公开(公告)号：US5756420A

公开(公告)日：1998-05-26

申请号：US740971

申请日：1996-11-05

Applicant: Robert J. Wittenbrink ,  Daniel F. Ryan ,  William C. Baird, Jr. ,  Kenneth L. Riley ,  Jack W. Johnson

Inventor： Robert J. Wittenbrink ,  Daniel F. Ryan ,  William C. Baird, Jr. ,  Kenneth L. Riley ,  Jack W. Johnson

IPC: B01J23/85 ,  B01J23/885 ,  C10G45/60 ,  B01J23/70 ,  B01J23/72 ,  B01J23/74 ,  B01J23/75

CPC classification number: B01J23/85 ,  B01J23/885 ,  C10G45/60

Abstract: Hydroconversion of paraffin containing hydrocarbon feeds is effected over a supported Group VIII and Group VI metal containing catalyst also containing a hydrocracking suppressant such as a Group IB metal, wherein the catalyst is preferably prepared by fixing the Group IB metal on to the support prior to incorporating the Group VI metal on to the support.

Abstract translation: 含有烃的烃进料的加氢转化在含有还含有加氢裂化抑制剂如IB族金属的负载的第VIII族和第VI族金属催化剂上进行，其中催化剂优选通过将IB族金属固定在载体上而制备， 第六组金属对支持。

公开(公告)号：US5340657A

公开(公告)日：1994-08-23

申请号：US935504

申请日：1992-08-26

Applicant: Michael C. Kerby ,  Kenneth L. Riley ,  Fred M. Long ,  Jack W. Johnson ,  John F. Brody

Inventor： Michael C. Kerby ,  Kenneth L. Riley ,  Fred M. Long ,  Jack W. Johnson ,  John F. Brody

IPC: B01J29/04 ,  B22F5/00 ,  B28D1/32

CPC classification number: B01J29/049 ,  Y10T428/12056

Abstract: This invention relates to pillared micas, which comprise an active metal selected from the group consisting of Pt, Cr, Pd, It, Rh and mixtures thereof, and a first modifier metal selected from the group consisting of Sn, Ga and mixtures thereof. The mica may also be modified with a second modifier metal selected from the group consisting of alkali metals, alkaline earth metals, or rare earth metals and mixtures thereof. This invention further relates to a process for preparing such a catalyst.

Abstract translation: 本发明涉及柱状云母，其包含选自Pt，Cr，Pd，It，Rh及其混合物的活性金属和选自Sn，Ga及其混合物的第一修饰金属。 云母也可以用选自碱金属，碱土金属或稀土金属的第二种改性金属及其混合物进行改性。 本发明还涉及制备这种催化剂的方法。

公开(公告)号：US5330734A

公开(公告)日：1994-07-19

申请号：US28485

申请日：1993-03-09

Applicant: Jack W. Johnson ,  John F. Brody

Inventor： Jack W. Johnson ,  John F. Brody

IPC: B01J20/12 ,  B01J21/16 ,  B01J29/04 ,  C01B33/42 ,  C01B39/00 ,  C01B33/26

CPC classification number: B01J29/049 ,  B01J20/12

Abstract: Microporous materials of low acidity useful as sorbents and catalytic supports have been produced by pillaring tetrasilicic mica with silica polyoxocations generated by hydrolysis of organosilane precursors. Calcination at an intermediate temperature followed by washing of the solid with water is important in producing highly microporous material.

Abstract translation: 通过用有机硅烷前体水解生成的二氧化硅聚氧化苯撑，将四硅云母作为吸附剂和催化剂载体，制备了低酸度的微孔材料。 在中间温度下煅烧，然后用水洗涤固体对于生产高度微孔的材料是重要的。

公开(公告)号：US4518534A

公开(公告)日：1985-05-21

申请号：US525142

申请日：1983-08-22

Applicant: Jack W. Johnson ,  Allan J. Jacobson

Inventor： Jack W. Johnson ,  Allan J. Jacobson

IPC: B01D15/00 ,  B01J20/18 ,  B01J27/198 ,  B01J31/02 ,  B01J31/12 ,  B01J31/16 ,  B01J31/18 ,  C07B61/00 ,  C07C31/02 ,  C07C33/20 ,  C07F9/00 ,  C07F9/09 ,  C07F9/38 ,  C07F9/70

CPC classification number: C07F9/703 ,  B01J23/002 ,  B01J27/198 ,  B01J31/1691 ,  B01J31/185 ,  C07C31/02 ,  C07C33/20 ,  C07F9/09 ,  C07F9/38 ,  B01J2523/00 ,  B01J2531/56

Abstract: A layered oxide containing vanadium together with phosphorus or arsenic and an organic group may be prepared which has a unique layered structure of the formula: VORAO.sub.3.nS or VOROAO.sub.3.nS where A is phosphorus or arsenic, S is a solvent molecule, R is an unsubstituted or alkyl-, alkoxy- or aryl-substituted alkyl or aryl group, and n is zero or a positive number. These layered compounds are characterized in that the vanadium is substantially in a 4+ oxidation state and is present in an amount such that the molar ratio of A:V ranges from 0.8 to 1.2 throughout the oxide. Also the R groups are covalently bound to an A atom in the vanadium oxide layer directly through either carbon or oxygen atoms.

Abstract translation: 可以制备含有钒与磷或砷的有机基团的层状氧化物和有机基团，其具有下式的独特层状结构：VORAO3.nS或VOROAO3.nS，其中A为磷或砷，S为溶剂分子，R为 未取代或烷基，烷氧基或芳基取代的烷基或芳基，n为零或正数。 这些层状化合物的特征在于钒基本上处于4+氧化态，并且存在的量使得在整个氧化物中A:V的摩尔比范围为0.8-1.2。 R基团也直接通过碳原子或氧原子与氧化钒层中的A原子共价结合。

公开(公告)号：US4201839A

公开(公告)日：1980-05-06

申请号：US956746

申请日：1978-11-01

Applicant: Jack W. Johnson ,  M. Stanley Whittingham

Inventor： Jack W. Johnson ,  M. Stanley Whittingham

IPC: H01M6/16 ,  H01M10/0566 ,  H01M6/14 ,  H01M10/36

CPC classification number: H01M10/0566

Abstract: A novel electrochemical cell is disclosed which contains an alkali metal anode, a solid cathode, and an electrolyte containing one or more closoborane and/or closocarborane compounds in aprotic solvent. Preferred cells are those containing lithium anodes, chalcogenide cathodes and electrolytes containing one or more closoborane compounds in aprotic solvent with a chelating agent.

Abstract translation: 公开了一种新颖的电化学电池，其包含碱金属阳极，固体阴极和在非质子溶剂中含有一种或多种氯三硼烷和/或氯代硼烷化合物的电解质。 优选的细胞是包含锂阳极，硫族化物阴极和在非质子溶剂中含有螯合剂的含有一种或多种氯三硼烷化合物的电解质。

公开(公告)号：US09005561B2

公开(公告)日：2015-04-14

申请号：US13406100

申请日：2012-02-27

Applicant: Daniel P. Leta ,  Preeti Kamakoti ,  Jack W. Johnson ,  Peter I. Ravikovitch ,  Harry Deckman

Inventor： Daniel P. Leta ,  Preeti Kamakoti ,  Jack W. Johnson ,  Peter I. Ravikovitch ,  Harry Deckman

IPC: B01D53/14 ,  B01D53/047 ,  B01D53/04 ,  C10L3/10 ,  B01J20/18 ,  B01J20/20 ,  B01J20/22 ,  B01J20/34 ,  B01J20/28 ,  B01D53/52 ,  C01B17/04 ,  C01B17/16

CPC classification number: B01D53/047 ,  B01D53/0438 ,  B01D53/0462 ,  B01D53/0473 ,  B01D53/526 ,  B01D2252/20431 ,  B01D2252/20436 ,  B01D2252/20489 ,  B01D2253/102 ,  B01D2253/106 ,  B01D2253/108 ,  B01D2253/1085 ,  B01D2253/116 ,  B01D2253/204 ,  B01D2253/25 ,  B01D2253/304 ,  B01D2253/306 ,  B01D2253/311 ,  B01D2253/34 ,  B01D2256/24 ,  B01D2256/245 ,  B01D2257/102 ,  B01D2257/304 ,  B01D2257/504 ,  B01D2257/7022 ,  B01D2259/40022 ,  B01D2259/40052 ,  B01D2259/402 ,  B01D2259/41 ,  B01J20/18 ,  B01J20/186 ,  B01J20/20 ,  B01J20/226 ,  B01J20/28016 ,  B01J20/28019 ,  B01J20/28042 ,  B01J20/28057 ,  B01J20/28078 ,  B01J20/28095 ,  B01J20/3408 ,  B01J20/3416 ,  B01J20/3483 ,  B01J20/3491 ,  B01J2220/42 ,  B01J2220/46 ,  B01J2220/56 ,  C01B17/0408 ,  C01B17/167 ,  C10L3/103 ,  C10L3/104 ,  C10L3/105 ,  Y02C10/08 ,  Y02P20/152 ,  Y10T428/2991

Abstract: A cyclic process for selectively separating hydrogen sulfide from a gas mixture including CO2 is operated by contacting the gas mixture under sorption conditions with a non-aqueous sorbent comprising a basic non-protogenic nitrogenous compound to react the H2S with the basic compound so that the H2S can be sorbed by the compound. The compound containing the sorbed H2S can then be subjected to desorption conditions by which the H2S is desorbed and the sorbent readied for another sorption step in the cycle. The basic nitrogenous compound can be carried on a porous solid sorbent, e.g., a solid oxide such as alumina, silica, silica-alumina, zeolites, or a mesoporous and/or macroporous solid oxide. The process may be operated using a pressure swing, temperature swing, partial pressure swing, purge displacement, or a combination thereof between the sorption and desorption portions of the cycle, preferably in a rapid cycle operation.

Abstract translation: 通过在吸附条件下将气体混合物与包含碱性非原生态含氮化合物的非水性吸附剂接触使氢气与碱性化合物反应，从而使H2S与碱性化合物反应，从而选择性地从包括CO 2的气体混合物中分离硫化氢的循环方法进行操作， 可以被化合物吸收。 然后可以将含有吸附的H 2 S的化合物进行解吸附条件，通过该条件解吸H2S，吸附剂准备在循环中进行另一个吸附步骤。 碱性含氮化合物可以承载在多孔固体吸附剂，例如固体氧化物如氧化铝，二氧化硅，二氧化硅 - 氧化铝，沸石或中孔和/或大孔固体氧化物上。 该方法可以在循环的吸附和解吸部分之间，优选在快速循环操作中使用压力摆动，温度摆动，分压，吹扫位移或其组合来操作。

公开(公告)号：US20120308456A1

公开(公告)日：2012-12-06

申请号：US13406100

申请日：2012-02-27

Applicant: Daniel P. Leta ,  Preeti Kamakoti ,  Jack W. Johnson ,  Peter I. Ravikovitch ,  Harry Deckman

Inventor： Daniel P. Leta ,  Preeti Kamakoti ,  Jack W. Johnson ,  Peter I. Ravikovitch ,  Harry Deckman

IPC: B01D53/00 ,  C10L3/10 ,  C01B17/04

CPC classification number: B01D53/047 ,  B01D53/0438 ,  B01D53/0462 ,  B01D53/0473 ,  B01D53/526 ,  B01D2252/20431 ,  B01D2252/20436 ,  B01D2252/20489 ,  B01D2253/102 ,  B01D2253/106 ,  B01D2253/108 ,  B01D2253/1085 ,  B01D2253/116 ,  B01D2253/204 ,  B01D2253/25 ,  B01D2253/304 ,  B01D2253/306 ,  B01D2253/311 ,  B01D2253/34 ,  B01D2256/24 ,  B01D2256/245 ,  B01D2257/102 ,  B01D2257/304 ,  B01D2257/504 ,  B01D2257/7022 ,  B01D2259/40022 ,  B01D2259/40052 ,  B01D2259/402 ,  B01D2259/41 ,  B01J20/18 ,  B01J20/186 ,  B01J20/20 ,  B01J20/226 ,  B01J20/28016 ,  B01J20/28019 ,  B01J20/28042 ,  B01J20/28057 ,  B01J20/28078 ,  B01J20/28095 ,  B01J20/3408 ,  B01J20/3416 ,  B01J20/3483 ,  B01J20/3491 ,  B01J2220/42 ,  B01J2220/46 ,  B01J2220/56 ,  C01B17/0408 ,  C01B17/167 ,  C10L3/103 ,  C10L3/104 ,  C10L3/105 ,  Y02C10/08 ,  Y02P20/152 ,  Y10T428/2991

Abstract: A cyclic process for selectively separating hydrogen sulfide from a gas mixture including CO2 is operated by contacting the gas mixture under sorption conditions with a non-aqueous sorbent comprising a basic non-protogenic nitrogenous compound to react the H2S with the basic compound so that the H2S can be sorbed by the compound. The compound containing the sorbed H2S can then be subjected to desorption conditions by which the H2S is desorbed and the sorbent readied for another sorption step in the cycle. The basic nitrogenous compound can be carried on a porous solid sorbent, e.g., a solid oxide such as alumina, silica, silica-alumina, zeolites, or a mesoporous and/or macroporous solid oxide. The process may be operated using a pressure swing, temperature swing, partial pressure swing, purge displacement, or a combination thereof between the sorption and desorption portions of the cycle, preferably in a rapid cycle operation.

Abstract translation: 通过在吸附条件下将气体混合物与包含碱性非原生态含氮化合物的非水性吸附剂接触使氢气与碱性化合物反应，从而使H2S与碱性化合物反应，从而选择性地从包括CO 2的气体混合物中分离硫化氢的循环方法进行操作， 可以被化合物吸收。 然后可以将含有吸附的H 2 S的化合物进行解吸附条件，通过该条件解吸H2S，吸附剂准备在循环中进行另一个吸附步骤。 碱性含氮化合物可以承载在多孔固体吸附剂，例如固体氧化物如氧化铝，二氧化硅，二氧化硅 - 氧化铝，沸石或中孔和/或大孔固体氧化物上。 该方法可以在循环的吸附和解吸部分之间，优选在快速循环操作中使用压力摆动，温度摆动，分压，吹扫位移或其组合来操作。

公开(公告)号：US07125821B2

公开(公告)日：2006-10-24

申请号：US10657057

申请日：2003-09-05

Applicant: Teng Xu ,  Stephen Neil Vaughn ,  Richard B. Hall ,  Kenneth Ray Clem ,  Jack W. Johnson

Inventor： Teng Xu ,  Stephen Neil Vaughn ,  Richard B. Hall ,  Kenneth Ray Clem ,  Jack W. Johnson

IPC: B01J27/182 ,  B01J29/06

CPC classification number: B01J37/0045 ,  B01J29/06 ,  B01J29/85 ,  B01J2229/42 ,  C07C1/20 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/10 ,  C07C2521/12 ,  C07C2523/02 ,  C07C2523/10 ,  C07C2529/85 ,  C10G3/45 ,  C10G3/48 ,  C10G3/49 ,  C10G3/56 ,  C10G3/62 ,  C10G2300/1022 ,  C10G2300/708 ,  C10G2300/802 ,  C10G2400/20 ,  Y02P30/20 ,  Y02P30/42 ,  C07C11/02

Abstract: The invention provides low metal content molecular sieve catalyst compositions, processes for making such catalysts, and processes for using such catalysts in the conversion of an oxygenate into one or more light olefins. Preferably, the catalyst composition comprises a matrix material having a low metal content. By utilizing matrix materials having low metal contents, the amount of metal-catalyzed side reaction byproducts formed in a reaction system, particularly in an oxygenate-to-olefin reaction system, can be advantageously reduced.

Abstract translation: 本发明提供了低金属含量的分子筛催化剂组合物，制备这种催化剂的方法，以及在将含氧化合物转化成一种或多种轻质烯烃时使用这种催化剂的方法。 优选地，催化剂组合物包含具有低金属含量的基质材料。 通过利用具有低金属含量的基质材料，可以有利地减少在反应体系中形成的金属催化的副反应副产物的量，特别是在含氧化合物 - 烯烃反应体系中。

公开(公告)号：US5563212A

公开(公告)日：1996-10-08

申请号：US248291

申请日：1994-05-24

Applicant: John P. Dismukes ,  Jack W. Johnson ,  Edward W. Corcoran, Jr. ,  Joseph Vallone

Inventor： John P. Dismukes ,  Jack W. Johnson ,  Edward W. Corcoran, Jr. ,  Joseph Vallone

IPC: C04B38/06 ,  C04B38/00 ,  C04B35/52

CPC classification number: C04B38/0022

Abstract: The present invention provides for microporous ceramic materials having a surface area in excess of 50 m.sup.2 /gm and an open microporous cell structure wherein the micropores have a mean width of less than 20 Angstroms and wherein said microporous structure comprises a volume of greater than about 0.015 cm.sup.3 /gm of the ceramic. The invention also provides for a preceramic composite intermediate composition comprising a mixture of a ceramic precursor and finely divided particles comprising a non-silicon containing ceramic, carbon, or an inorganic compound having a decomposition temperature in excess of 400.degree. C., whose pyrolysis product in inert atmosphere or in an ammonia atmosphere at temperatures of up to less than about 1100.degree. C. gives rise to the microporous ceramics of the invention. Also provided is a process for the preparation of the microporous ceramics of the invention involving pyrolysis of the ceramic intermediate under controlled conditions of heating up to temperatures of less than 1100.degree. C. to form a microporous ceramic product.

Abstract translation: 本发明提供了具有超过50m 2 / gm的表面积的微孔陶瓷材料和开孔的微孔孔结构，其中微孔具有小于20埃的平均宽度，并且其中所述微孔结构包括大于约0.015的体积 cm3 / gm的陶瓷。 本发明还提供一种预陶瓷复合中间体组合物，其包含陶瓷前体和包含非硅含量陶瓷，碳或分解温度超过400℃的无机化合物的细碎颗粒的混合物，其热分解产物 在惰性气氛中或在高达少于约1100℃的氨气氛中，产生本发明的微孔陶瓷。 还提供了制备本发明的微孔陶瓷的方法，其包括在加热至低于1100℃的温度的受控条件下陶瓷中间体的热解，以形成微孔陶瓷产品。

公开(公告)号：US5476982A

公开(公告)日：1995-12-19

申请号：US259717

申请日：1994-06-14

Applicant: John L. Robbins ,  Elise Marucchi-Soos ,  Jack W. Johnson ,  John F. Brody

Inventor： John L. Robbins ,  Elise Marucchi-Soos ,  Jack W. Johnson ,  John F. Brody

IPC: B01J23/60 ,  B01J23/62 ,  B01J29/04 ,  C07C5/32 ,  C07C5/333

CPC classification number: B01J29/049 ,  B01J23/60 ,  B01J23/62 ,  C07C5/325 ,  C07C5/3337

Abstract: The present invention is directed to a novel catalyst composition and its use in the dehydrogenation of paraffins to olefins. The catalyst comprises an alloy of a Group VIII noble metal and a metal selected from the group consisting of zinc and gallium on a support selected from the group consisting of silica, zinc oxide modified silica and zinc oxide modified silica-pillared clays when said alloy is a zinc alloy, and silica, gallium oxide modified silica and gallium oxide modified silica-pillared clays when said alloy is a gallium alloy. The instant catalyst is an active and selective catalyst for the catalytic dehydrogenation of paraffins to olefins, especially gaseous paraffins, having the added benefit of retaining high activity and selectivity even following repeated regeneration by calcination in oxygen containing gas at temperatures of 450.degree. C. to 650.degree. C., preferably 450.degree. C. to 500.degree. C.

Abstract translation: 本发明涉及新型催化剂组合物及其在链烷烃脱氢成烯烃中的应用。 所述催化剂包含由选自二氧化硅，氧化锌改性二氧化硅和氧化锌改性二氧化硅 - 柱状粘土的载体上的第八族贵金属和选自锌和镓的金属的合金，当所述合金为 锌合金，二氧化硅，氧化镓改性二氧化硅和氧化镓改性二氧化硅柱状粘土。 本催化剂是用于将链烷烃催化脱氢成烯烃，特别是气态烷烃的活性和选择性催化剂，具有保持高活性和选择性的附加益处，即使在含氧气体中通过在450℃至450℃的温度下煅烧反复再生， 650℃，优选450℃至500℃