公开(公告)号：US20050205165A1

公开(公告)日：2005-09-22

申请号：US11108880

申请日：2005-04-19

Applicant: Jun Akui ,  Akinori Nagai ,  Yasuhiko Haruta ,  Osamu Isozaki

Inventor： Jun Akui ,  Akinori Nagai ,  Yasuhiko Haruta ,  Osamu Isozaki

IPC: C01G23/04 ,  C01G23/053 ,  C09C1/36 ,  C09D1/00 ,  C23C18/12 ,  C23C22/06 ,  C23C26/00 ,  C23C30/00 ,  C23C22/07

CPC classification number: C23C30/00 ,  C01G23/04 ,  C01G23/053 ,  C01P2004/84 ,  C09C1/3607 ,  C09D1/00 ,  C23C18/1216 ,  C23C18/1241 ,  C23C18/1254 ,  C23C26/00

Abstract: The present invention provides a coating composition for forming a titanium oxide film, comprising (A) a specific titanium-containing aqueous liquid and (B) at least one compound selected from the group consisting of organic acids and their salts. The present invention also provides a process for forming a titanium oxide film using the coating composition, and a metal substrate coated therewith.

Abstract translation: 本发明提供了一种用于形成氧化钛膜的涂料组合物，其包含（A）特定的含钛水性液体和（B）至少一种选自有机酸及其盐的化合物。 本发明还提供了一种使用该涂料组合物形成氧化钛膜的方法和其上涂覆的金属基材。

公开(公告)号：US06733580B2

公开(公告)日：2004-05-11

申请号：US10408549

申请日：2003-04-08

Applicant: Osamu Isozaki

Inventor： Osamu Isozaki

IPC: C01G2304

CPC classification number: C23C18/1216 ,  C01G23/053 ,  C01P2004/84 ,  C01P2006/60

Abstract: A method for preparing an inorganic film-forming coating composition. The method involves reacting a titanium monomer and/or a low condensation product thereof containing a group hydrolyzed to form a hydroxyl group with a hydrogen peroxide water.

Abstract translation: 一种无机成膜涂料组合物的制备方法。 该方法包括使含有水解形成羟基的基团的钛单体和/或其低缩合产物与过氧化氢水反应。

公开(公告)号：US06331376B1

公开(公告)日：2001-12-18

申请号：US09582846

申请日：2000-07-05

Applicant: Daisuke Kojima ,  Genji Imai ,  Jun Akui ,  Hideo Kogure ,  Osamu Isozaki

Inventor： Daisuke Kojima ,  Genji Imai ,  Jun Akui ,  Hideo Kogure ,  Osamu Isozaki

IPC: G03F7029

CPC classification number: G03F7/027 ,  C08F290/067 ,  C08G18/672 ,  C08G18/7642 ,  G03F7/0388 ,  C08G18/48 ,  C08G18/0823

Abstract: An organic solvent based photocurable resist composition containing a photopolymerizable polyurethane compound having a repeating unit represented by the following formula: B—[X]n[Y]m—B, where X is represented by the formula: and Y is represented by the formula: —OOCHN—A—NHCOO(R2)—, A is a structural unit derived from a polyisocyanate compound, B is same or different and a structural unit derived from a hydroxy compound having at least one photopolymerizable unsaturated group at molecular terminals respectively and optionally containing an ether linkage, R1 is a structural unit derived from a carboxyl group-containing polyol compound, R2 is a structural unit derived from a polyol compound, n is an integer of 1 to 10, m is an integer of 1 to 10, provided that one X and one Y are bonded to each other, or three or more of X and/or Y are bonded to each other.

Abstract translation: 含有具有下式表示的重复单元的光聚合性聚氨酯化合物的有机溶剂型光固化抗蚀剂组合物：B- [X] n [Y] mB，其中X由下式表示：Y由下式表示： - OOCHN-A-NHCOO（R2） - ，A是衍生自多异氰酸酯化合物的结构单元，B相同或不同，并且衍生自在分子末端具有至少一个光聚合性不饱和基团的羟基化合物的结构单元，并且任选地含有 醚键，R1是衍生自含羧基的多元醇化合物的结构单元，R2是衍生自多元醇化合物的结构单元，n是1〜10的整数，m是1〜10的整数，条件是一个 X和一个Y彼此键合，或者X和/或Y中的三个或更多个彼此键合。

公开(公告)号：US5578695A

公开(公告)日：1996-11-26

申请号：US357267

申请日：1994-12-13

Applicant: Osamu Isozaki

Inventor： Osamu Isozaki

IPC: C08G59/42 ,  C08G67/04 ,  C08L63/00 ,  C08L73/02 ,  C09D133/06

CPC classification number: C08L63/00 ,  C08G59/42 ,  C08G67/04 ,  C08L73/02 ,  C09D133/068

Abstract: The invention provides a crosslinking agent comprising a compound having at least two noncyclic acid anhydride groups and represented by the following formula ##STR1## wherein R is a monovalent hydrocarbon group having 2 to 50 carbon atoms, R' is a bivalent hydrocarbon group having 2 to 50 carbon atoms, the hydrocarbon groups R and R' containing or not containing an ether linkage, urethane linkage or ester linkage, and n is an integer of 1 to 500.The invention also provides a curable composition including (A) at least one resin selected from the group consisting of (i) a resin having at least one epoxy group and at least one hydroxyl group in the molecule, (ii) a resin mixture of a resin having at least two epoxy groups in the molecule and a resin having at least two hydroxyl groups in the molecule, and (iii) a resin having at least two epoxy groups in the molecule, and (B) the above-mentioned crosslinking agent.

Abstract translation: 本发明提供了包含具有至少两个非环状酸酐基团并由下式表示的化合物的交联剂：其中R是具有2-50个碳原子的一价烃基，R'是二价烃基 具有2-50个碳原子，含有或不含醚键的烃基R和R'，氨基甲酸酯键或酯键，n是1至500的整数。本发明还提供一种可固化组合物，其包含（A） 至少一种树脂，其选自（i）分子中具有至少一个环氧基和至少一个羟基的树脂，（ii）分子中具有至少两个环氧基的树脂的树脂混合物和 分子中具有至少两个羟基的树脂，和（iii）分子中具有至少两个环氧基的树脂和（B）上述交联剂。

公开(公告)号：US5426135A

公开(公告)日：1995-06-20

申请号：US177934

申请日：1994-01-06

Applicant: Osamu Isozaki ,  Kiyoshi Nanishi ,  Hisashi Isaka

Inventor： Osamu Isozaki ,  Kiyoshi Nanishi ,  Hisashi Isaka

IPC: C08F8/42 ,  C08F8/46 ,  C08G77/442 ,  C09D5/16 ,  C09D135/00 ,  C09D183/06 ,  C09D183/10 ,  C09D201/08 ,  C09D201/10

CPC classification number: C08G77/442 ,  C08F8/42 ,  C08F8/46 ,  C09D135/00 ,  C09D183/06 ,  C09D183/10 ,  C09D201/08 ,  C09D201/10 ,  C09D5/165

Abstract: The present invention provides a soil preventing coating forming composition which consists essentially of a resin having at least two acid anhydride groups in the molecule on the average, the acid anhydride groups being represented by the formula ##STR1## wherein R is a C.sub.1-40 monovalent hydrocarbon group or a monovalent chain polysiloxane group represented by the formula ##STR2## wherein R.sub.1 and R.sub.2 are the same or different and are each alkyl, cycloalkyl, aryl, aralkyl or ##STR3## group, R.sub.3, R.sub.4, R.sub.5, R.sub.6 and R.sub.7 are the same or different and are each alkyl, cycloalkyl, aryl or aralkyl, n is an integer of 1 to 6, m is an integer of 0 or 1, p is an integer of 2 to 50, and q is an integer of 0 to 50.

Abstract translation: 本发明提供一种防污涂层形成组合物，其基本上由分子中具有至少两个酸酐基团的树脂组成，平均酸酐基由式碳基团表示，或由式 式（II）其中R 1和R 2相同或不同并且各自为烷基，环烷基，芳基，芳烷基或者基团，R 3，R 4，R 5，R 6和R 7相同或不同，各自为烷基 ，环烷基，芳基或芳烷基，n为1〜6的整数，m为0或1的整数，p为2〜50的整数，q为0〜50的整数。

公开(公告)号：US5093223A

公开(公告)日：1992-03-03

申请号：US278505

申请日：1988-12-01

Applicant: Naozumi Iwasawa ,  Osamu Isozaki

Inventor： Naozumi Iwasawa ,  Osamu Isozaki

IPC: B05D3/06 ,  C08G59/14 ,  C08J3/28 ,  G03F7/038

CPC classification number: G03F7/038 ,  B05D3/068 ,  C08G59/1433 ,  C08J3/28 ,  G03F7/0388 ,  Y10S522/904

Abstract: The invention provides a method of forming a cured coating film which comprises exposing a coating composition consisting of, or containing as a main component, a resin containing polymerizable unsaturated group and aprotic onium-containing group of the formula ##STR1## wherein R.sub.1 means a hydrogen atom or a hydrocarbon group of 1 to 8 carbon atoms which may optionally be substituted by a hydroxyl, alkoxy or ester group or a halogen atom; ##STR2## where Z means a nitrogen atom or phosphorus atom and Y means a sulfur atom; R.sub.2, R.sub.3 and R.sub.4 are the same or different and respectively mean an organic group of 1 to 14 carbon atoms, provided that R.sub.2 and R.sub.3, or R.sub.2, R.sub.3 and R.sub.4 may jointly form a heterocyclic group taken together with the adjacent nitrogen, phosphorus or sulfur atom, to actinic radiation or electron beams to thereby induce a crosslinking reaction and, then, subjecting the composition to heat treatment at a temperature not less than 80.degree. C.

Abstract translation: 本发明提供一种形成固化涂膜的方法，该方法包括使包含可聚合不饱和基团的树脂和式（Ⅰ）所示的非质子含鎓基团组成或包含作为主要成分的涂料组合物，其中R 1 是指氢原子或可任选被羟基，烷氧基或酯基或卤素原子取代的1至8个碳原子的烃基; 其中Z表示氮原子或磷原子，Y表示硫原子; R 2，R 3和R 4相同或不同，分别表示1至14个碳原子的有机基团，条件是R 2和R 3或R 2，R 3和R 4可以与相邻的氮，磷或磷一起形成杂环基 硫原子，光化辐射或电子束，从而引起交联反应，然后使组合物在不低于80℃的温度下进行热处理。

公开(公告)号：US5087286A

公开(公告)日：1992-02-11

申请号：US496201

申请日：1990-03-19

Applicant: Mitsuhiro Fukuda ,  Hirotoshi Inoue ,  Akira Kasari ,  Yuzo Miyamoto ,  Osamu Isozaki ,  Noboru Nakai

Inventor： Mitsuhiro Fukuda ,  Hirotoshi Inoue ,  Akira Kasari ,  Yuzo Miyamoto ,  Osamu Isozaki ,  Noboru Nakai

IPC: C09D133/08 ,  C09D163/00 ,  C09D167/00 ,  C09D183/04

CPC classification number: C09D167/00 ,  C09D133/08 ,  C09D163/00 ,  C09D183/04

Abstract: A heat-curable resinous coating composition comprising as a binder component(A) 5 to 90% by weight of a hydroxyl-containing resin selected from hydroxyl-containing acrylic resins and hydroxyl-containing polyester resins,(B) 5 to 50% by weight of an amino resin, and(C) 1 to 90% by weight of a crosslinkable resin selected from (C-a) polyfunctional resins having a number average molecular weight of at least 1000 and containing at least two carboxyl groups and at least two epoxy groups on an average per molecule and (C-b) polyorganosiloxanes having a number average molecular weight of at least 500 and containing at least two silanol groups on an average per molecule and if required, further containing an epoxy group.

公开(公告)号：US5026793A

公开(公告)日：1991-06-25

申请号：US402408

申请日：1989-09-05

Applicant: Noboru Nakai ,  Osamu Isozaki ,  Naozumi Iwasawa

Inventor： Noboru Nakai ,  Osamu Isozaki ,  Naozumi Iwasawa

IPC: C08G59/40 ,  C07F7/08 ,  C07F7/18 ,  C08G59/00 ,  C08G59/02 ,  C08G59/04 ,  C08G59/30 ,  C08G59/32 ,  C08G59/70 ,  C08K5/00 ,  C08K5/07 ,  C08K5/1515 ,  C08K5/5415 ,  C08L33/06 ,  C08L43/04 ,  C08L63/00 ,  C08L75/04 ,  C08L101/06 ,  C09D133/06 ,  C09D133/14 ,  C09D143/04 ,  C09D163/00

CPC classification number: C08L63/00 ,  C07F7/0836 ,  C07F7/0858 ,  C07F7/0859 ,  C07F7/182 ,  C07F7/1836 ,  C07F7/1844 ,  C07F7/1896 ,  C08G59/02 ,  C08G59/04 ,  C08G59/306 ,  C08G59/3254 ,  C08G59/70 ,  C08K5/00 ,  C08K5/0091 ,  C08K5/07 ,  C08K5/1515 ,  C08K5/5415 ,  C08L101/06 ,  C08L75/04 ,  C09D133/064 ,  C09D133/068 ,  C09D143/04 ,  C09D163/00 ,  C08L33/068 ,  C08L43/04

Abstract: A resinous composition containing (A) a high molecular weight hydroxy compound having 2 or more hydroxy groups per molecule and having a number average molecular weight of 3,000 to 200,000, (B) a high molecule weight epoxy compound having 2 or more epoxy groups per molecule and having a number average molecular weight of 120 to 200,000, (C) a silane compound having one or more silicon-containing functional groups per molecule and (D) a chelate of aluminum, titanium or zirconium with a ligand exhibiting ketoenol tautomerism, can be cured at temperatures not exceeding 100.degree. C. and forms a desirable coating when cured.

公开(公告)号：US4972027A

公开(公告)日：1990-11-20

申请号：US271268

申请日：1988-11-15

Applicant: Osamu Isozaki ,  Noboru Nakai ,  Shinji Sugiura ,  Satoru Ito ,  Seiji Takami

Inventor： Osamu Isozaki ,  Noboru Nakai ,  Shinji Sugiura ,  Satoru Ito ,  Seiji Takami

IPC: C08F2/08 ,  C08K5/00 ,  C09D143/04

CPC classification number: C08K5/0091 ,  C08F2/08 ,  C09D143/04

Abstract: Disclosed is a composition curable at a low temperature and characterized in that the composition comprises:(a) a nonaqueous dispersion of a particulate polymer insoluble in an organic liquid and prepared by polymerizing a radical-polymerizable unsaturated monomer in the organic liquid in the presence of a dispersion stabilizer resin, the stabilizer resin being at least one of a copolymer comprising as its monomer components an oxirane-containing vinyl monomer and an alkoxysilane-containing vinyl monomer and a vinyl copolymer comprising as its monomer components a polysiloxane macromonomer and an oxirane-containing vinyl monomer,(b) a chelate compound admixed with a nonaqueous dispersion.

Abstract translation: 本发明公开了一种可在低温下固化的组合物，其特征在于该组合物包括：（a）不溶于有机液体的颗粒状聚合物的非水分散体，其通过在有机液体存在下使可自由基聚合的不饱和单体聚合而制备 分散稳定剂树脂，所述稳定剂树脂是包含作为其单体组分的含环氧乙烷的乙烯基单体和含烷氧基硅烷的乙烯基单体和乙烯基共聚物中的至少一种，其包含作为其单体组分的聚硅氧烷大分子单体和含环氧乙烷的乙烯基共聚物 乙烯基单体，（b）与非水分散体混合的螯合化合物。

公开(公告)号：US4923945A

公开(公告)日：1990-05-08

申请号：US268406

申请日：1988-11-08

Applicant: Osamu Isozaki ,  Noboru Nakai ,  Satoru Ito ,  Seiji Takami

Inventor： Osamu Isozaki ,  Noboru Nakai ,  Satoru Ito ,  Seiji Takami

IPC: C08F283/12 ,  C08K5/00 ,  C08K5/1515 ,  C08K5/205 ,  C08L33/06 ,  C08L43/04 ,  C08L83/07

CPC classification number: C08K5/205 ,  C08F283/124 ,  C08K5/0091 ,  C08K5/1515 ,  C08L33/06 ,  C08L43/04

Abstract: Disclosed is a resin composition curable at a low temperature and characterized in that the composition comprises:(a) at least one of a copolymer comprising as its monomer components an oxirane-containing vinyl monomer and an alkoxysilane-containing vinyl monomer and a vinyl copolymer comprising at its monomer components a polysiloxane macromonomer and an oxirane-containing vinyl monomer,(b) a chelate compound, and(c) a compound having a number average molecular weight of up to about 1,000 and containing at least two alicyclic oxirane groups in the molecule.

Abstract translation: 公开了一种在低温下可固化的树脂组合物，其特征在于该组合物包含：（a）包含含环氧乙烷的乙烯基单体和含烷氧基硅烷的乙烯基单体作为其单体成分的共聚物和乙烯基共聚物中的至少一种， 其单体组分为聚硅氧烷大分子单体和含环氧乙烷的乙烯基单体，（b）螯合化合物，和（c）数均分子量高达约1,000并且在分子中含有至少两个脂环族环氧基团的化合物 。