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    Oxime Derivatives And Use Thereof As Latent Acids
    17.
    发明申请
    Oxime Derivatives And Use Thereof As Latent Acids 有权
    肟衍生物及其用作潜伏酸

    公开(公告)号：US20080085458A1

    公开(公告)日：2008-04-10

    申请号：US11632687

    申请日：2005-07-11

    Applicant: Hitoshi Yamato ,  Toshikage Asakura ,  Tobias Hintermann

    Inventor： Hitoshi Yamato ,  Toshikage Asakura ,  Tobias Hintermann

    IPC: C07C291/06 ,  C07D209/56 ,  G03F1/00

    CPC classification number: C07C309/67 ,  B33Y70/00 ,  C07C309/65 ,  C07C309/73 ,  C07C309/74 ,  C07C309/75 ,  C07C381/00 ,  C07C2603/18 ,  C07C2603/20 ,  C07C2603/66 ,  C07D209/86 ,  C07F9/097 ,  G03F7/0007 ,  G03F7/0045 ,  G03F7/0382 ,  G03F7/0392 ,  Y10S430/12

    Abstract: The invention pertain to novel photoacid generator compounds of the formula I, II or III wherein R1 is for example C1-C18alkylsulfonyl or phenylsulfonyl, phenyl-C1-C3alkylsulfonyl, naphthylsulfonyl, anthracylsulfonyl or phenanthrylsulfonyl, all optionally substituted, or R1 is a group X1, X2 and X3 independently of each other are O or S; R′1, is e.g. phenylenedisulfonyl, naphthylenedisulfonyl, diphenylenedisulfonyl, or oxydiphenylenedisulfonyl, all optionally substituted; R2 is halogen or C1-C10haloalkyl; X is halogen; Ar1 is for example biphenylyl or fluorenyl, or is substituted naphthyl; Ar′1 is heteroarylene, optionally substituted; R8, R9, R10 and R11 for example are C1-C6alkyl which is unsubstituted or substituted by halogen; or R8, R9 and R10 are phenyl which is unsubstituted or substituted by C1-C4alkyl or halogen; or R10 and R11 together are 1,2-phenylene or C2-C6alkylene which is unsubstituted or substituted by C1-C4alkyl or halogen.

    Abstract translation: 本发明涉及式I，II或III的新型光酸产生剂化合物，其中R 1是例如C 1 -C 18烷基磺酰基或 苯基磺酰基，苯基-C 1 -C 3烷基磺酰基，萘基磺酰基，蒽基磺酰基或菲基磺酰基，全部任意取代，或R 1是基团X， X 1，X 2和X 3 3彼此独立地为O或S; R'1，例如， 亚苯基二磺酰基，亚苯基二磺酰基，二苯基二磺酰基或氧基二苯基二磺酰基，全部任选被取代; R 2是卤素或C 1 -C 10卤代烷基; X是卤素; Ar 1是例如联苯基或芴基，或者是取代的萘基; Ar'1'是亚杂芳基，任选被取代; R 8，R 9，R 10和R 11是例如C 1〜N 未取代或被卤素取代的C 1 -C 6烷基; 或R 8，R 9和R 10是未被取代或被C 1 -C 3烷基取代的苯基， 烷基或卤素; 或R 10和R 11一起是1,2-亚苯基或C 2 -C 6 -C 6亚烷基，其是 未取代或被C 1 -C 4烷基或卤素取代。

    Oxime derivatives and the use thereof as photoinitiators
    18.
    发明授权
    Oxime derivatives and the use thereof as photoinitiators 有权
    肟衍生物及其作为光引发剂的用途

    公开(公告)号：US06806024B1

    公开(公告)日：2004-10-19

    申请号：US09914433

    申请日：2001-08-27

    Applicant: Hisatoshi Kura ,  Hitoshi Yamato ,  Masaki Ohwa ,  Kurt Dietliker

    Inventor： Hisatoshi Kura ,  Hitoshi Yamato ,  Masaki Ohwa ,  Kurt Dietliker

    IPC: G03F7004

    CPC classification number: G03F7/031 ,  B33Y70/00 ,  C07C309/66 ,  C07C309/73 ,  C07C323/57 ,  C07C381/00 ,  C07D307/66 ,  C07D333/36 ,  C07D339/08 ,  C07F9/097 ,  C07F9/655345 ,  C08F2/50 ,  Y10S430/12 ,  Y10S430/123

    Abstract: Radically photopolymerizable compositions comprising (a) at least one ethylenically unsaturated photopolymerizable compound; (b) as photoinitiator, at least one compound of formulae (I, II, III, IV, V and/or VI), wherein m is 0 or 1; n is 0, 1, 2 or 3; x is 1 or 2; R1 is inter alia phenyl, naphthyl, anthracyl or phenanthryl, a heteroaryl radical, C2-C12alkenyl, C4-C8cycloalkenyl, or C6-C12bicycloalkenyl; R′1 is inter alia C2-C12alkylene, or phenylene; R2 has one of the meanings of R1 or inter alia is phenyl; y is 1 or 2; R3 if x is 1 inter alia is C1-C18alkylsulfonyl, or phenyl-C1-C3alkylsulfonyl, R3 if x is 2, is for example C2-C12alkylenedisulfonyl; R4 and R5 inter alia are hydrogen, halogen, or C1-C8alkyl; R6, R7, R8 inter alia are hydrogen, R26Y—, or phenyl; R9 inter alia is C5-C8cycloalkyl, or phenyl; A is for example —S—, —O—, or —NR10—; Q is C1-C8-alkylene optionally interrupted by —O—; X is —O— or —NR9—; R10 inter alia is hydrogen, or phenyl; and (c) at least one coinitiator; are especially suitable for the preparation of color filter systems.

    Abstract translation: 自由基光聚合组合物，其包含（a）至少一种烯属不饱和光聚合化合物; （b）作为光引发剂，至少一种式（I，II，III，IV，V和/或VI）的化合物，其中m为0或1; n为0,1,2或3; x为1或2; R 1特别是苯基，萘基，蒽基或菲基，杂芳基，C 2 -C 12烯基，C 4 -C 8环烯基或C 6 -C 12双环烯基; R'1特别是C 2 -C 12亚烷基或亚苯基; R2具有R 1的含义之一，尤其是苯基; y为1或2; 如果x是1，则R3如果是C 1 -C 18烷基磺酰基，或苯基-C 1 -C 3烷基磺酰基，如果x是2，则R 3是例如C 2 -C 12亚烷基二磺酰基; R4和R5尤其是氢，卤素或C1-C8烷基; R6，R7，R8特别是氢，R26Y-或苯基; R9尤其是C5-C8环烷基或苯基; A是例如-S-，-O-或-NR 10 - ; Q是任选被-O-间隔的C1-C8-亚烷基; X是-O-或-NR 9 - ; R 10尤其是氢或苯基; 和（c）至少一种共引发剂; 特别适用于制备滤色器系统。

    Halo-substituted oxime carbamates
    20.
    发明授权
    Halo-substituted oxime carbamates 失效
    HALO取代的氧化碳酸盐

    公开(公告)号：US3748361A

    公开(公告)日：1973-07-24

    申请号：US3748361D

    申请日：1971-04-28

    Applicant: EXXON RESEARCH ENGINEERING CO

    Inventor： ROSENFELD D ,  LIPPINCOTT S ,  KILSHEIMER J

    IPC: A01N57/06 ,  C07F9/09 ,  C07F9/165 ,  C07F9/40 ,  C07C

    CPC classification number: A01N57/06 ,  C07F9/097 ,  C07F9/1657 ,  C07F9/4096

    Abstract: MONO OR POLY HALO-SUBSTITUTED OXIME CARBAMATES AND PHOSPHATES CHARACTERIZED BY EITHER ONE OF THE FOLLOWING FORMULAS:

    R-C6H4-C(-CF3)=N-O-C(=Y)-N(-R'')-R", OR R-C6H4-C(-CF3)=

    N-O-P(=Y)(-R'')-O-R"

    WHERE X IS HALOGEN.

    R-C6H4-CO-C(-X)3

    WHEREIN R IS ONE SELECTED FROM THE GROUP CONSISTING OF HYDROGEN, METHYL, ISOPROPYL, ETHYL, TRIFLUOROMETHYL, FLUORINE, CHLORINE, BROMINE, METHOXY, METHYLTHIO, NITRO, DIMETHYLAMINO, ETHOXY, AND ISOPROPYLOXY; R'' IS ONE SELECTED FROM THE GROUP CONSISTING OF OR", C1 TO C6 ALKYL, C6 TO C10 ARYL, SUBSTITUTED ALKYL OR ARYL WHEREIN SAID SUBSTITUENT GROUPS ARE SELECTED FROM THE GROUP CONSISTING OF METHYL, ETHYL, TRIFLUOROMETHYL, FLUORINE, CHLORINE, BROMINE; R" IS C1 TO C6 ALKYL, C6 TO C10 ARYL, SUBSTITUTED ALKYL, ARYL WHEREIN THE SUBSTITUENTS ARE THE SAME AS THAT ENUMERATED FOR R''; Y IS S OR O. THESE COMPOUNDS HAVE SHOWN ACTIVITY AS INSECTICIDES. SUCH OXIME CARBAMATES AND PHOSPHATES CAN BE PREPARED FROM KETONES SUCH AS THOSE OF THE FORMULA:

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