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公开(公告)号：US07708902B2
公开(公告)日：2010-05-04
申请号：US11521395
申请日：2006-09-15
Applicant: Shin-ichi Ohkoshi , Kazuhito Hashimoto , Shunsuke Sakurai , Shiro Kuroki
Inventor： Shin-ichi Ohkoshi , Kazuhito Hashimoto , Shunsuke Sakurai , Shiro Kuroki
CPC classification number: G11B5/70642 , B82Y25/00 , G11B5/714 , H01F1/0054 , H01F10/007 , Y10T428/11 , Y10T428/115 , Y10T428/32
Abstract: A magnetic material composed of ε-InxFe2-xO3 (wherein 0
Abstract translation: 由其中In取代Fe-Fe 2 O 3晶体的Fe部分的一部分组成的磁性材料（其中0≤x≤1,0.30）构成。 该晶体表现出类似于Fe 2 O 3晶体结构的X射线衍射图，并且具有与Fe 2 O 3相同的空间组。 In含量赋予磁性材料低于Fe 2 O 3的磁相变温度和比Fe-Fe2O3高的自旋重新取向温度。 In含量还可以使磁性材料的复合介电常数的虚部的峰值温度高于Fe 2 O 3的虚部。
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22.发明授权Titanium oxide photocatalyst thin film and production method of titanium oxide photocatalyst thin film 失效氧化钛光催化薄膜及氧化钛光催化薄膜的制备方法公开(公告)号：US07695774B2
公开(公告)日：2010-04-13
申请号：US11125260
申请日：2005-05-10
Applicant: Shigemi Ohtsu , Tatsuya Maruyama , Eiichi Akutsu , Kazuhito Hashimoto
Inventor： Shigemi Ohtsu , Tatsuya Maruyama , Eiichi Akutsu , Kazuhito Hashimoto
CPC classification number: C23C14/58 , A01N59/16 , C03C17/23 , C03C17/3417 , C03C2217/212 , C03C2217/71 , C23C14/083 , A01N59/00 , A01N25/34 , A01N2300/00
Abstract: The present invention provides a titanium oxide photocatalytic thin film having a surface layer containing silicon oxide and titanium oxide and a production method for producing a titanium oxide photocatalytic thin film having a surface layer containing silicon oxide and titanium oxide and comprising a step of radiating excimer beam to the titanium oxide thin film while heating substrate on which the titanium oxide thin film is disposed in vacuum or gas atmosphere in the presence of a silicon-including compound.
Abstract translation: 本发明提供了具有含有氧化硅和氧化钛的表面层的氧化钛光催化薄膜，以及具有含有氧化硅和氧化钛的表面层的二氧化钛光催化薄膜的制造方法，其特征在于，具有放射准分子束 在含有硅的化合物的存在下，在真空或气体气氛中加热氧化钛薄膜的基板上加热氧化钛薄膜。
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公开(公告)号：US07327074B2
公开(公告)日：2008-02-05
申请号：US11605374
申请日：2006-11-29
Applicant: Akira Fujishima , Kazuhito Hashimoto , Tomokazu Iyoda , Shigemichi Fukayama , Tetsuo Yoshimoto , Tokuyoshi Saitoh
Inventor： Akira Fujishima , Kazuhito Hashimoto , Tomokazu Iyoda , Shigemichi Fukayama , Tetsuo Yoshimoto , Tokuyoshi Saitoh
CPC classification number: A61L9/205 , B01D2255/20707 , B01D2255/802 , B01J21/06 , B01J21/063 , B01J21/066 , B01J35/002 , B01J35/004 , B01J37/0244 , C03C17/2456 , C03C17/256 , C03C17/3417 , C03C2217/212 , C03C2217/71 , H01J61/35 , H01J61/42
Abstract: An illuminating device is made from a transparent hollow envelope that encloses a filler gas. The envelope has inner and outer surfaces. The illuminating device has a coating of a fluorescent material deposited on the inner surface of the transparent envelope where the fluorescent material emits light having a visible component and an ultraviolet component; and a titanium dioxide film having first and second opposing surfaces where the first surface of the titanium dioxide film is formed on the outer surface of the transparent envelope. A light transmittance of the titanium dioxide film is at least 50% for light having a wavelength of 550 nm, and the light transmitted from the fluorescent material through the transparent envelope and the first surface of the titanium dioxide film to the second surface thereof causes photocatalytic activity to be generated on the second surface of the titanium dioxide film.
Abstract translation: 照明装置由包围填充气体的透明中空外壳制成。 信封具有内表面和外表面。 照明装置具有沉积在透明外壳的内表面上的荧光材料的涂层，其中荧光材料发射具有可见成分和紫外分量的光; 以及具有第一和第二相对表面的二氧化钛膜，其中二氧化钛膜的第一表面形成在透明外壳的外表面上。 对于波长为550nm的光，二氧化钛膜的透光率为至少50％，并且从荧光材料通过透明外壳和二氧化钛膜的第一表面向其第二表面透射的光引起光催化 在二氧化钛膜的第二表面上产生的活性。
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公开(公告)号：US20070218319A1
公开(公告)日：2007-09-20
申请号：US11521395
申请日：2006-09-15
Applicant: Shin-ichi Ohkoshi , Kazuhito Hashimoto , Shunsuke Sakurai , Shiro Kuroki
Inventor： Shin-ichi Ohkoshi , Kazuhito Hashimoto , Shunsuke Sakurai , Shiro Kuroki
CPC classification number: G11B5/70642 , B82Y25/00 , G11B5/714 , H01F1/0054 , H01F10/007 , Y10T428/11 , Y10T428/115 , Y10T428/32
Abstract: A magnetic material composed of ε-InxFe2-xO3 (wherein 0
Abstract translation: 由以下组成的磁性材料：其中In是由以下组成的其中In是由以下组成的ε-In×Fe 2 Fe 3 O 3（其中0
2 3。 In含量赋予磁性材料磁性相转变温度低于ε-Fe 2 O 3 3的磁相变温度，并且旋转重新取向温度高于ε-2 的ε-Fe 2 O 3 3。 In含量还可以使磁性材料的复合介电常数的虚部的峰值温度高于ε-Fe 2 O 3 3的复数介电常数的虚部。 -
公开(公告)号：US07157840B2
公开(公告)日：2007-01-02
申请号：US10327042
申请日：2002-12-24
Applicant: Akira Fujishima , Kazuhito Hashimoto , Tomokazu Iyoda , Shigemichi Fukayama , Tetsuo Yoshimoto , Tokuyoshi Saitoh
Inventor： Akira Fujishima , Kazuhito Hashimoto , Tomokazu Iyoda , Shigemichi Fukayama , Tetsuo Yoshimoto , Tokuyoshi Saitoh
IPC: H01J63/04
CPC classification number: A61L9/205 , B01D2255/20707 , B01D2255/802 , B01J21/06 , B01J21/063 , B01J21/066 , B01J35/002 , B01J35/004 , B01J37/0244 , C03C17/2456 , C03C17/256 , C03C17/3417 , C03C2217/212 , C03C2217/71 , H01J61/35 , H01J61/42
Abstract: An illuminating device is made from a transparent hollow envelope that encloses a filler gas. The envelope has inner and outer surfaces. The illuminating device has a coating of a fluorescent material deposited on the inner surface of the transparent envelope where the fluorescent material emits light having a visible component and an ultraviolet component; and a titanium dioxide film having first and second opposing surfaces where the first surface of the titanium dioxide film is formed on the outer surface of the transparent envelope. A light transmittance of the titanium dioxide film is at least 50% for light having a wavelength of 550 nm, and the light transmitted from the fluorescent material through the transparent envelope and the first surface of the titanium dioxide film to the second surface thereof causes photocatalytic activity to be generated on the second surface of the titanium dioxide film.
Abstract translation: 照明装置由包围填充气体的透明中空外壳制成。 信封具有内表面和外表面。 照明装置具有沉积在透明外壳的内表面上的荧光材料的涂层，其中荧光材料发射具有可见成分和紫外分量的光; 以及具有第一和第二相对表面的二氧化钛膜，其中二氧化钛膜的第一表面形成在透明外壳的外表面上。 对于波长为550nm的光，二氧化钛膜的透光率为至少50％，并且从荧光材料通过透明外壳和二氧化钛膜的第一表面向其第二表面透射的光引起光催化 在二氧化钛膜的第二表面上产生的活性。
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Patent Agency Ranking
26.发明授权公开(公告)号：US06830785B1
公开(公告)日：2004-12-14
申请号：US09374344
申请日：1999-08-13
Applicant: Makoto Hayakawa , Eiichi Kojima , Keiichiro Norimoto , Mitsuyoshi Machida , Atsushi Kitamura , Toshiya Watanabe , Makoto Chikuni , Akira Fujishima , Kazuhito Hashimoto
Inventor： Makoto Hayakawa , Eiichi Kojima , Keiichiro Norimoto , Mitsuyoshi Machida , Atsushi Kitamura , Toshiya Watanabe , Makoto Chikuni , Akira Fujishima , Kazuhito Hashimoto
IPC: B05D306
CPC classification number: C09K3/18 , C03C17/23 , C03C17/2456 , C03C17/256 , C03C2217/212 , C03C2217/229 , C03C2217/23 , C03C2217/71 , C03C2218/113 , C03C2218/151 , C03C2218/32 , G02B1/105 , G02B1/18
Abstract: The surface of a substrate is coated with an abrasion-resistant photocatalytic coating comprised of a semiconductor photocatalyst. upon irradiation by a light having a wavelength of an energy higher than the bandgap energy of the photocatalyst, water is chemisorbed onto the surface in the form of hydroxyl groups (OH−) whereby the surface of the photocatalytic coating is rendered highly hydrophilic. In certain embodiments, the surface of a mirror, lens, or windowpane is coated with the photocatalytic coating to exhibit a high degree of antifogging function. In another embodiment, an article or product coated with the photocatalytic coating is disposed outdoors and the highly hydrophilic surface thereof is self-cleaned as it is subjected to rainfall. In a still another embodiment, an article is coated with the photocatalytic coating and, when the article is soaked in, rinsed by or wetted with water, fatty dirt and contaminants are readily released without resort to a detergent.
Abstract translation: 用由半导体光催化剂组成的耐磨光催化涂层涂覆基材表面。 通过具有比光催化剂的带隙能量高的能量的光照射，水以羟基（OH - ）的形式被化学吸附到表面上，由此光催化涂层的表面变得高度亲水。 在某些实施例中，镜子，透镜或窗玻璃的表面涂覆有光催化涂层以显示高度的防雾功能。 在另一个实施方案中，涂覆有光催化涂层的制品或产品设置在室外，并且其高亲水性表面在遭受降雨时自我清洁。 在另一个实施方案中，用光催化涂层涂覆制品，并且当制品被浸泡，用水漂洗或用水润湿时，脂肪污垢和污染物容易释放，而不用洗涤剂。
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公开(公告)号：US06524664B1
公开(公告)日：2003-02-25
申请号：US09374347
申请日：1999-08-13
Applicant: Kazuhito Hashimoto , Akira Fujishima , Toshiya Watanabe , Mitsuhide Shimohigoshi , Makoto Hayakawa
Inventor： Kazuhito Hashimoto , Akira Fujishima , Toshiya Watanabe , Mitsuhide Shimohigoshi , Makoto Hayakawa
IPC: B05D306
CPC classification number: C03C17/256 , C03C17/2456 , C03C2217/212 , C03C2217/23 , C03C2217/71 , C03C2218/113 , C03C2218/151 , C09K3/18 , G02B1/105 , G02B1/18 , Y10T428/31504
Abstract: A method for highly hydrophilifying the surface of an article by photoexcitation of a semiconductor photocatalyst and maintaining the hydrophilicity is disclosed. A layer containing a photocatalyst is formed on a substrate. Onto the surface of the layer are fixed a hydroxyl group upon photoexcitation of the photocatalyst and a physically adsorbed water molecule in the vicinity of the hydroxyl group upon photoexcitation of the photocatalyst. Thus, the surface is highly hydrophilified. Further, this surface, simultaneously with the hydrophilification, exhibits higher hydrophobicity.
Abstract translation: 公开了通过光激发半导体光催化剂使物品的表面高度亲水化并保持亲水性的方法。 在基板上形成含有光催化剂的层。 在光催化剂的光激发下，在光催化剂的光激发和羟基附近的物理吸附水分子之间，层的表面固定羟基。 因此，表面高度亲水化。 此外，该表面与亲水化同时显示更高的疏水性。
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公开(公告)号：US06498000B2
公开(公告)日：2002-12-24
申请号：US09891263
申请日：2001-06-27
Applicant: Sadao Murasawa , Hajime Murakami , Yasuro Fukui , Mitsuru Watanabe , Akira Fujishima , Kazuhito Hashimoto
Inventor： Sadao Murasawa , Hajime Murakami , Yasuro Fukui , Mitsuru Watanabe , Akira Fujishima , Kazuhito Hashimoto
IPC: G03E1725
CPC classification number: B01J35/002 , B01J35/004 , B01J37/0219 , C03C17/007 , C03C17/256 , C03C17/3405 , C03C2204/02 , C03C2217/212 , C03C2217/25 , C03C2217/29 , C03C2217/445 , C03C2217/45 , C03C2217/477 , C03C2217/479 , C03C2217/71 , C03C2218/11 , Y10S430/148 , Y10S430/151
Abstract: A photocatalyst composite is provided which comprise a substrate having particles of a photocatalyst such as titanium oxide, adhered thereon via a less degradative adhesive such as a fluorinated polymer comprising a copolymer of a vinyl ester and/or vinyl ether and a fluoroolefin, or a silicon based polymer or cement. Furthermore, a process for producing the photocatalyst composite and a coating composition containing the photocatalyst composite are provided.
Abstract translation: 提供了一种光催化剂复合材料，其包括具有诸如氧化钛的光催化剂颗粒的基材，其通过较不降解的粘合剂粘附在其上，所述粘合剂例如包含乙烯基酯和/或乙烯基醚和氟代烯烃的共聚物的氟化聚合物，或硅 基聚合物或水泥。 此外，提供了光催化剂复合体的制造方法和含有光催化剂复合体的涂料组合物。
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29.发明授权Photocatalyst material, method for decomposition of organic material, interior member, air purification device, and apparatus for preparation of oxidizing agent 有权光催化剂材料，有机材料分解方法，内部构件，空气净化装置以及氧化剂的制备装置公开(公告)号：US08536084B2
公开(公告)日：2013-09-17
申请号：US12736209
申请日：2009-03-19
Applicant: Kazuhito Hashimoto , Hiroshi Irie , Syuhei Miura , Kazuhide Kamiya , Shinichiro Miki , Koichi Takahama , Mitsuo Yaguchi
Inventor： Kazuhito Hashimoto , Hiroshi Irie , Syuhei Miura , Kazuhide Kamiya , Shinichiro Miki , Koichi Takahama , Mitsuo Yaguchi
IPC: B01J23/888 , A61L2/08 , B32B19/00
CPC classification number: A61L9/18 , A61L9/205 , B01J23/72 , B01J23/888 , B01J35/004 , B01J37/0072 , B01J37/009 , B01J37/0211 , B01J37/0234 , B01J37/04
Abstract: The present invention provides a tungsten trioxide microparticle carrying on its surface divalent copper salt. The divalent copper salt is utilized to perform a multi-electron reduction of oxygen. The tungsten trioxide exhibits a high oxidative decomposition activity when exposed to visible light.
Abstract translation: 本发明提供了在其表面上具有二价铜盐的三氧化钨微粒。 二价铜盐用于进行氧的多电子还原。 当暴露于可见光时，三氧化钨显示出高的氧化分解活性。
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30.发明申请TITANIUM OXIDE PARTICLES, PROCESS FOR PRODUCING SAME, MAGNETIC MEMORY, OPTICAL INFORMATION RECORDING MEDIUM, AND CHARGE ACCUMULATION TYPE MEMORY 有权氧化钛颗粒，其生产方法，磁记忆体，光学信息记录介质和电荷累积型存储器公开(公告)号：US20130105723A1
公开(公告)日：2013-05-02
申请号：US13699082
申请日：2011-04-15
Applicant: Shin-ichi Ohkoshi , Hiroko Tokoro , Fumiyoshi Hakoe , Yoshihide Tsunobuchi , Kazuhito Hashimoto
Inventor： Shin-ichi Ohkoshi , Hiroko Tokoro , Fumiyoshi Hakoe , Yoshihide Tsunobuchi , Kazuhito Hashimoto
IPC: C01G23/04
CPC classification number: C01G23/04 , B82Y10/00 , B82Y25/00 , B82Y30/00 , B82Y40/00 , C01G23/043 , C01P2002/72 , C01P2002/76 , C01P2002/77 , C01P2004/04 , C01P2004/64 , C01P2006/10 , C01P2006/40 , C01P2006/42 , C09C1/36 , C09C1/3607 , H01L21/28273 , H01L43/10
Abstract: A titanium oxide particle that can develop non-conventional and novel physical properties, a method for manufacturing the same, and a magnetic memory, an optical information recording medium, and a charge accumulation type memory using the same are provided. A silica-coated titanium hydroxide compound particle is directly produced through a sol-gel technique and not through a reverse micelle technique, and the silica-coated titanium hydroxide compound particle is subjected to a calcination process. Hence, a titanium oxide particle 1 can be provided which can develop non-conventional and novel physical properties such that it does not perform phase transition at a room temperature and a Ti3O5 particle body can always maintain the characteristic as a paramagnetic metal in all temperature ranges unlike conventional bulk bodies that perform phase transition between a non-magnetic semiconductor and a paramagnetic metal at a temperature near about 460 K.
Abstract translation: 提供了可以发展非常规和新颖物理性质的二氧化钛颗粒，其制造方法，以及磁存储器，光学信息记录介质和使用其的电荷累积型存储器。 二氧化硅涂覆的氢氧化钛化合物颗粒通过溶胶 - 凝胶技术而不是通过反胶束技术直接制备，并且二氧化硅涂覆的氢氧化钛化合物颗粒经历煅烧过程。 因此，可以提供二氧化钛颗粒1，其可以产生非常规和新的物理性质，使得其在室温下不进行相变，并且Ti 3 O 5颗粒体可以在所有温度范围内始终保持作为顺磁性金属的特性 不同于在接近约460K的温度下执行非磁性半导体和顺磁金属之间的相变的常规体体。
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