公开(公告)号：US06956094B2

公开(公告)日：2005-10-18

申请号：US10772823

申请日：2004-02-05

Applicant: Simon Mawson ,  Sun-Chueh Kao ,  Tae Hoon Kwalk ,  Timothy Roger Lynn ,  David H. McConville ,  Matthew Gary McKee ,  John Francis Szul ,  Kersten Anne Terry ,  Timothy T. Wenzel ,  Mark Gregory Goode ,  John Henry Oskam ,  Robert J. Jorgensen ,  Robert Harold Vogel

Inventor： Simon Mawson ,  Sun-Chueh Kao ,  Tae Hoon Kwalk ,  Timothy Roger Lynn ,  David H. McConville ,  Matthew Gary McKee ,  John Francis Szul ,  Kersten Anne Terry ,  Timothy T. Wenzel ,  Mark Gregory Goode ,  John Henry Oskam ,  Robert J. Jorgensen ,  Robert Harold Vogel

IPC: C08F2/00 ,  C08F2/34 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F210/16 ,  C08F12/06

CPC classification number: C08F10/00 ,  C08F4/659 ,  C08F4/65912 ,  C08F4/65925 ,  C08F210/16 ,  Y10S526/905 ,  Y10S526/943 ,  C08F4/65904 ,  C08F4/65916 ,  C08F2/00 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/24 ,  C08F2500/18 ,  C08F2500/26

Abstract: The invention provides for polymerization catalyst compositions, and for methods for introducing the catalyst compositions into a polymerization reactor. More particularly, the method combines a catalyst component containing slurry and a catalyst component containing solution to form the completed catalyst composition for introduction into the polymerization reactor. The invention is also directed to methods of preparing the catalyst component slurry, the catalyst component solution and the catalyst compositions, to methods of controlling the properties of polymer products utilizing the catalyst compositions, and to polymers produced therefrom.

Abstract translation: 本发明提供聚合催化剂组合物以及用于将催化剂组合物引入聚合反应器的方法。 更具体地说，该方法结合了含催化剂组分的浆料和含催化剂组分的溶液以形成用于引入聚合反应器的完成的催化剂组合物。 本发明还涉及制备催化剂组分浆料，催化剂组分溶液和催化剂组合物的方法，以及使用该催化剂组合物控制聚合物产品性能的方法以及由其制备的聚合物。

公开(公告)号：US06605675B2

公开(公告)日：2003-08-12

申请号：US09729550

申请日：2000-12-04

Applicant: Simon Mawson ,  Sun-Chueh Kao ,  Tae Hoon Kwalk ,  Timothy Roger Lynn ,  David H. McConville ,  Matthew Gary McKee ,  John Francis Szul ,  Kersten Anne Terry ,  Timothy T. Wenzel ,  Mark Gregory Goode ,  John Henry Oskam ,  Robert J. Jorgensen ,  Robert Harold Vogel

Inventor： Simon Mawson ,  Sun-Chueh Kao ,  Tae Hoon Kwalk ,  Timothy Roger Lynn ,  David H. McConville ,  Matthew Gary McKee ,  John Francis Szul ,  Kersten Anne Terry ,  Timothy T. Wenzel ,  Mark Gregory Goode ,  John Henry Oskam ,  Robert J. Jorgensen ,  Robert Harold Vogel

IPC: C08F444

CPC classification number: B01J8/1827 ,  B01J4/002 ,  B01J2219/00108 ,  C08F4/659 ,  C08F4/65912 ,  C08F4/65925 ,  C08F10/00 ,  C08F210/16 ,  Y10S526/943 ,  C08F4/65916 ,  C08F4/65904 ,  C08F2/00 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/24 ,  C08F2500/18 ,  C08F2500/26

Abstract: The invention provides for polymerization catalyst compositions, and for methods for introducing the catalyst compositions into a polymerization reactor. More particularly, the method combines a catalyst component containing slurry and a catalyst component containing solution to form the completed catalyst composition for introduction into the polymerization reactor. The invention is also directed to methods of preparing the catalyst component slurry, the catalyst component solution and the catalyst compositions, to methods of controlling the properties of polymer products utilizing the catalyst compositions, and to polymers produced therefrom.

公开(公告)号：US06369174B1

公开(公告)日：2002-04-09

申请号：US09392417

申请日：1999-09-09

Applicant: Timothy T. Wenzel ,  David James Schreck ,  Thomas H. Peterson

Inventor： Timothy T. Wenzel ,  David James Schreck ,  Thomas H. Peterson

IPC: C08F200

CPC classification number: C08F110/02 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  Y10S526/901 ,  Y10S526/943 ,  C08F2/40

Abstract: The present invention relates to the use of at least one solid compound that when used with a polymerization catalyst in a polymerization process results in a phase change of the solid compound to a liquid that renders the polymerization catalyst substantially or completely inactive.

Abstract translation: 本发明涉及至少一种固体化合物的用途，当在聚合过程中与聚合催化剂一起使用时，固体化合物与使聚合催化剂基本上或完全无活性的液体相变。

公开(公告)号：US08785551B2

公开(公告)日：2014-07-22

申请号：US12962800

申请日：2010-12-08

Applicant: Daniel J. Arriola ,  Edmund M. Carnahan ,  Yunwa Wilson Cheung ,  David D. Devore ,  David D. Graf ,  Phillip D. Hustad ,  Roger L. Kuhlman ,  Colin Li Pi Shan ,  Benjamin C. Poon ,  Gordon R. Roof ,  James C. Stevens ,  Pamela J. Stirn ,  Timothy T. Wenzel

Inventor： Daniel J. Arriola ,  Edmund M. Carnahan ,  Yunwa Wilson Cheung ,  David D. Devore ,  David D. Graf ,  Phillip D. Hustad ,  Roger L. Kuhlman ,  Colin Li Pi Shan ,  Benjamin C. Poon ,  Gordon R. Roof ,  James C. Stevens ,  Pamela J. Stirn ,  Timothy T. Wenzel

IPC: C08F255/02 ,  C08F255/00 ,  C08F293/00

CPC classification number: B32B27/327 ,  B32B27/06 ,  B32B27/32 ,  C08F4/659 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65925 ,  C08F4/65927 ,  C08F10/00 ,  C08F10/14 ,  C08F110/02 ,  C08F210/14 ,  C08F210/16 ,  C08F295/00 ,  C08F297/00 ,  C08F297/08 ,  C08F297/083 ,  C08F297/086 ,  C08F2410/01 ,  C08F2410/04 ,  C08F2420/02 ,  C08L23/02 ,  C08L23/06 ,  C08L23/0815 ,  C08L23/0853 ,  C08L23/10 ,  C08L53/00 ,  C08L53/005 ,  Y10T428/24942 ,  Y10T428/24992 ,  Y10T428/2826 ,  Y10T428/31573 ,  Y10T428/31587 ,  C08F2/38 ,  C08F4/65904 ,  C08L2666/06 ,  C08F2500/09 ,  C08F2500/03 ,  C08F4/64148 ,  C08F4/64193 ,  C08F4/64048 ,  C08F4/6411 ,  C08F4/64144 ,  C08F2500/08 ,  C08F4/64113 ,  C08L2666/02 ,  C08L2666/04 ,  C08F2500/12 ,  C08F2500/20 ,  C08F210/08 ,  C08F2500/11 ,  C08F2500/21 ,  C08F210/02 ,  C08F212/08 ,  C08F232/02 ,  C08F232/08

Abstract: A composition for use in forming a multi-block copolymer, said copolymer containing therein two or more segments or blocks differing in chemical or physical properties, a polymerization process using the same, and the resulting polymers, wherein the composition comprises the admixture or reaction product resulting from combining: (A) a first metal complex olefin polymerization catalyst, (B) a second metal complex olefin polymerization catalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by catalyst (A) under equivalent polymerization conditions, and (C) a chain shuttling agent.

公开(公告)号：US08710143B2

公开(公告)日：2014-04-29

申请号：US13562600

申请日：2012-07-31

Applicant: Daniel J. Arriola ,  Edmund M. Carnahan ,  Yunwa Wilson Cheung ,  David D. Devore ,  David D. Graf ,  Phillip D. Hustad ,  Roger L. Kuhlman ,  Colin Li Pi Shan ,  Benjamin C. Poon ,  Gordon R. Roof ,  James C. Stevens ,  Pamela J. Stirn ,  Timothy T. Wenzel

Inventor： Daniel J. Arriola ,  Edmund M. Carnahan ,  Yunwa Wilson Cheung ,  David D. Devore ,  David D. Graf ,  Phillip D. Hustad ,  Roger L. Kuhlman ,  Colin Li Pi Shan ,  Benjamin C. Poon ,  Gordon R. Roof ,  James C. Stevens ,  Pamela J. Stirn ,  Timothy T. Wenzel

IPC: C08L53/00 ,  C08L23/08

CPC classification number: B32B27/327 ,  B32B27/06 ,  B32B27/32 ,  C08F4/659 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65925 ,  C08F4/65927 ,  C08F10/00 ,  C08F10/14 ,  C08F110/02 ,  C08F210/14 ,  C08F210/16 ,  C08F295/00 ,  C08F297/00 ,  C08F297/08 ,  C08F297/083 ,  C08F297/086 ,  C08F2410/01 ,  C08F2410/04 ,  C08F2420/02 ,  C08L23/02 ,  C08L23/06 ,  C08L23/0815 ,  C08L23/0853 ,  C08L23/10 ,  C08L53/00 ,  C08L53/005 ,  Y10T428/24942 ,  Y10T428/24992 ,  Y10T428/2826 ,  Y10T428/31573 ,  Y10T428/31587 ,  C08F2/38 ,  C08F4/65904 ,  C08L2666/06 ,  C08F2500/09 ,  C08F2500/03 ,  C08F4/64148 ,  C08F4/64193 ,  C08F4/64048 ,  C08F4/6411 ,  C08F4/64144 ,  C08F2500/08 ,  C08F4/64113 ,  C08L2666/02 ,  C08L2666/04 ,  C08F2500/12 ,  C08F2500/20 ,  C08F210/08 ,  C08F2500/11 ,  C08F2500/21 ,  C08F210/02 ,  C08F212/08 ,  C08F232/02 ,  C08F232/08

Abstract: A composition for use in forming a multi-block copolymer, said copolymer containing therein two or more segments or blocks differing in chemical or physical properties, a polymerization process using the same, and the resulting polymers, wherein the composition comprises the admixture or reaction product resulting from combining: (A) a first metal complex olefin polymerization catalyst, (B) a second metal complex olefin polymerization catalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by catalyst (A) under equivalent polymerization conditions, and (C) a chain shuttling agent.

Abstract translation: 一种用于形成多嵌段共聚物的组合物，所述共聚物中含有两个或更多个化学或物理性质不同的链段或嵌段，使用该多嵌段共聚物的聚合方法和所得聚合物，其中组合物包含混合物或反应产物 由（A）第一金属络合物烯烃聚合催化剂，（B）能够在等效聚合条件下制备由催化剂（A）制备的聚合物在化学或物理性质上不同的聚合物的第二金属络合物烯烃聚合催化剂，以及 （C）链式穿梭剂。

公开(公告)号：US08415434B2

公开(公告)日：2013-04-09

申请号：US12978006

申请日：2010-12-23

Applicant: Daniel J. Arriola ,  Edmund M. Carnahan ,  David D. Devore ,  Phillip D. Hustad ,  Brian A. Jazdzewski ,  Roger L. Kuhlman ,  Francis J. Timmers ,  Timothy T. Wenzel

Inventor： Daniel J. Arriola ,  Edmund M. Carnahan ,  David D. Devore ,  Phillip D. Hustad ,  Brian A. Jazdzewski ,  Roger L. Kuhlman ,  Francis J. Timmers ,  Timothy T. Wenzel

IPC: C08F255/00 ,  C08F255/02

CPC classification number: C08F297/08 ,  C08F4/659 ,  C08F4/65908 ,  C08F4/6592 ,  C08F4/65927 ,  C08F10/00 ,  C08F210/16 ,  C08F4/6492 ,  C08F4/65912 ,  C08F2/38 ,  C08F210/14 ,  C08F2/001 ,  C08F4/64048 ,  C08F4/64144 ,  C08F4/64148 ,  C08F4/64193

Abstract: A polymerization process and the resulting polymer composition, said process comprising polymerizing one or more addition polymerizable monomers and a polymerizable shuttling agent in the presence of at least one addition polymerization catalyst comprising a metal compound or complex and a cocatalyst under conditions characterized by the formation of a branched polymer, preferably comprising pseudo-block molecular architecture.

Abstract translation: 聚合方法和所得聚合物组合物，所述方法包括在至少一种包含金属化合物或络合物和助催化剂的加成聚合催化剂的存在下，聚合一种或多种可加聚单体和可聚合穿梭剂， 支链聚合物，优选包括伪嵌段分子结构。

公开(公告)号：US07981992B2

公开(公告)日：2011-07-19

申请号：US11817371

申请日：2006-01-30

Applicant: Daniel J. Arriola ,  Edmund M. Carnahan ,  David D. Devore ,  Phillip D. Hustad ,  Roger L. Kuhlman ,  Timothy T. Wenzel

Inventor： Daniel J. Arriola ,  Edmund M. Carnahan ,  David D. Devore ,  Phillip D. Hustad ,  Roger L. Kuhlman ,  Timothy T. Wenzel

IPC: C08F2/38 ,  C08F210/06 ,  C08F210/14 ,  C08F4/646

CPC classification number: C08F210/06 ,  C08F4/659 ,  C08F4/65912 ,  C08F4/65927 ,  C08F10/00 ,  C08F110/06 ,  C08F110/14 ,  C08F297/06 ,  C08F297/08 ,  C08F2410/01 ,  C08F2410/04 ,  C08L23/10 ,  C08L23/20 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2308/00 ,  C08F4/61904 ,  C08F2/38 ,  C08L2666/06 ,  C08F210/14 ,  C08F2500/15 ,  C08F2500/03 ,  C08F4/64144 ,  C08F4/64048 ,  C08F4/64165 ,  C08F4/7042 ,  C08F4/7006

Abstract: Copolymers, especially multi-block copolymer containing therein two or more segments or blocks, are prepared by polymerizing propylene, 4-methyl-1-pentene, or another C4-8 α-olefin in the presence of a composition comprising the admixture or reaction product resulting from combining: (A) a first metal complex olefin polymerization catalyst, (B) a second metal complex olefin polymerization catalyst capable of preparing polymers having increased incidence of regio-irregular branching compared to the polymer prepared by catalyst (A) under equivalent polymerization conditions, and (C) a chain shuttling agent.

Abstract translation: 通过在包含混合物或反应产物的组合物存在下聚合丙烯，4-甲基-1-戊烯或其它C 4-8α-烯烃来制备共聚物，特别是其中含有两个或多个链段或嵌段的多嵌段共聚物 由（A）第一金属络合物烯烃聚合催化剂组成，（B）第二金属络合物烯烃聚合催化剂，其能够制备与在等效聚合反应中由催化剂（A）制备的聚合物相比，区域不规则分支的发生率增加的聚合物 条件，（C）链式穿梭剂。

公开(公告)号：US07479529B2

公开(公告)日：2009-01-20

申请号：US11633197

申请日：2006-12-04

Applicant: Timothy T. Wenzel ,  Zondra Dee Dixon

Inventor： Timothy T. Wenzel ,  Zondra Dee Dixon

IPC: B01J31/22 ,  C08F4/60 ,  C08F4/606

CPC classification number: C08F10/00 ,  C07F7/003 ,  C08F210/16 ,  C08F210/14 ,  C08F4/64148

Abstract: A catalyst composition and method for olefin polymerization are provided. In one aspect, the catalyst composition is represented by the formula αaβbγgMXn wherein M is a metal; X is a halogenated aryloxy group; β and γ are groups that each comprise at least one Group 14 to Group 16 atom; α is a linking moiety that forms a chemical bond to each of β and γ; and a, b, g, and n are each integers from 1 to 4.

Abstract translation: 提供了一种用于烯烃聚合的催化剂组合物和方法。 在一个方面，催化剂组合物由式alphamatabgammagMXn表示，其中M是金属; X是卤代芳氧基; β和γ是各自包含至少一个第14族至第16族原子的基团; α是与β和γ各自形成化学键的连接部分; a，b，g和n分别为1〜4的整数。

公开(公告)号：US20080275189A1

公开(公告)日：2008-11-06

申请号：US12065861

申请日：2006-09-14

Applicant: Edmund M. Carnahan ,  Phillip D. Hustad ,  Brian A. Jazdzewski ,  Roger L. Kuhlman ,  Timothy T. Wenzel

Inventor： Edmund M. Carnahan ,  Phillip D. Hustad ,  Brian A. Jazdzewski ,  Roger L. Kuhlman ,  Timothy T. Wenzel

IPC: C08L23/06 ,  C08F110/02 ,  C08F4/76

CPC classification number: C08F10/00 ,  C08F4/659 ,  C08F4/65908 ,  C08F4/6592 ,  C08F4/65927 ,  C08F210/16 ,  C08F297/00 ,  C08F2410/01 ,  C08L23/0815 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2308/00 ,  C08L2314/06 ,  C08F2/38 ,  C08F4/65912 ,  C08L2666/06 ,  C08F210/14 ,  C08F2500/05 ,  C08F4/64048 ,  C08F4/64193 ,  C08F4/64148 ,  C08F4/64144

Abstract: A process for the polymerization of one or more addition polymerizable monomers and the resulting polymer composition, said process comprising contacting an addition polymerizable monomer or mixture of monomers in a reactor or reactor zone with a composition comprising at least one polymerization catalyst and a cocatalyst under polymerization conditions, characterized in that at least a portion of said polymerization is conducted in the presence of a multi-centered shuttling agent thereby causing the composition to have a bimodal molecular weight distribution.

Abstract translation: 一种用于聚合一种或多种可加聚单体和所得聚合物组合物的方法，所述方法包括在反应器或反应器区域中将可加聚单体或单体混合物与包含至少一种聚合催化剂和助催化剂的组合物在聚合反应 条件，其特征在于所述聚合的至少一部分在多中心穿梭剂的存在下进行，从而使组合物具有双峰分子量分布。

公开(公告)号：US20080262175A1

公开(公告)日：2008-10-23

申请号：US11817371

申请日：2006-01-30

Applicant: Daniel J. Arriola ,  Edmand M. Carnahan ,  David D. Devore ,  Phillip D. Hustad ,  Roger L. Kuhlman ,  Timothy T. Wenzel

Inventor： Daniel J. Arriola ,  Edmand M. Carnahan ,  David D. Devore ,  Phillip D. Hustad ,  Roger L. Kuhlman ,  Timothy T. Wenzel

IPC: C08F210/06 ,  C08F210/04 ,  C08F210/14

CPC classification number: C08F210/06 ,  C08F4/659 ,  C08F4/65912 ,  C08F4/65927 ,  C08F10/00 ,  C08F110/06 ,  C08F110/14 ,  C08F297/06 ,  C08F297/08 ,  C08F2410/01 ,  C08F2410/04 ,  C08L23/10 ,  C08L23/20 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2308/00 ,  C08F4/61904 ,  C08F2/38 ,  C08L2666/06 ,  C08F210/14 ,  C08F2500/15 ,  C08F2500/03 ,  C08F4/64144 ,  C08F4/64048 ,  C08F4/64165 ,  C08F4/7042 ,  C08F4/7006

Abstract: Copolymers, especially multi-block copolymer containing therein two or more segments or blocks, are prepared by polymerizing propylene, 4-methyl-1-pentene, or another C4-8 α-olefin in the presence of a composition comprising the admixture or reaction product resulting from combining: (A) a first metal complex olefin polymerization catalyst, (B) a second metal complex olefin polymerization catalyst capable of preparing polymers having increased incidence of regio-irregular branching compared to the polymer prepared by catalyst (A) under equivalent polymerization conditions, and (C) a chain shuttling agent.

Abstract translation: 共聚物，特别是含有两个或多个链段或嵌段的多嵌段共聚物，通过在丙烯，4-甲基-1-戊烯或另一种C 4-8α-烯烃存在下， 一种组合物，其包含通过组合得到的混合物或反应产物：（A）第一金属络合物烯烃聚合催化剂，（B）与制备的聚合物相比，能够制备区域不规则分支的发生率增加的聚合物的第二金属络合物烯烃聚合催化剂 通过催化剂（A）在等同的聚合条件下，和（C）链穿梭剂。