公开(公告)号：US20100204345A1

公开(公告)日：2010-08-12

申请号：US12670995

申请日：2008-08-07

申请人： Taku Yamanaka ,  Nobuhiko Tsuda ,  Masayuki Tsuji ,  Yasuhiko Sawada

发明人： Taku Yamanaka ,  Nobuhiko Tsuda ,  Masayuki Tsuji ,  Yasuhiko Sawada

IPC分类号： A61K47/32 ,  C08L27/18 ,  C08F214/26 ,  G03G9/08 ,  A61Q90/00

CPC分类号： C08F14/26 ,  C08F2/18 ,  C08F6/16 ,  C08F6/20 ,  C08F6/22 ,  C08F214/26 ,  G03G9/0872 ,  G03G9/09766 ,  C08L27/18 ,  C08F2/20 ,  C08F2/24

摘要： The present invention provides an aqueous dispersion of a low-molecular-weight polytetrafluoroethylene (PTFE), which contains an easily removable surfactant, and has a good dispersion stability. Specifically, the present invention provides an aqueous dispersion of a low-molecular-weight PTFE comprising tetrafluoroethylene (TFE) units, or TFE units and modifying monomer units which are copolymerizable with the TFE units, wherein the aqueous dispersion contains from 70 to 9,000 ppm, based on the aqueous dispersion, of a fluorine-containing compound of the formula (1) below: X—(CF2)m—Y  (1) where X is H or F; m is an integer from 3 to 5; and Y is —SO3M, —SO4M, —SO3R, —SO4R, —COOM, —PO3M2 or —PO4M2, M being H, NH4 or an alkali metal, and R being an alkyl group having 1 to 12 carbons, and the low-molecular-weight PTFE has an average primary particle size of from 100 to 350 nm.

摘要翻译： 本发明提供一种低分子量聚四氟乙烯（PTFE）的水分散体，其含有易于除去的表面活性剂，并且具有良好的分散稳定性。 具体地说，本发明提供了包含四氟乙烯（TFE）单元或TFE单元的低分子量PTFE的水性分散体和可与TFE单元共聚的改性单体单元，其中，水分散体含有70〜9000ppm， 基于水分散体的下式（1）的含氟化合物：X-（CF 2）m -Y（1）其中X是H或F; m为3〜5的整数; Y是-SO 3 M，-SO 4 M，-SO 3 R，-SO 4 R，-COOM，-PO 3 M 2或-PO 4 M 2，M是H，NH 4或碱金属，R是具有1至12个碳原子的烷基， 分子量的PTFE的平均一次粒径为100〜350nm。

公开(公告)号：US07714047B2

公开(公告)日：2010-05-11

申请号：US12476172

申请日：2009-06-01

申请人： Nobuhiko Tsuda ,  Chie Sawauchi ,  Yasuhiko Sawada ,  Tetsuo Shimizu

发明人： Nobuhiko Tsuda ,  Chie Sawauchi ,  Yasuhiko Sawada ,  Tetsuo Shimizu

IPC分类号： C08K5/41

CPC分类号： C08F6/20 ,  C08F6/16 ,  C08F14/18 ,  C08F14/26 ,  C08F214/26 ,  C08L27/12 ,  C08F2/16

摘要： The present invention provides a method of producing a fluoropolymer aqueous dispersion by which the fluorine-containing emulsifier contained in the fluoropolymer aqueous dispersion as obtained after polymerization can be efficiently removed as well as a fluoropolymer aqueous dispersion low in fluorine-containing emulsifier concentration. The present invention is a method of producing a fluoropolymer aqueous dispersion which comprises carrying out a concentration treatment comprising a concentration operation of a pretreatment fluoropolymer aqueous dispersion, wherein the pretreatment fluoropolymer aqueous dispersion is obtained by carrying out a polymerization in an aqueous medium in the presence of a fluorine-containing surfactant (A), the fluorine-containing surfactant (A) is a fluorine-containing surfactant having an octanol/water partition coefficient of 1.5 to 3.5.

摘要翻译： 本发明提供一种含氟聚合物水性分散体的制造方法，其中可以有效地除去聚合后得到的含氟聚合物水分散体中所含的含氟乳化剂以及含氟乳化剂浓度低的含氟聚合物水分散体。 本发明是一种含氟聚合物水性分散体的制造方法，其特征在于，进行包含预处理含氟聚合物水分散液的浓缩操作的浓缩处理，其中，所述预处理含氟聚合物水分散体是通过在水性介质中进行聚合而得到的 含氟表面活性剂（A）的含氟表面活性剂（A）为辛醇/水分配系数为1.5〜3.5的含氟表面活性剂。

公开(公告)号：US20090176942A1

公开(公告)日：2009-07-09

申请号：US12348025

申请日：2009-01-02

申请人： Takuji ISHIKAWA ,  Nobuhiko Tsuda ,  Yoshihiro Yamamoto

发明人： Takuji ISHIKAWA ,  Nobuhiko Tsuda ,  Yoshihiro Yamamoto

IPC分类号： C08G67/00 ,  C07C59/135 ,  C08L67/00 ,  C07C51/42

CPC分类号： C08F2/26 ,  B01F17/0035 ,  C07C51/09 ,  C07C59/135

摘要： The invention provides a fluoroethercarboxylic acid which is represented by the general formula (I): Rf1OCHFCF2ORf2COOM   (I) wherein Rf1 represents a partially or fully fluorinated alkyl group, which may optionally be interrupted with one or more oxygen atoms, Rf2 represents a partially or fully fluorinated alkylene group, which may optionally be interrupted with one or more oxygen atoms, and M represents a monovalent alkali metal, NH4 or H. The fluoroethercarboxylic acid can be suitably used as a surfactant and is low in bioaccumulation. The invention is also a method of fluoropolymer production and an aqueous fluoropolymer dispersion, using the fluoroethercarboxylic acid as a surfactant.

摘要翻译： 本发明提供由通式（I）表示的氟代醚羧酸：<？in-line-formula description =“In-line formula”end =“lead”？> Rf1OCHFCF2ORf2COOM（I）<βin-line-formula 描述=“内联式”末端=“尾”→其中Rf1表示部分或完全氟化的烷基，其可任选地被一个或多个氧原子间隔，Rf 2表示部分或完全氟化的亚烷基，其可以 任选地被一个或多个氧原子中断，并且M表示一价碱金属NH 4或H.氟代醚羧酸可以适当地用作表面活性剂，并且生物蓄积低。 本发明也是使用氟代醚羧酸作为表面活性剂的氟聚合物生产方法和含氟聚合物水分散体。

公开(公告)号：US20090069492A1

公开(公告)日：2009-03-12

申请号：US11911174

申请日：2006-04-13

申请人： Nobuhiko Tsuda ,  Chie Sawauchi

发明人： Nobuhiko Tsuda ,  Chie Sawauchi

IPC分类号： B01D53/56

CPC分类号： C08F6/20 ,  C08F6/16 ,  C08J3/05 ,  C08J2327/12 ,  C08L27/12

摘要： The invention provides a method of producing an aqueous fluoropolymer dispersion by which aqueous fluoropolymer dispersions high in fluoropolymer concentration can be prepared in a short period of time. The present invention provides a method of producing an aqueous fluoropolymer dispersion comprising a step (1) of adding a nonionic surfactant to an aqueous fluoropolymer dispersion to be treated, a step (2) of phase-separating into a supernatant phase and an aqueous fluoropolymer dispersion phase following the step (1), and a step (3) of recovering the aqueous fluoropolymer dispersion phase by removing the supernatant phase, stirring being provided in the step (2).

摘要翻译： 本发明提供了一种制备含氟聚合物含水聚合物分散体的方法，通过该方法可以在短时间内制备含氟聚合物浓度高的含氟聚合物分散体。 本发明提供一种含氟聚合物水分散体的制造方法，其特征在于，在含氟聚合物水性分散液中添加非离子性表面活性剂的工序（1），将上述相分离成上清相的步骤（2） 步骤（1）的步骤（3），和通过除去上清相，在步骤（2）中提供的搅拌来回收含氟聚合物水分散相的步骤（3）。

公开(公告)号：US20080114118A1

公开(公告)日：2008-05-15

申请号：US11547637

申请日：2005-04-05

申请人： Nobuhiko Tsuda ,  Yoshiki Tanaka ,  Shigeru Morita ,  Yasuhiko Sawada ,  Tetsuo Shimizu

发明人： Nobuhiko Tsuda ,  Yoshiki Tanaka ,  Shigeru Morita ,  Yasuhiko Sawada ,  Tetsuo Shimizu

IPC分类号： C08L27/12 ,  C08F16/24

CPC分类号： C08F14/18 ,  C08F2/16

摘要： Disclosed is a method for producing a fluorine-containing elastomer polymer which is excellent in productivity and crosslinkability. Specifically disclosed is a method for producing a fluorine-containing elastomer polymer wherein a fluorine-containing monomer is polymerized in an aqueous solvent in the presence of an emulsifying agent containing a fluorine-containing vinyl group and a chain transfer agent. This method for producing a fluorine-containing elastomer polymer is characterized in that the emulsifying agent containing a fluorine-containing vinyl group is composed of a compound having a radically polymerizable unsaturated bond and a hydrophilic group in a molecule.

摘要翻译： 公开了一种生产性和交联性优异的含氟弹性体聚合物的制造方法。 具体公开了一种含氟弹性体聚合物的制造方法，其中含氟单体在含有含氟乙烯基和链转移剂的乳化剂存在下，在含水溶剂中聚合。 该含氟弹性体聚合物的制造方法的特征在于，含有含氟乙烯基的乳化剂由分子内具有自由基聚合性不饱和键和亲水性基团的化合物构成。

公开(公告)号：US20060281946A1

公开(公告)日：2006-12-14

申请号：US10562730

申请日：2004-07-02

申请人： Shigeru Morita ,  Yoshiki Tanaka ,  Keiko Washino ,  Nobuhiko Tsuda ,  Mitsuru Kishine

发明人： Shigeru Morita ,  Yoshiki Tanaka ,  Keiko Washino ,  Nobuhiko Tsuda ,  Mitsuru Kishine

IPC分类号： C07C59/135

CPC分类号： C08F14/18 ,  C08F2/16

摘要： This invention provides a novel compound which can be properly used as a surfactant, a method of producing a fluoropolymer, surfactant and a fluoropolymer aqueous dispersions using the novel compound. This invention is a fluoroalkylcarboxylic acid derivative which is represented by the general formula (i): Rf1(OCH2CF2CF2)n1OCX1X2CF2(Rf2)n2COOM   (i) wherein Rf1 represents a straight or branched fluoroalkyl group containing 1 to 20 carbon atoms, which fluoroalkyl group may optionally contain 1 to 5 oxygen atoms in the principal chain thereof, Rf2 represents a straight or branched fluoroalkylene group containing 1 to 25 carbon atoms, said fluoroalkylene group may optionally contain 1 to 5 oxygen atoms in the principal chain thereof, n1 represents an integer of 0 to 3, n2 represents an integer of 0 or 1, X1 and X2 are the same or different and each represents hydrogen atom or fluorine atom, and M represents NH4 or a monovalent metal element.

摘要翻译： 本发明提供了可以适当地用作表面活性剂的新型化合物，使用该新化合物的含氟聚合物，表面活性剂和含氟聚合物水分散体的制造方法。 本发明是由通式（i）表示的氟代烷基羧酸衍生物：<？in-line-formula description =“In-line formula”end =“lead”？> Rf < OCH 2 2 CF 2 2 CF 2）n 1 OCX 1 X 2 CF 2（Rf 2）N 2 COOM（i）<？in-line-formula description =“In-Line Formulas “end =”tail“？>其中Rf 1表示含有1至20个碳原子的直链或支链氟烷基，该氟烷基可以任选地在其主链中含有1至5个氧原子，Rf 代表含有1至25个碳原子的直链或支链氟代亚烷基，所述氟亚烷基可以任选地在其主链中含有1至5个氧原子，n1表示0-3的整数，n2表示 0或1的整数，X 1和X 2相同或不同，各自表示氢原子或氟原子，M表示NH _{4 或一价金属元素。}

公开(公告)号：US07147922B2

公开(公告)日：2006-12-12

申请号：US10895945

申请日：2004-07-22

申请人： Nobuhiko Tsuda ,  Keisuke Matsumoto ,  Masaki Takakura ,  Ken Okanishi

发明人： Nobuhiko Tsuda ,  Keisuke Matsumoto ,  Masaki Takakura ,  Ken Okanishi

IPC分类号： B32B27/30 ,  C08L27/16

CPC分类号： C08L27/16 ,  B32B27/30 ,  C08L33/12 ,  Y10T428/3154 ,  Y10T428/31935 ,  C08L2666/04

摘要： There are provided a resin film being excellent in blocking resistance, scratch resistance, transparency, water resistance and chemical resistance and a member having the resin film as an outermost layer. The resin film comprises a vinylidene fluoride (VdF) copolymer and an acrylic polymer as essential components, in which a heat of fusion of crystal derived from the VdF copolymer in the resin film is from 15 to 30 J/g when measured with a differential scanning calorimeter (DSC), and light transmittance (light transmittance at 600 nm of 50 μm thick resin film) is not less than 85%. The member has the resin film as an outermost layer.

摘要翻译： 提供了耐粘连性，耐擦伤性，透明性，耐水性和耐化学性优异的树脂膜和具有树脂膜作为最外层的部件。 树脂膜包括偏二氟乙烯（VdF）共聚物和作为必要成分的丙烯酸类聚合物，当用差示扫描测量时，树脂膜中衍生自VdF共聚物的结晶的熔化热为15〜30J / g 热量计（DSC）和光透射率（50μm厚的树脂膜的600nm的透光率）不小于85％。 该构件具有作为最外层的树脂膜。

公开(公告)号：US06803419B2

公开(公告)日：2004-10-12

申请号：US10370653

申请日：2003-02-24

申请人： Nobuhiko Tsuda ,  Ryuzi Iwakiri

发明人： Nobuhiko Tsuda ,  Ryuzi Iwakiri

IPC分类号： C08L2712

CPC分类号： C09D127/16 ,  C08F259/06 ,  C08L27/16 ,  C08L33/12 ,  C09D133/12 ,  Y10S525/934 ,  Y10T428/2982 ,  Y10T428/2998 ,  C08F220/14 ,  C08L2666/04

摘要： The present invention is a method for preparing a thermosetting power coating composition having the steps of blending vinylidene fluorine copolymer particles and methyl methacrylate copolymer particles, and pulverizing the blended copolymer particles to an average particle size of 1 to 100 &mgr;m under 40° C.

摘要翻译： 本发明是一种制备热固性电力涂料组合物的方法，该组合物具有以下步骤：将亚乙烯基氟共聚物颗粒和甲基丙烯酸甲酯共​​聚物颗粒混合，并将共混共聚物颗粒在40℃下粉碎至平均粒径为1至100μm。

公开(公告)号：US5869574A

公开(公告)日：1999-02-09

申请号：US838063

申请日：1997-04-17

申请人： Tetsuo Shimizu ,  Yoshihisa Yamamoto ,  Seitaro Yamaguchi ,  Nobuhiko Tsuda ,  Noriyasu Yamane ,  Takafumi Yamato ,  Masahiro Kumegawa ,  Takayuki Araki

发明人： Tetsuo Shimizu ,  Yoshihisa Yamamoto ,  Seitaro Yamaguchi ,  Nobuhiko Tsuda ,  Noriyasu Yamane ,  Takafumi Yamato ,  Masahiro Kumegawa ,  Takayuki Araki

IPC分类号： C08G59/30 ,  C08G59/32 ,  C08G61/12 ,  C08L27/12 ,  C08L27/16 ,  C08L67/00 ,  C08L67/02 ,  C08L67/03 ,  C08L69/00 ,  C08L71/10 ,  C08L77/00 ,  C08L77/02 ,  C08L77/06 ,  C08L81/04 ,  C08L101/00

CPC分类号： C08L77/06 ,  C08G59/30 ,  C08G59/3254 ,  C08G61/12 ,  C08L101/00 ,  C08L27/12 ,  C08L27/16 ,  C08L67/00 ,  C08L67/02 ,  C08L67/03 ,  C08L69/00 ,  C08L77/00 ,  C08L77/02 ,  C08L81/04 ,  C08L2201/00

摘要： A thermoplastic resin composition comprising a blend obtainable by blending 0.1 to 99% by weight of (a) a fluorine-containing polymer having a number-average molecular weight of 2000 to 1000000 and having hydroxy group or epoxy group at least at one of end portions of a main chain and side chain of the polymer, and 1 to 99.9% by weight of (b) a heat resisting thermoplastic resin having a crystalline melting point or glass transition temperature of not less than 150.degree. C. The present invention can provide a composition comprising various heat resisting thermoplastic resins and a fluorine-containing polymer having a functional group which is capable of developing an affinity with said resins and forming a uniform dispersion.

公开(公告)号：US5081175A

公开(公告)日：1992-01-14

申请号：US635445

申请日：1990-12-28

申请人： Toshiharu Yagi ,  Tsuyoshi Noguchi ,  Yoshito Tanaka ,  Kohsaku Sakaguchi ,  Nobuhiko Tsuda

发明人： Toshiharu Yagi ,  Tsuyoshi Noguchi ,  Yoshito Tanaka ,  Kohsaku Sakaguchi ,  Nobuhiko Tsuda

IPC分类号： C08L27/16 ,  C08J3/09 ,  C08L27/14 ,  C08L33/06 ,  C09D127/00 ,  C09D127/10 ,  C09D127/12 ,  C09D127/16 ,  C09D133/04

CPC分类号： C09D127/16 ,  C08J3/095 ,  C09D133/04 ,  C08L27/16 ,  C08L33/06 ,  Y10T428/31699

摘要： The present invention provides a coating composition which comprises (a) a polymer containing vinylidene fluoride, (b) an acrylic polymer and (c) acetylacetone, as essential components, and an article which is coated or impregnated with the coating composition.