摘要:
Refractory or hard sulfur found in a hydrocarbon stream containing refractory sulfur heterocycle compounds, particularly those exhibiting steric hindrance, is removed from the stream by contacting it with a sodium reagent comprising a sodium component, having free sodium, supported on a solid support component. If the hydrocarbon stream contains more labile or easy sulfur, then it is treated, typically by hydrodesulfurization, to remove at least most of the labile sulfur before it is contacted with the sodium reagent. This is useful for bringing the sulfur level of middle distillate fuel streams, such as diesel and jet fuel fractions, down to a level of less than about 10 wppm, employing conventional hydrodesulfurizing catalysts and conditions.
摘要:
Multi-control password changing includes initiating a password change cycle to change a target user's password, selecting a plurality of administrators to provide password part inputs, receiving password part inputs separately and confidentially from the plurality of administrators, generating a multi-control password comprised of multiple password part inputs, changing the target user's password to the multi-control password, and transmitting either the single multi-control password or multiple password parts each separately to target user. In an exemplary embodiment, a system for multi-control password changing includes a multi-control password changing module configured to change a target user's password, a recruitment module configured to select a plurality of administrators to provide password part inputs, a regulation module configured to receive and process password part inputs from the plurality of administrators, and a change value module configured to generate a multi-control password comprised of multiple password part inputs.
摘要:
The present invention relates to methods and systems for removing polar molecule contaminants from a refinery stream in connection with the processing of hydrocarbon fluids, chemicals, whole crude oils, blends and fractions in refineries and chemical plants that include adding high surface energy and/or high surface area nanoparticle compounds to a refinery stream to remove the polar molecule contaminants.
摘要:
A gas separation process uses a structured particulate bed of adsorbent coated shapes/particles laid down in the bed in an ordered manner to simulate a monolith by providing longitudinally extensive gas passages by which the gas mixture to be separated can access the adsorbent material along the length of the particles. The particles can be laid down either directly in the bed or in locally structured packages/bundles which themselves are similarly oriented such that the bed particles behave similarly to a monolith but without at least some disadvantages. The adsorbent particles can be formed with a solid, non-porous core with the adsorbent formed as a thin, adherent coating on the exposed exterior surface. Particles may be formed as cylinders/hollow shapes to provide ready access to the adsorbent. The separation may be operated as a kinetic or equilibrium controlled process.
摘要:
A gas separation process uses a structured particulate bed of adsorbent coated shapes/particles laid down in the bed in an ordered manner to simulate a monolith by providing longitudinally extensive gas passages by which the gas mixture to be separated can access the adsorbent material along the length of the particles. The particles can be laid down either directly in the bed or in locally structured packages/bundles which themselves are similarly oriented such that the bed particles behave similarly to a monolith but without at least some disadvantages. The adsorbent particles can be formed with a solid, non-porous core with the adsorbent formed as a thin, adherent coating on the exposed exterior surface. Particles may be formed as cylinders/hollow shapes to provide ready access to the adsorbent. The separation may be operated as a kinetic or equilibrium controlled process.
摘要:
A method and system for drilling a wellbore is described. The system includes a wellbore with a variable density drilling mud, drilling pipe, a bottom hole assembly disposed in the wellbore and a drilling mud processing unit in fluid communication with the wellbore. The variable density drilling mud has compressible particles and drilling fluid. The bottom hole assembly is coupled to the drilling pipe while the drilling mud processing unit is configured to separate the compressible particles from the variable density drilling mud. The compressible particles in this embodiment may include compressible hollow objects filled with pressurized gas an configured to maintain the mud weight between the fracture pressure gradient and the pore pressure gradient. In addition, the system and method may also manage the use of compressible particles having different characteristics, such as size, during the drilling operations.
摘要:
Methods for fabricating compressible object are described. These compressible objects may be utilized in drilling mud and with a drilling system to manage the density of the drilling mud. The method includes selecting an architecture for a compressible object; selecting a wall material for the compressible object; and fabricating the compressible object, wherein the compressible object has a shell that encloses an interior region, and has an internal pressure (i) greater than about 200 pounds per square inch at atmospheric pressure and (ii) selected for a predetermined external pressure, wherein external pressures that exceed the internal pressure reduce the volume of the compressible object.
摘要:
An apparatus removes CO from a hydrogen-rich gas stream in a hydrogen fuel cell system. CO fouls costly catalytic particles in the membrane electrode assemblies. Both a catalyst adapted to perform a water gas shift reaction, and a carbon dioxide adsorbent are disposed in a rotating pressure swing adsorber housing. The adsorption of carbon dioxide shifts equilibrium toward carbon monoxide consumption. A second adsorbent may be disposed in the housing for adsorbing carbon monoxide at low temperatures, and is adapted to desorb carbon monoxide at high temperatures. The present invention advantageously eliminates a unit operation from a space-constrained fuel cell vehicle by combining the WGS catalyst and a CO2 adsorbent in a single reactor/housing. The apparatus further eliminates the use of a PROX reactor, by providing an apparatus which incorporates CO2 adsorption and consequent carbon monoxide consumption in the place of the PROX reactor.
摘要:
The use of one or more alkali metals, preferably sodium, to remove sulfur from hydrocarbon streams containing up to about 100 wppm sulfur. The hydrocarbon stream is introduced into a reactor where it is contacted with one or more alkali metals. The treated hydrocarbon stream is then subjected to a water wash thereby resulting in an aqueous phase fraction and a hydrocarbon phase fraction. The aqueous phase fraction, which is separated from the hydrocarbon phase fraction contains water-soluble sodium moieties.
摘要:
This invention relates to reactors with mitigation of fouling-related pressure buildup, the reactors having a reactor bed containing at least one catalyst layer through which reactants flow. The mitigation of fouling which occurs at the top of the reactor bed is accomplished by using at least one blowback ring located near the top of the reactor bed.