公开(公告)号：US20110313142A1

公开(公告)日：2011-12-22

申请号：US13063551

申请日：2009-09-10

申请人： Avelino Corma Canos ,  Hermenegildo Garcia Gomez ,  Adbessamad Grirrane

发明人： Avelino Corma Canos ,  Hermenegildo Garcia Gomez ,  Adbessamad Grirrane

IPC分类号： C07C245/02

CPC分类号： B01J23/52 ,  B01J21/06 ,  B01J21/063 ,  B01J31/064 ,  B01J35/0013 ,  B01J35/006 ,  B01J37/035 ,  B01J37/16 ,  B01J2231/70 ,  B01J2531/18 ,  C07C245/08 ,  C07C253/30 ,  C07D213/74 ,  C07C255/67

摘要： The present invention relates to a preparation process of azo compounds which comprises the reaction between at least: one amine or polyamine, molecular oxygen, a catalyst formed by at least one support selected from among at least one metal oxide of one of the elements of groups 3, 4, 5, 6, 8, 9, 11 and 13, silica, anionic laminar compound of hydrotalcite type or its derivatives, active carbon or an organic polymer. In addition, said catalyst may contain gold nanoparticles.

摘要翻译： 本发明涉及一种偶氮化合物的制备方法，其包括在至少一种胺或多胺，分子氧，由至少一种载体形成的催化剂之间的反应，所述载体选自基团元素之一的至少一种金属氧化物 3，4，5，6，8，9，11和13，二氧化硅，水滑石型阴离子层状化合物或其衍生物，活性炭或有机聚合物。 此外，所述催化剂可以含有金纳米颗粒。

公开(公告)号：US20100312018A1

公开(公告)日：2010-12-09

申请号：US12753279

申请日：2010-04-02

申请人： Avelino Corma Canos ,  Sara Iborra Chornet ,  Alexandra Velty

发明人： Avelino Corma Canos ,  Sara Iborra Chornet ,  Alexandra Velty

IPC分类号： C07C45/74 ,  C07C29/159

CPC分类号： C07C29/14 ,  C07C45/74 ,  C07C2601/10 ,  C07C33/12 ,  C07C47/225

摘要： The present invention relates to processes for producing 2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-butenal and 2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-buten-1-ol using heterogeneous bifunctional catalysts with a good yield. There is provided a process for producing 2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-butenal by the cross-aldol condensation between campholenic aldehyde and butanal using bifunctional heterogeneous catalysts in the presence of controlled amounts of an aliphatic alcohol; and a process for producing 2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-buten-1-ol useful as perfume, starting from 2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-butenal through a MPV reduction using an acid-base bifunctional heterogeneous catalyst. Both process can be coupled in a cascade process which involves the cross-aldol condensation between campholenic aldehyde and butanal followed by the Meerwein-Ponndorf-Verley (MPV) reduction in the presence of a secondary alcohol using the same heterogeneous bifunctional catalyst for obtaining (2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-buten-1-ol).

摘要翻译： 本发明涉及2-乙基-4-（2,2,3-三甲基-3-环戊烯-1-基）-2-丁烯醛和2-乙基-4-（2,2,3-三甲基 -3-环戊烯-1-基）-2-丁烯-1-醇，使用异构双官能催化剂，产率很高。 提供了一种通过使用双功能非均相催化剂在camp醛和丁醛之间的交换醛醇缩合产生2-乙基-4-（2,2,3-三甲基-3-环戊烯-1-基）-2-丁烯醛的方法 存在受控量的脂族醇; 和用作香料的2-乙基-4-（2,2,3-三甲基-3-环戊烯-1-基）-2-丁烯-1-醇的制备方法，由2-乙基-4-（2 ，2,3-三甲基-3-环戊烯-1-基）-2-丁烯醛，通过使用酸碱双功能多相催化剂的MPV还原。 这两种方法可以在级联方法中偶合，其涉及在醛醇和丁醛之间的交叉醛醇缩合，随后在仲醇存在下使用相同的异构双功能催化剂还原Meerwein-Ponndorf-Verley（MPV）以获得（2 - 乙基-4-（2,2,3-三甲基-3-环戊烯-1-基）-2-丁烯-1-醇）。

公开(公告)号：US20090234145A1

公开(公告)日：2009-09-17

申请号：US11911836

申请日：2006-04-06

申请人： Avelino Corma Canos ,  Marcelo Eduardo Domine

发明人： Avelino Corma Canos ,  Marcelo Eduardo Domine

IPC分类号： C07D301/04

CPC分类号： B01J29/0325 ,  B01J21/063 ,  B01J23/66 ,  B01J29/89 ,  B01J31/0274 ,  B01J35/006 ,  B01J2229/18 ,  B01J2229/32 ,  C07D301/10 ,  C07D303/04

摘要： The invention relates to a method for the epoxidation of an olefinic compound, which is characterised in that it comprises an oxidation reaction of at least one olefinic compound containing one or more double bonds C═C with oxygen in the presence of one or more reaction initiating agents, at least one catalyst containing at least one metal that is selected from a noble metal, a transition metal and mixtures of same, and at least one hydrocarbon that is selected from one or more branched alkanes, one or more alkyl cyclic or cyclic hydrocarbons, one or more alkyl aromatic or aromatic compounds and mixtures of same.

摘要翻译： 本发明涉及一种烯烃化合物的环氧化方法，其特征在于它包含在一种或多种反应引发剂存在下至少一种含有一个或多个双键CC与氧的烯属化合物的氧化反应， 至少一种含有至少一种选自贵金属，过渡金属及其混合物的金属的催化剂和至少一种选自一种或多种支链烷烃，一种或多种烷基环状或环状烃的烃，一种 或更多烷基芳族或芳族化合物及其混合物。

公开(公告)号：US20090220661A1

公开(公告)日：2009-09-03

申请号：US12280590

申请日：2007-02-22

申请人： Manuel Moliner Marin ,  Maria Jose Diaz Cabanas ,  Angel Cantin Sanz ,  Avelino Corma Canos

发明人： Manuel Moliner Marin ,  Maria Jose Diaz Cabanas ,  Angel Cantin Sanz ,  Avelino Corma Canos

IPC分类号： A23L1/48 ,  B01J29/04

CPC分类号： B01J29/70 ,  B01J29/04 ,  B01J2229/20 ,  C01B37/005 ,  C01B39/06 ,  C01B39/12 ,  C10G11/05 ,  C10G47/16 ,  C10G47/18 ,  C10G47/20 ,  C10G50/00

摘要： The present invention relates to a microporous crystalline material characterized in that it has the following chemical composition in the calcined from: xX2O3:nYO2:mGeO2 in which (n+m) is at least 5, X is one or more trivalent elements, Y corresponds to one or more tetravalent elements other than Ge, “x” may have any value, including zero, and the ratio Y/Ge is greater than 0.1, and it has a characteristic X-ray diffraction pattern. Its also relates to a method for preparing it and to its use in the conversion of organic-compounds supplies.

摘要翻译： 微孔结晶材料本发明涉及一种微孔结晶材料，其特征在于它具有以下煅烧成的化学组成：<？在线配方说明=“在线配方”末端=“铅”→xX 2 O 3 :nYO 2 :mGeO 2 其中（n + m）至少为5，X为一个或多个三价元素，Y对应于一个或多个四价元素 除了Ge之外，“x”可以具有包括0的任何值，并且比率Y / Ge大于0.1，并且具有特征X射线衍射图案。 它还涉及其制备方法及其在有机化合物用品转化中的应用。

公开(公告)号：US20090082588A1

公开(公告)日：2009-03-26

申请号：US12283450

申请日：2008-09-12

申请人： Ana Padilla Polo ,  Valentin Ruiz Santa Quiteria ,  Avelino Corma Canos ,  Hermenegildo Garcia Gomez ,  Raquel Juarez Marin

发明人： Ana Padilla Polo ,  Valentin Ruiz Santa Quiteria ,  Avelino Corma Canos ,  Hermenegildo Garcia Gomez ,  Raquel Juarez Marin

IPC分类号： C07C269/04 ,  C07C249/00

CPC分类号： C07C269/04 ,  C07C263/04 ,  C07C2601/14 ,  C07C265/10 ,  C07C265/14 ,  C07C271/24 ,  C07C271/28

摘要： The invention relates to a process for producing fluorinated carbamates comprising the reaction between an amine or polyamine and a fluorinated carbonate, in the presence of a catalyst which does not contain metals and comprises at least one tertiary amine group. The process can also comprise an additional step in which the carbamates are transformed into the corresponding isocyanates.

摘要翻译： 本发明涉及一种生产含氟氨基甲酸酯的方法，其包括胺或多胺与氟化碳酸酯之间在不含金属的催化剂存在下并包含至少一个叔胺基团的反应。 该方法还可以包括另外的步骤，其中将氨基甲酸酯转化成相应的异氰酸酯。

公开(公告)号：US20080267860A1

公开(公告)日：2008-10-30

申请号：US12023917

申请日：2008-01-31

申请人： Avelino Corma Canos ,  Fernando Rey Garcia ,  Maria Jose Diaz-Cabanas ,  Jose Luis Jorda Moret ,  Angel Cantin Sanz ,  Manuel Moliner Marin

发明人： Avelino Corma Canos ,  Fernando Rey Garcia ,  Maria Jose Diaz-Cabanas ,  Jose Luis Jorda Moret ,  Angel Cantin Sanz ,  Manuel Moliner Marin

IPC分类号： C01B39/02 ,  C01B39/00

CPC分类号： C01B37/02 ,  C01B37/005 ,  C01B39/06

摘要： A crystalline microporous material of zeolitic nature (ITQ-41) having in its calcined form a chemical composition represented by the empirical formula: x(M1/nXO2):yYO2:SiO2 wherein, Y is a chemical element other than Silicon with oxidation status +4; X is a chemical element with oxidation status +3; M is H+ or an inorganic cation with charge n+; n can take any value between 1 to 3; x can take any value comprised between from about 0 to about 0.2; preferably lower than 0.0666, and more preferably lower than 0.05; y can take any value comprised between 0 and 0.2, and wherein, said material is characterized by the presence of four reflections in its powder X-Ray diffraction pattern at 6.9°; 7.4°; 8.3°, and 9.6°2θ angles.

摘要翻译： 沸石性质的结晶微孔材料（ITQ-41），其煅烧形式为经验式表示的化学组成：<？in-line-formula description =“In-line formula”end =“lead”？> x（ M 1 / n XO 2 2）：y Y 2 2：SiO 2 <β在线公式描述= “In-line Formulas”end =“tail”？>其中，Y是氧化状态+4以外的硅以外的化学元素; X是氧化态为+3的化学元素; M是H + H +或具有电荷n +的无机阳离子。 n可以取1到3之间的任何值; x可以取约0至约0.2之间的任何值; 优选低于0.0666，更优选低于0.05; y可以取0至0.2之间的任何值，并且其中所述材料的特征在于在其粉末X射线衍射图中在6.9°存在四次反射; 7.4°; 8.3°和9.6°2θ角。

公开(公告)号：US20080203359A1

公开(公告)日：2008-08-28

申请号：US11665802

申请日：2005-10-21

申请人： Avelino Corma Canos ,  Hermenegildo Garcia Gomez ,  Mercedes Alvaro Rodriguez

发明人： Avelino Corma Canos ,  Hermenegildo Garcia Gomez ,  Mercedes Alvaro Rodriguez

IPC分类号： C09K11/06

CPC分类号： H01L51/0094 ,  C09B69/008 ,  C09B69/101 ,  C09K11/02 ,  C09K11/06 ,  C09K11/08 ,  C09K2211/1007 ,  C09K2211/1011 ,  H01L51/0052 ,  H01L51/5012 ,  H05B33/14

摘要： The invention relates to an electroluminescent organic-inorganic hybrid material which is characterised in that it comprises: at least one microporous or mesoporous solid having a structure that is selected from among the structures of zeolites, porous oxides, molecular sieves, silicoaluminophosphates and aluminosilicates; and at least one organic compound which confers electroluminescent properties thereto. The invention is also characterised in that the organic compound is a polycyclic aromatic hydrocarbon, at least part of which is joined to the structure of the microporous or mesoporous solid using covalent bonds. The invention also relates to the method of obtaining said material and to the use thereof.

摘要翻译： 本发明涉及一种电致发光有机 - 无机杂化材料，其特征在于其包括：至少一种具有选自沸石，多孔氧化物，分子筛，硅铝磷酸盐和铝硅酸盐的结构中的结构的微孔或介孔固体; 和赋予其电致发光性质的至少一种有机化合物。 本发明的特征还在于有机化合物是多环芳族烃，其至少一部分使用共价键连接到微孔或中孔固体的结构。 本发明还涉及获得所述材料及其用途的方法。

公开(公告)号：US20080021253A1

公开(公告)日：2008-01-24

申请号：US11597809

申请日：2005-05-25

申请人： Avelino Corma Canos ,  Jose Manuel Serra Alfaro ,  Vicente Fornes Segui ,  Rafael Castaneda Sanchez

发明人： Avelino Corma Canos ,  Jose Manuel Serra Alfaro ,  Vicente Fornes Segui ,  Rafael Castaneda Sanchez

IPC分类号： C07C5/27

CPC分类号： B01J29/80 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/78 ,  B01J2229/123 ,  B01J2229/126 ,  B01J2229/186 ,  B01J2229/32 ,  C07C6/123 ,  C07C6/126 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/12 ,  C07C2529/08 ,  C07C2529/18 ,  C07C2529/60 ,  C07C2529/70 ,  C07C2529/74 ,  C07C2529/76 ,  C07C2529/78 ,  C07C2529/80 ,  Y02P20/52 ,  C07C15/08

摘要： The invention relates to a catalytic method for the transalkylation/dealkylation of organic compounds, consisting in bringing a supply comprising organic compounds into contact with a catalyst containing a first zeolitic component that is selected from among: a) one or more zeolites having crystalline structure ITQ-13; b) one or more zeolites having crystalline structure ITQ-13, which are modified either by means of selectivation or with the incorporation of one or more metals, or both; and c) a mixture of a) and b). The invention also relates to a catalyst comprising one or more modified zeolites having crystalline structure ITQ-13.

摘要翻译： 本发明涉及一种用于有机化合物的烷基转移/脱烷基化的催化方法，其包括使包含有机化合物的供体与含有第一沸石组分的催化剂接触，所述催化剂选自以下之一：a）一种或多种具有结晶结构的沸石 -13; b）具有结晶结构ITQ-13的一种或多种沸石，其通过选择性或通过掺入一种或多种金属或两者来改性; 和c）a）和b）的混合物。 本发明还涉及包含一种或多种具有结晶结构ITQ-13的改性沸石的催化剂。

公开(公告)号：US20060286029A1

公开(公告)日：2006-12-21

申请号：US11392473

申请日：2006-03-29

申请人： Avelino Corma Canos ,  Maria Sabater Picot ,  Susana Valencia Valencia

发明人： Avelino Corma Canos ,  Maria Sabater Picot ,  Susana Valencia Valencia

IPC分类号： C01B39/48

CPC分类号： C01B37/005 ,  B01J29/035 ,  B01J29/70 ,  B01J29/87 ,  B01J29/89 ,  C01B37/02 ,  C01B39/065 ,  C01B39/48

摘要： The invention relates to a microporous crystalline zeolite material, zeolite ITQ-28, the production method thereof and the use of same. More specifically, the invention relates to a microporous crystalline zeolite material, ITQ-28, which, in the calcined state and in the absence of defects in the crystalline lattice thereof, manifested by the presence of silanols, is characterised by having empirical formula x (M1/nXO2): y YO2: SiO2, wherein: M is selected from H+, at least one inorganic cation with charge +n, preferably alkalines or alkaline earths, and a mixture of both; X is at least one chemical element in oxidation state +3, preferably Al, Ga, B, Fe, Cr or mixtures thereof; Y is at least a chemical element in oxidation state +4, which is different from Si, preferably Ge, Ti, Sn, V or mixtures of same; x has a value of between 0 and 0.2 inclusive; and y has a value of between 0 and 0.1 inclusive. The invention is further characterised in that the material as it is synthesised has an x-ray diffraction pattern with at least values of angle 2θ (degrees) and the relative intensities given in table 1. The invention also relates to the method of preparing said material and to the use thereof in the conversion of organic compounds.

摘要翻译： 本发明涉及微孔结晶沸石材料，沸石ITQ-28，其制备方法及其用途。 更具体地说，本发明涉及一种微孔结晶沸石材料ITQ-28，其在煅烧状态中并且在其不存在其晶格缺陷的情况下，通过硅烷醇的存在而表现出来，其特征在于具有经验式x（ M 1 / n 2 XO 2）：y Y 2 O 2 SiO 2其中：M选自H 至少一种带电荷的无机阳离子，优选碱金属或碱土金属，以及二者的混合物; X是氧化态+3，优选Al，Ga，B，Fe，Cr或其混合物中的至少一种化学元素; Y至少是氧化态+4的化学元素，其不同于Si，优选Ge，Ti，Sn，V或其混合物; x的值在0和0.2之间; y的值在0和0.1之间。 本发明的特征还在于其合成的材料具有x射线衍射图，其至少具有角度2θ（度）和表1中给出的相对强度。本发明还涉及制备所述材料的方法 以及其在有机化合物的转化中的用途。

公开(公告)号：US20060154814A1

公开(公告)日：2006-07-13

申请号：US10528813

申请日：2003-09-26

申请人： Laura Zanibelli ,  Giuseppe Bellussi ,  Avelino Corma Canos ,  Marcelo Domine ,  Maria Gagliardi

发明人： Laura Zanibelli ,  Giuseppe Bellussi ,  Avelino Corma Canos ,  Marcelo Domine ,  Maria Gagliardi

IPC分类号： B01J21/08 ,  B01J21/12 ,  B01J21/14

CPC分类号： B01J21/063 ,  B01J21/06 ,  B01J35/10 ,  B01J35/1023 ,  B01J35/1047 ,  B01J35/1057 ,  B01J35/1061 ,  C10G27/12 ,  C10G67/12

摘要： The present invention concerns a process for oxidative desulphurization of hydrotreated hydrocarbon mixtures which boil within the range of 180° to 360° C., containing less than 350 ppm of sulphur as thiophenic compounds, said process comprising the steps of a) putting these mixtures in contact, in the presence of an organic peroxide, with a catalytic composition comprising a completely amorphous micro and/or mesoporous mixed oxide containing an oxide matrix selected from silica, alumina, ceria, magnesia and mixtures of thereof, wherein one or more oxidative metal oxides selected from transition metal oxides and group IVA metal oxides are uniformly dispersed, and b) separating the obtained corresponding sulphur oxygenated products from the hydrocarbon mixture.

摘要翻译： 本发明涉及一种加氢处理的烃混合物的氧化脱硫方法，其在180℃至360℃的范围内沸腾，含有少于350ppm的硫作为噻吩化合物，所述方法包括以下步骤：a）将这些混合物置于 在有机过氧化物的存在下与包含含有选自二氧化硅，氧化铝，二氧化铈，氧化镁及其混合物的氧化物基质的完全无定形微孔和/或介孔混合氧化物的催化组合物接触，其中一种或多种氧化性金属氧化物 选自过渡金属氧化物和IVA族金属氧化物均匀分散，b）从烃混合物中分离得到的相应硫氧化产物。