公开(公告)号：US4621103A

公开(公告)日：1986-11-04

申请号：US645489

申请日：1984-08-29

Applicant: Masao Kosuge ,  Junji Fukuda

Inventor： Masao Kosuge ,  Junji Fukuda

IPC: B01D59/30 ,  B01J41/04 ,  B01J41/14 ,  B01J41/20 ,  B01J45/00 ,  B01J49/00 ,  C08F8/00 ,  C08F8/30 ,  C08F8/32 ,  G01N30/88 ,  G01N30/96

CPC classification number: B01D59/30 ,  B01J41/14 ,  B01J41/20

Abstract: An anion exchange resin for separating boron isotopes which is a resin having an aminopolyol group as a functional group and has been treated with an alkali solution containing:A: an alkali metal hydroxide or ammonium hydroxide; andB: an alkali metal salt or an ammonium saltand which is to be used in steps comprising passing a boric acid solution through a column packed with said resin to form a boric acid adsorption band and thereafter developing said adsorption band with an acid solution thereby separating boron isomers.

Abstract translation: 一种阴离子交换树脂，用于分离作为官能团的具有氨基多元醇基团的树脂的硼同位素，并且已经用碱性溶液处理：A：碱金属氢氧化物或氢氧化铵; 和B：碱金属盐或铵盐，其用于将硼酸溶液通过填充有所述树脂的柱形成硼酸吸附带并随后用酸溶液显影所述吸附带的步骤 分离硼异构体。

公开(公告)号：US4585559A

公开(公告)日：1986-04-29

申请号：US625539

申请日：1984-06-28

Applicant: Irving W. DeVoe ,  Bruce E. Holbein

Inventor： Irving W. DeVoe ,  Bruce E. Holbein

IPC: A23L2/42 ,  A23L2/78 ,  A23L3/3463 ,  A61L2/16 ,  B01J45/00 ,  C01F15/00 ,  C02F1/64 ,  C12H1/052 ,  C12P9/00 ,  C22B3/18 ,  C22B3/26 ,  C22B3/32 ,  B01D15/00

CPC classification number: A23L3/3463 ,  A23L2/42 ,  A23L2/78 ,  A61L2/16 ,  B01J45/00 ,  C01F15/00 ,  C02F1/64 ,  C12H1/0416 ,  C12P9/00 ,  C22B3/0008 ,  C22B3/0024 ,  C22B3/18 ,  Y02P10/234 ,  Y10S210/912

Abstract: The present invention relates to insoluble compositions, which are capable of removing metal (e.g. selectively) from solution (e.g. Fe.sup.3+ from a liquid nutrient medium so as to lower the Fe.sup.3+ content to less than 0.1 .mu.M); the insoluble compositions comprise: a suitable insoluble carrier and organic co-ordinating sites covalently fixed to the surface of said carrier, said co-ordinating sites being capable of chelating Fe.sup.3+, Th.sup.4+ and/or UO.sub.2.sup.2+.

公开(公告)号：US4564659A

公开(公告)日：1986-01-14

申请号：US525473

申请日：1983-08-22

Applicant: Yushin Kataoka ,  Masaaki Matsuda ,  Kenji Ochi ,  Masahiro Aoi

Inventor： Yushin Kataoka ,  Masaaki Matsuda ,  Kenji Ochi ,  Masahiro Aoi

IPC: C08F8/00 ,  B01J45/00 ,  C08F8/30 ,  C08F8/32 ,  C08J5/22

CPC classification number: B01J45/00 ,  C08F8/30 ,  C08F8/32 ,  C08F2810/20

Abstract: A chelate resin having a functional group of the formula: ##STR1## wherein R.sub.1 and R.sub.2 are each independently hydrogen, alkyl, aminoalkyl, phenyl or a substituted group thereof and another functional group of the formula: ##STR2## wherein R.sub.3 is amino, alkylamino, polyethylenepolyamino, hydrazo, hydrazino, hydrazono, amidino, guanidino, semicarbazide or a substituted group thereof, has an excellent adsorption capacity for metal ions.

Abstract translation: 具有下式的官能团的螯合树脂：其中R 1和R 2各自独立地为氢，烷基，氨基烷基，苯基或其取代基，另一种下式的官能团：其中R 3为氨基，烷基氨基 ，聚亚乙基聚氨基，水合肼，肼基，亚肼基，脒基，胍基，氨基脲或其取代基对金属离子具有优异的吸附能力。

公开(公告)号：US4530963A

公开(公告)日：1985-07-23

申请号：US469431

申请日：1983-02-24

Applicant: Irving W. DeVoe ,  Bruce E. Holbein

Inventor： Irving W. DeVoe ,  Bruce E. Holbein

IPC: A23L2/42 ,  A23L2/78 ,  A23L3/3463 ,  A61L2/16 ,  B01J45/00 ,  C01F15/00 ,  C02F1/64 ,  C12H1/052 ,  C12P9/00 ,  C22B3/18 ,  C22B3/26 ,  C22B3/32 ,  B07C5/36 ,  B07B13/05

CPC classification number: A23L3/3463 ,  A23L2/42 ,  A23L2/78 ,  A61L2/16 ,  B01J45/00 ,  C01F15/00 ,  C02F1/64 ,  C12H1/0416 ,  C12P9/00 ,  C22B3/0008 ,  C22B3/0024 ,  C22B3/18 ,  Y02P10/234 ,  Y10S210/912

Abstract: The present invention relates to insoluble compositions, which are capable of removing metal (e.g. selectively) from solution (e.g. Fe.sup.3+ from a liquid nutrient medium so as to lower the Fe.sup.3+ content to less than 0.1 .mu.M); the insoluble compositions comprise: a suitable insoluble carrier and organic co-ordinating sites covalently fixed to the surface of said carrier, said co-ordinating sites being capable of chelating Fe.sup.3+, Th.sup.4+ and/or UO.sub.2.sup.2+.

Abstract translation: 本发明涉及不溶性组合物，其能够从溶液（例如来自液体营养培养基的Fe 3+）中除去金属（例如选择性地）以将Fe 3+含量降低至小于0.1μM; 不溶性组合物包含：合适的不溶性载体和共价固定在所述载体表面的有机配位，所述配位位点能够螯合Fe 3+，Th 4+和/或UO 22 +。

公开(公告)号：US4517096A

公开(公告)日：1985-05-14

申请号：US596539

申请日：1984-04-04

Applicant: Kunio Sekine ,  Hitoshi Masuda ,  Kodo Ishibashi ,  Masahide Hirai ,  Shozo Tomoshige ,  Kozo Kondo

Inventor： Kunio Sekine ,  Hitoshi Masuda ,  Kodo Ishibashi ,  Masahide Hirai ,  Shozo Tomoshige ,  Kozo Kondo

IPC: C02F1/42 ,  B01J45/00 ,  C01G15/00 ,  C22B58/00 ,  B01D15/04

CPC classification number: C01G15/003 ,  B01J45/00 ,  C22B3/24 ,  C22B3/42 ,  Y02P10/234

Abstract: A novel method is disclosed which enables gallium and/or indium to be selectively separated and concentrated from a solution containing them in very low concentrations together with many other metal ions in rather high concentrations. The solution is passed through a bed of a chelating ion exchange resin having an amino carboxylic acid group either immediately or after the pH adjustment. Gallium and/or indium adsorbed on the chelate resin is desorbed by eluting with a mineral acid. The eluate, after the pH adjustment, is passed through another bed of a chelating ion exchange resin having an amino carboxylic acid group, and the resin is treated with a mineral acid to elute the metal ions adsorbed on the resin to thereby recover gallium and/or indium in the form of a concentrated solution.

Abstract translation: 公开了一种新颖的方法，其使得镓和/或铟能够从非常低浓度的含有它们的溶液与许多其它金属离子以相当高的浓度选择性地分离和浓缩。 将溶液立即或在pH调节之后通过具有氨基羧酸基团的螯合离子交换树脂床。 通过用无机酸洗脱来解吸吸附在螯合树脂上的镓和/或铟。 pH调节后的洗脱液通过具有氨基羧酸基团的螯合离子交换树脂的另一床，并用无机酸处理树脂以洗脱吸附在树脂上的金属离子，从而回收镓和/ 或浓缩溶液形式的铟。

公开(公告)号：US4515906A

公开(公告)日：1985-05-07

申请号：US470371

申请日：1983-02-28

Applicant: Dwayne Friesen ,  Walter C. Babcock ,  Mark Tuttle

Inventor： Dwayne Friesen ,  Walter C. Babcock ,  Mark Tuttle

IPC: C08L101/00 ,  B01D69/02 ,  B01J41/00 ,  B01J45/00 ,  B01J47/00 ,  B01J47/12 ,  C08J5/20 ,  C08J5/22 ,  C08L1/00 ,  C08L27/00 ,  C08L33/00 ,  C08L33/02 ,  C08L67/00 ,  C08L77/00 ,  C08L81/06

CPC classification number: B01D69/141 ,  B01D67/0088 ,  B01J45/00 ,  B01J47/12 ,  C22B3/42 ,  B01D2325/022 ,  Y02P10/234

Abstract: Novel ion-exchange media are disclosed, the media comprising polymeric anisotropic microporous supports containing polymeric ion-exchange or ion-complexing materials. The supports are anisotropic, having small exterior pores and larger interior pores, and are preferably in the form of beads, fibers and sheets.

Abstract translation: 公开了新型离子交换介质，该介质包含含有聚合物离子交换或离子络合材料的聚合物各向异性微孔载体。 载体是各向异性的，具有小的外部孔和较大的内部孔，并且优选为珠粒，纤维和片材的形式。

公开(公告)号：US4423159A

公开(公告)日：1983-12-27

申请号：US375232

申请日：1982-05-05

Applicant: Martha A. Ebra ,  Richard M. Wallace

Inventor： Martha A. Ebra ,  Richard M. Wallace

IPC: B01J45/00 ,  C01D17/00 ,  C01F11/00 ,  C01G1/00 ,  C08G14/06 ,  B01J39/18

CPC classification number: C01F11/005 ,  B01J45/00 ,  C01D17/00 ,  C22B3/42 ,  Y02P10/234

Abstract: A phenolic cation exchange resin with a chelating group has been prepared by reacting resorcinol with iminodiacetic acid in the presence of formaldehyde at a molar ratio of about 1:1:6. The material is highly selective for the simultaneous recovery of both cesium and strontium from aqueous alkaline solutions, such as, aqueous alkaline nuclear waste solutions. The organic resins are condensation polymers of resorcinol and formaldehyde with attached chelating groups. The column performance of the resins compares favorably with that of commercially available resins for either cesium or strontium removal. By combining Cs.sup.+ and Sr.sup.2+ removal in the same bed, the resins allow significant reduction of the size and complexity of facilities for processing nuclear waste.

Abstract translation: 具有螯合基团的酚类阳离子交换树脂已经通过在甲醛存在下，以约1:1:1的摩尔比将间苯二酚与亚氨基二乙酸反应来制备。 该材料对于从碱性水溶液如碱性碱性废水溶液中同时回收铯和锶是高选择性的。 有机树脂是间苯二酚和甲醛与附着螯合基团的缩聚物。 树脂的柱性能优于用于铯或锶去除的市售树脂的柱性能。 通过将Cs +和Sr2 +除去在同一床中，树脂可显着减少用于处理核废料的设施的大小和复杂性。

公开(公告)号：US4414183A

公开(公告)日：1983-11-08

申请号：US400190

申请日：1982-07-20

Applicant: Akio Sasaki ,  Yoshiaki Echigo

Inventor： Akio Sasaki ,  Yoshiaki Echigo

IPC: B01J20/26 ,  B01J45/00 ,  C02F1/28 ,  C08G8/00 ,  C08G8/16 ,  C08G8/18 ,  C08G8/24 ,  C08G8/28 ,  C08G14/12 ,  C22B3/00 ,  C22B60/02

CPC classification number: C02F1/285 ,  B01J45/00 ,  C08G14/12 ,  C08G8/24 ,  C08G8/28 ,  C22B3/24 ,  C22B60/0265 ,  C02F2101/006 ,  Y02P10/234 ,  Y10S210/912

Abstract: The phenolic chelate resin has a chelate-forming group wherein part or all of the hydrogen atoms in a primary and/or secondary alkylamino group introduced in a phenol nucleus are replaced by a methylenephosphonate group. Also disclosed is a process for producing such a chelate resin, and a method for recovering heavy metal ions with such a resin. The resin has particularly high selectivity for adsorbing uranium ions, as well as high heat, acid and alkali resistance as well as dimensional stability. The resin is very effective for recovering uranium from various uranium-containing solutions such as sea water, crude phosphoric acid fertilizer solutions, low-grade uranium ore, waste water from uranium refining, and uranium mine water.

Abstract translation: 酚类螯合树脂具有螯合形成基团，其中引入酚核中的伯和/或仲烷基氨基中的部分或全部氢原子被亚甲基膦酸酯基取代。 还公开了制备这种螯合树脂的方法，以及用这种树脂回收重金属离子的方法。 该树脂具有特别高的吸附铀离子的选择性，以及高的耐热，耐酸碱性以及尺寸稳定性。 该树脂对于从各种含铀溶液如海水，粗磷酸肥料溶液，低级铀矿石，铀精炼废水和铀矿水中回收铀非常有效。

公开(公告)号：US4399235A

公开(公告)日：1983-08-16

申请号：US262670

申请日：1981-05-11

Applicant: Charles F. Raley, Jr. ,  Edward R. Husser

Inventor： Charles F. Raley, Jr. ,  Edward R. Husser

IPC: B01J39/20 ,  B01J41/14 ,  B01J45/00 ,  B01J47/00 ,  C22B60/02 ,  B01J39/08 ,  B01J41/08 ,  C08L23/28

CPC classification number: B01J47/006 ,  B01J39/20 ,  B01J41/14 ,  B01J45/00 ,  C22B60/0265

Abstract: High density, ion exchange resins having excellent integrity are prepared from cross-linked, aromatic polymers which have been halogenated in the presence of an organic liquid having a sufficiently high dielectric constant to prevent substantial halogenation of the polymer backbone such as various organic nucleophiles having a free electron pair associated with a nonhalogen atom, e.g., ethanol or dimethylformamide. For example, a cross-linked polystyrene which has been brominated in methylene chloride containing a small amount of ethanol can subsequently be chloromethylated and aminated to form a high density anion exchange resin useful in removing anions from thick slurries such as those employed in uranium recovery.

Abstract translation: 具有优异完整性的高密度离子交换树脂由具有足够高介电常数的有机液体存在下被卤化的交联的芳族聚合物制备，以防止聚合物骨架的基本上卤化，例如具有 与非卤素原子相关的自由电子对，例如乙醇或二甲基甲酰胺。 例如，在含有少量乙醇的二氯甲烷中溴化的交联聚苯乙烯可随后被氯甲基化并胺化以形成高密度阴离子交换树脂，用于从诸如用于铀回收的那些粗浆中除去阴离子。

公开(公告)号：US4263146A

公开(公告)日：1981-04-21

申请号：US50563

申请日：1979-06-21

Applicant: Hans Wegmuller ,  Rudolf F. Wurster

Inventor： Hans Wegmuller ,  Rudolf F. Wurster

IPC: C02F1/42 ,  B01J39/22 ,  B01J41/16 ,  B01J45/00 ,  C02F1/28 ,  C08B11/145 ,  C08J5/20

CPC classification number: C02F1/286 ,  B01J39/22 ,  C08B11/145

Abstract: A process for removing cationic substances from an aqueous solution, which comprises bringing the solution into contact with a cellulose-containing material which has been chemically modified anionically and in which the anionic constituent is bonded to the cellulose moiety by a grouping of the general formula--O--CH.sub.2 --N

Abstract translation: 一种从水溶液中除去阳离子物质的方法，该方法包括使溶液与已经通过阴离子化学改性的含纤维素材料接触，并且其中阴离子组分通过通式 - O-CH 2 -N <其中氮属于阴离子组分的酰胺基，氧原子与纤维素结合。