摘要:
Modified copolymers of vinyl aromatic compounds or diene hydrocarbons with diisopropenylbenzene. They contain at least 0.2% of polymerized units of a group of the general formulaThe copolymers are intermediates in the manufacture of block copolymers and graft copolymers suitable for use as impact-resistant plastics or polymeric antistatic agents.
摘要:
Described are lanthanide-containing metal coordination complexes which may be used as precursors in thin film depositions, e.g. atomic layer deposition processes. More specifically, described are homoleptic lanthanide-aminoalkoxide metal coordination complexes, lanthanide-carbohydrazide metal coordination complexes, and lanthanide-diazadiene metal coordination complexes. Additionally, methods for depositing lanthanide-containing films through an atomic layer deposition process are described.
摘要:
An improved process and method for the formation of stable intermediate cyclophanes. Embodiments describe a general method for the production of substituted and unsubstituted cyclophanes. The components include a pyrolysis reaction tube that may be electrically heated into which a flowing stream of nitrous oxide with xylene vapor in an optional inert carrier gas at atmospheric pressure. The exit gas is condensed resulting in the deposition of [2,2′]paracyclophane. Additionally a process and method whereby the reactive intermediates of the reaction described above can be directly deposited and polymerized at atmospheric pressures or thereabout is disclosed.
摘要:
Carbon nanotube (CNT) yarns and sheets having enhanced mechanical strength using infused and bonded nano-resins. A CNT yarn or sheet is surface-activated to produce open bonds in the CNT walls prior to resin infusion. The CNT yarn or sheet is infused with a low viscosity nano-resin that penetrates spaces between individual CNTs and is cured to cross-link and chemically bond to the CNT walls, either directly or through a functional molecule, to bond the individual CNTs or ropes to each other. The nano-resin can comprise dicyclopentadiene having an uncured viscosity near that of water. The cross-linking process involves ring-opening metathesis polymerization and catalysis of the nano-resin in combination with a functionalizing material such as norbornene, to enhance bonding between the carbon and nano-resin. The process increases load capability, tensile strength, and elastic modulus of the yarns and sheets, for use as a structural component in composite materials.
摘要:
The present invention relates to a monomodal coupled diene elastomer having a silanol functional group in the middle of the chain, to its process of preparation and to a rubber composition which can be used in particular in the manufacture of tyre covers, having improved hysteresis and physical properties in the vulcanized state and an improved processing in the raw state, comprising a monomodal diene polymer having a silanol functional group in the middle of the chain and a reinforcing inorganic filler.The process for obtaining this elastomer having a silanol functional group in the middle of the chain comprises a reaction of the diene monomer(s) and of the polymerization initiator in the presence of a chelating polar agent, a reaction of the living diene polymer with a coupling agent and then, after hydrolysis, a recovery of the coupled diene polymer having a functional group in the middle of the chain.A rubber composition according to the invention comprises a reinforcing inorganic filler and this monomodal elastomer having a silanol functional group in the middle of the chain.
摘要:
In an isoolefin-diolefin rubber production process (e.g. a butyl rubber production process), the cold rubber slurry produced in the reaction vessel is transported from the reaction vessel to the flash tank during which time the cold slurry may be expressed to separate at least part of the cold liquid reaction medium from the isoolefin-diolefin rubber. The separated cold liquid reaction medium is transported off stream, for example by a mechanical filter, where it can be recycled back into the reaction vessel and/or where it can be used to cool a feed stream or streams of the reaction components. The isoolefin-diolefin rubber and the residual liquid reaction medium are transported to a flash tank for further processing. The ability to separate and recycle cold liquid reaction medium makes the process more economical. In one aspect, the slurry may be transported from the reaction vessel to the flash tank by a self-cleaning fully intermeshing co-rotating twin screw extruder, which helps overcome the problem of plugging due to rubber sticking to the surfaces of the slurry transfer apparatus.
摘要:
The molecular weight of a liquid, linear dead polymer terminated with an alpha-alkoxyalkyl ether group, is increased by heating with an acid catalyst in the absence of a solvent.
摘要:
The present invention relates, in particular, to a coating composition, cross-linkable under the action of UV-visible radiation, which has the advantage of being thermoformable and having excellent scratch and abrasion resistant properties. The present invention also relates to a method for preparing a thermoformable coating, resistant to scratches and abrasion, comprising the cross-linking of a composition according to the invention under the action of UV-visible radiation. The present invention also relates to a method for protecting a substrate against scratches and abrasion, preferably said substrate being thermoformable or thermodrapable. The present invention also relates to a coated article, resistant to scratches and abrasion, preferably a thermoformable or thermodrapable coated article that can be obtained by a method according to the invention, as well as the use of a composition according to the invention to protect a possibly thermoformable or thermodrapable substrate against scratches and abrasion. The present invention also relates to the use of a composition according to the invention for preparing thermoformable coatings, resistant to scratches and abrasion. The present invention further relates to a thermoformable coating, resistant to scratches and abrasion, characterised in that it results from cross-linking under the action of UV-visible radiation at least one composition according to the invention.
摘要:
A silanized surface, stable selective dehydration catalyst for dienes production, a method for producing a silanized surface, stable, selective dehydration catalyst, and a method for dehydrating at least one of an alkenol and a diol to a diene. The present invention also relates to the fermentation of sugars to afford bio-alkenols that are then separated and converted to a diene using a dehydration catalyst and a method for converting alkenols or diols to dienes with high selectivity and conversion. The dienes are useful in preparing synthetic rubber, plastics copolymers, and fuels.
摘要:
A golf ball having a good rebound and excellent flight performance can be obtained using a golf ball composition which includes a diene polymer containing not more than 1.5% of components having a molecular weight of 30,000 or less.