公开(公告)号：US08916620B2

公开(公告)日：2014-12-23

申请号：US13591077

申请日：2012-08-21

Applicant: Warren A. Kaplan ,  Angelo R. Gabbianelli ,  David J. Norberg

Inventor： Warren A. Kaplan ,  Angelo R. Gabbianelli ,  David J. Norberg

IPC: C08G18/09

CPC classification number: C08J9/0066 ,  C08G18/4202 ,  C08G18/4208 ,  C08G18/4288 ,  C08G2101/0025 ,  C08G2101/005 ,  C08G2101/0083 ,  C08G2105/02 ,  C08J9/141 ,  C08J2375/04 ,  C08K3/32 ,  C08K5/49

Abstract: A method for improving the thermal stability of polyurethane-modified polyisocyanurate (PU-PIR) foams is provided. Moreover, a process for producing the PU-PIR foams exhibiting improved thermal stability is provided. The foams have incorporated therein a high molecular weight ammonium polyphosphate (APP). APP is employed as a partial or complete substitute for flame retardants conventionally employed in PU-PIR foams. The foams of the invention exhibit excellent and improved thermal stability characteristics as compared to foams to which no APP has been added.

Abstract translation: 提供了改善聚氨酯改性聚异氰脲酸酯（PU-PIR）泡沫体的热稳定性的方法。 此外，提供了表现出改善的热稳定性的PU-PIR泡沫体的制造方法。 泡沫中掺有高分子量多磷酸铵（APP）。 APP用作PU-PIR泡沫中常规使用的阻燃剂的部分或完全替代物。 与没有添加APP的泡沫相比，本发明的泡沫体显示出优异和改善的热稳定性特性。

公开(公告)号：US08835562B2

公开(公告)日：2014-09-16

申请号：US12498778

申请日：2009-07-07

Applicant: Gregory Paul Dado ,  Dale Lee Handlin, Jr. ,  Carl Lesley Willis

Inventor： Gregory Paul Dado ,  Dale Lee Handlin, Jr. ,  Carl Lesley Willis

IPC: C08F8/36 ,  C08F297/04 ,  C08C19/20

CPC classification number: C08L53/025 ,  C08F8/36 ,  C08F2800/20 ,  C08G81/022 ,  C08L2201/56 ,  C08F297/044 ,  C08F8/04

Abstract: Improved methods for preparing sulfonated block polymers with acyl sulfates in non-halogenated aliphatic solvents are provided. The methods include the sulfonation of a precursor block polymer with an acyl sulfate in a reaction mixture further comprising at least one non-halogenated aliphatic solvent to form a sulfonated block polymer, wherein the initial concentration of the precursor block polymer is in the range of from about 0.1 wt % to a concentration that is below the limiting concentration of the precursor block polymer based on the total weight of the reaction mixture. A sulfonation degree of greater than about 1.0 milliequivalent sulfonic acid per gram sulfonated block polymer can be achieved substantially free of polymer precipitation and free of disabling gelation.

Abstract translation: 提供了在非卤代脂族溶剂中制备具有酰基硫酸盐的磺化嵌段聚合物的改进方法。 所述方法包括在还含有至少一种非卤代脂族溶剂的反应混合物中使用酰基硫酸酯磺化前体嵌段聚合物以形成磺化嵌段聚合物，其中前体嵌段聚合物的初始浓度范围为 约0.1重量％至低于前体嵌段聚合物的极限浓度的浓度，基于反应混合物的总重量。 可以实现大于约1.0毫当量磺酸/克磺化嵌段聚合物的磺化度，基本上不含聚合物沉淀并且没有失效的凝胶化。

公开(公告)号：US20130303693A1

公开(公告)日：2013-11-14

申请号：US13947730

申请日：2013-07-22

Applicant: Stepan Company

Inventor： Jean M. Seibold ,  John C. Hutchinson ,  Gary R. Luebke ,  Robert A. Krueger ,  Jungsik Lee

IPC: C08K5/13 ,  C08K5/521

CPC classification number: C08K5/13 ,  C08K5/06 ,  C08K5/41 ,  C08K5/521 ,  C11D1/00 ,  C11D1/146 ,  C11D1/22 ,  C11D1/72

Abstract: The present technology generally relates to emulsion polymer latexes, particularly those used in pressure sensitive adhesives, paints and coatings. Surfactant compositions of the present technology for use in forming at least one emulsion polymer latex comprise at least one branched surfactant, at least one sterically bulky surfactant, or a mixture of branched and sterically bulky surfactants. One preferred surfactant composition comprises at least one alkoxylated polyaryl substituted aromatic compound or at least one alkoxylated polyalkyl substituted aromatic compound. Another preferred surfactant composition comprises a mixture of at least one branched-alkyl sulfate and at least one ethoxylated polystyrylphenol. Another preferred surfactant composition comprises at least one sulfated polystyrylphenol.

Abstract translation: 本技术通常涉及乳液聚合物胶乳，特别是用于压敏粘合剂，油漆和涂料的乳液聚合物胶乳。 用于形成至少一种乳液聚合物胶乳的本技术的表面活性剂组合物包含至少一种支化表面活性剂，至少一种空间庞大表面活性剂，或支链和空间庞大表面活性剂的混合物。 一种优选的表面活性剂组合物包含至少一种烷氧基化聚芳基取代的芳族化合物或至少一种烷氧基化聚烷基取代的芳族化合物。 另一种优选的表面活性剂组合物包含至少一种支链烷基硫酸盐和至少一种乙氧基化聚苯乙烯基苯酚的混合物。 另一种优选的表面活性剂组合物包含至少一种硫酸化聚苯乙烯基苯酚。

公开(公告)号：US20130225473A1

公开(公告)日：2013-08-29

申请号：US13880007

申请日：2011-10-25

Applicant: Dave R Allen ,  Randal J Bernhardt ,  Aaron Brown ,  Gary Luebke ,  Renee Luka ,  Andrew D. Malec ,  Ronald A. Masters ,  Patti Skelton ,  Brian Sook ,  Jeremy Aaron Weitgenant ,  Patrick Shane Wolfe

Inventor： Dave R Allen ,  Randal J Bernhardt ,  Aaron Brown ,  Gary Luebke ,  Renee Luka ,  Andrew D. Malec ,  Ronald A. Masters ,  Patti Skelton ,  Brian Sook ,  Jeremy Aaron Weitgenant ,  Patrick Shane Wolfe

IPC: C07C303/32 ,  C07C309/17

CPC classification number: C07C303/32 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N33/12 ,  A01N37/18 ,  A01N37/44 ,  A01N41/04 ,  A61K8/416 ,  A61K8/42 ,  A61K8/44 ,  A61K8/466 ,  A61K8/92 ,  A61K2800/10 ,  A61Q5/12 ,  A61Q19/00 ,  A61Q19/10 ,  A62D1/0071 ,  B01F17/0028 ,  B01F17/0057 ,  C07C69/533 ,  C07C69/593 ,  C07C209/12 ,  C07C211/21 ,  C07C219/08 ,  C07C231/12 ,  C07C237/16 ,  C07C303/18 ,  C07C309/17 ,  C08G65/2615 ,  C08K5/01 ,  C08K5/20 ,  C09K8/00 ,  C09K8/524 ,  C09K8/74 ,  C09K15/28 ,  C11C3/00 ,  C11C3/003 ,  C11C3/08 ,  C11D1/002 ,  C11D1/04 ,  C11D1/143 ,  C11D1/28 ,  C11D1/62 ,  C11D1/652 ,  C11D1/74 ,  C11D1/83 ,  C11D1/90 ,  C11D1/92 ,  C11D1/94 ,  C11D3/48 ,  C07C211/63 ,  C07C211/64 ,  C07C233/38 ,  C07C309/14 ,  A01N33/18 ,  A01N39/04 ,  A01N43/653 ,  A01N51/00 ,  A01N57/20 ,  A01N43/40 ,  A01N43/56 ,  A01N53/00

Abstract: Sulfonate compositions are disclosed. The compositions include alkanesulfonates, alkenesulfonates, sultones, and hydroxy-substituted alkanesulfonates. The sulfonates comprise a reaction product of a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives with a sulfonating or sulfitating agent. In one aspect, the sulfonate composition is a sulfo-estolide made by reacting a metathesis-derived C10-C17 monounsaturated acid or octadecene-1,18-dioic acid with a sulfonating agent, optionally in the presence of a saturated fatty acid. The sulfonates are valuable for a wide variety of end uses, including cleaners, fabric treatment, hair conditioning, personal care (liquid cleansing products, conditioning bars, oral care products), paint additives, antimicrobial compositions, agricultural uses, and oil field applications.

Abstract translation: 公开了磺酸盐组合物。 组合物包括烷基磺酸盐，烷基磺酸盐，磺内酯和羟基取代的烷基磺酸盐。 磺酸盐包含由复分解衍生的C10-C17单不饱和酸，十八碳烯-1,18-二酸或其酯衍生物与磺化或硫酸化剂的反应产物。 在一个方面，磺酸盐组合物是通过使选择性衍生的C10-C17单不饱和酸或十八碳烯-1,18-二酸与磺化剂任选在饱和脂肪酸存在下反应而制备的磺基 - 内酯化物。 磺化物对于各种最终用途是有价值的，包括清洁剂，织物处理，头发调理，个人护理（液体清洁产品，调理棒，口腔护理产品），涂料添加剂，抗微生物组合物，农业用途和油田应用。

公开(公告)号：US20130225469A1

公开(公告)日：2013-08-29

申请号：US13879792

申请日：2011-10-25

Applicant: Dave R Allen ,  Randal J Bernhardt ,  Aaron Brown ,  Ronald A. Masters ,  Patrick Shane Wolfe ,  Lena Titievsky

Inventor： Dave R Allen ,  Randal J Bernhardt ,  Aaron Brown ,  Ronald A. Masters ,  Patrick Shane Wolfe ,  Lena Titievsky

IPC: C11D1/28 ,  C11D1/83 ,  C11D1/94 ,  C11D1/92 ,  C11D1/04

CPC classification number: C11C3/08 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N33/12 ,  A01N37/18 ,  A01N37/44 ,  A01N41/04 ,  A61K8/416 ,  A61K8/42 ,  A61K8/44 ,  A61K8/466 ,  A61K8/92 ,  A61Q5/12 ,  A61Q19/10 ,  A62D1/0071 ,  B01F17/0028 ,  B01F17/0057 ,  C07C6/04 ,  C07C41/03 ,  C07C43/11 ,  C07C67/26 ,  C07C69/533 ,  C07C69/593 ,  C07C209/12 ,  C07C211/21 ,  C07C219/08 ,  C07C231/12 ,  C07C237/16 ,  C07C303/18 ,  C08G65/2615 ,  C08K5/01 ,  C08K5/20 ,  C09K8/00 ,  C09K15/28 ,  C11C3/00 ,  C11D1/002 ,  C11D1/04 ,  C11D1/28 ,  C11D1/62 ,  C11D1/652 ,  C11D1/74 ,  C11D1/83 ,  C11D1/90 ,  C11D1/92 ,  C11D1/94 ,  C11D3/48 ,  C07C211/63 ,  C07C211/64 ,  C07C233/38 ,  C07C309/14 ,  A01N33/18 ,  A01N39/04 ,  A01N43/653 ,  A01N51/00 ,  A01N57/20 ,  A01N43/40 ,  A01N43/56 ,  A01N53/00

Abstract: Aqueous hard surface cleaner compositions derived from metathesized natural oil feedstocks are disclosed. In one aspect, the compositions comprise at least one anionic surfactant derived from a metathesis-derived C10-C17 monounsaturated acid, 5 octadecene-1,18-dioic acid, or their ester derivatives. In another aspect, aqueous hard surface cleaners comprising at least one nonionic or amphoteric surfactant derived from a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives are disclosed. The aqueous cleaners noted above rival or outperform commercial baselines in a Gardner straight-line washability test. Industrial degreasers comprising a C10 or C12 amide solvent and derived from a metathesis-derived C10-C17 monounsaturated acid are superior to commercial standards.

Abstract translation: 公开了衍生自复分解天然油原料的水性硬表面清洁剂组合物。 一方面，组合物包含至少一种衍生自复分解衍生的C10-C17单不饱和酸，十八碳烯-1,18-二酸或其酯衍生物的阴离子表面活性剂。 在另一方面，公开了包含至少一种衍生自复分解衍生的C10-C17单不饱和酸，十八烯-1,18-二酸或其酯衍生物的非离子或两性表面活性剂的水性硬表面清洁剂。 在Gardner直线可洗性试验中，上述水性清洁剂在竞争对手或优于商业基线中得到了证实。 由C10或C12酰胺溶剂组成的衍生自复分解衍生的C10-C17单不饱和酸的工业脱脂剂优于商业标准。

公开(公告)号：US20130090399A1

公开(公告)日：2013-04-11

申请号：US13692507

申请日：2012-12-03

Applicant: Stepan Company

Inventor： Leo F. Hickey ,  Timothy Lambert ,  Chunhua Yao

IPC: C08G18/06

CPC classification number: C08G18/06 ,  C08G18/36 ,  C08G18/4288 ,  C08G18/6662 ,  C08G63/20 ,  C08G63/668 ,  C08G63/916 ,  C08G2101/0025 ,  C08G2101/005 ,  C08G2105/02 ,  C08J9/141 ,  C08J2375/06

Abstract: There are provided aromatic polyester polyol compositions comprising: (i) at least one aromatic acid component; (ii) at least one hydroxylated component; (iii) at least one functionalized natural oil component; and (iv) optionally at least one catalyst component for use in preparing foams. The aromatic polyester polyol compositions can be formed by esterification and/or transesterification. The present technology also provides a polyol blend for use in preparing foams wherein the polyol blend comprises (a) an aromatic polyester polyol formed by an interesterification reaction between (i) a phthalic acid based material; (ii) a hydroxylated material; and (iii) a hydrophobic material, wherein the hydrophobic material is present in an amount of from about 1% to about 50% by weight of the aromatic polyester polyol; and (b) a natural oil based polyol, wherein the hydrophobic material in the aromatic polyester polyol compatibilizes the natural oil based polyol to form a phase stable polyol blend.

Abstract translation: 提供了芳族聚酯多元醇组合物，其包含：（i）至少一种芳族酸组分; （ii）至少一种羟基化成分; （iii）至少一种官能化天然油组分; 和（iv）任选的至少一种用于制备泡沫的催化剂组分。 芳族聚酯多元醇组合物可以通过酯化和/或酯交换形成。 本技术还提供用于制备泡沫的多元醇共混物，其中多元醇共混物包含（a）通过（i）邻苯二甲酸基材料之间的酯交换反应形成的芳族聚酯多元醇; （ii）羟基化材料; 和（iii）疏水性材料，其中所述疏水性材料以所述芳族聚酯多元醇的约1％至约50％重​​量的量存在; 和（b）天然油基多元醇，其中芳族聚酯多元醇中的疏水性材料与天然油基多元醇相容，形成相稳定的多元醇共混物。

公开(公告)号：US08124577B2

公开(公告)日：2012-02-28

申请号：US12506930

申请日：2009-07-21

Applicant: Randal J. Bernhardt ,  Gregory P. Dado ,  Branko Sajic ,  Irene Shapiro

Inventor： Randal J. Bernhardt ,  Gregory P. Dado ,  Branko Sajic ,  Irene Shapiro

IPC: C11D1/28

CPC classification number: A61K8/466 ,  A61Q19/10

Abstract: Formulations of personal care compositions and personal care concentrate compositions containing sulfo-estolides are described. Personal care compositions of the present technology include liquid hand soaps, bath and shower washes, shampoos, 2-in-1 or 3-in-1 shampoos, antidandruff shampoo, facial cleaners, among others.

Abstract translation: 描述了含有磺基内酯的个人护理组合物和个人护理浓缩物组合物的制剂。 本技术的个人护理组合物包括液体手肥皂，洗浴和淋浴洗涤剂，洗发剂，2合1或3合1洗发剂，去头皮屑洗发剂，洗面奶等。

公开(公告)号：US08058223B2

公开(公告)日：2011-11-15

申请号：US12507018

申请日：2009-07-21

Applicant: Randal J. Bernhardt ,  Lourdes R. Alonso ,  Gregory P. Dado ,  Ronald A. Masters

Inventor： Randal J. Bernhardt ,  Lourdes R. Alonso ,  Gregory P. Dado ,  Ronald A. Masters

IPC: C11D1/28

CPC classification number: C11D3/386 ,  C11D1/008 ,  C11D1/123 ,  C11D1/28 ,  C11D3/38618 ,  C11D3/38627

Abstract: Sulfo-estolides and methods of making them are described. Useful methods include acid side bleaching, partial hydrogenation of the fatty acid, pretreatment of the fatty acid to provide color inhibition, acid side hydrolysis of the sulfo-estolides, or conversion of SHP to an essentially fully hydrolyzed product (HSHP) or a partially hydrolyzed product (PHSHP). Formulations and concentrated formulations of automatic dishwasher detergent or machine wash detergent compositions containing sulfo-estolides, among others, are also included.

Abstract translation: 描述了磺胺类药物及其制备方法。 有用的方法包括酸侧漂白，脂肪酸的部分氢化，脂肪酸的预处理以提供颜色抑制，磺基酯的酸侧水解，或将SHP转化成基本上完全水解的产物（HSHP）或部分水解 产品（PHSHP）。 还包括自动洗碗机洗涤剂或含有磺基甲壳素的机洗洗涤剂组合物的制剂和浓缩配方。

公开(公告)号：US08026206B2

公开(公告)日：2011-09-27

申请号：US12905874

申请日：2010-10-15

Applicant: Branko Sajic ,  Xue Min Dong ,  Carmen Matache ,  Christopher A. Gariepy

Inventor： Branko Sajic ,  Xue Min Dong ,  Carmen Matache ,  Christopher A. Gariepy

IPC: C11D1/835

CPC classification number: C11D1/62 ,  C11D1/40 ,  C11D1/645 ,  C11D3/0015 ,  C11D11/0094

Abstract: Disclosed are low solids and high viscosity fabric softener compositions and processes for preparing them. The composition contains from about 0.05% to about 10% by weight of a rheology modifying fabric softening active comprising at least one long chain amine of the present technology, a derivative thereof, or a mixture thereof, and from about 1% to 10% by weight of an additional fabric softening active dispersed in water.

Abstract translation: 公开了低固体和高粘度织物柔软剂组合物及其制备方法。 该组合物含有约0.05％至约10％重量的流变改性织物软化性活性剂，其包含本发明技术的至少一种长链胺，其衍生物或其混合物，和约1％至10％ 附加织物软化活性物质分散在水中的重量。

公开(公告)号：US07879790B2

公开(公告)日：2011-02-01

申请号：US12506861

申请日：2009-07-21

Applicant: Randal J. Bernhardt ,  Gregory P. Dado ,  Eddie I. Filipovic ,  Jeremy Aaron Weitgenant

Inventor： Randal J. Bernhardt ,  Gregory P. Dado ,  Eddie I. Filipovic ,  Jeremy Aaron Weitgenant

IPC: C11D1/28

CPC classification number: C07C303/06 ,  C07C303/22 ,  C11D1/123 ,  C11D1/28 ,  C11D3/0026 ,  C11D3/3788 ,  C07C309/17

Abstract: Sulfo-estolides and methods of making them are described. Also described are phase-stable compositions formed from mixtures of different salts of sulfo-estolides, particularly mixtures of sodium and potassium salts of sulfo-estolides, and methods of obtaining phase-stable sulfo-estolide mixed salt compositions. The sulfo-estolide mixed salt compositions can be used in detergent formulations, such as laundry detergents, household, industrial and institutional cleaning formulations, and person care products.

Abstract translation: 描述了磺胺类药物及其制备方法。 还描述了由磺基内酯的不同盐的混合物形成的相稳定组合物，特别是磺基 - 内酯的钠盐和钾盐的混合物，以及获得相稳定的磺基 - 内酯盐混合盐组合物的方法。 磺基 - 内酯混合盐组合物可用于洗涤剂配方中，例如衣物洗涤剂，家用，工业和机构清洁制剂以及人体护理产品。