Olefinically unsaturated polyisocyanates
    22.
    发明授权
    Olefinically unsaturated polyisocyanates 失效
    烯属不饱和多异氰酸酯

    公开(公告)号:US6111053A

    公开(公告)日:2000-08-29

    申请号:US436939

    申请日:1995-05-08

    摘要: The invention relates to olefinically unsaturated polyisocyanates containing allophanate groups and having an NCO content of 6 to 20% by weight, an iodine value of 15 to 150, a content of hydrocarbon chains containing 12 to 30 carbon atoms of 100 to 700 mg/g and a content of allophanate groups of 10 to 300 mg/g, to a process for their production by reaction of a polyisocyanate component containing urethane groups with excess polyisocyanates, and to a one-component coating composition containing these olefinically unsaturated polyisocyanates as binders.

    摘要翻译: 本发明涉及含有脲基甲酸酯基,NCO含量为6〜20重量%,碘值为15〜150,含有12〜30个碳原子的烃链含量为100〜700mg / g的烯属不饱和多异氰酸酯, 脲基甲酸酯基的含量为10〜300mg / g,通过使含有氨基甲酸酯基的多异氰酸酯成分与过量的多异氰酸酯反应生成的方法,以及含有这些烯属不饱和多异氰酸酯作为粘合剂的单组分涂料组合物。

    Coating compositions, a process for their production and their use for
coating water-resistant substrates
    23.
    发明授权
    Coating compositions, a process for their production and their use for coating water-resistant substrates 失效
    涂料组合物,其制备方法及其用于涂覆耐水基材的用途

    公开(公告)号:US5459197A

    公开(公告)日:1995-10-17

    申请号:US251876

    申请日:1994-06-01

    摘要: The present invention relates to an aqueous two-component coating composition wherein the binder contains(a) a component which is dissolved and/or dispersed in water, has an average hydroxyl number of 15 to 200 mg KOH/g, and contains(a1) a polyol component having a content of 8 to 450 milliequivalents, per 100 g of component (a1) solids, of chemically incorporated ammonium groups, .dbd.N.dbd..sup.+, comprising one or more polyaddition resins which are water-dilutable, contain hydroxyl groups, and have a molecular weight (M.sub.n) of 500 to 20,000 and(a2) up to 10 wt %, based on the weight of component (a1), of one or more reactive diluents which are water-soluble, have a molecular weight (M.sub.n) below 500, and contain at least one isocyanate-reactive group, and(b) a polyisocyanate component having an NCO content of 5 to 25 wt % comprising one or more polyisocyanates which are emulsified in the aqueous solution and/or dispersion of hydroxyl group-containing component (a),wherein components (a) and (b) are present in an amount sufficient to provide an equivalent ratio of isocyanate groups of component (b) to isocyanate-reactive groups of component (a) of 0.5:1 to 5:1.The present invention also relates to a process for the production of this coating composition and to their use for the production of coatings on water-resistant substrates.

    摘要翻译: 本发明涉及水性双组分涂料组合物,其中粘合剂含有(a)溶解和/或分散在水中的组分,其平均羟值为15-200mg KOH / g,并含有(a1) 含有8至450毫当量的多元醇组分,每100g组分(a1)固体,化学掺入的铵基,= N = +,包含一种或多种可水稀释的加聚树脂,含有羟基,和 基于组分(a1)的重量,分子量(Mn)为500至20,000的(a2)至多10重量%,一种或多种水溶性的具有分子量(Mn)的反应性稀释剂, 低于500,并且含有至少一个异氰酸酯反应性基团,和(b)NCO含量为5至25重量%的多异氰酸酯组分,其包含在水溶液中乳化的一种或多种多异氰酸酯和/或羟基 - (a),其中组分(a)和(b) 以足以提供组分(b)的异氰酸酯基与组分(a)的异氰酸酯反应性基团的当量比为0.5:1至5:1的量存在。 本发明还涉及一种生产该涂料组合物的方法及其在耐水基材上生产涂料的用途。

    Use of isocyanates containing urethane groups as drying agents and a
process for the production of a coating composition
    25.
    发明授权
    Use of isocyanates containing urethane groups as drying agents and a process for the production of a coating composition 失效
    含有脲基团的异氰酸酯作为干燥剂的使用和涂料组合物的制备方法

    公开(公告)号:US5179187A

    公开(公告)日:1993-01-12

    申请号:US655019

    申请日:1991-02-14

    摘要: The present invention relates to a process for the preparation of a coating composition bya) treating moisture-containing auxiliaries and additives at 60.degree. to 120.degree. C. with urethane group-containing isocyanates having (cyclo)aliphatically bound isocyanate groups, an (average) NCO functionality of 0.8 to less than 2.0 and an NCO content of 5 to 17% by weight andb) after completion of the isocyanate/water reaction, combining the mixture obtained in step a) with iscyanate prepolymers having (cyclo)aliphatically bound isocyanate groups.The present invention also relates to the coating composition obtained by this process and to a composition containing urethane group-containing isocyanates having (cyclo)aliphatically bound isocyanate groups, an (average) NCO functionality of 0.8 to less than 2.0 and an NCO content of 5 to 17% by weight and moisture-containing auxiliaries or additives.

    摘要翻译: 本发明涉及一种通过以下方法制备涂料组合物的方法:a)在含有(环)脂族结合的异氰酸酯基团的氨基甲酸酯基的异氰酸酯基团上,在60〜120℃下处理含水助剂和添加剂, )NCO官能度为0.8至小于2.0,NCO含量为5至17重量%,b)异氰酸酯/水反应完成后,将步骤a)中获得的混合物与具有(环)脂族结合异氰酸酯的异氰酸酯预聚物 团体 本发明还涉及通过该方法获得的涂料组合物和含有具有(环)脂族结合的异氰酸酯基团,(平均)NCO官能度为0.8至小于2.0,NCO含量为5的含氨基甲酸酯基异氰酸酯的组合物 至17重量%,含水分的助剂或添加剂。

    Moisture-hardening coating composition and method for its production
    26.
    发明授权
    Moisture-hardening coating composition and method for its production 失效
    水分硬化涂料组合物及其生产方法

    公开(公告)号:US5081203A

    公开(公告)日:1992-01-14

    申请号:US543641

    申请日:1990-06-26

    摘要: The present invention relates to of a coating composition containing a moisture-hardening binder based on organic polyisocyanates which is prepared by forming a mixture containing at least those auxiliaries and additives which are not completely dry and an isocyanate component a) which has an average NCO functionality of 1.05 to 1.8 and is based on the reaction product ofa1) a polyisocyanate mixture of the diphenylmethane series witha2) a monohydric C.sub.1-26 alkanol which may contain ether bridges,and after the isocyanate/water reaction is substantially complete, further mixing the mixture with an isocyanate component b) which has an isocyanate content of 2.5 to 25% by weight and any remaining auxiliaries and additives, the quantities of components a) and b) corresponding to a weight ratio of a) to b) of 1:1 to 1:30.The present invention also relates to a process for the preparation of these coating compositions.

    摘要翻译: 本发明涉及包含基于有机多异氰酸酯的湿固化粘合剂的涂料组合物,其通过形成至少含有那些不完全干燥的那些助剂和添加剂的混合物和具有平均NCO官能度的异氰酸酯组分a) 为1.05〜1.8,并且基于a1)二苯基甲烷系列的多异氰酸酯混合物与a2)可能含有醚桥的一元C1-26链烷醇的反应产物,并且在异氰酸酯/水反应基本上完成后,进一步混合 与异氰酸酯含量为2.5至25重量%的异氰酸酯组分b)和任何其余助剂和添加剂的混合物,a)和b)的组分的量对应于a)至b)的重量比为1:1 至1:30。 本发明还涉及制备这些涂料组合物的方法。

    Polyol mixtures containing reactive blowing agents and use thereof for
the production of foamed polyurethanes
    27.
    发明授权
    Polyol mixtures containing reactive blowing agents and use thereof for the production of foamed polyurethanes 失效
    含有反应性发泡剂的多元醇混合物及其用于生产发泡聚氨酯的用途

    公开(公告)号:US4352896A

    公开(公告)日:1982-10-05

    申请号:US309636

    申请日:1981-10-08

    摘要: This invention relates to mixtures of polyols which are liquid at room temperature with functional aldoximes as blowing agents, wherein the aldoxime groups react with polyisocyanates to liberate carbon dioxide and are simultaneously incorporated by means of the functional group thereof into the polyurethane formed. The present invention also relates to a process for the production of polyurethane foams using these incorporated reactive blowing agents as the primary blowing agent in combination with blowing agents known in polyurethane chemistry. The process according to the invention described herein is suitable for the production of various polyurethane foams or cellular polyurethane elastomers, particularly including the production of semi-rigid and rigid polyurethane integral skin foams which are obtained by foaming the reaction mixture in closed molds.

    摘要翻译: 本发明涉及在室温下为功能性醛肟作为发泡剂的多元醇混合物,其中醛肟基与多异氰酸酯反应以释放二氧化碳,并通过其功能基团同时引入所形成的聚氨酯中。 本发明还涉及使用这些掺入的反应性发泡剂作为主要发泡剂与聚氨酯化学中已知的发泡剂组合来生产聚氨酯泡沫体的方法。 根据本文所述的本发明的方法适用于生产各种聚氨酯泡沫或多孔聚氨酯弹性体,特别是包括通过在闭合模具中使反应混合物发泡获得的半刚性和硬质聚氨酯整体表皮泡沫的生产。

    Process for the production of molded foams
    28.
    发明授权
    Process for the production of molded foams 失效
    生产模制泡沫的方法

    公开(公告)号:US4263408A

    公开(公告)日:1981-04-21

    申请号:US57935

    申请日:1979-07-16

    摘要: The instant invention is directed to a process for the production of molded foams having a compact surface and cellular core and an integral density distribution over the cross-section of the body, comprising reacting(A) polyisocyanates, and(B) relatively high molecular and/or low molecular compounds having an average of at least two isocyanate-reactive hydrogen atoms in the presence of:(C) catalysts for the isocyanate polyaddition reaction and(D) blowing agents and optionally other known additives, in a closed mold under the conditions of foaming inside molds, the improvement wherein said polyisocyanates are aliphatic and/or alicyclic polyisocyanates and said catalysts are catalyst combinations of:(i) an alkali metal and/or alkaline earth metal hydroxide and(ii) a metal compound, the metal compound being the acetylacetonate of iron, C.sub.1 -C.sub.8 alcoholates, phenolates, enolates and/or acetylacetonates of metals of the 4th Main Group or sulfur compounds of metals of the 4th Main Group of the Periodic System of Elements in which the sulfur is directly attached to the metal atom.

    摘要翻译: 本发明涉及一种生产具有紧凑的表面和多孔芯的模制泡沫的方法以及在主体的横截面上的整体密度分布,包括使(A)多异氰酸酯与(B)相对高分子和 /或在以下情况下平均具有至少两个异氰酸酯反应性氢原子的低分子化合物:(C)用于异氰酸酯加聚反应的催化剂和(D)发泡剂和任选的其它已知添加剂,在封闭模具中在条件 在模具中发泡的改进,其中所述多异氰酸酯是脂族和/或脂环族多异氰酸酯,所述催化剂是以下催化剂组合:(i)碱金属和/或碱土金属氢氧化物和(ii)金属化合物,金属化合物为 第四主要金属的金属的乙酰丙酮化物,C1-C8醇盐,酚盐,烯醇化物和/或乙酰丙酮化物或第四主族金属的硫化合物 的元素周期系统,其中硫直接连接到金属原子上。