摘要:
A polymeric lubricant additive that behaves as a viscosity index improver and imparts enhanced anti-oxidancy, dispersnacy, and anti-wear properties to said lubricant oil has been prepared. The polymeric substrate is a random co- or terpolyer of ethylene propylene and a third monomer onto which an ethylenically unsaturated carboxylic acid or acid anhydride has been grafted. The polymer is imidized with aminoheterocyclics and hydroxylalkylated using an aldehyde or ketone an alkylation; than alkylated using mercaptoheterocyclics.
摘要:
A railway diesel crankcase lubricant composition comprising a major portion of a diesel lubricating oil and a minor amount of, as an oxidation and corrosion inhibiting additive, a condensate product prepared by the process comprising:(a) reacting a dibasic acid anhydride with an oligomeric isobutylene to form a succinic anhydride;(b) reacting the succinic anhydride with an N-alkyl alkylene diamine to produce a succinimide-amine;(c) reacting the succinimide-amine with a polyaromatic diisocyanate to produce a phenylurea isocyanophenylmethane;(d) reacting the isocyanophenylmethane with a heterocyclic compound containing a thiadiazole nucleus to a condensation product of a mercaptothiadiazole-phenylmethane; and(e) recovering the condensation product.
摘要:
A polymeric additive prepared from ethylene and at least one (C.sub.3 -C.sub.10) alpha-monoolefin and a non-conjugated dienes or triene comprising from about 15 to 80 mole percent of ethylene and from about 20 to 85 mole percent of the (C.sub.3 -C.sub.10) alpha-monoolefin and from about 0 to 15 mole percent of the diene or triene. This polymeric substrate has a number average molecular weight ranging from about 5,000 to about 500,000. It is modified by reacting the polymer with an unsaturated epoxide wherein the intermediate graft co- or terpolymer is characterized as having pendant epoxides within the substrate.Post-reacting this graft co- or terpolymer with 1,3,4-thiadiazine modified with substituted phenols, diaryl amines, or phenophiazines generates a polymeric lubricant additive with enhanced anti-oxidant, dispersant, and anti-wear properties.
摘要:
A railway diesel crankcase lubricant composition comprising a major portion of a diesel lubricating oil and a minor amount of, as an oxidation and corrosion inhibiting agent, a condensate product prepared by the process comprising:(a) reacting a dibasic acid anhydride, separately, with:(i) a oligomeric isobutylene, and(ii) 2,5-dimercapto-1,3,4,-thiadiazole, to produce, respectively, oligomeric(isobutylene-g-succinic anhydride) and 2-thio-(5-mercapto-1,3,4-thiadiazole) succinic anhydride;(b) reacting both of the succinic anhydrides with pentamethylenediamine to produce the [2-thio-(5-mercapto-1,3,4-thiadiazole)]-[oligomeric(isobutylene-g-succinic)]-pentamethylenetetraamine-bis succinimide product; and(c) recovering the bis-succinimide product.
摘要:
A lubricant additive that imparts enhanced dispersancy and antioxidancy has been prepared by reacting a copolymer or terpolymer with an acrylating agent followed by treatment with a dialiphatic or aromatic phosphate. The copolymer is prepared from ethylene and at least one (C.sub.3 -C.sub.10) alpha-monoolefin and, optionally, a polyene selected from non-conjugated dienes and trienes comprising from about 15 to 80 mole percent of ethylene, from about 20 to 85 mole percent of said (C.sub.3 -C.sub.10) alpha-monoolefin and from about 0 to 15 mole percent of said polyene having a number average molecular weight ranging from about 5,000 to about 500,000.
摘要:
A fuel composition comprising (a) a major amount of an internal combustion engine hydrocarbon fuel containing at least one alcohol, it being provided that MTBE is substantially absent from the fuel and (b) a friction modifying amount of a reaction product of at least one natural or synthetic oil and at least one alkanolamine is provided. Also provided is a method for operating an engine employing the fuel composition therefor.
摘要:
A two-cycle engine fuel composition comprising (a) a major amount of a two-cycle engine fuel; (b) a lubricant component; and, (c) a two-cycle engine fuel combustion deposit-inhibiting amount of at least one hydrocarbyl polyoxyalkylene aminoalcohol of the general formula wherein R1 is an alkyl, an alicyclic or an alkylalicyclic radical having from about 4 to about 30 carbon atoms or an alkylaryl where the alkyl group is from about 4 to about 30 carbon atoms; x is an integer from 0 to about 5, y is an integer from 1 to about 49, z is an integer from 1 to about 49 and the sum of x+y+z is equal to 3 to about 50; R2 and R3 each is different and is an alkyl group of from 1 to 4 carbon atoms and each oxyalkylene radical can be any combination of repeating oxyalkylene units to form random or block copolymers; R4 is the same as R2 or R3; R5 is hydrogen or where R7 is hydrogen or an alkyl group of from 1 to 5 carbon atoms and R6 is hydrogen or an alkyl group of from 1 to 5 carbon atoms and methods for using same are provided.
摘要:
A method has been developed to solubilize hydroxy S-triazines containing at least one hydroxy function in diesel fuel and to enhance their overall thermal stability. The products which result from the full or partial encapsulation of hydroxy-S-triazine with calix[8]arene have unique and novel properties and reduce or eliminate nitrogen oxides level in diesel fuel.
摘要:
Mixtures of block alkoxy co- or terpolymer hydrocarboxylates and aminopolyazole increase the oxidation and corrosion resistance of lubricants, particularly diesel engine oil.