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1.发明申请Protected Air-Activated Organotin Catalysts for Polyurethane Synthesis and Processes Therefore 审中-公开因此，保护性空气活化有机锡催化剂用于聚氨酯合成和工艺公开(公告)号：US20090197006A1
公开(公告)日：2009-08-06
申请号：US12085248
申请日：2006-12-18
CPC分类号： C08G18/792 , C08G18/242 , C08G18/244 , C08G18/341 , C08G18/718 , H05K3/285
摘要： This invention relates to a protected organotin-based catalyst system for polyurethane synthesis that is useful in coatings applications. The catalyst has low activity in the absence of oxygen. When a coating mixture comprising the catalyst is sprayed and/or applied to a substrate as a thin film in air, the catalyst is activated. For solvent-based refinish systems comprising hydroxyl and isocyanate species at high solids levels, the catalyst system therefore provides extended viscosity stability, i.e., pot life.
摘要翻译： 本发明涉及用于聚氨酯合成的受保护的有机锡基催化剂体系，其可用于涂料应用。 催化剂在不存在氧的情况下具有低活性。 当包含催化剂的涂料混合物在空气中作为薄膜喷涂和/或施加到基材上时，催化剂被活化。 对于含有高固体含量的羟基和异氰酸酯物质的基于溶剂的修补体系，催化剂体系因此提供了延长的粘度稳定性，即适用期。
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公开(公告)号：US6034259A
公开(公告)日：2000-03-07
申请号：US891398
申请日：1997-07-10
申请人： Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Samuel David Arthur , Jerald Feldman , Stephan James McLain , Kristina Ann Kreutzer , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Steven Dale Ittel , Anju Parthasarathy , Daniel Joseph Tempel
发明人： Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Samuel David Arthur , Jerald Feldman , Stephan James McLain , Kristina Ann Kreutzer , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Steven Dale Ittel , Anju Parthasarathy , Daniel Joseph Tempel
IPC分类号： B01J31/00 , B01J37/00 , C07C2/32 , C07C69/52 , C07C251/08 , C07F7/00 , C07F15/00 , C07F19/00 , C08F4/02 , C08F4/06 , C08F4/60 , C08F4/70 , C08F4/80 , C08F10/00 , C08F10/02 , C08F10/06 , C08F10/08 , C08F12/30 , C08F20/06 , C08F110/02 , C08F110/06 , C08F110/14 , C08F132/04 , C08F210/02 , C08F210/14 , C08F210/16 , C08F220/10 , C08F232/00 , C08F232/04 , C08F255/00 , C08L23/02
CPC分类号： C08F110/02 , C08F110/06 , C08F210/02 , C08F210/14 , C08F210/16 , C08L23/02 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/14 , C08F232/00 , Y10S430/165 , Y10T428/1352 , Y10T428/1386 , Y10T428/139 , Y10T428/24942 , Y10T428/2878 , Y10T428/31692 , Y10T428/31855 , Y10T428/31895 , Y10T428/31938 , Y10T442/20 , Y10T442/60 , Y10T442/626
摘要： Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear .alpha.-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected .alpha.-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected .alpha.-diimine nickel complexes with ethylene.
摘要翻译： 本文公开了聚合乙烯，无环烯烃和/或选择的环烯烃，和任选选择的烯属酯或羧酸和其它单体的方法。 聚合由选择的过渡金属化合物，有时是其他助催化剂催化。 由于一些聚合表现出活性聚合的某些特性，因此可以容易地制备嵌段共聚物。 所生产的许多聚合物通常是新颖的，特别是在它们的微结构方面，这给出了其中一些不寻常的性质。 公开了许多新颖的催化剂，以及一些制备它们的新方法。 制备的聚合物可用作弹性体，模塑树脂，粘合剂等。本文还描述了通过使用作为催化剂体系的乙烯低聚来合成线性α-烯烃，将具有选定的α-二亚胺配体的镍化合物和 选择的Lewis或布朗斯台德酸，或通过使选择的α-二亚胺镍络合物与乙烯接触。
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公开(公告)号：US5714556A
公开(公告)日：1998-02-03
申请号：US671392
申请日：1996-06-27
申请人： Lynda Kaye Johnson , Jerald Feldman , Kristina Ann Kreutzer , Stephan James McLain , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Dennis Scott Donald , Lissa Taka Jennings Nelson , Anju Parthasarathy , Xing Shen , Wilson Tam , Yueli Wang
发明人： Lynda Kaye Johnson , Jerald Feldman , Kristina Ann Kreutzer , Stephan James McLain , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Dennis Scott Donald , Lissa Taka Jennings Nelson , Anju Parthasarathy , Xing Shen , Wilson Tam , Yueli Wang
IPC分类号： C07F15/04 , C08F4/06 , C08F4/70 , C08F10/00 , C08F10/02 , C08F12/00 , C08F12/04 , C08F12/08 , C08F32/08 , C08F36/00 , C08F36/20 , C08F110/02 , C08F210/02
CPC分类号： C08F32/08 , C07F15/04 , C08F10/00 , C08F10/02 , C08F12/08 , C08F110/02 , C08F210/02
摘要： Disclosed herein is a process for the polymerization of ethylene, norbornenes and styrenes, by contacting in solution a selected nickel compound and a selected compound which is or can coordinated to the nickel with the olefin(s). The polymers produced are useful for films and molding resins.
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公开(公告)号：US07919423B2
公开(公告)日：2011-04-05
申请号：US12698288
申请日：2010-02-02
IPC分类号： B01J31/00 , B01J27/135 , B01J21/04 , B01J23/02
CPC分类号： C09D175/04 , B01J31/0202 , B01J31/0207 , B01J31/0211 , B01J31/28 , B01J2531/42 , C07F7/2208 , C07F7/2288 , C08G18/242 , C08G18/792
摘要： This invention relates to an organotin-based catalyst system for polyurethane synthesis that is useful in coatings applications. The catalyst has low activity in the absence of oxygen. When a coating mixture comprising the catalyst is sprayed and/or applied to a substrate as a thin film in air, the catalyst is activated. For solvent-based refinish systems comprising hydroxyl and isocyanate species at high solids levels, the catalyst system therefore provides extended viscosity stability, i.e., pot life.
摘要翻译： 本发明涉及用于聚氨酯合成的有机锡基催化剂体系，其可用于涂料应用。 催化剂在不存在氧的情况下具有低活性。 当包含催化剂的涂料混合物在空气中作为薄膜喷涂和/或施加到基材上时，催化剂被活化。 对于含有高固体含量的羟基和异氰酸酯物质的基于溶剂的修补体系，催化剂体系因此提供了延长的粘度稳定性，即适用期。
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5.发明申请公开(公告)号：US20100213454A1
公开(公告)日：2010-08-26
申请号：US12738460
申请日：2008-10-24
申请人： Charles D. Lang , Paul Anthony Sant , Jerald Feldman , Steven Dale Ittel , Stephan James McLain
发明人： Charles D. Lang , Paul Anthony Sant , Jerald Feldman , Steven Dale Ittel , Stephan James McLain
CPC分类号： H01L51/0005 , G03F7/0046 , G03F7/027 , H01G11/48 , H01G11/56 , H01L51/0003 , H01L51/0012 , H01L51/5048 , H01L51/56 , Y02E60/13
摘要： There is provided a process for forming a contained second layer over a first layer. The process comprises forming the first layer having a first surface energy and then treating the first layer with a photocurable surface-active composition which is a fluorinated ester or fluorinated imide of an α,β-unsaturated polyacid; exposing the photocurable surface-active composition patternwise with radiation resulting in exposed areas and unexposed areas; developing the photocurable surface-active composition to remove the unexposed areas resulting in a first layer having untreated portions in the unexposed areas and treated portions in the exposed areas, where the treated portions have a second surface energy that is lower than the first surface energy; and forming the second layer on the untreated portions of the first layer. There is also provided an organic electronic device made by the process.
摘要翻译： 提供了一种用于在第一层上形成包含的第二层的方法。 该方法包括形成具有第一表面能的第一层，然后用可光固化的表面活性组合物处理第一层，该组合物是α，β-不饱和多元酸的氟化酯或氟化酰亚胺; 用辐射曝光可光固化的表面活性组合物，导致曝光区域和未曝光区域; 显影可光固化表面活性组合物以除去未曝光区域，从而在未曝光区域中具有未处理部分的第一层和暴露区域中的处理部分，其中处理部分具有低于第一表面能的第二表面能; 以及在所述第一层的未处理部分上形成所述第二层。 还提供了通过该方法制造的有机电子装置。
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公开(公告)号：US6002034A
公开(公告)日：1999-12-14
申请号：US172367
申请日：1998-10-14
IPC分类号： C07C251/20 , C07F15/04 , C08F4/70 , C08F10/00 , C08F32/08 , C08F297/08 , C07F15/02 , C07C249/00
CPC分类号： C08F32/08 , C07C251/20 , C07F15/045 , C08F10/00 , C08F297/08 , C07C2103/20 , C08F110/14
摘要： Certain olefins such as ethylene, .alpha.-olefins and cyclopentene can be polymerized by using catalyst system containing a nickel or palladium .alpha.-diimine complex, a metal containing hydrocarbylation compound, and a selected Lewis acid, or a catalyst system containing certain nickel[II] or palladium[II] compounds, an .alpha.-diimine, a metal containing hydrocarbylation compound, and optionally a selected Lewis acid. The process advantageously produces polyolefins useful for molding resins, films, elastomers and other uses.
摘要翻译： 某些烯烃如乙烯，α-烯烃和环戊烯可以通过使用含有镍或钯的α-二亚胺络合物，含有金属的烃基化合物和选择的路易斯酸的催化剂体系或含有某些镍[II] 或钯[II]化合物，α-二亚胺，含金属的烃基化合物和任选的选择的路易斯酸。 该方法有利地产生可用于模制树脂，薄膜，弹性体和其它用途的聚烯烃。
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7.发明授权公开(公告)号：US08309376B2
公开(公告)日：2012-11-13
申请号：US12738460
申请日：2008-10-24
申请人： Charles D. Lang , Paul Anthony Sant , Jerald Feldman , Steven Dale Ittel , Stephan James McLain
发明人： Charles D. Lang , Paul Anthony Sant , Jerald Feldman , Steven Dale Ittel , Stephan James McLain
CPC分类号： H01L51/0005 , G03F7/0046 , G03F7/027 , H01G11/48 , H01G11/56 , H01L51/0003 , H01L51/0012 , H01L51/5048 , H01L51/56 , Y02E60/13
摘要： There is provided a process for forming a contained second layer over a first layer. The process comprises forming the first layer having a first surface energy and then treating the first layer with a photocurable surface-active composition which is a fluorinated ester or fluorinated imide of an α,β-unsaturated polyacid; exposing the photocurable surface-active composition patternwise with radiation resulting in exposed areas and unexposed areas; developing the photocurable surface-active composition to remove the unexposed areas resulting in a first layer having untreated portions in the unexposed areas and treated portions in the exposed areas, where the treated portions have a second surface energy that is lower than the first surface energy; and forming the second layer on the untreated portions of the first layer. There is also provided an organic electronic device made by the process.
摘要翻译： 提供了一种用于在第一层上形成包含的第二层的方法。 该方法包括形成具有第一表面能的第一层，然后用可光固化的表面活性组合物处理第一层，该组合物是α，β-不饱和多元酸的氟化酯或氟化酰亚胺; 用辐射曝光可光固化的表面活性组合物，导致曝光区域和未曝光区域; 显影所述光固化性表面活性组合物以除去未曝光区域，从而在未曝光区域中具有未处理部分的第一层和暴露区域中的处理部分，其中处理部分具有低于第一表面能的第二表面能; 以及在所述第一层的未处理部分上形成所述第二层。 还提供了通过该方法制造的有机电子装置。
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公开(公告)号：US06310163B1
公开(公告)日：2001-10-30
申请号：US08899002
申请日：1997-07-10
申请人： Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Samuel David Arthur , Jerald Feldman , Elizabeth Forrester McCord , Stephan James McLain , Kristina Ann Kreutzer , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Steven Dale Ittel , Anju Parthasarathy , Daniel Joseph Tempel
发明人： Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Samuel David Arthur , Jerald Feldman , Elizabeth Forrester McCord , Stephan James McLain , Kristina Ann Kreutzer , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Steven Dale Ittel , Anju Parthasarathy , Daniel Joseph Tempel
IPC分类号： C08F22010
CPC分类号： C08F110/02 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/06 , C08F110/14 , C08F210/02 , C08F210/14 , C08F210/16 , C08F232/00 , C08L23/02 , Y10S430/165 , Y10T428/1352 , Y10T428/1386 , Y10T428/139 , Y10T428/24942 , Y10T428/2878 , Y10T428/31692 , Y10T428/31855 , Y10T428/31895 , Y10T428/31938 , Y10T442/20 , Y10T442/60 , Y10T442/626
摘要： Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear &agr;-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected &agr;-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected &agr;-diimine nickel complexes with ethylene.
摘要翻译： 本文公开了聚合乙烯，无环烯烃和/或选择的环烯烃，和任选选择的烯属酯或羧酸和其它单体的方法。 聚合由选择的过渡金属化合物，有时是其他助催化剂催化。 由于一些聚合表现出活性聚合的某些特性，因此可以容易地制备嵌段共聚物。 所生产的许多聚合物通常是新颖的，特别是关于它们的微观结构，这给出了其中一些不寻常的性质。 公开了许多新颖的催化剂，以及一些制备它们的新方法。 制备的聚合物可用作弹性体，模塑树脂，粘合剂等。本文还描述了通过使用作为催化剂体系的乙烯低聚法合成线性α-烯烃，将具有选定的α-二亚胺配体的镍化合物和 选择的Lewis或布朗斯台德酸，或通过使选择的α-二亚胺镍络合物与乙烯接触。
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公开(公告)号：US5866663A
公开(公告)日：1999-02-02
申请号：US891332
申请日：1997-07-10
申请人： Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Samuel David Arthur , Jerald Feldman , Elizabeth Forrester McCord , Stephan James McLain , Kristina Ann Kreutzer , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Steven Dale Ittel , Anju Parthasarathy , Lin Wang , Zhen-Yu Yang
发明人： Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Samuel David Arthur , Jerald Feldman , Elizabeth Forrester McCord , Stephan James McLain , Kristina Ann Kreutzer , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Steven Dale Ittel , Anju Parthasarathy , Lin Wang , Zhen-Yu Yang
IPC分类号： B01J31/00 , B01J37/00 , C07C2/32 , C07C69/52 , C07C251/08 , C07F7/00 , C07F15/00 , C07F19/00 , C08F4/02 , C08F4/06 , C08F4/60 , C08F4/70 , C08F4/80 , C08F10/00 , C08F10/02 , C08F10/06 , C08F10/08 , C08F12/30 , C08F20/06 , C08F110/02 , C08F110/06 , C08F110/14 , C08F132/04 , C08F210/02 , C08F210/14 , C08F210/16 , C08F220/10 , C08F232/00 , C08F232/04 , C08F255/00 , C08L23/02
CPC分类号： C08F110/02 , C08F110/06 , C08F210/02 , C08F210/14 , C08F210/16 , C08L23/02 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/14 , C08F232/00 , Y10S430/165 , Y10T428/1352 , Y10T428/1386 , Y10T428/139 , Y10T428/24942 , Y10T428/2878 , Y10T428/31692 , Y10T428/31855 , Y10T428/31895 , Y10T428/31938 , Y10T442/20 , Y10T442/60 , Y10T442/626
摘要： Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear .alpha.-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected .alpha.-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected .alpha.-diimine nickel complexes with ethylene.
摘要翻译： 本文公开了聚合乙烯，无环烯烃和/或选择的环烯烃，和任选选择的烯属酯或羧酸和其它单体的方法。 聚合由选择的过渡金属化合物，有时是其他助催化剂催化。 由于一些聚合表现出活性聚合的某些特性，因此可以容易地制备嵌段共聚物。 所生产的许多聚合物通常是新颖的，特别是在它们的微结构方面，这给出了其中一些不寻常的性质。 公开了许多新颖的催化剂，以及一些制备它们的新方法。 制备的聚合物可用作弹性体，模塑树脂，粘合剂等。本文还描述了通过使用作为催化剂体系的乙烯低聚来合成线性α-烯烃，将具有选定的α-二亚胺配体的镍化合物和 选择的Lewis或布朗斯台德酸，或通过使选择的α-二亚胺镍络合物与乙烯接触。
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公开(公告)号：US5852145A
公开(公告)日：1998-12-22
申请号：US897805
申请日：1997-07-21
IPC分类号： C07C251/20 , C07F15/04 , C08F4/70 , C08F10/00 , C08F32/08 , C08F297/08
CPC分类号： C08F32/08 , C07C251/20 , C07F15/045 , C08F10/00 , C08F297/08 , C07C2103/20 , C08F110/14
摘要： Certain olefins such as ethylene, .alpha.-olefins and cyclopentene can be polymerized by using catalyst system containing a nickel or palladium .alpha.-diimine complex, a metal containing hydrocarbylation compound, and a selected Lewis acid, or a catalyst system containing certain nickel �II! or palladium �II! compounds, an .alpha.-diimine, a metal containing hydrocarbylation compound, and optionally a selected Lewis acid. The process advantageously produces polyolefins useful for molding resins, films, elastomers and other uses.
摘要翻译： 某些烯烃如乙烯，α-烯烃和环戊烯可以通过使用含有镍或钯的α-二亚胺络合物，含有金属的烃基化合物和选择的路易斯酸的催化剂体系或含有某些镍[II] 或钯[II]化合物，α-二亚胺，含金属的烃基化合物和任选的选择的路易斯酸。 该方法有利地产生可用于模制树脂，薄膜，弹性体和其它用途的聚烯烃。
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