Single-Component System Based On Co-Reactive Latex, Preparation Method And Use In The Field Of Formol-Free Coatings
    21.
    发明申请
    Single-Component System Based On Co-Reactive Latex, Preparation Method And Use In The Field Of Formol-Free Coatings 审中-公开
    基于共反应胶乳的单组分体系,无氟涂层领域的制备方法和用途

    公开(公告)号:US20080028982A1

    公开(公告)日:2008-02-07

    申请号:US11630828

    申请日:2006-02-02

    IPC分类号: C08L9/10

    摘要: The invention concerns a single-component system based on co-reactive latex capable of leading to formol-free coatings, crosslinkable at room temperature and post-crosslinkable by heat treatment, said system consisting of a mixture of two particle dispersions, (A) and (B) obtained each by emulsion polymerization in aqueous medium of a composition of respectively A and B monomers: (a) at least one free-radical polymerizable ethylenically unsaturated monomer, comprising a functional group, of formula (A), being a constituent of monomer A composition, and (b) at least one free-radical polymerizable ethylenically unsaturated monomer, comprising a radical (R) identical to or different from that of monomer (a); a functional group selected among acetal, mercaptal, mercaptol, dioxolane et dithiolane, being a constituent of monomer B composition. The invention also concerns the preparation method and the use of said system in the field of coatings.

    摘要翻译: 本发明涉及一种基于共反应性胶乳的单组分体系,其能够导致无溶剂涂层,在室温下可交联并通过热处理可后交联,所述体系由两种颗粒分散体(A)和 (B)分别通过在A和B单体的组合物的水性介质中的乳液聚合获得:(a)至少一种可自由基聚合的烯键式不饱和单体,其包含式(A)的官能团,其为 单体A组合物,和(b)至少一种可自由基聚合的烯键式不饱和单体,其包含与单体(a)相同或不同的基团(R)。 选自缩醛,巯基,巯基,二氧杂环戊烷和二硫戊环的官能团,是单体B组成的组分。 本发明还涉及在涂料领域中所述系统的制备方法和用途。

    Thin films for controlled protein interaction
    22.
    发明申请
    Thin films for controlled protein interaction 有权
    用于控制蛋白质相互作用的薄膜

    公开(公告)号:US20050282925A1

    公开(公告)日:2005-12-22

    申请号:US11063952

    申请日:2005-02-23

    IPC分类号: G02B1/04

    CPC分类号: C02F1/4693 G02B1/04 C08L39/00

    摘要: A medium for isolating or releasing an electrostatically charged component from or into an aqueous composition. The medium has a polyelectrolyte film on at least one surface of an article wherein the polyelectrolyte film is characterized by an interpenetrating network of a predominantly positively charged polymer and a predominantly negatively charged polymer. The predominantly positively charged polymer, the predominantly negatively charged polymer or both contain (i) a pH sensitive imidazole repeat unit having a pKa between 3 and 9, or (ii) a redox sensitive repeat unit selected from the group consisting of quaternized bipyridine repeat units, coordinated metal repeat units, pyrrole repeat units, aniline repeat units, thiophene repeat units and combinations thereof having a redox potential between +1.2 volts and −1.2 volts versus a standard hydrogen electrode.

    摘要翻译: 用于从水性组合物中分离或释放静电荷组分的介质。 介质在制品的至少一个表面上具有聚电解质膜,其中聚电解质膜的特征在于主要带正电荷的聚合物和主要带负电荷的聚合物的互穿网络。 主要带正电荷的聚合物,主要带负电荷的聚合物或两者都含有(i)pKa在3和9之间的pH敏感的咪唑重复单元,或(ii)选自季铵化联吡啶重复单元的氧化还原敏感性重复单元 ,配位金属重复单元,吡咯重复单元,苯胺重复单元,噻吩重复单元及其组合与标准氢电极之间具有+1.2伏和-1.2伏之间的氧化还原电位。

    Washing process for the purification of polymers containing N or amino, ammonium or spirobicyclic ammonium groups
    24.
    发明授权
    Washing process for the purification of polymers containing N or amino, ammonium or spirobicyclic ammonium groups 有权
    用于纯化含有N或氨基,铵或螺二环铵基团的聚合物的洗涤方法

    公开(公告)号:US06806350B2

    公开(公告)日:2004-10-19

    申请号:US10362512

    申请日:2003-02-24

    IPC分类号: C08F600

    CPC分类号: C08F6/00 C08F6/008 C08L39/00

    摘要: The invention relates to a washing process for cleaning polymers containing N or amine, ammonium or spirobicyclic ammonium groups, comprising cationic groups containing N, in addition to suitable counterions, whereby the gelled-out polymers are obtained through polymerization and cross-linking by a) adding a base which is partially or fully deprotonated, b) the partially or fully deprotonated polymers are washed, then c) optionally, are reprotonated in an organic solvent or in an organic solvent/water mixture by adding an acid, whereupon d) optionally, they are washed in an organic solvent or an organic solvent/water mixture in order to shrink the gels and optionally, e) in connection with step c) or d), the steps a)-c) or -d) are repeated.

    摘要翻译: 本发明涉及清洗含有N或胺,铵或螺二环铵基团的聚合物的洗涤方法,除了合适的抗衡离子外,还包含含有N的阳离子基团,由此通过聚合和交联得到凝胶聚合物,通过a) 加入部分或完全去质子化的碱,b)部分或完全去质子化的聚合物被洗涤,然后c)任选地,通过加入酸在有机溶剂或有机溶剂/水混合物中再生,然后d)任选地, 它们在有机溶剂或有机溶剂/水混合物中洗涤以收缩凝胶,并且任选地e)与步骤c)或d)相结合,重复步骤a)-c)或-d)。