公开(公告)号：US5401392A

公开(公告)日：1995-03-28

申请号：US148543

申请日：1993-11-08

申请人： Philippe Courty ,  Pierre Dufresne ,  Jean P. Boitiaux ,  Germain Martino

发明人： Philippe Courty ,  Pierre Dufresne ,  Jean P. Boitiaux ,  Germain Martino

IPC分类号： C10G25/00 ,  C10G45/04 ,  C10G67/06 ,  C10G45/08

CPC分类号： C10G25/003 ,  C10G45/04 ,  C10G67/06 ,  C10G2300/205

摘要： For removing mercury and any arsenic in hydrocarbon charges containing mercury and sulfur, the charge is contacted with an arsenic collecting material having catalytic properties ("catalyst") in hydrogen, the material containing at least one metal selected from the group consisting of nickel, cobalt, iron, palladium, and platinum; at least one metal selected from the group consisting of chromium, molybdenum, tungsten, and uranium; and an active phase carrier. Downstream of the catalyst or mixed therewith is a mercury collecting material containing a sulfide of at least one metal selected from the group consisting of copper, iron, and silver or sulfur, and an active phase carrier.

摘要翻译： 为了除去含有汞和硫的烃装料中的汞和任何砷，电荷与氢气中具有催化性质（“催化剂”）的砷收集材料接触，该材料含有选自镍，钴中的至少一种金属 ，铁，钯和铂; 选自铬，钼，钨和铀中的至少一种金属; 和活性载体。 催化剂的下游或与其混合的是含有选自铜，铁和银或硫的至少一种金属的硫化物的汞收集材料和活性相载体。

公开(公告)号：US5268091A

公开(公告)日：1993-12-07

申请号：US700120

申请日：1991-05-10

申请人： Jean P. Boitiaux ,  Philippe Courty ,  Patrick Sarrazin

发明人： Jean P. Boitiaux ,  Philippe Courty ,  Patrick Sarrazin

IPC分类号： C10G25/00 ,  C10G17/02

CPC分类号： C10G25/00

摘要： A method for removing arsenic and/or phosphorus from a petroleum charge with a retaining material comprising:(a) from 60 to 97% of a carrier containing, by weight, from 1.5 to 60% of oxide of at least one metal A selected from the group consisting of Mg, Ca, Sr, Ba, Mn, Fe, Co, Ni, Cu and Zn, dissolved in alumina in the form of aluminate, and from 40 to 98.5% of at least one alumina,(b) from 3 to 40% of nickel oxide, with which the carrier is impregnated by exchange or depositing, and(c) possibly from 0 to 1% of platinum and/or palladium oxide with which the carrier is impregnated.

摘要翻译： 一种从具有保留材料的石油装料中除去砷和/或磷的方法，包括：（a）60至97％的载体，其含有至少一种选自以下的金属的氧化物的1.5至60重量％ 以铝酸盐形式溶解在氧化铝中的Mg，Ca，Sr，Ba，Mn，Fe，Co，Ni，Cu和Zn组成的组和40至98.5％的至少一种氧化铝，（b）3 至40％的氧化镍，载体通过其交换或沉积而浸渍，和（c）可能含有0至1％的载体浸渍的铂和/或氧化钯。

公开(公告)号：US4277369A

公开(公告)日：1981-07-07

申请号：US98453

申请日：1979-11-29

申请人： Philippe Courty ,  Jean Miquel ,  Germain Martino ,  Alain Convers

发明人： Philippe Courty ,  Jean Miquel ,  Germain Martino ,  Alain Convers

IPC分类号： B01J23/96 ,  B01J27/00 ,  C07B61/00 ,  C07C1/00 ,  C07C4/20 ,  C07C15/04 ,  C07C67/00 ,  B01J21/20 ,  C07C4/18

CPC分类号： C07C4/20 ,  B01J23/96 ,  C07C2521/06 ,  C07C2523/04 ,  C07C2523/36 ,  C07C2523/40 ,  C07C2523/50 ,  C07C2523/52 ,  Y02P20/584

摘要： A catalyst for the steam dealkylation of aromatic hydrocarbons, comprising a carrier and 3 metals, is regenerated in the reaction zone containing the catalyst bed, after disconnection of said zone from the producing unit, by proceeding to the successive steps of: scavenging said zone with hydrogen and then with an inert gas, progressively replacing said inert gas by a gas containing molecular oxygen, burning the catalyst at a temperature lower than 650.degree. C. so as to calcine the carbon deposits of the catalyst, passing through the catalyst bed an air stream containing halogen to increase the halogen content of the catalyst, calcining by means of an air stream at a temperature of 300.degree.-600.degree. C. and purging with an inert gas before reconnecting said reaction zone to the producing unit.

摘要翻译： 包含载体和3种金属的芳烃的蒸汽脱烷基化催化剂在包含催化剂床的反应区中，在从所述生产单元断开所述区域之后，通过以下连续步骤进行再生：将所述区域与 氢气，然后用惰性气体逐渐用含有分子氧的气体代替所述惰性气体，在低于650℃的温度下燃烧催化剂，以便煅烧催化剂的碳沉积物，通过催化剂床空气 含有卤素的物流以增加催化剂的卤素含量，通过空气流在300-600℃的温度下煅烧，并在将所述反应区重新连接到生产单元之前用惰性气体吹扫。

公开(公告)号：US06462097B1

公开(公告)日：2002-10-08

申请号：US09822409

申请日：2001-04-02

申请人： Germain Martino ,  Philippe Courty ,  Pierpaulo Garibaldi

发明人： Germain Martino ,  Philippe Courty ,  Pierpaulo Garibaldi

IPC分类号： C07C2700

CPC分类号： C07C1/0485 ,  C02F1/22 ,  C02F1/281 ,  C02F3/00 ,  C02F2101/32 ,  C02F2103/16

摘要： A process for the production of purified water and hydrocarbons comprising at least one stage of separation of the water and hydrocarbons formed during a Fischer-Tropsch synthesis, at least one stage of purification of the separated water by bringing it into contact with at least one adsorbent selected from the group consisting of: the active carbons, clays which are hydrophobic or rendered hydrophobic, and zeolites which are hydrophobic or rendered hydrophobic. This process may optionally include a stripping stage before the adsorption step.

摘要翻译： 一种用于生产净化水和烃的方法，包括在费 - 托合成期间形成的水和烃的至少一个阶段的分离，至少一个阶段通过使分离的水与至少一种吸附剂 选自：活性炭，疏水性或疏水性的粘土和疏水性或疏水性的沸石。 该方法可任选地包括在吸附步骤之前的汽提阶段。

公开(公告)号：US4207169A

公开(公告)日：1980-06-10

申请号：US1653

申请日：1979-01-08

申请人： Philippe Courty ,  Germain Martino ,  Jean-Francois Le Page

发明人： Philippe Courty ,  Germain Martino ,  Jean-Francois Le Page

IPC分类号： C07C15/04 ,  B01J21/00 ,  B01J23/00 ,  B01J23/46 ,  B01J23/56 ,  B01J23/89 ,  B01J37/02 ,  C07B61/00 ,  C07C1/00 ,  C07C4/20 ,  C07C15/02 ,  C07C67/00 ,  C10G59/02 ,  C07C3/58 ,  B01J23/64 ,  C10G11/02 ,  C10G35/08

CPC分类号： C10G59/02 ,  B01J23/46 ,  B01J23/56 ,  B01J23/89 ,  B01J23/8946 ,  B01J37/0207 ,  C07C4/20 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2523/04 ,  C07C2523/08 ,  C07C2523/12 ,  C07C2523/14 ,  C07C2523/20 ,  C07C2523/22 ,  C07C2523/26 ,  C07C2523/28 ,  C07C2523/30 ,  C07C2523/34 ,  C07C2523/36 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2523/755 ,  Y02P20/52

摘要： Catalytic process for steam dealkylation of a charge containing at least one alkyl aromatic hydrocarbon, such as a charge issued from effluents of units for catalytic reforming or for producing aromatic hydrocarbons, wherein the catalyst contains an alumina carrier, from 0.1 to 1% of rhodium, from 0.05 to 1% of TiO.sub.2 and optionally from 0.1 to 1% of ruthenium, palladium, iridium, platinum or osmium and/or from 0.01 to 5% of lithium, sodium, potassium, rubidium or cesium.

摘要翻译： 含有至少一种烷基芳族烃的电荷的蒸汽脱烷基化的催化方法，例如由用于催化重整的单元的流出物或用于生产芳烃的电荷产生的电荷，其中所述催化剂含有氧化铝载体，0.1至1％的铑， 钌，钯，铱，铂或锇的0.05至1％的TiO 2和任选的0.1至1％的锂和/或0.01至5％的锂，钠，钾，铷或铯。

公开(公告)号：US5591323A

公开(公告)日：1997-01-07

申请号：US474766

申请日：1995-06-07

申请人： Christian Marcilly ,  Serge Leporq ,  Philippe Courty

发明人： Christian Marcilly ,  Serge Leporq ,  Philippe Courty

IPC分类号： B01J21/16 ,  B01J27/26 ,  B01J29/06 ,  B01J37/00 ,  C10G25/00 ,  C10G27/10 ,  C10G27/00 ,  C10G27/04

CPC分类号： B01J21/16 ,  B01J27/26 ,  C10G27/10 ,  B01J37/0009

摘要： A process for sweetening a petroleum cut containing mercaptans, wherein said petroleum cut is subjected to oxidation conditions by being contacted with a porous catalyst, in the presence of air said process being characterised in that said catalyst comprises 10 to 98% by weight of at least one mineral solid phase constituted of an alkaline aluminosilicate with a Si/Al atomic ratio less than or equal to 5, 1 to 60% by weight of active carbon, 0.02 to 2% by weight of at least one metal chelate and 0 to 20% by weight of at least one organic or mineral binding agent, has a basicity determined according to the 2896 ASTM standard with 20 milligrams of potash per gram and a total BET surface area of 10 m.sup.2 g.sup.-1, and contains inside its pore structure a permanent aqueous phase representing 0.1 to 40% by weight of dry catalyst.

摘要翻译： 一种用于甜化含有硫醇的石油馏分的方法，其中所述石油馏分通过与多孔催化剂接触而经受氧化条件，在空气存在下，所述方法的特征在于所述催化剂至少包含10至98重量％ 一个矿物固相由Si / Al原子比小于或等于5,1-60重量％的活性炭，0.02-2重量％的至少一种金属螯合物和0-20重量％的碱性硅铝酸盐构成， 的至少一种有机或矿物结合剂，具有根据2896 ASTM标准确定的碱度，每克20mg的钾碱和10m 2 g -1的总BET表面积，并且在其孔结构内部含有永久性水性 相为干燥催化剂的0.1-40重量％。

公开(公告)号：US5112591A

公开(公告)日：1992-05-12

申请号：US656892

申请日：1991-02-19

申请人： Patrick Chaumette ,  Fabienne Le Peltier ,  Raymond F. Szymanski ,  Philippe Courty ,  Catherine Verdon

发明人： Patrick Chaumette ,  Fabienne Le Peltier ,  Raymond F. Szymanski ,  Philippe Courty ,  Catherine Verdon

IPC分类号： C01B3/32 ,  B01J23/80 ,  B01J37/03 ,  C07C29/153 ,  C07C29/154 ,  C07C31/02

CPC分类号： C07C29/154 ,  B01J23/80 ,  B01J37/03 ,  Y02P20/52

摘要： The present invention relates to a process for preparing a precursor of a catalyst containing copper, aluminum and zinc.This precursor is formed by the mixing of two ternary precursors, at different stages of their manufacturing, these two ternary precursors being different from one another in their metallic stoichiometry (atomic ratios between Cu, Zn and Al), in their crystallographic structure and in their elemental morphology.The catalyst obtained from this precursor can be used in particular for the synthesis of methanol.

公开(公告)号：US5051392A

公开(公告)日：1991-09-24

申请号：US527769

申请日：1990-05-24

申请人： Gil Mabilon ,  Daniel Durand ,  Philippe Courty ,  Michel Prigent

发明人： Gil Mabilon ,  Daniel Durand ,  Philippe Courty ,  Michel Prigent

IPC分类号： F01N3/28 ,  B01D53/86 ,  B01D53/94 ,  B01J23/56 ,  B01J23/58 ,  B01J23/63 ,  B01J29/06 ,  F01N3/10

CPC分类号： B01D53/945 ,  B01J23/58 ,  B01J23/63 ,  Y02T10/22

摘要： A multifunctional catalyst, a method of preparing the catalyst and the use of the catalyst in treating exhaust fumes from internal combustion engines are described. The catalyst includes a porous layer containing (weight %, dry):about 50 to about 99.7% of at least one refractory inorganic oxide,about 0.1 to about 25% of at least one uranium oxide,about 0.1 to about 35% of at least one oxide of at least one metal P selected from the group consisting of lithium, sodium, potassium, rubidium, cesium, beryllium, magnesium, calcium, strontium, barium, lanthanum, praseodymium, neodymium, gadolinium, and yttrium andabout 0.1 to 20% of a metal A selected from the group consisting of platinum, rhodium, palladium, ruthenium, iridium, and mixtures thereof.

摘要翻译： 描述了一种多功能催化剂，一种制备该催化剂的方法以及该催化剂在处理来自内燃机的废气中的用途。 催化剂包括含有（重量％，干）的多孔层：约50-约99.7％的至少一种耐火无机氧化物，约0.1至约25％的至少一种氧化铀，至少约0.1-约35％ 选自锂，钠，钾，铷，铯，铍，镁，钙，锶，钡，镧，镨，钕，钆和钇中的至少一种金属P的一种氧化物，以及约0.1至20％ 的选自铂，铑，钯，钌，铱的金属A及其混合物。

公开(公告)号：US5019547A

公开(公告)日：1991-05-28

申请号：US514059

申请日：1990-04-24

申请人： Patrick Chaumette ,  Fabienne Le Peltier ,  Raymond Szymanski ,  Philippe Courty ,  Catherine Verdon

发明人： Patrick Chaumette ,  Fabienne Le Peltier ,  Raymond Szymanski ,  Philippe Courty ,  Catherine Verdon

IPC分类号： C01B3/32 ,  B01J23/80 ,  B01J37/03 ,  C07C29/153 ,  C07C29/154 ,  C07C31/02

CPC分类号： C07C29/154 ,  B01J23/80 ,  B01J37/03 ,  Y02P20/52

摘要： The present invention relates to a process for preparing a precursor of a catalyst containing copper, aluminum and zinc.This precursor is formed by the mixing of two ternary precursors, at different stages of their manufacturing, these two ternary precursors being different from one another in their metallic stoichiometry (atomic ratios between Cu, Zn and Al), in their crystalographic structure and in their elemental morphology.The catalyst obtained from this precursor can be used in particular for the synthesis of methanol.

摘要翻译： 本发明涉及一种制备含有铜，铝和锌的催化剂前体的方法。 这种前体是通过混合两种三元前体在其制造的不同阶段形成的，这两种三元前体在其金属化学计量学（Cu，Zn和Al之间的原子比），它们的晶体结构和它们的结构中彼此不同 元素形态。 从该前体获得的催化剂可特别用于合成甲醇。

公开(公告)号：US4840783A

公开(公告)日：1989-06-20

申请号：US133843

申请日：1987-12-16

申请人： Dang Vu Quang ,  Michel Davidson ,  Daniel Durand ,  Philippe Courty

发明人： Dang Vu Quang ,  Michel Davidson ,  Daniel Durand ,  Philippe Courty

IPC分类号： B01J23/72 ,  B01J23/80 ,  B01J23/86 ,  B01J23/887 ,  C01B3/32

CPC分类号： B01J23/868 ,  B01J23/72 ,  B01J23/8873 ,  C01B3/323 ,  Y02P20/52

摘要： The invention relates to a process for the production of hydrogen by catalytic reforming of methanol with water vapor. A mixture of methanol, water and carbon dioxide is passed in contact with a catalyst, containing copper, in a fixed bed, in a catalytic zone, at a temperature comprised between 150.degree. and 400.degree. C., the molar ratio of the carbon dioxide to the methanol, at the entrance of the catalytic zone, being comprised between 0.001 and 0.2.

摘要翻译： 本发明涉及通过甲醇与水蒸气的催化重整来生产氢的方法。 将甲醇，水和二氧化碳的混合物在含有铜的催化剂中在固定床中在催化区中在150-400℃的温度下接触，二氧化碳的摩尔比 在催化区入口处的甲醇为0.001至0.2。