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    Process for preparing a dielectric interlayer film containing silicon beta zeolite
    22.
    发明申请
    Process for preparing a dielectric interlayer film containing silicon beta zeolite 审中-公开
    制备含硅β沸石的介电中间膜的方法

    公开(公告)号：US20060142143A1

    公开(公告)日：2006-06-29

    申请号：US11012809

    申请日：2004-12-15

    申请人： Hayim Abrevaya ,  Richard Willis ,  Stephen Wilson

    发明人： Hayim Abrevaya ,  Richard Willis ,  Stephen Wilson

    IPC分类号： B01J29/04

    CPC分类号： C01B39/026

    摘要： A process for forming a zeolite beta dielectric layer onto a substrate such as a silicon wafer has been developed. The zeolite beta is characterized in that it has a Si/Al of at least 25 and has crystallites from about 5 to about 40 nanometers. The process involves first dealuminating a starting zeolite beta, then preparing a slurry of the dealuminated zeolite beta followed by coating a substrate, e.g. silicon wafer with the slurry, heating to form a zeolite beta film and treating the zeolite beta with a silylating agent.

    摘要翻译： 已经开发了用于在诸如硅晶片的基底上形成沸石β电介质层的工艺。 沸石β的特征在于其具有至少25的Si / Al，并且具有约5至约40纳米的微晶。 该方法首先对起始沸石β进行脱铝，然后制备脱铝沸石β的浆料，然后涂覆底物，例如。 硅晶片与浆料，加热形成沸石β膜并用甲硅烷基化剂处理沸石β。

    Process for oligomer production and saturation
    23.
    发明授权
    Process for oligomer production and saturation 失效
    低聚物生产和饱和的过程

    公开(公告)号：US06689927B1

    公开(公告)日：2004-02-10

    申请号：US09850471

    申请日：2001-05-07

    申请人： Robert R. Frame ,  Laurence O. Stine ,  Hayim Abrevaya

    发明人： Robert R. Frame ,  Laurence O. Stine ,  Hayim Abrevaya

    IPC分类号： C07C206

    CPC分类号： C07C2/08 ,  C07C2/18 ,  C07C2527/173 ,  C07C11/113

    摘要： A process for the production of C8 alkenes with high selectivities to 2,4,4-trimethylpentene by the oligomerization of isobutene and/or n-butene at lower temperatures is disclosed. Higher proportions of heavy paraffins mixed with the butene feed in the oligomerization zone improve the selectivity to 2,4,4-trimethylpentene along with better selectivity to octene and lower selectivity to dodecene. Additionally, we have found that n-butene codimerizes with isobutene selectively to 2,4,4-trimethylpentene.

    摘要翻译： 公开了通过在较低温度下异丁烯和/或正丁烯低聚生产具有高选择性的C8烯烃的方法制备2,4,4-三甲基戊烯的方法。 在低聚区域中与丁烯进料混合的较高比例的重链烷烃提高了对2,4,4-三甲基戊烯的选择性，同时具有对辛烯的更好的选择性和对十二碳烯的较低选择性。 另外，我们已经发现，正丁烯与异丁烯选择性地与2,4,4-三甲基戊烯进行编码。

    Reaction process in hybrid reactor for propylene ammoxidation
    24.
    发明授权
    Reaction process in hybrid reactor for propylene ammoxidation 失效
    用于丙烯氨氧化的混合反应器中的反应过程

    公开(公告)号：US06649130B1

    公开(公告)日：2003-11-18

    申请号：US09635953

    申请日：2000-08-10

    申请人： Robert L. Zhou ,  W. Patrick Dennler ,  Anil R. Oroskar ,  Bipin V. Vora ,  Hayim Abrevaya ,  Laurence O. Stine

    发明人： Robert L. Zhou ,  W. Patrick Dennler ,  Anil R. Oroskar ,  Bipin V. Vora ,  Hayim Abrevaya ,  Laurence O. Stine

    IPC分类号： B01J808

    CPC分类号： B01J8/0055 ,  B01J8/1827 ,  B01J8/26 ,  B01J19/26 ,  B01J2208/00132 ,  B01J2208/00292 ,  B01J2208/00548 ,  C07C253/26 ,  Y02P20/52 ,  C07C255/08

    摘要： A hybrid reactor arrangement provides a reactive design that achieves higher acrylonitrile yield and lower catalyst circulating rate. The hybrid reactor design first passes a mixture of reactants and catalyst through a circulating bubbling bed reaction section. Heat exchange coils or other cooling medium in the bubbling bed reactor section maintain temperature in a range that will maximize the selectivity of reactants to the acrylonitrile product. The bubbling bed reactor section provides the initial conversion of the reactant. A circulating fluidized bed reaction zone finishes the conversion of reactants to a high yield under conditions that reduce the occurrence of secondary reactions that could otherwise produce unwanted by-products. The circulating fluidized bed reactor section maintains nearly plug flow conditions that allow continued conversion of unreacted feed components through primary reactions while limiting the time for secondary reactions to continue and diminish the final yield of products. Selectivity and conversion may also be improved by sequential addition of oxygen into the CFB reaction section. The sequential addition of oxygen may occur by the direct injection of an oxygen-containing gas or by the delivery of re-oxidized catalyst particles that are fully recharged with the lattice oxygen necessary for the reaction. Through this method the hybrid reactor provides the typical 5% improvement of higher acrylonitrile product yield from CFB-type reaction zones while reducing the required catalyst circulation by a factor of 10 or more.

    摘要翻译： 混合反应器装置提供了实现较高丙烯腈产率和较低催化剂循环速率的反应性设计。 混合反应器设计首先将反应物和催化剂的混合物通过循环鼓泡床反应段。 鼓泡床反应器部分中的热交换盘管或其它冷却介质将温度保持在使反应物对丙烯腈产物的选择性最大化的范围内。 起泡床反应器部分提供反应物的初始转化。 循环流化床反应区在减少可能产生不需要的副产物的次级反应的情况下，完成反应物转化为高收率。 循环流化床反应器部分保持几乎堵塞流动条件，其允许未反应的进料组分继续转化通过初级反应，同时限制二级反应的持续时间并降低产物的最终产率。 还可以通过将顺序加入到CFB反应部分中来提高选择性和转化率。 氧的顺序添加可以通过直接注入含氧气体或通过输送用反应所需的晶格氧充分再充电的再氧化的催化剂颗粒进行。 通过该方法，混合反应器提供了CFB型反应区中较高丙烯腈产物产率的典型的5％的改进，同时将需要的催化剂循环减少10倍或更多。

    Reaction process in hybrid reactor for propylene ammoxidation
    25.
    发明授权
    Reaction process in hybrid reactor for propylene ammoxidation 有权

    公开(公告)号：US6143915A

    公开(公告)日：2000-11-07

    申请号：US198300

    申请日：1998-11-23

    申请人： Lubo Zhou ,  W. Patrick Dennler ,  Anil R. Oroskar ,  Bipin V. Vora ,  Hayim Abrevaya ,  Laurence O. Stine

    发明人： Lubo Zhou ,  W. Patrick Dennler ,  Anil R. Oroskar ,  Bipin V. Vora ,  Hayim Abrevaya ,  Laurence O. Stine

    IPC分类号： B01J8/00 ,  B01J8/24 ,  B01J8/26 ,  B01J19/26 ,  C07C253/26 ,  C07C255/08 ,  C07C253/00

    CPC分类号： B01J8/0055 ,  B01J19/26 ,  B01J8/1827 ,  B01J8/26 ,  C07C253/26 ,  B01J2208/00132 ,  B01J2208/00292 ,  B01J2208/00548 ,  Y02P20/52

    摘要： A hybrid reactor arrangement provides a reactive design that achieves higher acrylonitrile yield and lower catalyst circulating rate. The hybrid reactor design first passes a mixture of reactants and catalyst through a circulating bubbling bed reaction section. Heat exchange coils or other cooling medium in the bubbling bed reactor section maintain temperature in a range that will maximize the selectivity of reactants to the acrylonitrile product. The bubbling bed reactor section provides the initial conversion of the reactant. A circulating fluidized bed reaction zone finishes the conversion of reactants to a high yield under conditions that reduce the occurrence of secondary reactions that could otherwise produce unwanted by-products. The circulating fluidized bed reactor section maintains nearly plug flow conditions that allow continued conversion of unreacted feed components through primary reactions while limiting the time for secondary reactions to continue and diminish the final yield of products. Selectivity and conversion may also be improved by sequential addition of oxygen into the CFB reaction section. The sequential addition of oxygen may occur by the direct injection of an oxygen-containing gas or by the delivery of re-oxidized catalyst particles that are fully recharged with the lattice oxygen necessary for the reaction. Through this method the hybrid reactor provides the typical 5% improvement of higher acrylonitrile product yield from CFB-type reaction zones while reducing the required catalyst circulation by a factor of 10 or more.

    Mixture of catalysts for cracking naphtha to olefins
    26.
    发明授权
    Mixture of catalysts for cracking naphtha to olefins 有权
    石脑油裂解烯烃的催化剂混合物

    公开(公告)号：US08137533B2

    公开(公告)日：2012-03-20

    申请号：US12257929

    申请日：2008-10-24

    申请人： Gavin P. Towler ,  Hayim Abrevaya

    发明人： Gavin P. Towler ,  Hayim Abrevaya

    IPC分类号： C10G11/05

    CPC分类号： C10G11/05 ,  C10G2300/1044 ,  C10G2300/4018 ,  C10G2400/20

    摘要： A process is presented for the selective catalytic cracking of naphtha to light olefins. The process includes contacting a naphtha feedstream with a mixture of catalysts to reduce the amount of recycle, and especially the recycle of light paraffins. The mixture of catalysts includes a first molecular sieve made up from a small pore zeolite having a pore index between 13 and 26, and a second molecular sieve made up from an intermediate pore zeolite having a pore index between 26 and 30.

    摘要翻译： 介绍了石脑油对轻质烯烃的选择性催化裂化的方法。 该方法包括使石脑油原料流与催化剂的混合物接触以减少再循环的量，特别是轻链烷烃的再循环。 催化剂的混合物包括由孔隙率为13至26的小孔沸石构成的第一分子筛和由具有26至30的孔隙指数的中间孔沸石制成的第二分子筛。

    Hydrocarbon Conversion Using An Improved Molecular Sieve
    27.
    发明申请
    Hydrocarbon Conversion Using An Improved Molecular Sieve 失效
    使用改进的分子筛的烃转化

    公开(公告)号：US20100152512A1

    公开(公告)日：2010-06-17

    申请号：US12365584

    申请日：2009-02-04

    申请人： Hayim Abrevaya ,  Julio C. Marte ,  John E. Bauer

    发明人： Hayim Abrevaya ,  Julio C. Marte ,  John E. Bauer

    IPC分类号： C07C5/22

    CPC分类号： C07C5/2737 ,  C07C5/2775 ,  C07C15/08

    摘要： The present invention comprises a hydrocarbon-conversion process using an improved MgMxAPSO-31 molecular sieve which demonstrates a favorable combination of conversion and selectivity in aromatics conversion. The sieve comprises at least two divalent elements with narrow specific concentration limits in the framework structure having defined crystal characteristics. The element Mx may comprise one or more of manganese, cobalt, nickel, iron and zinc.

    摘要翻译： 本发明包括使用改进的MgMxAPSO-31分子筛的烃转化方法，其表现出芳烃转化率的转化率和选择性的有利组合。 该筛包含至少两个具有限定晶体特征的骨架结构中具有窄比浓度极限的二价元素。 元素Mx可以包含锰，钴，镍，铁和锌中的一种或多种。

    Molecular Sieve
    29.
    发明申请
    Molecular Sieve 审中-公开
    分子筛

    公开(公告)号：US20100152025A1

    公开(公告)日：2010-06-17

    申请号：US12365545

    申请日：2009-02-04

    申请人： Hayim Abrevaya ,  Julio C. Marte

    发明人： Hayim Abrevaya ,  Julio C. Marte

    IPC分类号： B01J29/068 ,  C01B39/02 ,  B01J29/06

    CPC分类号： C01B39/54 ,  B01J23/42 ,  B01J29/84 ,  B01J29/85 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/20 ,  B01J2229/20 ,  B01J2229/42 ,  C07C5/2708 ,  Y02P20/52 ,  C07C15/08

    摘要： The present invention comprises an improved MgMxAPSO-31 molecular sieve and a catalyst composite which demonstrates a favorable combination of conversion and selectivity in aromatics conversion. The sieve comprises a at least two divalent elements with narrow specific concentration limits in the framework structure having defined crystal characteristics. The element Mx may comprise one or more of manganese, cobalt, nickel, iron and zinc.

    摘要翻译： 本发明包括改进的MgMxAPSO-31分子筛和催化剂复合物，其表现出在芳烃转化中转化率和选择性的有利组合。 该筛包括具有限定的晶体特性的骨架结构中具有窄特定浓度限度的至少两个二价元素。 元素Mx可以包含锰，钴，镍，铁和锌中的一种或多种。

    Mixture of Catalysts for Cracking Naphtha to Olefins
    30.
    发明申请
    Mixture of Catalysts for Cracking Naphtha to Olefins 有权
    用于裂解石脑油与烯烃的混合物

    公开(公告)号：US20100105974A1

    公开(公告)日：2010-04-29

    申请号：US12257929

    申请日：2008-10-24

    申请人： Gavin P. Towler ,  Hayim Abrevaya

    发明人： Gavin P. Towler ,  Hayim Abrevaya

    IPC分类号： C07C4/02

    CPC分类号： C10G11/05 ,  C10G2300/1044 ,  C10G2300/4018 ,  C10G2400/20

    摘要： A process is presented for the selective catalytic cracking of naphtha to light olefins. The process includes contacting a naphtha feedstream with a mixture of catalysts to reduce the amount of recycle, and especially the recycle of light paraffins. The mixture of catalysts includes a first molecular sieve made up from a small pore zeolite having a pore index between 13 and 26, and a second molecular sieve made up from an intermediate pore zeolite having a pore index between 26 and 30.

    摘要翻译： 介绍了石脑油对轻质烯烃的选择性催化裂化的方法。 该方法包括使石脑油原料流与催化剂的混合物接触以减少再循环的量，特别是轻链烷烃的再循环。 催化剂的混合物包括由孔隙率为13至26的小孔沸石构成的第一分子筛和由具有26至30的孔隙指数的中间孔沸石制成的第二分子筛。