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公开(公告)号：US20100004478A1
公开(公告)日：2010-01-07
申请号：US12165743
申请日：2008-07-01
Applicant: Stephan James Mclain
Inventor： Stephan James Mclain
Abstract: A compound comprising Formula 5 RfOCFHCF2O(CH2CH2O)v—H Formula 5 wherein Rf is CcF(2c+1); c is 2 to about 6; and v is 2 to about 4; and a process for its preparation comprising contacting a compound of Formula 6 Rf—O—CF═CF2 Formula 6 wherein Rf is CcF(2c+1), and c is 2 to about 6, with a compound of Formula 7 HO—(CH2CH2O)v—H Formula 7 wherein v is 2 to about 4.
Abstract translation: 包含式5的RfOCFHCF2O（CH2CH2O）v-H式5的化合物，其中Rf为CcF（2c + 1）; c为2至约6; v为2至约4; 和其制备方法，包括使式6的Rf-O-CF-CF 2式6化合物，其中Rf为CcF（2c + 1），c为2至约6，与式7化合物HO-（CH 2 CH 2 O ）vH式7其中v为2至约4。
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公开(公告)号：US06140439A
公开(公告)日：2000-10-31
申请号：US891405
申请日：1997-07-10
Applicant: Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Stephan James McLain
Inventor： Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Stephan James McLain
IPC: B01J31/00 , B01J37/00 , C07C2/32 , C07C69/52 , C07C251/08 , C07F7/00 , C07F15/00 , C07F19/00 , C08F4/02 , C08F4/06 , C08F4/60 , C08F4/70 , C08F4/80 , C08F10/00 , C08F10/02 , C08F10/06 , C08F10/08 , C08F12/30 , C08F20/06 , C08F110/02 , C08F110/06 , C08F110/14 , C08F132/04 , C08F210/02 , C08F210/14 , C08F210/16 , C08F220/10 , C08F232/00 , C08F232/04 , C08F255/00 , C08L23/02
CPC classification number: C08F110/02 , C08F110/06 , C08F210/02 , C08F210/14 , C08F210/16 , C08L23/02 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/14 , C08F232/00 , Y10S430/165 , Y10T428/1352 , Y10T428/1386 , Y10T428/139 , Y10T428/24942 , Y10T428/2878
Abstract: Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear .alpha.-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected .alpha.-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected .alpha.-diimine nickel complexes with ethylene.
Abstract translation: 本文公开了聚合乙烯，无环烯烃和/或选择的环烯烃，和任选选择的烯属酯或羧酸和其它单体的方法。 聚合由选择的过渡金属化合物，有时是其他助催化剂催化。 由于一些聚合表现出活性聚合的某些特性，因此可以容易地制备嵌段共聚物。 所生产的许多聚合物通常是新颖的，特别是在它们的微结构方面，这给出了其中一些不寻常的性质。 公开了许多新颖的催化剂，以及一些制备它们的新方法。 制备的聚合物可用作弹性体，模塑树脂，粘合剂等。本文还描述了通过使用作为催化剂体系的乙烯低聚来合成线性α-烯烃，将具有选定的α-二亚胺配体的镍化合物和 选择的Lewis或布朗斯台德酸，或通过使选择的α-二亚胺镍络合物与乙烯接触。
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公开(公告)号：US6034259A
公开(公告)日：2000-03-07
申请号：US891398
申请日：1997-07-10
Applicant: Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Samuel David Arthur , Jerald Feldman , Stephan James McLain , Kristina Ann Kreutzer , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Steven Dale Ittel , Anju Parthasarathy , Daniel Joseph Tempel
Inventor： Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Samuel David Arthur , Jerald Feldman , Stephan James McLain , Kristina Ann Kreutzer , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Steven Dale Ittel , Anju Parthasarathy , Daniel Joseph Tempel
IPC: B01J31/00 , B01J37/00 , C07C2/32 , C07C69/52 , C07C251/08 , C07F7/00 , C07F15/00 , C07F19/00 , C08F4/02 , C08F4/06 , C08F4/60 , C08F4/70 , C08F4/80 , C08F10/00 , C08F10/02 , C08F10/06 , C08F10/08 , C08F12/30 , C08F20/06 , C08F110/02 , C08F110/06 , C08F110/14 , C08F132/04 , C08F210/02 , C08F210/14 , C08F210/16 , C08F220/10 , C08F232/00 , C08F232/04 , C08F255/00 , C08L23/02
CPC classification number: C08F110/02 , C08F110/06 , C08F210/02 , C08F210/14 , C08F210/16 , C08L23/02 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/14 , C08F232/00 , Y10S430/165 , Y10T428/1352 , Y10T428/1386 , Y10T428/139 , Y10T428/24942 , Y10T428/2878 , Y10T428/31692 , Y10T428/31855 , Y10T428/31895 , Y10T428/31938 , Y10T442/20 , Y10T442/60 , Y10T442/626
Abstract: Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear .alpha.-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected .alpha.-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected .alpha.-diimine nickel complexes with ethylene.
Abstract translation: 本文公开了聚合乙烯，无环烯烃和/或选择的环烯烃，和任选选择的烯属酯或羧酸和其它单体的方法。 聚合由选择的过渡金属化合物，有时是其他助催化剂催化。 由于一些聚合表现出活性聚合的某些特性，因此可以容易地制备嵌段共聚物。 所生产的许多聚合物通常是新颖的，特别是在它们的微结构方面，这给出了其中一些不寻常的性质。 公开了许多新颖的催化剂，以及一些制备它们的新方法。 制备的聚合物可用作弹性体，模塑树脂，粘合剂等。本文还描述了通过使用作为催化剂体系的乙烯低聚来合成线性α-烯烃，将具有选定的α-二亚胺配体的镍化合物和 选择的Lewis或布朗斯台德酸，或通过使选择的α-二亚胺镍络合物与乙烯接触。
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公开(公告)号：US5714556A
公开(公告)日：1998-02-03
申请号：US671392
申请日：1996-06-27
Applicant: Lynda Kaye Johnson , Jerald Feldman , Kristina Ann Kreutzer , Stephan James McLain , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Dennis Scott Donald , Lissa Taka Jennings Nelson , Anju Parthasarathy , Xing Shen , Wilson Tam , Yueli Wang
Inventor： Lynda Kaye Johnson , Jerald Feldman , Kristina Ann Kreutzer , Stephan James McLain , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Dennis Scott Donald , Lissa Taka Jennings Nelson , Anju Parthasarathy , Xing Shen , Wilson Tam , Yueli Wang
IPC: C07F15/04 , C08F4/06 , C08F4/70 , C08F10/00 , C08F10/02 , C08F12/00 , C08F12/04 , C08F12/08 , C08F32/08 , C08F36/00 , C08F36/20 , C08F110/02 , C08F210/02
CPC classification number: C08F32/08 , C07F15/04 , C08F10/00 , C08F10/02 , C08F12/08 , C08F110/02 , C08F210/02
Abstract: Disclosed herein is a process for the polymerization of ethylene, norbornenes and styrenes, by contacting in solution a selected nickel compound and a selected compound which is or can coordinated to the nickel with the olefin(s). The polymers produced are useful for films and molding resins.
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公开(公告)号：US08173848B2
公开(公告)日：2012-05-08
申请号：US12165743
申请日：2008-07-01
Applicant: Stephan James Mclain
Inventor： Stephan James Mclain
IPC: C07C43/11
Abstract: A compound comprising Formula 5 RfOCFHCF2O(CH2CH2O)v—H Formula 5 wherein Rf is CcF(2c+1); c is 2 to about 6; and v is 2 to about 4; and a process for its preparation comprising contacting a compound of Formula 6 Rf—O—CF═CF2 Formula 6 wherein Rf is CcF(2c+1), and c is 2 to about 6, with a compound of Formula 7 HO—(CH2CH2O)v—H Formula 7 wherein v is 2 to about 4.
Abstract translation: 包含式5的RfOCFHCF2O（CH2CH2O）v-H式5的化合物，其中Rf为CcF（2c + 1）; c为2至约6; v为2至约4; 和其制备方法，包括使式6的化合物Rf-O-CF = CF 2式6，其中Rf为CcF（2c + 1），c为2至约6，与式7的化合物HO-（CH 2 CH 2 O ）v-H式7其中v为2至约4。
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Patent Agency Ranking
公开(公告)号：US08022152B2
公开(公告)日：2011-09-20
申请号：US12002925
申请日：2007-12-19
Applicant: Steven Dale Ittel , Lynda Kaye Johnson , Lin Wang , Ying Wang , Elizabeth Forrester McCord , Catherine E. Radzewich , Stephan James McLain , Karl Jeffrey Sweetman , Alison Margaret Anne Bennett , Alex Sergey Ionkin , Rinaldo Soria Schiffino
Inventor： Steven Dale Ittel , Lynda Kaye Johnson , Lin Wang , Ying Wang , Elizabeth Forrester McCord , Catherine E. Radzewich , Stephan James McLain , Karl Jeffrey Sweetman , Alison Margaret Anne Bennett , Alex Sergey Ionkin , Rinaldo Soria Schiffino
IPC: C08F2/38 , C08F4/00 , C08F30/08 , C08F210/00
CPC classification number: C08F210/02 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F4/619 , C08F2500/03 , C08F2500/10 , C08F230/08 , C08F2500/04 , C08F2500/12 , C08F210/06 , C08F4/7006
Abstract: Ethylene and allyl- or vinylsilanes are efficiently copolymerized by certain late transition metal complexes containing selected bidentate or tridentate ligands. The resulting novel polymers may be crosslinked by moisture when vinylsilane contains groups bound to silicon which are hydrolyzable. The polymers are useful for wire coating, crosslinked foams, pipes, and other uses.
Abstract translation: 乙烯和烯丙基或乙烯基硅烷通过含有选择的二齿或三齿配体的某些后期过渡金属络合物有效共聚。 当乙烯基硅烷含有与可水解的硅结合的基团时，所得到的新型聚合物可以通过水分交联。 聚合物可用于线涂，交联泡沫，管道和其他用途。
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公开(公告)号：US20110009668A1
公开(公告)日：2011-01-13
申请号：US12500817
申请日：2009-07-10
Applicant: Alexander Borisovich Shtarov , Peter Michael Murphy , Brent Ryan Gonska , Stephan James McLain
Inventor： Alexander Borisovich Shtarov , Peter Michael Murphy , Brent Ryan Gonska , Stephan James McLain
IPC: C07C311/01
CPC classification number: C07C311/09 , C07C303/38 , C07C303/40
Abstract: Current methods for making polyfluorosulfonamido amines, which involve the use of a diamine reactant, provide low yields and produce an undesirable fluorine containing bis-sulfonamide by-product representing an economic loss. The bis-sulfonamide by-product is particularly undesirable because it shares very similar physical properties with the desired monoamine product thus making isolation of the desired polyfluorosulfonamido amine product difficult and costly. Furthermore, instead of the efficient incorporation of fluorine to make the desired polyfluorosulfonamido amine product, the bis-sulfonamide by-product constitutes a substantial loss of costly fluorinated starting material. The bis-sulfonamide by-product also constitutes an undesirable impurity that can worsen surfactancy, repellency, or other performance characteristics of the desired polyfluorosulfonamido amine product. The present invention provides a method of making a polyfluorosulfonamido amine without the production of a bis-sulfonamide by-product by reacting a polyfluoroalkylsulfonic compound with a monoamino amide rather than with a diamine reactant as in previously known methods.
Abstract translation: 涉及使用二胺反应物的制备多氟磺酰氨基胺的现有方法提供低产率并产生表示经济损失的不希望的含氟双磺酰胺副产物。 双磺酰胺副产物是特别不希望的，因为它与所需的单胺产物分享非常相似的物理性质，从而使所需的多氟磺酰胺胺产物的分离困难且昂贵。 此外，代替有效地引入氟以制备所需的多氟磺酰氨基胺产物，双磺酰胺副产物构成昂贵的氟化原料的显着损失。 双磺酰胺副产物也构成可恶化期望的多氟磺酰氨基胺产物的表面活性，排斥性或其它性能特征的不期望的杂质。 本发明提供了如先前已知的方法，通过使多氟烷基磺酸化合物与单氨基酰胺而不是二胺反应物反应而制备多氟磺酰胺，不产生双磺酰胺副产物的方法。
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28.发明申请Protected Air-Activated Organotin Catalysts for Polyurethane Synthesis and Processes Therefore 审中-公开因此，保护性空气活化有机锡催化剂用于聚氨酯合成和工艺公开(公告)号：US20090197006A1
公开(公告)日：2009-08-06
申请号：US12085248
申请日：2006-12-18
Applicant: Jerald Feldman , Stephan James McLain , Robert John Barsotti , James William O'Neil
Inventor： Jerald Feldman , Stephan James McLain , Robert John Barsotti , James William O'Neil
CPC classification number: C08G18/792 , C08G18/242 , C08G18/244 , C08G18/341 , C08G18/718 , H05K3/285
Abstract: This invention relates to a protected organotin-based catalyst system for polyurethane synthesis that is useful in coatings applications. The catalyst has low activity in the absence of oxygen. When a coating mixture comprising the catalyst is sprayed and/or applied to a substrate as a thin film in air, the catalyst is activated. For solvent-based refinish systems comprising hydroxyl and isocyanate species at high solids levels, the catalyst system therefore provides extended viscosity stability, i.e., pot life.
Abstract translation: 本发明涉及用于聚氨酯合成的受保护的有机锡基催化剂体系，其可用于涂料应用。 催化剂在不存在氧的情况下具有低活性。 当包含催化剂的涂料混合物在空气中作为薄膜喷涂和/或施加到基材上时，催化剂被活化。 对于含有高固体含量的羟基和异氰酸酯物质的基于溶剂的修补体系，催化剂体系因此提供了延长的粘度稳定性，即适用期。
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公开(公告)号：US6002034A
公开(公告)日：1999-12-14
申请号：US172367
申请日：1998-10-14
Applicant: Stephan James McLain , Jerald Feldman
Inventor： Stephan James McLain , Jerald Feldman
IPC: C07C251/20 , C07F15/04 , C08F4/70 , C08F10/00 , C08F32/08 , C08F297/08 , C07F15/02 , C07C249/00
CPC classification number: C08F32/08 , C07C251/20 , C07F15/045 , C08F10/00 , C08F297/08 , C07C2103/20 , C08F110/14
Abstract: Certain olefins such as ethylene, .alpha.-olefins and cyclopentene can be polymerized by using catalyst system containing a nickel or palladium .alpha.-diimine complex, a metal containing hydrocarbylation compound, and a selected Lewis acid, or a catalyst system containing certain nickel[II] or palladium[II] compounds, an .alpha.-diimine, a metal containing hydrocarbylation compound, and optionally a selected Lewis acid. The process advantageously produces polyolefins useful for molding resins, films, elastomers and other uses.
Abstract translation: 某些烯烃如乙烯，α-烯烃和环戊烯可以通过使用含有镍或钯的α-二亚胺络合物，含有金属的烃基化合物和选择的路易斯酸的催化剂体系或含有某些镍[II] 或钯[II]化合物，α-二亚胺，含金属的烃基化合物和任选的选择的路易斯酸。 该方法有利地产生可用于模制树脂，薄膜，弹性体和其它用途的聚烯烃。
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公开(公告)号：US5891963A
公开(公告)日：1999-04-06
申请号：US891442
申请日：1997-07-10
Applicant: Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Samuel David Arthur , Elizabeth Forrester McCord , Stephan James McLain
Inventor： Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Samuel David Arthur , Elizabeth Forrester McCord , Stephan James McLain
IPC: B01J31/00 , B01J37/00 , C07C2/32 , C07C69/52 , C07C251/08 , C07F7/00 , C07F15/00 , C07F19/00 , C08F4/02 , C08F4/06 , C08F4/60 , C08F4/70 , C08F4/80 , C08F10/00 , C08F10/02 , C08F10/06 , C08F10/08 , C08F12/30 , C08F20/06 , C08F110/02 , C08F110/06 , C08F110/14 , C08F132/04 , C08F210/02 , C08F210/14 , C08F210/16 , C08F220/10 , C08F232/00 , C08F232/04 , C08F255/00 , C08L23/02
CPC classification number: C08F110/02 , C08F110/06 , C08F210/02 , C08F210/14 , C08F210/16 , C08L23/02 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/14 , C08F232/00 , Y10S430/165 , Y10T428/1352 , Y10T428/1386 , Y10T428/139 , Y10T428/24942 , Y10T428/2878 , Y10T428/31692 , Y10T428/31855 , Y10T428/31895 , Y10T428/31938 , Y10T442/20 , Y10T442/60 , Y10T442/626
Abstract: Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microsructure, which give some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear .alpha.-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected .alpha.-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected .alpha.-diimine nickel complexes with ethylene.
Abstract translation: 本文公开了聚合乙烯，无环烯烃和/或选择的环烯烃，和任选选择的烯属酯或羧酸和其它单体的方法。 聚合由选择的过渡金属化合物，有时是其他助催化剂催化。 由于一些聚合表现出活性聚合的某些特性，因此可以容易地制备嵌段共聚物。 所生产的许多聚合物通常是新颖的，特别是关于它们的微结构，其中给出了其中一些不寻常的性质。 公开了许多新颖的催化剂，以及一些制备它们的新方法。 制备的聚合物可用作弹性体，模塑树脂，粘合剂等。本文还描述了通过使用作为催化剂体系的乙烯低聚来合成线性α-烯烃，将具有选定的α-二亚胺配体的镍化合物和 选择的Lewis或布朗斯台德酸，或通过使选择的α-二亚胺镍络合物与乙烯接触。
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