Abstract:
Provided herein are poly-capped estolides, including those of the Formula IV in which n is an integer equal to or greater than 0; m is an integer equal to or greater than 2; R1 is selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; R2 is selected from hydrogen and optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; and R3 and R4, independently for each occurrence, are selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched. Hydroxy estolides are also described herein, which may be suitable end products, or serve as intermediates to provide poly-capped estolides. Also provided are compositions containing poly-capped estolides and methods of making both said poly-capped estolides and compositions thereof.
Abstract:
Provided herein are processes for preparing estolides and estolide base oils from fatty acid reactants utilizing catalysts. Further provided herein are processes for preparing carboxylic esters from at least one carboxylic acid reactant and at least one olefin.
Abstract:
Provided herein are compositions comprising at least one estolide compound of formula: in which n is an integer equal to or greater than 0; m is an integer equal to or greater than 1; R1, independently for each occurrence, is selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; R2 is selected from hydrogen and optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; and R3 and R4, independently for each occurrence, are selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched. Also provided are uses of the compositions described herein.
Abstract:
Provided herein are dielectric fluids comprising at least one estolide compound of formula: in which n is an integer equal to or greater than 0; m is an integer equal to or greater than 1; R1, independently for each occurrence, is selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; R2 is selected from hydrogen and optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; and R3 and R4, independently for each occurrence, are selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched. Also provided herein are uses of dielectric fluids and electrical devices such as transformers that comprise a dielectric fluid comprising at least one estolide compound.
Abstract:
Provided herein are estolide compositions having high oxidative stability, said compositions comprising at least one compound of formula: in which n is an integer equal to or greater than 0; m is an integer equal to or greater than 1; R1, independently for each occurrence, is selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; R2 is selected from hydrogen and optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; and R3 and R4, independently for each occurrence, are selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched. Also provided herein are uses for the compositions and methods of preparing the same.
Abstract translation:本发明提供了具有高氧化稳定性的耳粉剂组合物,所述组合物包含至少一种下式化合物:其中n为等于或大于0的整数; m是等于或大于1的整数; 独立地,R 1独立地选自任选取代的饱和或不饱和的,支链或非支链的烷基; R2选自氢和任选取代的饱和或不饱和的烷基,并且是支链或非支链的; R 3和R 4各自独立地选自任选取代的饱和或不饱和的,分支或非支链的烷基。 本文还提供了组合物及其制备方法的用途。
Abstract:
A device for centering a work piece with respect to a centerline of a tool includes a radially-stationary component rigidly secured with respect to the tool such that the radially-stationary component and the tool are concentric. A biasing mechanism is biased away from the radially-stationary component to apply substantially equally-distributed radial force at a periphery of the work piece to thereby center the work piece with respect to the tool. A method of broaching a work piece having an inner and an outer diameter includes machining the outer diameter and then applying circumferentially-distributed radial force to the inner diameter or the outer diameter to thereby center the work piece with respect to a broach tool. After the applying step, the method includes broaching the inner diameter of the work piece using the broach tool.
Abstract:
A bottle holder that automatically seals a bottle opening when the bottle holder is placed for storage. The bottle may rest within a recess of the holder base, and the nozzle of the bottle is held in place by a nozzle catch that is conically shaped and has an inner cup that tapers to a terminal point so that a nozzle that it placed within will be sealed by the inner wall of the cup. The nozzle catch is spring loaded and presses down against the bottle to hold it in place and maintain a seal on the nozzle. A bottle may be placed in the holder by positioning a nozzle in the nozzle catch on the upper side of the holder and pushing upwards and inwards, which causes the spring to compress and allows the bottle bottom to pass over the base and into the recess.
Abstract:
Provided herein are estolide compositions having high oxidative stability, said compositions comprising at least one compound of formula: in which n is an integer equal to or greater than 0; m is an integer equal to or greater than 1; R1, independently for each occurrence, is selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; R2 is selected from hydrogen and optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; and R3 and R4, independently for each occurrence, are selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched. Also provided herein are uses for the compositions and methods of preparing the same.
Abstract translation:其中n是等于或大于0的整数; m是等于或大于1的整数; 独立地,R 1独立地选自任选取代的饱和或不饱和的,支链或非支链的烷基; R2选自氢和任选取代的饱和或不饱和的烷基,并且是支链或非支链的; R 3和R 4各自独立地选自任选取代的饱和或不饱和的,分支或非支链的烷基。 本文还提供了组合物及其制备方法的用途。
Abstract:
Provided herein are estolide base oils and oligomeric compounds prepared from processes that include cross metathesis. Exemplary processes include the preparation of terminally-unsaturated fatty acids by cross metathesis, and the subsequent oligomerization of terminally-unsaturated fatty acids to provide estolide compounds, such as the process set forth below:
Abstract:
Provided herein are compositions comprising at least one estolide compound of formula: in which n is an integer equal to or greater than 0; m is an integer equal to or greater than 1; R1, independently for each occurrence, is selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; R2 is selected from hydrogen and optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; and R3 and R4, independently for each occurrence, are selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched. Also provided are uses of the compositions described herein.
Abstract translation:本文提供的组合物包含至少一种下式的炔雌醇化合物:其中n为等于或大于0的整数; m是等于或大于1的整数; 独立地,R 1独立地选自任选取代的饱和或不饱和的,支链或非支链的烷基; R2选自氢和任选取代的饱和或不饱和的烷基,并且是支链或非支链的; R 3和R 4各自独立地选自任选取代的饱和或不饱和的,分支或非支链的烷基。 还提供了本文所述的组合物的用途。