 , C08G64/00 , C08G64/14 , C08G64/20 , C08G64/22 , C08G64/26 , C08G64/30 , C08G85/00
摘要： In an improved process condensation polymers having terminal arylcyclobutene moieties are prepared. Such polymers are prepared by adding to a condensation polymerization process one or more arylcyclobutene chain terminating compounds along with the multi-hydric compounds and condensation polymer precursors that are typically employed in such a process. Desirably the condensation polymers have an average degree of polymerization of at least about 2, preferably at least about 3 based on multi-hydric compound. This process can be used to prepare a range of condensation polymers including polycarbonates, polyesters and polyester-carbonates. The resulting products can be easily processed and shaped into various forms and structures according to the known techniques. During or subsequent to the processing, the polymers can be crosslinked, by exposure to heat or radiation, for example, to provide crosslinked polymer compositions. These compositions have a good combination of properties, including for example, processability into shaped articles having unexpectedly good combinations of toughness, solvent resistance, ignition resistance, modulus and resistance to thermal linear expansion.
摘要翻译： 在改进的方法中，制备具有末端芳基环丁烯部分的缩合聚合物。 这样的聚合物通过在缩合反应过程中加入一种或多种芳基环丁烯链终止化合物以及通常用于这种方法中的多羟基化合物和缩聚物前体而制备。 理想地，缩合聚合物的平均聚合度基于多羟基化合物至少约2，优选至少约3。 该方法可用于制备一系列缩合聚合物，包括聚碳酸酯，聚酯和聚酯 - 碳酸酯。 所得产品可以根据已知技术容易地加工成各种形式和结构。 在加工期间或之后，聚合物可以通过暴露于热或辐射而交联，例如提供交联的聚合物组合物。 这些组合物具有良好的性能组合，包括例如具有出乎意料的良好的韧性，耐溶剂性，耐点火性，模量和耐热线性膨胀组合的成型制品的加工性能。
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公开(公告)号：US5145953A
公开(公告)日：1992-09-08
申请号：US151682
申请日：1988-02-02
IPC分类号： C07C245/08 , C07C245/10 , C09B27/00 , C09B69/10
CPC分类号： C07C245/10 , C07C245/08 , C09B27/00 , C09B69/106 , C07C2102/06 , Y10S534/03
摘要： A biscyclobutarene monomer is prepared having two cyclobutarene moieties bridged by a divalent radical having at least one azo linkage. The monomers can be polymerized to form polymers exhibiting outstanding thermooxidative stability at high temperatures for prolonged time periods.
摘要翻译： 制备具有由具有至少一个偶氮键的二价基团桥连的两个环丁烷部分的双环丁腈单体。 单体可以聚合以形成在高温下长时间显示出优异的热氧化稳定性的聚合物。
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