摘要:
This invention relates to a new process for the production of polyisocyanates having a biuret structure by reacting aliphatic or cycloaliphatic diisocyanates with sub-stoichiometric quantities of specified aldoximes. When aldoximes are used as the biuretizing agents insoluble ureas are not formed during the reaction and nitriles which are easy to handle and distill are formed as secondary products.
摘要:
The invention relates to olefinically unsaturated polyisocyanates containing allophanate groups and having an NCO content of 6 to 20% by weight, an iodine value of 15 to 150, a content of hydrocarbon chains containing 12 to 30 carbon atoms of 100 to 700 mg/g and a content of allophanate groups of 10 to 300 mg/g, to a process for their production by reaction of a polyisocyanate component containing urethane groups with excess polyisocyanates, and to a one-component coating composition containing these olefinically unsaturated polyisocyanates as binders.
摘要:
The present invention relates to an aqueous two-component coating composition wherein the binder contains(a) a component which is dissolved and/or dispersed in water, has an average hydroxyl number of 15 to 200 mg KOH/g, and contains(a1) a polyol component having a content of 8 to 450 milliequivalents, per 100 g of component (a1) solids, of chemically incorporated ammonium groups, .dbd.N.dbd..sup.+, comprising one or more polyaddition resins which are water-dilutable, contain hydroxyl groups, and have a molecular weight (M.sub.n) of 500 to 20,000 and(a2) up to 10 wt %, based on the weight of component (a1), of one or more reactive diluents which are water-soluble, have a molecular weight (M.sub.n) below 500, and contain at least one isocyanate-reactive group, and(b) a polyisocyanate component having an NCO content of 5 to 25 wt % comprising one or more polyisocyanates which are emulsified in the aqueous solution and/or dispersion of hydroxyl group-containing component (a),wherein components (a) and (b) are present in an amount sufficient to provide an equivalent ratio of isocyanate groups of component (b) to isocyanate-reactive groups of component (a) of 0.5:1 to 5:1.The present invention also relates to a process for the production of this coating composition and to their use for the production of coatings on water-resistant substrates.
摘要:
The present invention is directed to a thickener composition for thickening aqueous systems which contains a mixture ofa) a water-soluble or water-dispersible thickener containing urethane groups,b) a non-ionic emulsifier andc) a compound corresponding to the formula ##STR1## wherein R.sub.1 and R.sub.3 may be the same or different and represent hydrocarbon radicals andR.sub.2 and R.sub.4 may be the same of different and represent hydrogen or hydrocarbon radicals,Q represents alkylene oxide units obtained by the alkoxylation of alcohols with alkylene oxides having 2 to 4 carbon atoms, andn represents a number from 0 to 120.The invention also relates to the use of this thickener composition as a thickener for aqueous systems.
摘要:
The present invention relates to a process for the preparation of a coating composition bya) treating moisture-containing auxiliaries and additives at 60.degree. to 120.degree. C. with urethane group-containing isocyanates having (cyclo)aliphatically bound isocyanate groups, an (average) NCO functionality of 0.8 to less than 2.0 and an NCO content of 5 to 17% by weight andb) after completion of the isocyanate/water reaction, combining the mixture obtained in step a) with iscyanate prepolymers having (cyclo)aliphatically bound isocyanate groups.The present invention also relates to the coating composition obtained by this process and to a composition containing urethane group-containing isocyanates having (cyclo)aliphatically bound isocyanate groups, an (average) NCO functionality of 0.8 to less than 2.0 and an NCO content of 5 to 17% by weight and moisture-containing auxiliaries or additives.
摘要:
The present invention relates to of a coating composition containing a moisture-hardening binder based on organic polyisocyanates which is prepared by forming a mixture containing at least those auxiliaries and additives which are not completely dry and an isocyanate component a) which has an average NCO functionality of 1.05 to 1.8 and is based on the reaction product ofa1) a polyisocyanate mixture of the diphenylmethane series witha2) a monohydric C.sub.1-26 alkanol which may contain ether bridges,and after the isocyanate/water reaction is substantially complete, further mixing the mixture with an isocyanate component b) which has an isocyanate content of 2.5 to 25% by weight and any remaining auxiliaries and additives, the quantities of components a) and b) corresponding to a weight ratio of a) to b) of 1:1 to 1:30.The present invention also relates to a process for the preparation of these coating compositions.
摘要:
This invention relates to mixtures of polyols which are liquid at room temperature with functional aldoximes as blowing agents, wherein the aldoxime groups react with polyisocyanates to liberate carbon dioxide and are simultaneously incorporated by means of the functional group thereof into the polyurethane formed. The present invention also relates to a process for the production of polyurethane foams using these incorporated reactive blowing agents as the primary blowing agent in combination with blowing agents known in polyurethane chemistry. The process according to the invention described herein is suitable for the production of various polyurethane foams or cellular polyurethane elastomers, particularly including the production of semi-rigid and rigid polyurethane integral skin foams which are obtained by foaming the reaction mixture in closed molds.
摘要:
The instant invention is directed to a process for the production of molded foams having a compact surface and cellular core and an integral density distribution over the cross-section of the body, comprising reacting(A) polyisocyanates, and(B) relatively high molecular and/or low molecular compounds having an average of at least two isocyanate-reactive hydrogen atoms in the presence of:(C) catalysts for the isocyanate polyaddition reaction and(D) blowing agents and optionally other known additives, in a closed mold under the conditions of foaming inside molds, the improvement wherein said polyisocyanates are aliphatic and/or alicyclic polyisocyanates and said catalysts are catalyst combinations of:(i) an alkali metal and/or alkaline earth metal hydroxide and(ii) a metal compound, the metal compound being the acetylacetonate of iron, C.sub.1 -C.sub.8 alcoholates, phenolates, enolates and/or acetylacetonates of metals of the 4th Main Group or sulfur compounds of metals of the 4th Main Group of the Periodic System of Elements in which the sulfur is directly attached to the metal atom.
摘要:
This invention relates to new polyurethane resins produced by a process in which aromatic diamines containing thio-groups are used as chain-lengthening agents.