公开(公告)号：US5191144A

公开(公告)日：1993-03-02

申请号：US772184

申请日：1991-10-07

申请人： Quang N. Le ,  Robert T. Thomson

发明人： Quang N. Le ,  Robert T. Thomson

IPC分类号： B01J29/70 ,  C07C6/04

CPC分类号： B01J29/70 ,  C07C6/04 ,  B01J2229/26 ,  B01J2229/36 ,  B01J2229/42

摘要： In the process of olefin disproportionation, a feedstock containing predominatly mono-olefin the feedstock is charged at elevated temperature into a catalytic conversion zone in contact with mesoporous acid olefin conversion catalyst under selective olefin interconversion conditions.The improvement is characterized by a mesoporous acid metallosilicate crystalline catalyst material having Bronsted acid sites in a hexagonal lattice structure, said catalyst material having substantially uniform pores in hexagonal arrangement with a pore size of about 20 to 100 Angstroms units. In the preferred embodiments the olefinic feedstock is reacted for less than 10 seconds in contact with MCM-41 mesoporous metallosilicate catalyst under partial reaction conditions sufficient to provide increased yield of C4 alkene having a ratio of isobutene to normal butenes greater than equilibrium.

摘要翻译： 在烯烃歧化过程中，主要含有单烯烃的原料将原料在高温下加入到与中孔酸烯烃转化催化剂在选择性烯烃互转条件下接触的催化转化区。 该改进的特征在于具有六角形格子结构的布朗斯台德酸位点的中孔酸金属硅酸盐结晶催化剂材料，所述催化剂材料具有基本上均匀的孔，其孔径大约为20至100埃单位。 在优选的实施方案中，烯烃原料在部分反应条件下与MCM-41介孔金属硅酸盐催化剂接触反应少于10秒，足以提供具有比平衡高的异丁烯与正丁烯的比例的增加的C4烯烃的产率。

公开(公告)号：US5191135A

公开(公告)日：1993-03-02

申请号：US673925

申请日：1991-03-25

申请人： Francis G. Dwyer ,  Quang N. Le

发明人： Francis G. Dwyer ,  Quang N. Le

IPC分类号： C07C2/66

CPC分类号： C07C2/66 ,  C07C2529/08 ,  C07C2529/70

摘要： Long chain alkyl substituted aromatic compounds, particularly alkylated naphthalenes, are produced by the alkylation of aromatics, e.g. naphthalene, with an olefin or other alkylating agent possessing at least 6 carbon atoms, usually 12 to 20 carbon atoms, in the presence of a zeolite alkylation catalyst, preferably a large pore size zeolite such as zeolite Y and in the presence of from about 0.5 to 3.0 weight percent water, preferably 1.0 to 3.0 weight percent. The use of the water co-feed increases the selectivity of the alkylation for the production of long chain mono-alkyl substituted naphthalenes in preference to more highly substituted products and also increases activity and catalyst stability.

摘要翻译： 长链烷基取代的芳族化合物，特别是烷基化萘，通过芳族化合物的烷基化，例如， 萘与具有至少6个碳原子，通常12-20个碳原子的烯烃或其它烷基化剂在沸石烷基化催化剂，优选大孔沸石如沸石Y的存在下并在约0.5的存在下反应 至3.0重量％的水，优选1.0至3.0重量％。 使用水共进料增加了烷基化用于生产长链单烷基取代萘的选择性，优于更高取代的产物，并且还增加了活性和催化剂的稳定性。

公开(公告)号：US5171916A

公开(公告)日：1992-12-15

申请号：US715269

申请日：1991-06-14

申请人： Quang N. Le ,  Michael S. Sarli

发明人： Quang N. Le ,  Michael S. Sarli

IPC分类号： C10G29/20

CPC分类号： C10G29/205

摘要： Alkylated aromatic functional fluids are prepared by alkylating a light cycle oil with an alkylating agent, such as an alpha C.sub.14 -olefin or coker gas oil, over a crystalline metallosiicate catalyst, preferably an aluminosilicate, including MCM-22, USY or an acid treated kaolin clay. The process produces an improved light cycle oil in which the heteroatom content of the oil is reduced and a high quality synthetic alkylated aromatic functional fluid base stock boiling above 600.degree. F. The reactor temperature can be elevated to increase the functional fluid yield and the extent of heteroatom removal.

摘要翻译： 烷基化芳族官能流体通过在结晶金属化合催化剂，优选包括MCM-22，USY或酸处理的高岭土的铝硅酸盐上，用烷基化剂如αC 14 - 烯烃或焦化瓦斯油将轻质循环油烷基化来制备 粘土。 该方法产生改进的轻循环油，其中油的杂原子含量降低，高质量的合成烷基化芳族官能液基料沸点高于600°F。可以提高反应器温度以增加功能流体产率和程度 的杂原子去除。

公开(公告)号：US4826792A

公开(公告)日：1989-05-02

申请号：US193151

申请日：1988-05-05

申请人： Quang N. Le ,  Stephen S. Wong

发明人： Quang N. Le ,  Stephen S. Wong

IPC分类号： B01J29/90 ,  B01J38/60 ,  B01J38/66 ,  B01J29/38 ,  B01J23/96

CPC分类号： B01J29/90 ,  B01J38/60 ,  B01J38/66 ,  Y10S502/517

摘要： A method for reactivating noble metal-containing zeolites containing sulfur oxide poisoned noble metal such as oxygen regenerated platinum zeolite beta catalysts, by contacting the catalyst with an acidic aqueous solution having a pH below about 7. The solution contains a Bronsted acid compound having a dissociation constant ranging from about 1.times.10.sup.-14 to about 2.times.10.sup.-1.

摘要翻译： 通过使催化剂与pH低于约7的酸性水溶液接触，使含有硫氧化物中毒的贵金属如贵金属贵金属如氧再生的铂沸石β催化剂再生的方法。该溶液含有具有解离性的布朗斯台德酸化合物 常数范围为约1×10-14至约2×10 -1。

公开(公告)号：US5602086A

公开(公告)日：1997-02-11

申请号：US634135

申请日：1996-04-19

申请人： Quang N. Le ,  Joosup Shim

发明人： Quang N. Le ,  Joosup Shim

IPC分类号： C10M105/00 ,  C10M111/04 ,  C10M169/04 ,  C10N20/02 ,  C10N30/08 ,  C10N30/10 ,  C10N40/08 ,  C10N40/16 ,  C10N40/22 ,  C10N40/25

CPC分类号： C10M111/04 ,  C10M169/04 ,  C10M2203/06 ,  C10M2203/065 ,  C10M2205/00 ,  C10M2205/0206 ,  C10M2205/028 ,  C10M2205/0285 ,  C10M2207/282 ,  C10M2207/285 ,  C10M2207/286 ,  C10M2207/34 ,  C10N2220/02 ,  C10N2240/04 ,  C10N2240/042 ,  C10N2240/044 ,  C10N2240/046 ,  C10N2240/06 ,  C10N2240/10 ,  C10N2240/101 ,  C10N2240/104 ,  C10N2240/106 ,  C10N2240/401

摘要： The inclusion of alkylated aromatic base fluids, such as alkylated naphthalene, blending stocks with polyalphaolefin base fluids provides significant performance improvements in oxidation stability, solubility, elastomer compatibility and hydrolytic stability.

摘要翻译： 包含烷基化芳族基础流体，如烷基化萘，共混料与聚α-烯烃基础液体在氧化稳定性，溶解度，弹性体相容性和水解稳定性方面提供显着的性能改进。

公开(公告)号：US5326922A

公开(公告)日：1994-07-05

申请号：US929547

申请日：1992-08-13

申请人： Albin Huss, Jr. ,  Quang N. Le ,  Robert T. Thomson

发明人： Albin Huss, Jr. ,  Quang N. Le ,  Robert T. Thomson

IPC分类号： C07C2/58 ,  C07C5/52

CPC分类号： C07C5/52 ,  C07C2/58 ,  C07C2529/70

摘要： The transfer of hydrogen from a paraffin to an olefin is carried out in the presence of, as catalyst, MCM-36. Especially when the paraffin reactant is an isoparaffin, the olefin produced from the reacted isoparaffin may react with unreacted isoparaffin to also produce an alkylate product.

摘要翻译： 氢气从烷烃转化为烯烃在作为催化剂的MCM-36存在下进行。 特别是当链烷烃反应物是异链烷烃时，由反应的异链烷烃产生的烯烃可与未反应的异链烷烃反应，产生烷基化产物。

公开(公告)号：US5134243A

公开(公告)日：1992-07-28

申请号：US718893

申请日：1991-06-21

申请人： Nazeer A. Bhore ,  Quang N. Le ,  Grant H. Yokomizo

发明人： Nazeer A. Bhore ,  Quang N. Le ,  Grant H. Yokomizo

IPC分类号： C07C2/12

CPC分类号： B01J29/041 ,  C07C2/12 ,  C07C2529/70

摘要： A process for upgrading olefins employing new synthetic catalyst of ultra-large pore crystalline material. The new crystalline material exhibits unusually large sorption capacity demonstrated by its benzene adsorption capacity of greater than about 15 grams benzene/100 grams at 50 torr and 25.degree. C., a hexagonal electron diffraction pattern that can be indexed with a d.sub.100 value greater than about 18 Angstrom Units and a hexagonal arrangement of uniformly sized pores with a maximum perpendicular cross section of at least about 13 Angstrom units.A new process is provided for catalytic oligomerization of olefin feedstock which comprises contacting the feedstock under catalytic conversion conditions with acid metallosilicate solid catalyst having the structure of MCM-41 with hexagonal honeycomb lattice structure consisting essentially of uniform pores in the range of about 20 to 100 Angstroms. The oligomerization reaction is very selective, especially when conducted at temperature of about 40.degree. to 250.degree. C. Low severity reaction permits excellent conversion of lower olefins at pressure of about 100-13,000 pKa range and moderate space velocity.

摘要翻译： 一种使用超大孔结晶材料的新型合成催化剂改质烯烃的方法。 新的结晶材料表现出非常大的吸附能力，其吸附能力在50托和25℃时苯吸附能力大于约15克苯/ 100克，可以用大于约100的d100值进行指数的六方电子衍射图 18埃单位和具有至少约13埃单位的最大垂直截面的均匀尺寸孔的六边形排列。 提供了用于烯烃原料的催化低聚的新方法，其包括在催化转化条件下使原料与具有MCM-41结构的酸性金属硅酸盐固体催化剂接触，其具有基本上由约20至100范围内的均匀孔组成的六方蜂窝晶格结构 埃 低聚反应是非常有选择性的，特别是在约40℃至250℃的温度下进行。低强度反应允许在约100-13000pKa范围和适度的空间速度的压力下对低级烯烃进行极好的转化。

公开(公告)号：US5118894A

公开(公告)日：1992-06-02

申请号：US732265

申请日：1991-07-18

申请人： Quang N. Le

发明人： Quang N. Le

IPC分类号： B01J29/04 ,  B01J35/10 ,  C07C2/66

CPC分类号： C07C2/66 ,  B01J29/04 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1028 ,  B01J35/1057 ,  B01J35/1061 ,  C07C2529/70

摘要： Ethylbenzene is produced by the alkylation of benzene with ethylene in the presence of an alkylation catalyst which comprises an inorganic, non-layered, porous, crystalline phase aluminosilicate material whcih exhibits a benzene adsorption capacity of greater than about 15 grams benzene per 100 grams at 50 torr and 25.degree. C. In its preferred catalytic form, the crystalline material has a uniform, hexagonal arrangement of pores with diameters of at least about 13 .ANG. and exhibiting, after calcination, an X-ray diffraction pattern with at least one d-spacing greater than about 18 A and a hexagonal electron diffraction pattern that can be indexed with a d.sub.100 value greater than about 18 .ANG. which corresponds to at least one peak in the X-ray diffraction pattern. The process is typically carried out at a temperatue of 200.degree. to 1000.degree. F. but the catalyst provides sufficient activity for the reaction to be carried out at temperatures below 700.degree. F. Liquid phase operation is preferred, giving a lower yield of polyethylated products. The use of the selected catalyst also results in a reduction of the xylene impurity level.

摘要翻译： 在烷基化催化剂存在下，通过苯与乙烯的烷基化生产乙苯，该烷基化催化剂包含无机，非分层，多孔的结晶相铝硅酸盐材料，其在50℃下表现出大于约15克苯/ 100克的苯吸附能力 托和25℃。在其优选的催化形式中，结晶材料具有均匀的六边形排列的孔，其直径至少​​约为13，并且在煅烧之后表现出具有至少一个d间距的X射线衍射图 大于约18的六边形电子衍射图案和可以对应于X射线衍射图中的至少一个峰值的d100值大于约18的折射率的六角形电子衍射图案。 该方法通常在200至1000°F的温度下进行，但催化剂提供足够的活性以使反应在低于700°F的温度下进行。优选液相操作，从而降低聚乙烯化产物的产率 。 使用所选择的催化剂也导致二甲苯杂质水平的降低。

公开(公告)号：US5107048A

公开(公告)日：1992-04-21

申请号：US470017

申请日：1990-01-25

申请人： Albin Huss, Jr. ,  Quang N. Le ,  Samuel A. Tabak ,  Stephen S. Wong

发明人： Albin Huss, Jr. ,  Quang N. Le ,  Samuel A. Tabak ,  Stephen S. Wong

IPC分类号： C07C2/68

CPC分类号： C07C2/68 ,  C07C2521/08 ,  C07C2527/10 ,  C07C2527/1213 ,  C07C2527/133

摘要： Aromatic hydrocarbons are alkylated with relatively long chain alkylating agents, e.g., C.sub.8 + olefins, at mole ratio of aromatic to alkylating agent of not greater than about 5 in the presence of, as catalyst, a Lewis acid-promoted amorphous, porous inorganic oxide such as silica to provide long chain alkyl aromatic products which are useful, inter alia, as lubricating oil stocks.

摘要翻译： 使用相对较长链烷基化剂（例如C 8+烯烃）将芳族烃烷基化，在作为催化剂的路易斯酸促进的无定形多孔无机氧化物如芳族化合物与烷基化剂的摩尔比不大于约5的情况下， 二氧化硅以提供长链烷基芳族化合物，其特别可用作润滑油原料。

公开(公告)号：US4975177A

公开(公告)日：1990-12-04

申请号：US382077

申请日：1989-07-17

申请人： William E. Garwood ,  Quang N. Le ,  Stephen S. Wong

发明人： William E. Garwood ,  Quang N. Le ,  Stephen S. Wong

IPC分类号： C10G65/04 ,  C10G67/04

CPC分类号： C10G65/043 ,  C10G67/04

摘要： Lubricant basestocks of high viscosity index, typically with V.I. of at least 130 or higher, and low pour point, typically below 5.degree. F., are produced by hydroisomerizing petroleum waxes such as slack wax or de-oiled wax, over zeolite beta and then dewaxing to target pour point. A preferred process employs a solvent dewaxing after the hydroisomerization step to effect a partial dewaxing with the separated waxes being recycled to the hydroisomerization step; dewaxing is then completed catalytically, typically over ZSM-5 or ZSM-23.

摘要翻译： 高粘度指数的润滑油基础油，通常用V.I. 至少为130或更高，低倾点（通常低于5°F）通过沸石蜡或脱油蜡等石油蜡加氢异构化生产，然后脱蜡至目标倾点。 优选的方法是在加氢异构化步骤之后进行溶剂脱蜡以进行部分脱蜡，将分离的蜡再循环至加氢异构化步骤; 催化后完成脱蜡，通常在ZSM-5或ZSM-23上完成。