2-STEP IRON CONVERSION SYSTEM
    11.
    发明公开

    公开(公告)号:US20230366115A1

    公开(公告)日:2023-11-16

    申请号:US18226626

    申请日:2023-07-26

    CPC classification number: C25C1/06 C25C7/02 C22B3/06 C25C7/04 C22B5/00

    Abstract: Methods and systems for producing are disclosed. A method for producing iron, for example, comprises: providing an iron-containing ore to a dissolution subsystem comprising a first electrochemical cell; wherein the first anolyte has a different composition than the first catholyte; dissolving at least a portion of the iron-containing ore using an acid to form an acidic iron-salt solution having dissolved first Fe3+ ions; providing at least a portion of the acidic iron-salt solution to the first cathodic chamber; first electrochemically reducing said first Fe3+ ions in the first catholyte to form Fe2+ ions; transferring the formed Fe2+ ions from the dissolution subsystem to an iron-plating subsystem having a second electrochemical cell; second electrochemically reducing a first portion of the transferred formed Fe2+ ions to Fe metal at a second cathode of the second electrochemical cell; and removing the Fe metal.

    2-step iron conversion system
    14.
    发明授权

    公开(公告)号:US11767604B2

    公开(公告)日:2023-09-26

    申请号:US17884260

    申请日:2022-08-09

    CPC classification number: C25C1/06 C22B3/06 C22B5/00 C25C7/02 C25C7/04

    Abstract: Methods and systems for producing are disclosed. A method for producing iron, for example, comprises: providing an iron-containing ore to a dissolution subsystem comprising a first electrochemical cell; wherein the first anolyte has a different composition than the first catholyte; dissolving at least a portion of the iron-containing ore using an acid to form an acidic iron-salt solution having dissolved first Fe3+ ions; providing at least a portion of the acidic iron-salt solution to the first cathodic chamber; first electrochemically reducing said first Fe3+ ions in the first catholyte to form Fe2+ ions; transferring the formed Fe2+ ions from the dissolution subsystem to an iron-plating subsystem having a second electrochemical cell; second electrochemically reducing a first portion of the transferred formed Fe2+ ions to Fe metal at a second cathode of the second electrochemical cell; and removing the Fe metal.

    OXYGEN-GENERATING ELECTRODE
    15.
    发明公开

    公开(公告)号:US20230279568A1

    公开(公告)日:2023-09-07

    申请号:US18005795

    申请日:2021-05-26

    CPC classification number: C25B11/093 C25B1/02 C25B11/052 C25C7/02 C25B11/063

    Abstract: The present invention provides an oxygen generation electrode provided with a catalyst layer having a high specific electric conductivity, and having excellent durability such that even when an acidic electrolyte is electrolyzed, the catalyst components are unlikely to be consumed and long-term electrolysis can be performed. The oxygen generation electrode is an oxygen generation electrode 10 provided with a substrate 2 formed with titanium or a titanium alloy, and a catalyst layer 4 disposed on the substrate 2 and formed with a mixed metal oxide, wherein the catalyst layer 4 satisfies at least any one of the following condition (1) and condition (2). Condition (1): containing ruthenium, tin, and trivalent or higher polyvalent metal element excluding a tetravalent metal element. Condition (2): containing ruthenium and tin, and having a content of ruthenium of 40 mol % or more based on the total content of the ruthenium and tin.

    Polyoxometalate derivatized metal oxide electrodes

    公开(公告)号:US11725293B2

    公开(公告)日:2023-08-15

    申请号:US16599555

    申请日:2019-10-11

    CPC classification number: C25B11/091 C25B1/55 C25C1/22 C25C7/02 G01N27/305

    Abstract: A porous transparent electrode is formed where a film comprising of semiconducting nanoparticles is decorated with polyoxometalates (POMs) bonded to their surfaces. The semiconducting nanoparticles are transparent metal oxide. The semiconducting nanoparticles include tin-doped indium oxide (ITO), fluorine-doped tin oxide (FTO), or titanium dioxide (TiO2). In an embodiment, the POM is [SiW12O40]4−; [α-P2W18O62]6−; or [α2-P2W17O61]10−. The semiconducting nanoparticles bond to the POM through a combination of electrostatic interactions and hydrogen bonds. The porous transparent electrode can be placed in a protonated form or ion-paired with alkali metal cations or tetraalkylammonium cations.

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