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    Titania nanotube arrays, methods of manufacture, and photocatalytic conversion of carbon dioxide using same
    24.
    发明申请
    Titania nanotube arrays, methods of manufacture, and photocatalytic conversion of carbon dioxide using same 审中-公开
    二氧化钛纳米管阵列，制造方法和使用其的二氧化碳的光催化转化

    公开(公告)号：US20100213046A1

    公开(公告)日：2010-08-26

    申请号：US12655753

    申请日：2010-01-05

    申请人： Craig A. Grimes ,  Oomman K. Varghese ,  Maggie Paulose

    发明人： Craig A. Grimes ,  Oomman K. Varghese ,  Maggie Paulose

    IPC分类号： C01B31/00 ,  B01J27/24 ,  B01J21/18 ,  C01B3/00

    CPC分类号： C10G2/35 ,  B01J21/063 ,  B01J23/42 ,  B01J23/72 ,  B01J23/8926 ,  B01J27/24 ,  B01J35/004 ,  B01J35/06 ,  B01J37/347 ,  B01J37/348 ,  C10G2/33 ,  Y02E60/324

    摘要： Nitrogen-doped titania nanotubes exhibiting catalytic activity on exposure to any one or more of ultraviolet, visible, and/or infrared radiation, or combinations thereof are disclosed. The nanotube arrays may be co-doped with one or more nonmetals and may further include co-catalyst nanoparticles. Also, methods are disclosed for use of nitrogen-doped titania nanotubes in catalytic conversion of carbon dioxide alone or in admixture with hydrogen-containing gases such as water vapor and/or other reactants as may be present or desirable into products such as hydrocarbons and hydrocarbon-containing products, hydrogen and hydrogen-containing products, carbon monoxide and other carbon-containing products, or combinations thereof.

    摘要翻译： 公开了在暴露于紫外线，可见光和/或红外辐射中的任何一种或多种的情况下显示催化活性的氮掺杂的二氧化钛纳米管或其组合。 纳米管阵列可以与一种或多种非金属共掺杂，并且还可以包括助催化剂纳米颗粒。 此外，公开了使用氮掺杂二氧化钛纳米管单独或与含氢气体如水蒸汽和/或其它可能存在或需要的其它反应物（例如烃和烃）的催化转化的方法 含氢产物，一氧化碳和其它含碳产品，或其组合。

    Methods for synthesizing carbon nanotubes
    27.
    发明申请
    Methods for synthesizing carbon nanotubes 审中-公开
    合成碳纳米管的方法

    公开(公告)号：US20080159943A1

    公开(公告)日：2008-07-03

    申请号：US11821160

    申请日：2007-06-22

    申请人： Gang Gu ,  Lawrence Pan ,  Lian Zhang

    发明人： Gang Gu ,  Lawrence Pan ,  Lian Zhang

    IPC分类号： C01B31/02

    CPC分类号： B01J37/347 ,  B01J23/24 ,  B01J23/74 ,  B01J23/745 ,  B01J23/85 ,  B01J23/881 ,  B01J37/0238 ,  B01J37/08 ,  B01J37/14 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/162

    摘要： A catalyst material for carbon nanotube synthesis includes a uniform dispersion of host particles on a substrate. The host particles themselves include catalyst nanoparticles that are effective to catalyze nanotube syntheses reactions and provide nucleation sites. Methods for preparing catalyst materials include co-sputtering a catalytic species and a host species to form a precursor thin film on a substrate, followed by an oxidation reaction of the precursor thin film in air. The precursor thin film can be patterned on the substrate to limit the locations of the catalyst material to well-defined areas. Methods for nanotube synthesis employ CVD in conjunction with the catalyst materials of the invention. During the synthesis, the catalyst nanoparticles catalyze carbon nanotubes to grown from a carbon-containing gas.

    摘要翻译： 用于碳纳米管合成的催化剂材料包括主体颗粒在基底上的均匀分散。 主体颗粒本身包括有效催化纳米管合成反应并提供成核位点的催化剂纳米颗粒。 制备催化剂材料的方法包括共催化催化物质和主体物质，以在基底上形成前体薄膜，随后在空气中氧化前体薄膜。 可以在衬底上图案化前体薄膜，以将催化剂材料的位置限制到明确界定的区域。 纳米管合成方法与本发明的催化剂材料结合使用CVD。 在合成过程中，催化剂纳米粒子催化从含碳气体生长的碳纳米管。

    Method of Selectively Applying Carbon Nanotube Catalyst
    29.
    发明申请
    Method of Selectively Applying Carbon Nanotube Catalyst 审中-公开
    选择性应用碳纳米管催化剂的方法

    公开(公告)号：US20070265158A1

    公开(公告)日：2007-11-15

    申请号：US11547105

    申请日：2005-03-28

    申请人： Ayumi Mitsumori ,  Osamu Kumasaka ,  Makoto Okano ,  Tetsuya Imai

    发明人： Ayumi Mitsumori ,  Osamu Kumasaka ,  Makoto Okano ,  Tetsuya Imai

    IPC分类号： B01J37/34

    CPC分类号： B01J37/342 ,  B01J23/74 ,  B01J35/0033 ,  B01J37/0215 ,  B01J37/0238 ,  B01J37/347 ,  B82Y10/00 ,  B82Y30/00 ,  H01J9/025 ,  H01J2201/30469

    摘要： A method for applying a carbon nanotube growth catalyst to at least one specified location on a substrate surface of a substrate formed of conductive material, and the method includes a preparation step for preparing on the substrate a coating layer having a hole contacting the substrate surface at a location corresponding to the specified location. The method also includes a deposition step for forming by deposition a conical deposited material on a substrate surface portion contacting the hole by irradiating the substrate with electrically conductive material particles in a oblique direction from above the coating layer while rotating the substrate about a shaft perpendicular to the substrate surface, and for forming by deposition an eaves-like deposited layer which extends to close an opening of the hole. The method also includes a determination step for measuring a size of the opening in accordance with extension of the eaves-like deposited layer, and a catalyst applying step for applying the catalyst to a tip of the conical deposited material by way of irradiation of material particles of the catalyst via the opening when the opening is measured to have a specified size.

    摘要翻译： 一种将碳纳米管生长催化剂施加到由导电材料形成的基板的基板表面上的至少一个特定位置的方法，该方法包括制备步骤，用于在基板上制备具有与基板表面接触的孔的涂层 与指定位置相对应的位置。 所述方法还包括沉积步骤，用于通过在与所述孔接触的基底表面部分上沉积圆锥形沉积材料，通过从所述涂层上方沿倾斜方向照射所述基底导电材料颗粒，同时沿垂直于 衬底表面，并且用于通过沉积形成延伸以封闭孔的开口的檐状沉积层。 该方法还包括用于根据檐状沉积层的延伸来测量开口的尺寸的确定步骤，以及用于通过材料颗粒的照射将催化剂施加到锥形沉积材料的尖端的催化剂施加步骤 当开口被测量为具有特定尺寸时，该催化剂通过开口。