Process for photochlorination
    13.
    发明授权
    Process for photochlorination 失效
    光氯化工艺

    公开(公告)号:US5944962A

    公开(公告)日:1999-08-31

    申请号:US18322

    申请日:1998-02-03

    CPC classification number: C07C17/395

    Abstract: An improvement in the process for the photochlorination of liquid mixtures of 2 to 6 carbon-containing aliphatic hydrofluorohalocarbons or hydrofluorocarbons and unsaturated hydrocarbons with ultraviolet light is disclosed. The improvement comprises using ultraviolet light emitted from an ultraviolet light source that delivers from about 0.01 to about 0.10 Einsteins per inch of arc at an input power of from about 0.50 to about 4.0 watts per inch of arc at a wavelength that is substantially the same as the wavelength absorption band of chlorine.

    Abstract translation: 公开了使用2至6个含碳脂族氢氟卤烃或氢氟碳烷和不饱和烃与紫外线的液体混合物进行光氯化的方法的改进。 该改进包括使用从紫外光源发射的紫外光,其输出功率为每英寸电弧约0.50至约4.0瓦特,每英寸弧度的大约0.01至大约0.10埃因斯坦,其波长基本相同 氯的波长吸收带。

    Cooling by conversion of para to ortho-hydrogen
    14.
    发明授权
    Cooling by conversion of para to ortho-hydrogen 失效
    通过将para转化为邻位氢进行冷却

    公开(公告)号:US4393039A

    公开(公告)日:1983-07-12

    申请号:US301075

    申请日:1981-09-10

    Applicant: Allan Sherman

    Inventor: Allan Sherman

    CPC classification number: C01B3/0089

    Abstract: The cooling capacity of a solid hydrogen cooling system is significantly increased by exposing vapor created during evaporation of a solid hydrogen mass to a catalyst and thereby accelerating the endothermic para-to-ortho transition of the vapor to equilibrium hydrogen. Catalysts such as nickel, copper, iron or metal hydride gels of films of nickel, copper or iron or hydride gels of nickel, copper or iron in a low pressure drop catalytic reactor are suitable for accelerating the endothermic para-to-ortho conversion.

    Abstract translation: 通过将固体氢物质蒸发期间产生的蒸气暴露于催化剂,从而加速蒸汽的吸附对 - 邻位过渡到平衡氢,固体氢冷却系统的冷却能力显着提高。 在低压降催化反应器中,诸如镍,铜,铁或金属氢化物的镍,铜或铁或氢,镍或铜的氢化物凝胶的催化剂适合于加速吸热对位转化。

    Process for recovering evolved hydrogen enriched with at least one heavy
hydrogen isotope
    15.
    发明授权
    Process for recovering evolved hydrogen enriched with at least one heavy hydrogen isotope 失效
    用于回收富含至少一种重氢同位素的进化氢的方法

    公开(公告)号:US4075312A

    公开(公告)日:1978-02-21

    申请号:US804124

    申请日:1977-06-06

    CPC classification number: C01B4/00 C01B3/00 C01B3/0031 Y02E60/327

    Abstract: This invention relates to a separation means and method for enriching a hydrogen atmosphere with at least one heavy hydrogen isotope by using a solid titaniun alloy hydride. To this end, the titanium alloy hydride containing at least one metal selected from the group consisting of vanadium, chromium, manganese, molybdenum, iron, cobalt and nickel is contacted with a circulating gaseous flow of hydrogen containing at least one heavy hydrogen isotope at a temperature in the range of -20.degree. to +40.degree. C and at a pressure above the dissociation pressure of the hydrided alloy selectively to concentrate at least one of the isotopes of hydrogen in the hydrided metal alloy. The contacting is continued until equilibrium is reached, and then the gaseous flow is isolated while the temperature and pressure of the enriched hydride remain undisturbed selectively to isolate the hydride. Thereafter, the enriched hydrogen is selectively recovered in accordance with the separation factor (S.F.) of the alloy hydride employed.

    Abstract translation: 本发明涉及通过使用固体钛合金氢化物富集至少一种重氢同位素的氢气氛的分离方法和方法。 为此,含有选自钒,铬,锰,钼,铁,钴和镍中的至少一种金属的钛合金氢化物与含有至少一种重氢同位素的氢气循环气流在 温度在-20℃至+ 40℃的范围内,并且在高于氢化合金的解离压力的压力下选择性地浓缩氢化金属合金中至少一种氢同位素。 继续接触直到达到平衡,然后分离气流,同时富集氢化物的温度和压力保持不受干扰以分离氢化物。 此后,根据所用合金氢化物的分离因子(S.F.)选择性地回收富集氢。

    Method for producing high temperature hydrogen
    16.
    发明授权
    Method for producing high temperature hydrogen 失效
    生产高温氢的方法

    公开(公告)号:US3948700A

    公开(公告)日:1976-04-06

    申请号:US522157

    申请日:1974-11-08

    CPC classification number: H01S3/095 C01B3/00 C01B4/00 C06B27/00 C06D5/00

    Abstract: A storable solid propellant composition based on unsolvated aluminum deutde or unsolvated aluminum hydride and ferric oxide is provided for use in a method for producing high temperature hydrogen or deuterium that is acceptable for use in HF/DF and HCl chemical laser, the gas dynamic laser (GDL), or a source to generate chemically pure and hot hydrogen gas as a reducing fuel.

    Abstract translation: 提供了一种基于非溶剂型氘化铝或未溶剂化氢化铝和三氧化二铁的可储存的固体推进剂组合物,用于生产HF / DF和HCl化学激光器中可接受的高温氢或氘的方法,气体动态激光 GDL)或源,以产生化学纯的和热的氢气作为还原燃料。

    Method of producing an homogeneous gas mixture
    17.
    发明授权
    Method of producing an homogeneous gas mixture 失效
    制备均质气体混合物的方法

    公开(公告)号:US3946104A

    公开(公告)日:1976-03-23

    申请号:US486495

    申请日:1974-07-08

    CPC classification number: C01C1/0405 B01F5/045 B01J8/0492 C07C29/152 Y02P20/52

    Abstract: A method for the production of a homogenous gas mixture from two gas streams of different parameters in which an open or free equalizing space downstream of a superimposed catalyst layer is provided. Within such open space is a mixing assembly imposing a little deflection upon the reaction gas stream causing a low pressure drop in the stream with a consequent reduced loss of energy. Quench gas is admitted through a two stage pressure reduction. It is first expanded from a duct surrounding the mixing assembly through a plurality of openings where the gas velocities are reduced and equalized. The second pressure reduction takes place across openings in the mixing assembly. Quench gas and reaction gas are then thoroughly mixed in the mixing assembly and the gas mixture is consequently passed to the entrance of a second catalyst layer downstream.

    Abstract translation: 一种用于从不同参数的两个气流生产均匀气体混合物的方法,其中提供了叠加的催化剂层下游的开放或自由均衡空间。 在这样的开放空间内是混合组件,其在反应气流上施加一点偏转,导致流中的低压降,从而减少能量的损失。 淬火气体通过两阶段减压进入。 它首先从混合组件周围的管道膨胀通过多个开口,其中气体速度被减小和均衡。 第二减压发生在混合组件中的开口处。 然后将骤冷气体和反应气体在混合组件中充分混合,然后将气体混合物通入下游的第二催化剂层的入口。

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