公开(公告)号：US20160347889A1

公开(公告)日：2016-12-01

申请号：US15116696

申请日：2015-02-10

Applicant: UNIVATION TECHOLOGIES, LLC

Inventor： Ching-Tai Lue ,  Francis C. Rix ,  C. Jeff Harlan ,  Laughlin G. McCullough

IPC: C08F210/16

CPC classification number: C08F210/16 ,  C07F17/00 ,  C08F2/00 ,  C08F2/34 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65925 ,  C08F4/65927 ,  C08F4/76 ,  C08F210/02 ,  C08F210/08 ,  C08F210/14 ,  C08F2410/02 ,  C08F2420/00 ,  C08F2420/01 ,  C08F2500/01 ,  C08F2500/02 ,  C08F2500/08 ,  C08F2500/09 ,  C08F2500/10 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/13 ,  C08F2500/18 ,  C08F2800/20 ,  C08J5/18 ,  C08J2323/08 ,  C08L23/0815 ,  C08F2500/03

Abstract: Catalyst systems and methods for making and using the same. A method of polymerizing olefins to produce a polyolefin polymer with a multimodal composition distribution, includes contacting ethylene and a comonomer with a catalyst system. The catalyst system includes a first catalyst compound and a second catalyst compound that are co-supported to form a commonly supported catalyst system. The first catalyst compound includes a compound with the general formula (C5HaR1b)(C5HcR2d)HfX2. The second catalyst compound includes at least one of the following general formulas: In both catalyst systems, the R groups can be independently selected from any number of substituents, including, for example, H, a hydrocarbyl group, a substituted hydrocarbyl group, or a heteroatom group, among others.

公开(公告)号：US09493593B2

公开(公告)日：2016-11-15

申请号：US14442527

申请日：2014-06-30

Applicant: LG CHEM, LTD.

Inventor： Sun Keun Kim ,  Sung Ho Park ,  Sung Cheol Yoon ,  Jun Seok Ko ,  Soo Young Choi

IPC: C08F210/18 ,  C08F236/20

CPC classification number: C08F210/18 ,  C08F4/65908 ,  C08F236/02 ,  C08F236/20 ,  C08F255/06 ,  C08F2420/02 ,  C08F2500/09 ,  C08F210/06 ,  C08F2500/25 ,  C08F2500/21 ,  C08F2500/17 ,  C08F2500/08 ,  C08F2500/03 ,  C08F4/6592

Abstract: The present invention relates to a long-chain branched elastic terpolymer capable of satisfying excellent processability and elasticity (flexibility) at the same time, which is obtained in the presence of a Group IV transition metal catalyst, and a preparation method thereof. The elastic terpolymer is a copolymer of ethylene, an alpha-olefin having 3 to 20 carbon atoms, and a diene, wherein i) its weight average molecular weight measured by GPC is 100,000 to 500,000, and ii) its LCB Index which is a ratio of 1st harmonics of storage modulus to 5th harmonics of storage modulus measured at 125° C. using a rubber process analyzer according to a LAOS (Large Angles of Oscillation and high Strains) method has a positive value.

Abstract translation: 本发明涉及在IV族过渡金属催化剂的存在下能够同时满足优异的加工性和弹性（柔软性）的长支链状弹性三元共聚物及其制备方法。 弹性三元共聚物是乙烯，具有3-20个碳原子的α-烯烃和二烯的共聚物，其中i）其通过GPC测量的重均分子量为100,000至500,000，和ii）其LCB指数，其比率 使用根据LAOS（大角度振荡和高应变）方法的橡胶过程分析仪，在125℃下测量的储能模量的1次谐波至5次谐波储能模量的积分值为正值。

公开(公告)号：US09481750B2

公开(公告)日：2016-11-01

申请号：US15044140

申请日：2016-02-16

Applicant: Chevron Phillips Chemical Company LP

Inventor： Jeffrey F. Greco

IPC: C08F4/6592 ,  C08F10/02 ,  C08F210/16 ,  C07F17/00 ,  C08F110/02 ,  C08L23/08 ,  C07F7/00 ,  C08F4/659

CPC classification number: C08F210/16 ,  C07F7/00 ,  C07F17/00 ,  C08F4/65904 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  C08F10/02 ,  C08F110/02 ,  C08F210/08 ,  C08F210/14 ,  C08L23/0815 ,  C08F4/025 ,  C08F2500/09 ,  C08F2500/12 ,  C08F2500/08 ,  C08F2500/03 ,  C08F2500/04

Abstract: Disclosed herein are catalyst compositions containing boron bridged, bis-indenyl metallocene compounds with an alkenyl substituent. These catalyst compositions can be used for the polymerization of olefins. For example, ethylene copolymers produced using these catalyst compositions can be characterized by a density less than 0.92 g/cm3 and a melt index greater than 25 g/10 min.

Abstract translation: 本文公开了含有桥连的具有烯基取代基的双茚基茂金属化合物的催化剂组合物。 这些催化剂组合物可用于烯烃的聚合。 例如，使用这些催化剂组合物生产的乙烯共聚物的特征可以是密度小于0.92g / cm 3，熔体指数大于25g / 10min。

公开(公告)号：US20160257772A1

公开(公告)日：2016-09-08

申请号：US15058375

申请日：2016-03-02

Applicant: EQUISTAR CHEMICALS, LP

Inventor： MICHAEL W LYNCH ,  Mark K. Reinking

IPC: C08F10/02 ,  B01J37/08 ,  B01J37/04 ,  B01J23/26 ,  B01J35/10

CPC classification number: C08F10/02 ,  B01J23/26 ,  B01J35/0006 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1042 ,  B01J35/1047 ,  B01J37/04 ,  B01J37/08 ,  C08F210/16 ,  C08F2410/01 ,  C08F4/69 ,  C08F210/14 ,  C08F2500/09 ,  C08F4/6222 ,  C08F4/6232

Abstract: The present disclosure relates to catalysts comprising two heterogeneous chromium catalysts for the polymerization of olefins are provided herein. The catalysts, as well as related compositions and methods using the same, may be used to for the production of polyolefins, including for the production of bimodal molecular weight distribution polyolefins, e.g., polyethylene and copolymers of ethylene and 1-hexene.

Abstract translation: 本公开涉及包含用于烯烃聚合的两种非均相铬催化剂的催化剂。 催化剂以及使用其的相关组合物和方法可用于生产聚烯烃，包括用于生产双峰分子量分布的聚烯烃，例如聚乙烯和乙烯与1-己烯的共聚物。

公开(公告)号：US09376549B2

公开(公告)日：2016-06-28

申请号：US14414825

申请日：2013-07-19

Applicant: Borealis AG

Inventor： Katja Klimke ,  Hermann Braun

IPC: C08L23/00 ,  C08K5/52 ,  C08F210/06 ,  C08F210/16 ,  C08F2/48 ,  C08F2/52 ,  C08F2/54 ,  C08F255/02 ,  C08F10/06 ,  C08L23/12 ,  C08L23/14 ,  C08K3/26 ,  C08K5/11 ,  C08L23/26

CPC classification number: C08K5/52 ,  C08F2/48 ,  C08F2/52 ,  C08F2/54 ,  C08F10/06 ,  C08F210/06 ,  C08F210/16 ,  C08F255/02 ,  C08K3/26 ,  C08K5/11 ,  C08L23/12 ,  C08L23/142 ,  C08L2023/42 ,  C08L2205/025 ,  C08L2207/07 ,  C08F110/06 ,  C08F2500/09 ,  C08F2500/11 ,  C08F2500/26 ,  C08F2500/12 ,  C08F2500/06

Abstract: Process for providing a polypropylene composition comprising a branched polypropylene in which a polypropylene with a melt flow rate MFR2 (230° C.) of more than 1.0 g/10 min is reacted with a thermally decomposing free radical-forming agent and optionally with a bifunctionally unsaturated monomer obtaining thereby the branched polypropylene, wherein the polypropylene composition has a F30 melt strength of more than 5.8 cN and a v30 melt extensibility of more than 200 mm/s.

Abstract translation: 提供包含支化聚丙烯的聚丙烯组合物的方法，其中熔体流动速率MFR 2（230℃）大于1.0g / 10分钟的聚丙烯与热分解自由基形成剂和任选的双功能 得到支链聚丙烯的不饱和单体，其中聚丙烯组合物具有大于5.8cN的F30熔体强度和超过200mm / s的v30熔体延展性。

公开(公告)号：US09334350B2

公开(公告)日：2016-05-10

申请号：US14639582

申请日：2015-03-05

Applicant: Chevron Phillips Chemical Company LP

Inventor： Max P. McDaniel ,  Ashish M. Sukhadia ,  Errun Ding ,  Chung Ching Tso ,  Albert P. Masino ,  Qing Yang ,  Lloyd W. Guatney ,  Guylaine St. Jean ,  Daniel G. Hert

IPC: C08F210/02 ,  C08F210/16 ,  C08F210/14 ,  C08J5/18 ,  C08L23/08

CPC classification number: C08F210/16 ,  C08F4/65916 ,  C08F4/65925 ,  C08F4/65927 ,  C08F210/14 ,  C08F2410/02 ,  C08F2500/05 ,  C08F2500/08 ,  C08F2500/09 ,  C08F2500/12 ,  C08J5/18 ,  C08J2323/08 ,  C08L23/0815 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2314/06 ,  C08F4/65904 ,  C08F2500/04 ,  C08F2500/07 ,  C08F2500/26

Abstract: Disclosed herein are broad molecular weight distribution olefin polymers having densities in the 0.895 to 0.930 g/cm3 range, and with improved impact and tear resistance. These polymers can have a ratio of Mw/Mn in the 8 to 35 range, a high load melt index in the 4 to 50 range, less than about 0.008 LCB per 1000 total carbon atoms, and a reverse comonomer distribution.

公开(公告)号：US20160115255A1

公开(公告)日：2016-04-28

申请号：US14933847

申请日：2015-11-05

Applicant: Chevron Phillips Chemical Company LP

Inventor： Carlos A. CRUZ ,  Max P. MCDANIEL ,  Qing YANG ,  Jared L. BARR ,  Youlu YU

IPC: C08F10/02

CPC classification number: C08F10/02 ,  C08F2810/20 ,  C08F10/00 ,  C08F4/65927 ,  C08F110/02 ,  C08F2500/07 ,  C08F2500/12 ,  C08F2500/09 ,  C08F2500/10 ,  C08F2500/04 ,  C08F4/65916 ,  C08F210/16 ,  C08F210/14

Abstract: A radically coupled polymer having a density of from about 0.915 g/ml to about 0.975 g/ml characterized by a crossover modulus that is equal to or less than ymn where ymn=18000e−0.15x and x is the number average molecular weight of the radically coupled polymer. An ethylene polymer having a level of short chain branching ranging from about 0 to about 10 mol. %; a level of long chain branching ranging from about 0.001 LCB/103 carbons to about 1.5 LCB/103 carbons as determined by SEC-MALS; and characterized by a crossover modulus that is equal to or less than ymn where ymn=18000e−0.15x and x is the number average molecular weight of the radically coupled polymer.

Abstract translation: 密度为约0.915g / ml至约0.975g / ml的自由基偶联聚合物，其特征在于等于或小于ymn的交叉模量，其中ymn = 18000e-0.15x，x为数均分子量 自由基聚合物。 具有约0至约10mol的短链支化水平的乙烯聚合物。 ％; 通过SEC-MALS测定的长链支化水平为约0.001LCB / 103碳至约1.5LCB / 103碳; 其特征在于等于或小于ymn的交叉模量，其中ymn = 18000e-0.15x，x是自由基结合聚合物的数均分子量。

公开(公告)号：US20160102161A1

公开(公告)日：2016-04-14

申请号：US14510153

申请日：2014-10-09

Applicant: Chevron Phillips Chemical Company LP

Inventor： Carlos A. Cruz ,  Jared L. Barr ,  Jeremy M. Praetorius

IPC: C08F210/16

CPC classification number: C08F10/02 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/65925 ,  C08F4/65927 ,  C08F210/16 ,  C08F2420/04 ,  C08F2420/05 ,  C08F2500/04 ,  C08F2500/08 ,  C08F2500/09 ,  C08F2500/10 ,  C08F2500/12 ,  C08F4/65904 ,  C08F110/02 ,  C08F2500/07 ,  C08F210/02 ,  C08F210/14

Abstract: Catalyst compositions containing activator-supports and half-metallocene titanium phosphinimide complexes or half-metallocene titanium iminoimidazolidide complexes are disclosed. These catalyst compositions can be used to produce olefin polymers having relatively broad molecular weight distributions and low levels of long chain branching.

Abstract translation: 公开了含有活化剂 - 载体和半金属茂钛膦酰亚胺络合物或半金属茂钛亚氨基咪唑烷络合物的催化剂组合物。 这些催化剂组合物可用于生产具有较宽分子量分布和低水平长链支化的烯烃聚合物。

公开(公告)号：US09303109B2

公开(公告)日：2016-04-05

申请号：US14533161

申请日：2014-11-05

Applicant: Chevron Phillips Chemical Company LP

Inventor： Jeffrey F. Greco

IPC: C08F4/6592 ,  C08F4/642 ,  C08F210/16 ,  C08L23/08 ,  C08F110/02 ,  C08F10/02 ,  C08F4/659

CPC classification number: C08F10/02 ,  C07F7/00 ,  C07F17/00 ,  C08F4/65904 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  C08F110/02 ,  C08F210/16 ,  C08L23/0815 ,  C08F4/025 ,  C08F2500/09 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/08 ,  C08F2500/03 ,  C08F2500/04

Abstract: Disclosed herein are catalyst compositions containing boron-bridged, cyclopentadienyl-fluorenyl metallocene compounds with an alkenyl substituent. These catalyst compositions can be used for the polymerization of olefins. For example, ethylene copolymers produced using these catalyst compositions can be characterized by a combination of a flat or a conventional comonomer distribution and low levels of long chain branching.

公开(公告)号：US09290600B2

公开(公告)日：2016-03-22

申请号：US14414796

申请日：2013-07-19

Applicant: Borealis AG

Inventor： Hermann Prokschi ,  Hermann Braun

IPC: C08F255/02 ,  C08J9/00 ,  C08L23/14 ,  C08L23/26 ,  C08L23/12

CPC classification number: C08F255/02 ,  C08J9/00 ,  C08L23/12 ,  C08L23/142 ,  C08L23/26 ,  C08L2205/02 ,  C08L2205/025 ,  C08F110/06 ,  C08F2500/12 ,  C08F2500/09 ,  C08F2500/11 ,  C08F210/06

Abstract: Process for providing a polypropylene composition comprising a branched polypropylene in which a polypropylene with a melt flow rate MFR2 (230° C.) of more than 0.5 g/10 min is reacted with a thermally decomposing free radical-forming agent and optionally with a bifunctionally unsaturated monomer obtaining thereby the branched polypropylene, wherein the polypropylene composition has a F30 melt strength of more than 20.0 cN and a V30 melt extensibility of more than 200 mm/s.

Abstract translation: 提供包含支化聚丙烯的聚丙烯组合物的方法，其中熔体流动速率MFR 2（230℃）大于0.5g / 10min的聚丙烯与热分解自由基形成剂和任选的双功能 得到支链聚丙烯的不饱和单体，其中聚丙烯组合物具有大于20.0cN的F30熔体强度和大于200mm / s的V30熔体延展性。