公开(公告)号：US09416099B2

公开(公告)日：2016-08-16

申请号：US14867263

申请日：2015-09-28

Applicant: Stepan Company

Inventor： Dave R Allen ,  Marcos Alonso ,  Randal J Bernhardt ,  Aaron Brown ,  Sangeeta Ganguly-Mink ,  Andrew Malec ,  Teresa Manuel ,  Ronald A. Masters ,  Lawrence A. Munie ,  Dennis S. Murphy ,  Patti Skelton ,  Brian Sook ,  Michael R. Terry ,  Jeremy Aaron Weitgenant ,  Laura Lee Whitlock ,  Michael Wiester ,  Patrick Shane Wolfe

IPC: A01N25/02 ,  A01N25/04 ,  A01N33/12 ,  A01N37/18 ,  A01N41/04 ,  A61K8/41 ,  A61K8/46 ,  C07C6/04 ,  C07C41/03 ,  A61Q5/02 ,  C04B24/12 ,  C11D1/83 ,  C07C309/69 ,  C07C43/11 ,  C07C67/26 ,  A01N25/30 ,  A01N37/44 ,  A61K8/42 ,  A61K8/44 ,  A61K8/92 ,  A61Q5/12 ,  A61Q19/10 ,  A62D1/02 ,  B01F17/00 ,  C07C69/533 ,  C07C69/593 ,  C07C209/12 ,  C07C211/21 ,  C07C219/08 ,  C07C231/12 ,  C07C237/16 ,  C07C303/18 ,  C08G65/26 ,  C08K5/01 ,  C08K5/20 ,  C09K15/28 ,  C11C3/00 ,  C11C3/08 ,  C11D1/00 ,  C11D1/04 ,  C11D1/28 ,  C11D1/62 ,  C11D1/65 ,  C11D1/74 ,  C11D1/90 ,  C11D1/92 ,  C11D1/94 ,  C11D3/48 ,  C04B24/16 ,  C07C211/63 ,  C07C229/12 ,  C07C233/36 ,  C09K8/54 ,  C09K8/60 ,  C09K15/22 ,  C09K8/00

CPC classification number: C07C309/69 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N33/12 ,  A01N37/18 ,  A01N37/44 ,  A01N41/04 ,  A61K8/416 ,  A61K8/42 ,  A61K8/44 ,  A61K8/447 ,  A61K8/466 ,  A61K8/92 ,  A61Q5/02 ,  A61Q5/12 ,  A61Q19/10 ,  A62D1/0071 ,  B01F17/0028 ,  B01F17/0057 ,  C04B24/121 ,  C04B24/124 ,  C04B24/16 ,  C07C6/04 ,  C07C41/03 ,  C07C43/11 ,  C07C67/26 ,  C07C69/533 ,  C07C69/593 ,  C07C209/12 ,  C07C211/21 ,  C07C211/63 ,  C07C219/08 ,  C07C229/12 ,  C07C231/12 ,  C07C233/36 ,  C07C237/16 ,  C07C303/18 ,  C08G65/2615 ,  C08K5/01 ,  C08K5/20 ,  C09K8/00 ,  C09K8/54 ,  C09K8/60 ,  C09K15/22 ,  C09K15/28 ,  C11C3/00 ,  C11C3/08 ,  C11D1/002 ,  C11D1/04 ,  C11D1/28 ,  C11D1/62 ,  C11D1/652 ,  C11D1/74 ,  C11D1/83 ,  C11D1/90 ,  C11D1/92 ,  C11D1/94 ,  C11D3/48 ,  C07C211/64 ,  C07C233/38 ,  C07C309/14 ,  A01N33/18 ,  A01N39/04 ,  A01N43/653 ,  A01N51/00 ,  A01N57/20 ,  A01N43/40 ,  A01N43/56 ,  A01N53/00

Abstract: Quaternary ammonium, betaine, or sulfobetaine compositions derived from fatty amines, wherein the fatty amine is made by reducing the amide reaction product of a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives and a secondary amine, are disclosed. Quaternary ammonium, betaine, or sulfobetaine compositions derived from fatty amidoamines, wherein the amidoamine is made by reacting of a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives and an aminoalkyl-substituted tertiary amine, are also disclosed. The quaternized compositions are advantageously sulfonated or sulfitated. In one aspect, the ester derivative of the C10-C17 monounsaturated acid or octadecene-1,18-dioic acid is a lower alkyl ester. In other aspects, the ester derivative is a modified triglyceride made by self-metathesis of a natural oil or an unsaturated triglyceride made by cross-metathesis of a natural oil with an olefin. The quaternary ammonium, betaine, and sulfobetaine compositions and their sulfonated or sulfitated derivatives are valuable for a wide variety of end uses, including cleaners, fabric treatment, hair conditioning, personal care (liquid cleansing products, conditioning bars, oral care products), antimicrobial compositions, agricultural uses, and oil field applications.

Abstract translation: 衍生自脂肪胺的季铵，甜菜碱或磺基甜菜碱组合物，其中所述脂肪胺是通过还原由复分解衍生的C 10 -C 17单不饱和酸，十八碳烯-1,18-二酸或其酯衍生物的酰胺反应产物和 公开了仲胺。 衍生自脂肪酰氨基胺的季铵，甜菜碱或磺基甜菜碱组合物，其中酰氨基胺是由易位素衍生的C 10 -C 17单不饱和酸，十八碳烯-1,18-二酸或其酯衍生物和氨基烷基取代的叔碳酸酯 胺也被公开。 季铵化组合物有利地被磺化或硫酸化。 一方面，C10-C17单不饱和酸或十八碳烯-1,18-二酸的酯衍生物是低级烷基酯。 在其它方面，酯衍生物是通过天然油或不饱和甘油三酸酯通过天然油与烯烃的交叉复分解而制备的改性甘油三酸酯。 季铵，甜菜碱和磺基甜菜碱组合物及其磺化或亚硫酸盐衍生物对于各种最终用途是有价值的，包括清洁剂，织物处理，头发调理，个人护理（液体清洁产品，调理棒，口腔护理产品），抗微生物剂 组合物，农业用途和油田应用。

公开(公告)号：US20160102271A1

公开(公告)日：2016-04-14

申请号：US14881283

申请日：2015-10-13

Applicant: Stepan Company

Inventor： Dave R. Allen ,  Marcos Alonso ,  Randal J. Bernhardt ,  Aaron Brown ,  Kelly Buchek ,  Sangeeta Ganguly-Mink ,  Brian Holland ,  Andrew D. Malec ,  Ronald A. Masters ,  Dennis S. Murphy ,  Patti Skelton ,  Brian Sook ,  Michael Wiester ,  Patrick Shane Wolfe

IPC: C11C3/04

CPC classification number: C11C3/04 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N33/12 ,  A01N37/18 ,  A01N37/44 ,  A01N41/04 ,  A61K8/39 ,  A61K8/416 ,  A61K8/42 ,  A61K8/44 ,  A61K8/466 ,  A61K8/86 ,  A61K8/92 ,  A61Q5/12 ,  A61Q17/005 ,  A61Q19/10 ,  A62D1/0071 ,  B01F17/0028 ,  B01F17/0057 ,  C07C6/04 ,  C07C41/03 ,  C07C43/11 ,  C07C67/02 ,  C07C67/26 ,  C07C69/533 ,  C07C69/593 ,  C07C209/12 ,  C07C211/21 ,  C07C219/08 ,  C07C231/12 ,  C07C237/16 ,  C07C303/18 ,  C08G65/2615 ,  C08K5/01 ,  C08K5/20 ,  C09K8/00 ,  C09K15/28 ,  C11C3/00 ,  C11C3/08 ,  C11D1/002 ,  C11D1/04 ,  C11D1/28 ,  C11D1/62 ,  C11D1/652 ,  C11D1/74 ,  C11D1/83 ,  C11D1/90 ,  C11D1/92 ,  C11D1/94 ,  C11D3/48 ,  C07C211/63 ,  C07C211/64 ,  C07C233/38 ,  C07C309/14 ,  A01N33/18 ,  A01N39/04 ,  A01N43/653 ,  A01N51/00 ,  A01N57/20 ,  A01N43/40 ,  A01N43/56 ,  A01N53/00

Abstract: Alkoxylated fatty ester compositions are disclosed. In one aspect, the compositions comprise a reaction product of a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives with one or more alkylene oxides in the presence of an insertion catalyst to give an alkoxylated fatty ester. In another aspect, the metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or its ester derivative is reacted with a glycol ether or a glycol ether alkoxylate, to give an alkoxylated fatty ester. In yet another aspect, the metathesis-derived C10-C17 monounsaturated acid or octadecene-1,18-dioic acid is reacted with one or more alkylene oxides to give a fatty acid alkoxylate, followed by etherification of the fatty acid alkoxylate.

Abstract translation: 公开了烷氧基化脂肪酸酯组合物。 在一个方面，组合物包含在插入催化剂存在下由易位素衍生的C 10 -C 17单不饱和酸，十八碳烯-1,18-二酸或其酯衍生物与一种或多种环氧烷烃的反应产物，得到 烷氧基化脂肪酸酯。 另一方面，将复分解衍生的C10-C17单不饱和酸，十八碳烯-1,18-二酸或其酯衍生物与二醇醚或二醇醚烷氧基化物反应，得到烷氧基化脂肪酸酯。 在另一方面，将来自复分解的衍生的C10-C17单不饱和酸或十八碳烯-1,18-二酸与一种或多种烯化氧反应，得到脂肪酸烷氧基化物，然后醚化脂肪酸烷氧基化物。

公开(公告)号：US20150225674A1

公开(公告)日：2015-08-13

申请号：US14426362

申请日：2013-09-05

Applicant: Stepan Company

Inventor： Ronald A. Masters ,  Wilma Gorman

IPC: C11D3/32 ,  C11D3/20

CPC classification number: C11D3/32 ,  C11D1/02 ,  C11D1/29 ,  C11D1/521 ,  C11D1/65 ,  C11D1/66 ,  C11D1/72 ,  C11D1/83 ,  C11D1/835 ,  C11D1/94 ,  C11D3/2082 ,  C11D3/2086

Abstract: Aqueous hard surface cleaners and concentrates are disclosed. In one aspect, the cleaners comprise water, a monounsaturated C8-C14 fatty N,N-dialkylamide, and at least one anionic, cationic, nonionic, or amphoteric surfactant. The cleaners have a pH within the range of 6.0 to 9.0. Dilutable hard surface cleaner concentrates comprising the monounsaturated N,N-dialkylamide and a surfactant are also disclosed. Also included are aqueous hard surface cleaners which comprise a monounsaturated N,N-dialkylamide, and which by measure of ASTM D4488-95 A5 soil, provide superior percent cleaning at a pH less than 10 than they do at pH 10 and higher. Surprisingly, when a monounsaturated C8-C14 fatty N,N-dialkylamide is included in the aqueous hard surface cleaner or concentrate, rapid and thorough cleaning performance can be achieved even at relatively neutral pH. Consequently, the hard surface cleaners are effective on greasy soils, including baked-on soils, despite their low alkalinity.

Abstract translation: 公开了水性硬表面清洁剂和浓缩物。 一方面，清洁剂包括水，单不饱和C8-C14脂肪N，N-二烷基酰胺和至少一种阴离子，阳离子，非离子或两性表面活性剂。 清洁剂的pH值在6.0至9.0的范围内。 还公开了包含单不饱和N，N-二烷基酰胺和表面活性剂的可稀释的硬表面清洁剂浓缩物。 还包括含有单不饱和N，N-二烷基酰胺的水性硬表面清洁剂，并且通过测量ASTM D4488-95 A5土壤，在比pH10和更高的pH小于10的pH下提供优异的百分比清洗。 令人惊奇的是，当含水硬质表面清洁剂或浓缩物中包含单不饱和C8-C14脂肪N，N-二烷基酰胺时，即使在相对中性的pH下也能实现快速彻底的清洗性能。 因此，硬表面清洁剂对油腻的土壤（包括烤土壤）有效，尽管它们的碱度低。