Nitromethylene derivative insecticides
    22.
    发明授权
    Nitromethylene derivative insecticides 失效
    硝基亚甲基衍生物杀虫剂

    公开(公告)号:US4774247A

    公开(公告)日:1988-09-27

    申请号:US29303

    申请日:1987-03-23

    摘要: Novel insecticides of the formula ##STR1## in which R is a hydrogen atom or a lower alkyl group,X is a halogen atom, a lower alkyl group, a lower alkoxy group, a lower alkylthio group, a lower alkylsulfinyl group, a lower alkylsulfonyl group, a lower alkenyl group, a lower alkynyl group, an aryl group, an aryloxy group which may be optionally substituted by a halogen atom, an arylthio group which may be optionally substituted by a halogen atom, or an aralkyl group,l is 1, 2, 3 or 4,m is 2, 3 or 4, andn is 0, 1, 2 or 3,or salts thereof. Intermediates therefor of the formula ##STR2## are also new.

    摘要翻译: 式中,R为氢原子或低级烷基的式“IMAGE”的新型杀虫剂,X为卤素原子,低级烷基,低级烷氧基,低级烷硫基,低级烷基亚磺酰基,低级烷基磺酰基 低级烯基,低级炔基,芳基,可以被卤素原子任选取代的芳氧基,可以被卤素原子取代的芳硫基或芳烷基,l为1 ,2,3或4,m为2,3或4,n为0,1,2或3,或其盐。 具有公式的中间体也是新的。

    Pyridyl insecticidally active cyano compounds
    27.
    发明授权
    Pyridyl insecticidally active cyano compounds 失效
    吡啶类杀虫活性氰化合物

    公开(公告)号:US5066808A

    公开(公告)日:1991-11-19

    申请号:US584398

    申请日:1990-09-14

    摘要: A cyano compound useful as an insecticide, of the formula (I) ##STR1## wherein R.sup.1 is hydrogen, cyano or C.sub.1-4 alkyl, m is 0 or 1,R.sup.2 is hydrogen, C.sub.1-6 alkyl, C.sub.3-4 alkenyl optionally substituted by halogen,C.sub.3-4 alkynyl, C.sub.3-8 cycloalkyl optionally substituted by methyl, optionally substituted phenyl, optionally substituted benzyl, hydroxy, C.sub.1-4 alkoxy or --CH.sub.2 --Z, in which Z has the same meanings as stated below,R.sup.3 is ##STR2## in which R.sup.4 is C.sub.1-6 alkyl, C.sub.3-4 alkenyl, C.sub.3-4 alkynyl, C.sub.3-8 cycloalkyl, optionally substituted phenyl, optionally substituted benzyl or --(CH.sub.2)n-Z, in which n is 1 or 2 andZ has the same meanings as stated below, andR.sup.5 and R.sup.6 are hydrogen, C.sub.1-9 alkyl optionally substituted by at least one selected from a group consisting of halogen, hydroxy, mercapto, C.sub.1-2 alkoxy, C.sub.1-2 alkylthio, C.sub.3-6 cycloalkyl, amino, C.sub.1-2 monoalkylamino, C.sub.2-4 (in total)di-alkylamino, carboxy, C.sub.1-2 alkoxy-carbonyl and cyano, C.sub.3-4 alkenyl optionally substituted by halogen, C.sub.3-4 alkynyl, optionally substituted phenyl, optionally substituted benzyl, C.sub.1-4 alkoxy, hydroxy, formyl, C.sub.1-4 alkoxy-carbonyl, C.sub.1-4 alkylamino, C.sub.2-4 (in total)di-alkylamino, amino, acyl or ##STR3## in which R.sup.1 and m have the same meanings as stated above, and Z has the same meanings as stated below, and in addition,R.sup.5 and R.sup.6 may form, together with the N-atom to which they are bonded, a 3 to 7 membered ring which may be substituted by C.sub.1-2 alkyl and may contain N, O or S as the member of said ring, besides the N-atom to which they are bonded, andZ is a substituted 5 or 6 membered heterocyclic group which contains at least one heteroatom selected from N, O and S as a ring member, provided that where Z is pyridyl substituted by halogen, m is 1, R.sup.2 is C.sub.1-6 alkyl and R.sup.3 is --S--alkyl(C.sub.1-6) or --S--benzyl, then R.sup.1 is cyano or C.sub.1-4 alkyl.

    Pesticidal nitro-substituted heterocyclic compounds
    28.
    发明授权
    Pesticidal nitro-substituted heterocyclic compounds 失效
    杀虫硝基取代的杂环化合物

    公开(公告)号:US4876263A

    公开(公告)日:1989-10-24

    申请号:US208421

    申请日:1988-06-17

    摘要: Nitro-subsliluted heterocyclic compounds of the formula (I) ##STR1## wherein R is hydrogen or alkyl, Z is an optionally substituted aryl or optionally subtituted heterocyclic groun containing at least one atom selected from N, O and S,A is optionally substituted ethylene or optionally substituted trimethylene, andB stands for 2 or 3 members of a heterocyclic ring which is formed, together with the adjacent C-atom and N-aom and at least one of said members may represent a hetero atom and may be optionally substituted, provided that when B stands for 3 members, two of which are carbon atoms and the other one is a nitrogen atom which is located in the middle of the three members, then at least one of said two carbon atoms must be substituted by a keto group. Such compounds being useful as insecticides.

    摘要翻译: 硝基亚稀释的式(I)的杂环化合物其中R是氢或烷基,Z是任选取代的芳基或含有至少一个选自N,O和S的原子的任选取代的杂环化合物,A是 任选取代的乙烯或任选取代的三亚甲基,B代表杂环的2或3个成员,其与相邻的C原子和N-aom一起形成,并且所述成员中的至少一个可以表示杂原子,并且可以是 任选取代,条件是当B代表3个成员时,其中两个是碳原子,另一个是位于三个成员中间的氮原子,则所述两个碳原子中的至少一个必须被 一个酮基。 这些化合物可用作杀虫剂。