公开(公告)号：US20130217895A1

公开(公告)日：2013-08-22

申请号：US13881181

申请日：2011-11-29

申请人： Shinya Yamada ,  Hironori Maeda ,  Yoji Hori

发明人： Shinya Yamada ,  Hironori Maeda ,  Yoji Hori

IPC分类号： B01J31/26 ,  C07B35/02

CPC分类号： B01J31/26 ,  B01J23/38 ,  B01J23/40 ,  B01J23/44 ,  B01J23/46 ,  B01J31/0209 ,  B01J31/0237 ,  B01J31/0245 ,  B01J31/04 ,  B01J2231/643 ,  C07B35/02 ,  C07B53/00 ,  C07B2200/07 ,  C07C45/62 ,  C07D207/12 ,  C07D317/08 ,  C07D333/22 ,  C07C47/21

摘要： The present invention provides a catalyst used for manufacturing an optically active carbonyl compound by selective asymmetric hydrogenation of an α, β-unsaturated carbonyl compound, which is insoluble in a reaction mixture, and a method for manufacturing the corresponding optically active carbonyl compound. Particularly, the invention provides a catalyst for obtaining an optically active citronellal useful as a flavor or fragrance, by selective asymmetric hydrogenation of citral, geranial or neral. The invention relates to a catalyst for asymmetric hydrogenation of an α, β-unsaturated carbonyl compound, which comprises: a powder of at least one metal selected from metals belonging to Group 8 to Group 10 of the Periodic Table, or a metal-supported substance in which the at least one metal is supported on a support; an optically active cyclic nitrogen-containing compound; and an acid, and also relates to a method for manufacturing an optically active carbonyl compound using the same.

摘要翻译： 本发明提供了通过选择性不对称氢化不溶于反应混合物的α，β-不饱和羰基化合物和用于制备相应的光学活性羰基化合物的方法制备光学活性羰基化合物的催化剂。 特别地，本发明提供了一种用于获得可用作香料或香料的光学活性香茅醛的催化剂，通过柠檬醛，香叶醛或柠檬酸的选择性不对称氢化。 本发明涉及α，β-不饱和羰基化合物的不对称氢化催化剂，其包括：选自属于元素周期表第8族至第10族的金属中的至少一种金属的粉末或金属负载物质 其中所述至少一种金属支撑在支撑件上; 光学活性环状含氮化合物; 和酸，并且还涉及使用其制备具有光学活性的羰基化合物的方法。

公开(公告)号：US08345220B2

公开(公告)日：2013-01-01

申请号：US12043578

申请日：2008-03-06

申请人： Hironori Maeda

发明人： Hironori Maeda

IPC分类号： G03B27/52 ,  G03B27/68

CPC分类号： G01M11/0264 ,  G01M11/0271 ,  G03F7/706

摘要： A method for measuring a spherical aberration or a coma aberration of a projection optical system of an exposure apparatus configured to transfer an image of a pattern formed on an original plate onto a substrate through the projection optical system. The method for measuring the spherical aberration includes obtaining a focal position of the projection optical system under a first measurement condition, obtaining a focal position of the projection optical system under a second measurement condition different from the first measurement condition, and measuring the spherical aberration of the projection optical system based on a difference of the focal position obtained under the first and the second measurement conditions.

摘要翻译： 一种用于测量曝光装置的投影光学系统的球面像差或彗形像差的方法，所述曝光装置被配置为通过所述投影光学系统将形成在原版上的图案的图像转印到基板上。 用于测量球面像差的方法包括在第一测量条件下获得投影光学系统的焦点位置，在与第一测量条件不同的第二测量条件下获得投影光学系统的焦点位置，并且测量球面像差 基于在第一和第二测量条件下获得的焦点位置的差异的投影光学系统。

公开(公告)号：US08217204B2

公开(公告)日：2012-07-10

申请号：US12792016

申请日：2010-06-02

申请人： Hironori Maeda ,  Yoji Hori

发明人： Hironori Maeda ,  Yoji Hori

IPC分类号： C07C45/62 ,  C07C29/17 ,  B01J31/02

CPC分类号： C07D207/06 ,  B01J31/181 ,  B01J2231/645 ,  B01J2531/821 ,  B01J2531/822 ,  B01J2531/824 ,  B01J2531/827 ,  B01J2531/828 ,  B01J2531/847 ,  C07B53/00 ,  C07B2200/07 ,  C07C45/62 ,  C07D207/08 ,  C07D207/16 ,  C07D233/32 ,  C07D241/44 ,  C07D405/04 ,  C07C47/21

摘要： This invention aims at providing a catalyst for producing an optically active aldehyde or an optically active ketone, which is an optically active carbonyl compound, by carrying out selective asymmetric hydrogenation of an α,β-unsaturated carbonyl compound, particularly a catalyst which is insoluble in a reaction mixture for obtaining optically active citronellal which is useful as a flavor or fragrance, by carrying out selective asymmetric hydrogenation of citral, geranial or neral; and a method for producing a corresponding optically active carbonyl compound. The invention relates to a catalyst for asymmetric hydrogenation of an α,β-unsaturated carbonyl compound, which comprises a powder of at least one metal selected from metals belonging to Group 8 to Group 10 of the Periodic Table, or a metal-supported substance in which at least one metal selected from metals belonging to Group 8 to Group 10 of the Periodic Table is supported on a support, an optically active cyclic nitrogen-containing compound and an acid.

摘要翻译： 本发明的目的在于提供一种用于制备光学活性醛或光学活性酮的催化剂，它是光学活性的羰基化合物，通过进行α，β-不饱和羰基化合物的选择性不对称氢化，特别是不溶于 在用于获得可用作香料或香料的光学活性香茅醛的反应混合物中，通过进行柠檬醛，香叶醛或香精的选择性不对称氢化; 以及制备相应的光学活性羰基化合物的方法。 本发明涉及一种α，β-不饱和羰基化合物的不对称氢化催化剂，它包括选自属于元素周期表第8至第10族金属的至少一种金属的粉末或金属负载物质 其中选自属于元素周期表第8族至第10族的金属中的至少一种金属负载在载体，光学活性环状含氮化合物和酸上。

公开(公告)号：US07580116B2

公开(公告)日：2009-08-25

申请号：US12168341

申请日：2008-07-07

申请人： Hironori Maeda

发明人： Hironori Maeda

IPC分类号： G03B27/74 ,  G03B27/42

CPC分类号： G03B27/74 ,  G03F9/7049 ,  G03F9/7088 ,  G03F9/7092

摘要： The present invention provides an exposure apparatus including a position detection apparatus that detects at least one of a position of a reticle and a position of a substrate. The position detection apparatus includes an optical member whose position can be changed, a photoelectric conversion device that receives light from a mark and outputs a detection signal, and a control unit that controls the position of the optical member based on information on a first evaluation value representing a symmetry of a waveform of the detection signal at each of a plurality of positions of the optical member and information on a second evaluation value representing a position shift of the mark detected upon changing a position of the mark in an optical axis direction of an optical system at each of the plurality of positions of the optical member.

摘要翻译： 本发明提供了一种曝光装置，其包括检测掩模版的位置和基板的位置中的至少一个的位置检测装置。 位置检测装置包括可以改变其位置的光学构件，从标记接收光并输出检测信号的光电转换装置，以及基于关于第一评估值的信息来控制光学构件的位置的控制单元 表示在光学构件的多个位置的每个位置处的检测信号的波形的对称性，以及表示在改变标记在光轴方向上的位置时检测到的标记的位置偏移的第二评估值的信息 在光学构件的多个位置的每一个处的光学系统。

公开(公告)号：US20080239271A1

公开(公告)日：2008-10-02

申请号：US12043578

申请日：2008-03-06

申请人： Hironori Maeda

发明人： Hironori Maeda

IPC分类号： G03B27/54

CPC分类号： G01M11/0264 ,  G01M11/0271 ,  G03F7/706

摘要： A method for measuring a spherical aberration or a coma aberration of a projection optical system of an exposure apparatus configured to transfer an image of a pattern formed on an original plate onto a substrate through the projection optical system. The method for measuring the spherical aberration includes obtaining a focal position of the projection optical system under a first measurement condition, obtaining a focal position of the projection optical system under a second measurement condition different from the first measurement condition, and measuring the spherical aberration of the projection optical system based on a difference of the focal position obtained under the first and the second measurement conditions.

摘要翻译： 一种用于测量曝光装置的投影光学系统的球面像差或彗形像差的方法，所述曝光装置被配置为通过所述投影光学系统将形成在原版上的图案的图像转印到基板上。 用于测量球面像差的方法包括在第一测量条件下获得投影光学系统的焦点位置，在与第一测量条件不同的第二测量条件下获得投影光学系统的焦点位置，并且测量球面像差 基于在第一和第二测量条件下获得的焦点位置的差异的投影光学系统。

公开(公告)号：US09061959B2

公开(公告)日：2015-06-23

申请号：US13990872

申请日：2011-12-01

申请人： Hironori Maeda ,  Hisanori Itoh ,  Shinya Yamada ,  Yoji Hori

发明人： Hironori Maeda ,  Hisanori Itoh ,  Shinya Yamada ,  Yoji Hori

IPC分类号： C07C29/132 ,  C07B53/00 ,  C07C29/17 ,  C07C29/56 ,  B01J31/18 ,  B01J31/26 ,  B01J21/18 ,  B01J23/44

CPC分类号： C07C29/132 ,  B01J21/18 ,  B01J23/44 ,  C07B53/00 ,  C07B2200/07 ,  C07C29/17 ,  C07C29/56 ,  C07C2601/14 ,  C07C35/12 ,  C07C35/17

摘要： An object of the present invention is to provide a method for manufacturing an optically active menthol having fewer steps, which generates less environmentally polluting waste because a catalytic reaction is involved in all of the steps, and is capable of saving a production cost. The present invention relates to a method for manufacturing an optically active menthol, including the following steps: A-1) asymmetrically hydrogenating at least one of geranial and neral to thereby obtain an optically active citronellal, B-1) conducting a ring-closure reaction of the optically active citronellal in the presence of an acid catalyst to thereby obtain an optically active isopulegol, and C-1) hydrogenating the optically active isopulegol to thereby obtain an optically active menthol.

摘要翻译： 本发明的目的是提供一种制造具有较少步骤的光学活性薄荷醇的方法，其由于在所有步骤中都涉及催化反应而产生较少环境污染的废物，并且能够节省生产成本。 本发明涉及一种光学活性薄荷醇的制造方法，其包括以下步骤：A-1）不对称地氢化至少一种香叶酸和盐酸，从而获得光学活性香茅醛B-1，进行闭环反应 的光学活性香茅醛在酸催化剂的存在下反应，从而得到光学活性的异胡列酮，和C-1）氢化光学活性异胡脑酮，从而得到光学活性的薄荷醇。

公开(公告)号：US08842294B2

公开(公告)日：2014-09-23

申请号：US13523717

申请日：2012-06-14

申请人： Ken Minoda ,  Yoshihiro Shiode ,  Kazuhiko Mishima ,  Hironori Maeda

发明人： Ken Minoda ,  Yoshihiro Shiode ,  Kazuhiko Mishima ,  Hironori Maeda

IPC分类号： G01B11/14 ,  G03F7/00 ,  G03F9/00 ,  G01D5/38

CPC分类号： B29D11/00769 ,  B29L2011/00 ,  B82Y10/00 ,  B82Y40/00 ,  G01D5/38 ,  G02B5/18 ,  G03F7/0002 ,  G03F9/7038 ,  G03F9/7049 ,  G03F9/7069 ,  G03F9/7076 ,  Y10T29/49769

摘要： A position detection apparatus includes an illumination optical system for illuminating a first diffraction grating having periods in each of a first direction and a second direction different from the first direction, and a second diffraction grating having a period different from the period in the second direction of the first diffraction grating in the second direction, at an oblique incidence, and a detection optical system for detecting diffracted light from the first diffraction grating and the second diffraction grating, wherein a relative position of the first diffraction grating and the second diffraction grating is detected based on the detected diffracted light, and wherein the illumination optical system includes a plurality of light intensity distributions in the first direction except for on an optical axis of the detection optical system, in a pupil plane thereof.

摘要翻译： 位置检测装置包括照明光学系统，用于照亮具有与第一方向不同的第一方向和第二方向的周期的第一衍射光栅，以及第二衍射光栅，其周期与第二方向的周期不同 第一衍射光栅在第二方向上以倾斜入射，以及检测光学系统，用于检测来自第一衍射光栅和第二衍射光栅的衍射光，其中检测第一衍射光栅和第二衍射光栅的相对位置 基于所检测的衍射光，并且其中所述照明光学系统在其瞳面中包括除了所述检测光学系统的光轴之外的第一方向上的多个光强度分布。

公开(公告)号：US20120328725A1

公开(公告)日：2012-12-27

申请号：US13523717

申请日：2012-06-14

申请人： Ken Minoda ,  Yoshihiro Shiode ,  Kazuhiko Mishima ,  Hironori Maeda

发明人： Ken Minoda ,  Yoshihiro Shiode ,  Kazuhiko Mishima ,  Hironori Maeda

IPC分类号： B29C59/02 ,  B23Q17/00 ,  G01B11/14

CPC分类号： B29D11/00769 ,  B29L2011/00 ,  B82Y10/00 ,  B82Y40/00 ,  G01D5/38 ,  G02B5/18 ,  G03F7/0002 ,  G03F9/7038 ,  G03F9/7049 ,  G03F9/7069 ,  G03F9/7076 ,  Y10T29/49769

摘要： A position detection apparatus includes an illumination optical system for illuminating a first diffraction grating having periods in each of a first direction and a second direction different from the first direction, and a second diffraction grating having a period different from the period in the second direction of the first diffraction grating in the second direction, at an oblique incidence, and a detection optical system for detecting diffracted light from the first diffraction grating and the second diffraction grating, wherein a relative position of the first diffraction grating and the second diffraction grating is detected based on the detected diffracted light, and wherein the illumination optical system includes a plurality of light intensity distributions in the first direction except for on an optical axis of the detection optical system, in a pupil plane thereof.

摘要翻译： 位置检测装置包括照明光学系统，用于照亮具有与第一方向不同的第一方向和第二方向的周期的第一衍射光栅，以及第二衍射光栅，其周期与第二方向的周期不同 第一衍射光栅在第二方向上以倾斜入射，以及检测光学系统，用于检测来自第一衍射光栅和第二衍射光栅的衍射光，其中检测第一衍射光栅和第二衍射光栅的相对位置 基于所检测的衍射光，并且其中所述照明光学系统在其瞳面中包括除了所述检测光学系统的光轴之外的第一方向上的多个光强度分布。

公开(公告)号：US20120206701A1

公开(公告)日：2012-08-16

申请号：US13453907

申请日：2012-04-23

申请人： Hironori Maeda

发明人： Hironori Maeda

IPC分类号： G03B27/52

CPC分类号： G01M11/0264 ,  G01M11/0271 ,  G03F7/706

摘要： A method for measuring a spherical aberration amount of a projection optical system that projects an image of a pattern formed on an original plate onto a substrate, includes: obtaining a first focal position in a direction of an optical axis of the projection optical system under a first measurement condition; obtaining a second focal position in the direction of the optical axis of the projection optical system under a second measurement condition; calculating the spherical aberration amount of the projection optical system based on a difference between the first focal position and the second focal position. Under the first measurement condition the focal position in the direction of the optical axis with respect to the spherical aberration amount does not change; and under the second measurement condition the focal position in the direction of the optical axis with respect to the spherical aberration amount changes.

摘要翻译： 一种用于测量将形成在原版上的图案的图像投影到基板上的投影光学系统的球面像差量的方法包括：在投影光学系统的光轴的方向上获得第一焦点位置 第一测量条件; 在第二测量条件下获得在所述投影光学系统的光轴方向上的第二焦点位置; 基于第一焦点位置和第二焦点位置之间的差来计算投影光学系统的球面像差量。 在第一测量条件下，相对于球面像差量在光轴方向上的焦点位置不变; 并且在第二测量条件下，相对于球面像差量在光轴方向上的焦点位置发生变化。

公开(公告)号：US20100209291A1

公开(公告)日：2010-08-19

申请号：US12666987

申请日：2008-06-25

申请人： Shiro Sasaguri ,  Hironori Maeda ,  Munetoshi Kawamura

发明人： Shiro Sasaguri ,  Hironori Maeda ,  Munetoshi Kawamura

IPC分类号： A61L2/03

CPC分类号： A01N1/02 ,  A01N1/0294

摘要： A method of preserving a biomaterial according to the present invention includes the step of simultaneously applying negative DC voltage and AC voltage to a biomaterial (O). It is preferable that in the simultaneous voltage application step, the biomaterial (O) is stored in a container (1) that surrounds at least the periphery of the biomaterial (O), and a voltage application plate (2) supplied with negative DC voltage and AC voltage in a superposed manner is placed along one outer surface of the container (1), so that the voltage is indirectly applied to the biomaterial (O).

摘要翻译： 根据本发明的保存生物材料的方法包括同时将负DC电压和AC电压施加到生物材料（O）的步骤。 优选的是，在同步电压施加工序中，生物材料（O）被储存在至少围绕生物材料（O）的周围的容器（1）中，以及供给负的直流电压的电压施加板（2） 并且叠加的AC电压沿着容器（1）的一个外表面放置，使得电压间接地施加到生物材料（O）。