摘要:
The invention concerns a process for the elimination of mercury from hydrocarbons by passage of the feedstock with hydrogen over a catalyst then bringing the product obtained into contact with a mercury retention bed, the catalyst comprising at least one element selected from the group constituted by iron, nickel, cobalt, molybdenum, tungsten, palladium, wherein at least 5% is in the sulphide state. Any arsenic present in the feedstock is also eliminated.In accordance with the invention, the catalyst is simultaneously presulphurated and reduced.The invention results in a considerable reduction in operation period and high retention efficiency at temperatures between 120.degree. C. and 250.degree. C. and in the presence of 0-1000 mg of sulphur/kg of feed.
摘要:
For removing mercury and any arsenic in hydrocarbon charges containing mercury and sulfur, the charge is contacted with an arsenic collecting material having catalytic properties ("catalyst") in hydrogen, the material containing at least one metal selected from the group consisting of nickel, cobalt, iron, palladium, and platinum; at least one metal selected from the group consisting of chromium, molybdenum, tungsten, and uranium; and an active phase carrier. Downstream of the catalyst or mixed therewith is a mercury collecting material containing a sulfide of at least one metal selected from the group consisting of copper, iron, and silver or sulfur, and an active phase carrier.
摘要:
The invention concerns a multifunctional catalyst containing cerium, uranium and at least one metal, for converting pollutants emitted by internal combustion engines, and their preparation.A catalyst comprises a porous layer containingfrom about 20% to about 99% of at least one refractory oxidefrom about 0.8% to about 70% of at least one cerium oxidefrom about 0.1% to about 50% of at least one uranium oxidefrom about 0.1% to about 20% of a metal selected from the group made up of Pt, Rh, Pd, Ru, Ir and Au, and mixtures thereof.Applications are in the catalytic converter industry.
摘要:
Manufacture of catalysts containing at least three essential metals consisting of copper, zinc and aluminum.The process for manufacturing the catalyst comprises the formation of homogeneous amorphous precipitate of the above-mentioned metals, followed with a washing in two steps, first with water, then with an acid solution.These catalysts are used in balanced reactions involving alcohols and synthesis gas, particularly in methanol synthesis.
摘要:
A gas containing carbon oxysulfide or carbon disulfide is passed in admixture with oxygen through a catalyst formed of a carrier, vanadium oxide and silver, the proportion of iron oxide, if any, being lower than 1% by weight. The amount of vanadium oxide may be 0.5 to 10% by weight and that of silver 0.05 to 4% by weight.
摘要:
Catalyst for the decomposition of nitrogen oxides, particularly for use in catalytic exhaust boxes in view of decomposing the nitrogen oxides contained in the exhaust gases from internal combustion engines, comprising, deposited on a carrier, from 3 to 20% of an active phase of the formula Ni.sub.x (Fe.sub.y Cr.sub.z)O.sub.t, in which x has a value from 0.5 to 1.5, y + z a value from 1.5 to 3, the ratio ##EQU1## A VALUE FROM 0.01 TO 0.9 AND T A VALUE LOWER THAN 10.
摘要:
The invention relates to a personal weapon, intended for semi-automatic and automatic firing of caseless ammunitions, provided with an electronic fire controller with biometric identification of the person firing. The weapon has a sealing device for the chamber based on using segments or corollas with variation of bore size mechanically or with gas pressure. A delay in opening the barrel/breech unit may be introduced using spigots driven by propellant gases. A device for sequencing compartments in tandem of the magazine uses the volume reduction of ammunition to double the power of the firearm. A removable locker permits the integral locking of breech unit, trigger, magazine and dismantling bolt for an absolute weapon safety. A telescopic extension device for the barrel increases the power of the ammunition and a gas bleed in the chamber permits the stabilisation of the firing.
摘要:
A process is described for synthetizing hydrocarbons from a mixture comprising carbon monoxide and hydrogen in the presence of a catalyst comprising at least one group VIII metal supported on a silica-alumina prepared by co-precipitating and calcining at a temperature in the range from about 500° C. to about 1200° C. for at least 6 hours such that said silica-alumina has a specific surface area of less than 260 m2/g. Said catalyst is used in a fixed bed or in suspension in a liquid phase of a three-phase reactor.
摘要:
The present invention relates to a catalyst comprising an extruded essentially alumina-based support, constituted by a plurality of juxtaposed agglomerates and partially in the form of packs of flakes and partially in the form of needles, and optionally comprising at least one catalytic metal or a compound of a catalytic metal from group VIB, and/or optionally at least one catalytic metal or compound of a catalytic metal from group VIII. The invention also relates to its use in a fixed bed reactor, for hydrorefining and hydroconverting hydrocarbon feeds.
摘要:
A process for the elimination of arsenic from hydrocarbons with a retention mass wherein the retention mass is pretreated before being brought into contact with the feedstock to be purified. The retention mass contains at least one element selected from the group formed by iron, nickel, cobalt, molybdenum, tungsten, palladium and chromium. At least 5% by weight of these element(s) are in the sulfide form. The pretreatment involves impregnation with a sulfur compound carried out simultaneously with reduction. The arsenic elimination process is carried out between 120.degree. C. and 250.degree. C. in the presence of 0-1000 mg of sulfur/kg of feedstock