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公开(公告)号：US08633123B2
公开(公告)日：2014-01-21
申请号：US13059967
申请日：2009-08-24
申请人： Scott D. Allen , Anna E. Cherian , Chris A. Simoneau , Jay J. Farmer , Geoffrey W. Coates , Alexei Gridnev , Robert E. LaPointe
发明人： Scott D. Allen , Anna E. Cherian , Chris A. Simoneau , Jay J. Farmer , Geoffrey W. Coates , Alexei Gridnev , Robert E. LaPointe
CPC分类号： C07F15/065 , B01J31/0239 , B01J31/0259 , B01J31/0265 , B01J31/182 , B01J31/183 , B01J31/1835 , B01J31/2243 , B01J2531/0238 , B01J2531/025 , B01J2531/0252 , B01J2531/0294 , B01J2531/31 , B01J2531/62 , B01J2531/845 , C07C251/24 , C07C279/12 , C07C2601/14 , C07D213/53 , C07D487/04 , C07D487/22 , C07F9/5355 , C07F9/6561 , C07F19/005 , C08F4/80 , C08G64/34
摘要： The present invention provides unimolecular metal complexes having increased activity in the copolymerization of carbon dioxide and epoxides. Also provided are methods of using such metal complexes in the synthesis of polymers. According to one aspect, the present invention provides metal complexes comprising an activating species with co-catalytic activity tethered to a multidentate ligand that is coordinated to the active metal center of the complex.
摘要翻译： 本发明提供了在二氧化碳和环氧化物的共聚中具有增加的活性的单分子金属络合物。 还提供了在合成聚合物中使用这种金属络合物的方法。 根据一个方面，本发明提供金属络合物，其包含与辅助配位体配位的辅助催化活性的活化物质，其与配合物的活性金属中心配位。
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公开(公告)号：US20130172524A1
公开(公告)日：2013-07-04
申请号：US13822795
申请日：2011-09-14
申请人： Jay J. Farmer
发明人： Jay J. Farmer
IPC分类号： C08G64/34
CPC分类号： C08G64/34 , B01J31/1805 , B01J31/2226 , B01J2531/0216 , B01J2531/0252 , B01J2531/31 , B01J2531/62 , B01J2531/845 , C07F5/069 , C07F11/005 , C07F15/065
摘要： The present invention provides bimetallic complexes having increased activity in the copolymerization of carbon dioxide and epoxides. Also provided are methods of using such metal complexes in the synthesis of polymers. According to one aspect, the present invention provides metal complexes comprising an activating species with co-catalytic activity tethered to a multidentate ligand that is coordinated to one or more active metal centers of the complex.
摘要翻译： 本发明提供了在二氧化碳和环氧化物的共聚中具有增加的活性的双金属络合物。 还提供了在合成聚合物中使用这种金属络合物的方法。 根据一个方面，本发明提供了金属络合物，其包含与多配体配位的辅催化活性的活化物质，其与复合物的一个或多个活性金属中心配位。
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公开(公告)号：US20130066044A1
公开(公告)日：2013-03-14
申请号：US13584992
申请日：2012-08-14
申请人： Scott D. Allen , Geoffrey W. Coates , Anna E. Cherian , Chris A. Simoneau , Alexei A. Gridnev , Jay J. Farmer
发明人： Scott D. Allen , Geoffrey W. Coates , Anna E. Cherian , Chris A. Simoneau , Alexei A. Gridnev , Jay J. Farmer
IPC分类号： C08G64/34
CPC分类号： C08G64/34 , C08G18/44 , C08G64/0208
摘要： In one aspect, the present disclosure encompasses polymerization systems for the copolymerization of CO2 and epoxides comprising 1) a catalyst including a metal coordination compound having a permanent ligand set and at least one ligand that is a polymerization initiator, and 2) a chain transfer agent having two or more sites that can initiate polymerization. In a second aspect, the present disclosure encompasses methods for the synthesis of polycarbonate polyols using the inventive polymerization systems. In a third aspect, the present disclosure encompasses polycarbonate polyol compositions characterized in that the polymer chains have a high percentage of —OH end groups and a high percentage of carbonate linkages. The compositions are further characterized in that they contain polymer chains having an embedded polyfunctional moiety linked to a plurality of individual polycarbonate chains.
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24.发明申请公开(公告)号：US20120010200A1
公开(公告)日：2012-01-12
申请号：US13240297
申请日：2011-09-22
申请人： Jiacheng Zhou , Ashoke Bhattacharjee , Shili Chen , Yi Chen , Jay J. Farmer , Joel A. Goldberg , Roger Hanselmann , Rongliang Lou , Alia Orbin , Adegboyega K. Oyelere , Joseph M. Salvino , Dane M. Springer , Jennifer Tran , Deping Wang , Yusheng Wu
发明人： Jiacheng Zhou , Ashoke Bhattacharjee , Shili Chen , Yi Chen , Jay J. Farmer , Joel A. Goldberg , Roger Hanselmann , Rongliang Lou , Alia Orbin , Adegboyega K. Oyelere , Joseph M. Salvino , Dane M. Springer , Jennifer Tran , Deping Wang , Yusheng Wu
IPC分类号： A61K31/541 , C07D413/10 , C07D271/06 , C07D471/04 , C07D279/10 , A61K31/422 , A61K31/497 , A61K31/4245 , A61K31/519 , A61K31/5377 , A61P31/04 , A61P31/12 , A61P33/00 , A61P31/10 , A61P1/00 , A61P35/00 , C07D263/22
CPC分类号： C07D487/04 , C07D263/20 , C07D263/24 , C07D263/26 , C07D263/32 , C07D413/10 , C07D413/12 , C07D413/14 , C07D417/10 , C07D417/12 , C07D417/14 , C07D453/02 , C07D471/04 , C07D473/00 , C07D473/34
摘要： The present invention relates generally to the field of anti-infective, anti-proliferative, anti-inflammatory, and prokinetic agents. More particularly, the invention relates to a family of compounds having both a biaryl moiety and at least one heterocylic moiety that are useful as such agents.
摘要翻译： 本发明一般涉及抗感染，抗增殖，抗炎和促动力的领域。 更具体地，本发明涉及具有联芳基部分和至少一个可用作这种试剂的杂环部分的化合物族。
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公开(公告)号：US10138369B2
公开(公告)日：2018-11-27
申请号：US14116675
申请日：2012-05-09
摘要： The present invention encompasses polymer compositions comprising aliphatic polycarbonate chains containing functional groups that increase the polymer's ability to wet or adhere to inorganic materials. In certain embodiments, chain ends of the aliphatic polycarbonates are modified to introduce silicon-containing functional groups, boron-containing functional groups, phosphorous-containing functional groups, sulfonic acid groups or carboxylic acid groups.
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26.发明申请METHODS FOR COPRODUCTION OF TEREPHTHALIC ACID AND STYRENE FROM ETHYLENE OXIDE 有权用于从乙烯氧化物中共同对苯二酸和苯乙烯进行共聚的方法公开(公告)号：US20170001939A1
公开(公告)日：2017-01-05
申请号：US15199047
申请日：2016-06-30
申请人： Sadesh Sookraj , Jay J. Farmer
发明人： Sadesh H. Sookraj , Jay J. Farmer
IPC分类号： C07C51/14
CPC分类号： C07C51/14 , C07C51/09 , C07C51/377 , C07C51/416 , Y02P20/582 , C07C57/04 , C07C63/06 , C07C63/26
摘要： The present invention provides methods for the production of terephthalic acid and derivatives thereof using ethylene oxide, carbon monoxide and furan as feedstocks. The process is characterized by high yields and high carbon efficiency. The process can utilize 100% biobased feedstocks (EO via ethanol, CO via biomass gasification, and furan via known processes from cellulosic feedstocks). In one aspect, processes of the invention coproduce biobased terephthalic acid and biobased styrene.
摘要翻译： 本发明提供使用环氧乙烷，一氧化碳和呋喃作为原料生产对苯二甲酸及其衍生物的方法。 该方法的特点是高产率和高碳效率。 该方法可利用100％生物基原料（EO通过乙醇，CO通过生物质气化，呋喃通过已知方法从纤维素原料）。 一方面，本发明的方法共同生产生物基对苯二甲酸和生物基苯乙烯。
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公开(公告)号：US09284406B2
公开(公告)日：2016-03-15
申请号：US13822795
申请日：2011-09-14
申请人： Jay J. Farmer
发明人： Jay J. Farmer
CPC分类号： C08G64/34 , B01J31/1805 , B01J31/2226 , B01J2531/0216 , B01J2531/0252 , B01J2531/31 , B01J2531/62 , B01J2531/845 , C07F5/069 , C07F11/005 , C07F15/065
摘要： The present invention provides bimetallic complexes having increased activity in the copolymerization of carbon dioxide and epoxides. Also provided are methods of using such metal complexes in the synthesis of polymers. According to one aspect, the present invention provides metal complexes comprising an activating species with co-catalytic activity tethered to a multidentate ligand that is coordinated to one or more active metal centers of the complex.
摘要翻译： 本发明提供了在二氧化碳和环氧化物的共聚中具有增加的活性的双金属络合物。 还提供了在合成聚合物中使用这种金属络合物的方法。 根据一个方面，本发明提供了金属络合物，其包含与多配体配位的辅催化活性的活化物质，其与复合物的一个或多个活性金属中心配位。
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公开(公告)号：US08841263B2
公开(公告)日：2014-09-23
申请号：US13525900
申请日：2012-06-18
申请人： Jay J. Farmer , Ashoke Bhattacharjee , Yi Chen , Joel A. Goldberg , Joseph A. Ippolito , Zoltan F. Kanyo , Rongliang Lou , Adegboyega K. Oyelere , Edward C. Sherer , Joyce A. Sutcliffe , Deping Wang , Yusheng Wu , Yanming Du
发明人： Jay J. Farmer , Ashoke Bhattacharjee , Yi Chen , Joel A. Goldberg , Joseph A. Ippolito , Zoltan F. Kanyo , Rongliang Lou , Adegboyega K. Oyelere , Edward C. Sherer , Joyce A. Sutcliffe , Deping Wang , Yusheng Wu , Yanming Du
摘要： The present invention provides macrocyclic compounds useful as therapeutic agents of the formula: or a pharmaceutically acceptable salt, ester, N-oxide, or prodrug thereof, wherein T, R1, R2, R3, D, E, F, and G are as defined herein. More particularly, these compounds are useful as anti-infective, antiproliferative, anti-inflammatory and prokinetic agents.
摘要翻译： 本发明提供可用作下式的治疗剂的大环化合物：或其药学上可接受的盐，酯，N-氧化物或前药，其中T，R 1，R 2，R 3，D，E，F和G如上所定义 这里。 更具体地，这些化合物可用作抗感染，抗增殖，抗炎和促动力剂。
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公开(公告)号：US20140171617A1
公开(公告)日：2014-06-19
申请号：US14237447
申请日：2012-08-08
申请人： Jay J. Farmer
发明人： Jay J. Farmer
CPC分类号： C07F15/065 , B01J31/1815 , B01J31/182 , B01J31/183 , B01J31/1835 , B01J31/2243 , B01J2231/14 , B01J2231/341 , B01J2531/0216 , B01J2531/0252 , B01J2531/31 , B01J2531/62 , B01J2531/845 , C07D307/33 , C08G64/34 , Y02P20/142
摘要： The present invention provides oligomeric metal complexes having more than one metal center and methods of using such complexes. The provided metal complexes are useful in the copolymerization of carbon dioxide and epoxides.
摘要翻译： 本发明提供具有多于一个金属中心的低聚金属络合物和使用这种络合物的方法。 所提供的金属络合物可用于二氧化碳和环氧化物的共聚。
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公开(公告)号：US20140072806A1
公开(公告)日：2014-03-13
申请号：US14116675
申请日：2012-05-09
CPC分类号： C08L69/00 , B32B17/10036 , B32B17/10733 , C08G18/44 , C08G64/0208 , C08G64/0216 , C08G64/0225 , C08G64/0266 , C08G64/42 , C08K7/14 , C08L61/06 , Y10T428/31518
摘要： The present invention encompasses polymer compositions comprising aliphatic polycarbonate chains containing functional groups that increase the polymer's ability to wet or adhere to inorganic materials. In certain embodiments, chain ends of the aliphatic polycarbonates are modified to introduce silicon-containing functional groups, boron-containing functional groups, phosphorous-containing functional groups, sulfonic acid groups or carboxylic acid groups.
摘要翻译： 本发明包括包含脂族聚碳酸酯链的聚合物组合物，所述脂肪族聚碳酸酯链含有提高聚合物润湿或粘附于无机材料的能力的官能团。 在某些实施方案中，改性脂族聚碳酸酯的链端以引入含硅官能团，含硼官能团，含磷官能团，磺酸基团或羧酸基团。
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