公开(公告)号：US20140199583A1

公开(公告)日：2014-07-17

申请号：US14215926

申请日：2014-03-17

Applicant: KABUSHIKI KAISHA TOSHIBA

Inventor： Asato KONDO ,  Takashi KUBOKI

IPC: H01M4/131 ,  H01M4/136 ,  H01M4/62 ,  H01M10/0525

CPC classification number: H01M4/131 ,  H01M4/136 ,  H01M4/386 ,  H01M4/387 ,  H01M4/505 ,  H01M4/525 ,  H01M4/5825 ,  H01M4/623 ,  H01M10/052 ,  H01M10/0525

Abstract: An electrode for a nonaqueous electrolyte secondary battery of an embodiment has an active material layer containing an active material and a binder containing fluorine, and a current collector bound to the active material layer. When a thermal decomposition start temperature of the binder is T1° C. and the thermal decomposition end temperature is T2° C., one or more signals are present for any of the mass number of 81, 100, 132, and 200 in a thermal decomposition mass analysis between thermal decomposition temperatures of T1 and T2. When a signal area of the mass spectrum in the range of T1-100° C. or higher but lower than T1° C. is X, and a signal area of the mass spectrum in the range of T1 or higher but the same or lower than T2° C. is Y, the X and Y satisfy a relation of X≦Y.

Abstract translation: 本实施方式的非水电解质二次电池用电极具有包含活性物质和含氟的粘合剂的活性物质层和与活性物质层结合的集电体。 当粘合剂的热分解开始温度为T1℃并且热分解结束温度为T2℃时，对于质量数81,100,1002和200中的任何一种，在热能中存在一个或多个信号 T1和T2热分解温度之间的分解质量分析。 当质谱在T1-100℃以上但低于T1℃的范围内的信号区域为X时，质谱信号区域在T1以上且相同或更低的范围内 比T2°C为Y，X和Y满足关系X＆nlE; Y。

公开(公告)号：US20220294077A1

公开(公告)日：2022-09-15

申请号：US17446864

申请日：2021-09-03

Applicant: Kabushiki Kaisha Toshiba

Inventor： Yasuyuki HOTTA ,  Takashi KUBOKI ,  Shinsuke MATSUNO ,  Norio TAKAMI

IPC: H01M50/446 ,  H01M50/431 ,  H01M50/426

Abstract: An electrode group includes a negative electrode, a positive electrode and a separator. The negative electrode includes a negative electrode active material-containing layer and a mesh negative electrode current collector. The positive electrode includes a positive electrode active material-containing layer. The separator includes a composite membrane containing inorganic solid particles and a polymer material. At least one of a first polymer material constituting the negative electrode active material-containing layer is the same as a second polymer material. A ratio a/b of denseness a and denseness b is greater than 1.05. A peeling strength σ1 is greater than a peeling strength σ2. An air permeability coefficient of a joined body of the composite membrane and the negative electrode is 1×10−19 m2 or more and 1×10−15 m2 or less.

公开(公告)号：US20190088384A1

公开(公告)日：2019-03-21

申请号：US15916716

申请日：2018-03-09

Applicant: KABUSHIKI KAISHA TOSHIBA

Inventor： Takayuki FUKUSAWA ,  Keiko ALBESSARD ,  Takashi KUBOKI ,  Yasuhiro GOTO

IPC: H01B3/02 ,  H01B3/00 ,  H01B17/64 ,  C01B21/068 ,  C01B32/956

Abstract: A thermally conductive insulator consisting essentially of a silicon nitride member, comprise: a first region provided 10 μm or more away from a first surface of the member along a depth direction in a section vertical to the first surface and containing at least one substance selected from the group consisting of silicon carbide and a carbon material; and a second region provided between the first surface and the first region. A concentration of silicon nitride of the second region is higher than a concentration of silicon nitride of the first region.

公开(公告)号：US20180036801A1

公开(公告)日：2018-02-08

申请号：US15556232

申请日：2015-09-14

Applicant: Kabushiki Kaisha Toshiba

Inventor： Haruhiko ISHIHARA ,  Takayuki FUKASAWA ,  Masahiro KATO ,  Sara YOSHIO ,  Takashi KUBOKI

IPC: B22F3/105 ,  B33Y40/00 ,  B28B11/24 ,  B28B1/00 ,  B33Y10/00

CPC classification number: B22F3/1055 ,  B22F3/105 ,  B28B1/001 ,  B28B11/10 ,  B28B11/243 ,  B28B17/026 ,  B33Y10/00 ,  B33Y40/00 ,  B33Y70/00 ,  C22C29/12 ,  C22C32/0015 ,  Y02P10/295

Abstract: A three-dimensional manufacturing method includes: forming and adding a layer of secondary particles to manufacture a three-dimensional object, the secondary particles obtained by granulating primary particles; and heating the three-dimensional object to produce a sintered compact.

公开(公告)号：US20170267932A1

公开(公告)日：2017-09-21

申请号：US15255741

申请日：2016-09-02

Applicant: Kabushiki Kaisha Toshiba

Inventor： Takayuki FUKASAWA ,  Kenji ESSAKI ,  Shinsuke MATSUNO ,  Takashi KUBOKI

IPC: C10G2/00 ,  C10L1/04 ,  C07C29/156 ,  B01J23/755 ,  B01J35/02 ,  B01J35/00 ,  C10L1/02 ,  B01J23/83

CPC classification number: B01J35/026 ,  B01J23/002 ,  B01J23/005 ,  B01J23/755 ,  B01J23/78 ,  B01J23/83 ,  B01J35/0013 ,  B01J35/008 ,  B01J35/0086 ,  B01J35/023 ,  B01J35/08 ,  B01J37/0205 ,  B01J37/0207 ,  B01J37/03 ,  B01J37/033 ,  B01J37/18 ,  B01J2523/00 ,  C07C1/12 ,  C07C29/156 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/10 ,  C07C2523/10 ,  C07C2523/755 ,  C07C2523/83 ,  C10G2/332 ,  C10G2/341 ,  C10L1/02 ,  C10L1/04 ,  C10L3/06 ,  C10L2200/0492 ,  C10L2290/14 ,  C10L2290/42 ,  Y02P20/52 ,  C07C9/04 ,  C07C31/04 ,  B01J2523/31 ,  B01J2523/3712 ,  B01J2523/847 ,  B01J2523/3737 ,  B01J2523/48 ,  B01J2523/41 ,  B01J2523/47 ,  B01J2523/22 ,  B01J2523/842

Abstract: A fuel synthesis catalyst of an embodiment for hydrogenating a gas includes at least one selected from the group consisting of; carbon dioxide and carbon monoxide, the catalyst comprising, an oxide base material containing at least one oxide selected from the group consisting of; Al2O3, MgO, TiO2, and SiO2, first metal particles containing at least one metal selected from the group consisting of; Ni, Co, Fe, and Cu and brought into contact with the oxide base material, and a porous oxide layer containing at least one selected from the group consisting of; CeO2, ZrO2, TiO2, and SiO2 and having an interface with each of the first metal particles and the oxide base material.

公开(公告)号：US20160319232A1

公开(公告)日：2016-11-03

申请号：US15139832

申请日：2016-04-27

Applicant: Kabushiki Kaisha Toshiba

Inventor： Yasuko NORITOMI ,  Takashi KUBOKI ,  Ko YAMADA ,  Hiroyuki FUKE

IPC: C12M1/40 ,  G01N27/403

CPC classification number: C12M21/18 ,  G01N27/3277 ,  G01N27/49

Abstract: According to one embodiment, a measuring cell includes a main cell member, and a mixture supported by or held in the main cell member. The mixture includes a nonaqueous solvent-including medium and one or more enzyme bodies. The one or more enzyme bodies are selected from the group including an enzyme, a first composite including an enzyme and a molecular aggregate that includes a dispersant, a microcapsule including an enzyme-including core and a shell covering the core, a cell including an enzyme, a microorganism including an enzyme, and a second composite including an enzyme and a support immobilizing the enzyme.

Abstract translation: 根据一个实施例，测量单元包括主单元构件以及由主单元构件支撑或保持在主单元构件中的混合物。 该混合物包括非水溶剂的介质和一种或多种酶体。 一个或多个酶体选自包括酶，包括酶的第一复合物和包含分散剂的分子聚集体的组，包含含酶核心的微胶囊和覆盖该核心的壳，包含酶的细胞 ，包含酶的微生物和包含酶和固定酶的载体的第二复合物。

公开(公告)号：US20150086870A1

公开(公告)日：2015-03-26

申请号：US14478138

申请日：2014-09-05

Applicant: KABUSHIKI KAISHA TOSHIBA

Inventor： Takayuki FUKASAWA ,  Kenji ESSAKI ,  Tomokazu MORITA ,  Takashi KUBOKI ,  Mitsuhiro OKI ,  Yasuhiro GOTO

IPC: H01M4/134 ,  H01M4/38 ,  H01M4/62 ,  H01M4/36

CPC classification number: H01M4/134 ,  H01M4/131 ,  H01M4/136 ,  H01M4/366 ,  H01M4/386 ,  H01M4/485 ,  H01M4/58 ,  H01M4/62 ,  H01M4/625 ,  H01M2220/30

Abstract: An electrode material for nonaqueous electrolyte secondary battery of an embodiment includes a silicon nanoparticle, and a coating layer coating the silicon nanoparticle. The coating layer includes an amorphous silicon oxide and a silicon carbide phase. At least a part of the silicon carbide phase exists on a surface of the silicon nanoparticle.

Abstract translation: 实施方式的非水电解质二次电池用电极材料包括硅纳米颗粒和涂覆硅纳米颗粒的涂层。 涂层包括非晶氧化硅和碳化硅相。 在硅纳米颗粒的表面上存在至少一部分碳化硅相。

公开(公告)号：US20150037681A1

公开(公告)日：2015-02-05

申请号：US14496074

申请日：2014-09-25

Applicant: KABUSHIKI KAISHA TOSHIBA

Inventor： Tomokazu MORITA ,  Takashi KUBOKI ,  Takayuki FUKASAWA ,  Yasuyuki HOTTA ,  Yasuhiro GOTO ,  Toshiro HIRAOKA

IPC: H01M4/36 ,  H01M4/583 ,  H01M4/48 ,  H01M4/133

CPC classification number: H01M4/364 ,  H01M4/133 ,  H01M4/386 ,  H01M4/48 ,  H01M4/485 ,  H01M4/583 ,  H01M4/587 ,  H01M10/052 ,  H01M2004/027

Abstract: A negative electrode active material for a nonaqueous electrolyte secondary battery of an embodiment includes a carbonaceous material, a silicon oxide phase in the carbonaceous material, and a silicon phase in the silicon oxide phase. The negative electrode active material has a crack in the carbonaceous material, and the longest side of the crack has a length equal to or greater than ⅕ of the diameter of the negative electrode active material.

Abstract translation: 作为实施方式的非水电解质二次电池用负极活性物质，可以举出碳质材料，碳质材料中的氧化硅相，氧化硅相中的硅相。 负极活性物质在碳质材料中具有裂纹，裂纹的最长侧的长度等于或大于负极活性物质的直径的⅕。

公开(公告)号：US20140199579A1

公开(公告)日：2014-07-17

申请号：US14215158

申请日：2014-03-17

Applicant: KABUSHIKI KAISHA TOSHIBA

Inventor： Tomokazu MORITA ,  Takashi KUBOKI ,  Takayuki FUKASAWA ,  Yasuyuki HOTTA ,  Kenji ESSAKI ,  Norikazu OSADA

IPC: H01M4/36 ,  H01M4/48 ,  H01M4/583

CPC classification number: H01M4/364 ,  H01M4/386 ,  H01M4/48 ,  H01M4/583 ,  H01M4/587 ,  H01M10/052

Abstract: A negative electrode active material for a nonaqueous electrolyte secondary battery has a carbonaceous substance, a silicon oxide phase in the carbonaceous substance, a silicon phase in the silicon oxide phase, and a zirconia phase in the carbonaceous substance. The negative electrode active material has a diffraction peak at 2θ=30±1° in powder X-ray diffraction measurement.

Abstract translation: 作为非水电解质二次电池用负极活性物质，在碳质物质中含有碳质物质，氧化硅相，氧化硅相中的硅相，碳质物质中的氧化锆相。 在粉末X射线衍射测量中，负极活性物质的衍射峰在2θ= 30±1°。

公开(公告)号：US20140178767A1

公开(公告)日：2014-06-26

申请号：US14191503

申请日：2014-02-27

Applicant: KABUSHIKI KAISHA TOSHIBA

Inventor： Norio TAKAMI ,  Hiroki INAGAKI ,  Takashi KUBOKI

IPC: H01M2/16

CPC classification number: H01M2/1626 ,  H01M2/18 ,  H01M4/131 ,  H01M4/525 ,  H01M4/5825 ,  H01M10/052 ,  Y02E60/122 ,  Y02T10/7011

Abstract: A secondary battery includes a positive electrode, a negative electrode containing a metal compound having a lithium ion absorption potential of 0.2V (vs. Li/Li+) or more, a separator and a nonaqueous electrolyte. The separator is provided between the positive electrode and the negative electrode. The separator comprises cellulose fibers and pores having a specific surface area of 5 to 15 m2/g. The separator has a porosity of 55 to 80%, and a pore diameter distribution having a first peak in a pore diameter range of 0.2 μm (inclusive) to 2 μm (exclusive) and a second peak in a pore diameter range of 2 to 30 μm.

Abstract translation: 二次电池包括正极，含有锂离子吸收电位为0.2V（相对于Li / Li +）以上的金属化合物的负极，隔膜和非水电解质。 隔膜设置在正极和负极之间。 隔膜包括纤维素纤维和比表面积为5至15m2 / g的孔。 隔膜的孔隙率为55〜80％，孔径分布在孔径范围为0.2μm〜2μm（排他性）的孔径范围内，第2峰的孔径范围为2〜30 μm。