Coating composition
    21.
    发明授权
    Coating composition 失效
    涂料组成

    公开(公告)号:US5698618A

    公开(公告)日:1997-12-16

    申请号:US683213

    申请日:1996-07-18

    CPC classification number: C09D167/08 C09D201/06 C09D7/02

    Abstract: A coating composition is formed from an acid-set coating varnish and a pigment composition. The pigment composition includes a specific organic dyestuff derivative and a specific basic-group-containing resin-type pigment dispersant. The coating composition excels in pigment dispersibility, nonflocculation properties, noncrystallizability and fluidity. When used as a coating, the coating composition has excellent color tone, gloss, hardness, weather resistance, and solvent resistance.

    Abstract translation: PCT No.PCT / JP95 / 02355 Sec。 371日期:1996年7月18日 102(e)日期1996年7月18日PCT提交1995年11月17日PCT公布。 出版物WO96 / 16130 日期:1996年5月30日涂料组合物由酸性涂料清漆和颜料组合物形成。 颜料组合物包括特定的有机染料衍生物和特定的含碱性基团的树脂型颜料分散剂。 涂料组合物的颜料分散性,非絮凝性,非结晶性和流动性优异。 当用作涂层时,涂料组合物具有优异的色调,光泽度,硬度,耐候性和耐溶剂性。

    Low voc curable coating composition utilizing carbamate-functional
compound
    22.
    发明授权
    Low voc curable coating composition utilizing carbamate-functional compound 失效
    使用氨基甲酸酯官能化合物的低声可固化涂料组合物

    公开(公告)号:US5693723A

    公开(公告)日:1997-12-02

    申请号:US673936

    申请日:1996-07-01

    Inventor: Marvin L. Green

    CPC classification number: C09D201/025 C08G59/1477 C08G59/1494 C09D201/06

    Abstract: There is described a curable coating composition comprising: (A) a carbamate-functional component that is the reaction product of: (1) a compound having a plurality of hydroxyl groups that is the reaction product of: (a) a compound comprising at least one epoxide group and (b) a compound comprising at least one organic acid group and at least one hydroxyl group, (2) a compound comprising a carbamate group, and (B) a component comprising a plurality of groups that are reactive with the carbamate functional groups on component (A).

    Abstract translation: 描述了可固化涂料组合物,其包含:(A)氨基甲酸酯官能组分,其是以下物质的反应产物:(1)具有多个羟基的化合物,其为以下物质的反应产物:(a)至少包含 一个环氧基团和(b)包含至少一个有机酸基团和至少一个羟基的化合物,(2)包含氨基甲酸酯基团的化合物和(B)包含与氨基甲酸酯反应的多个基团的组分 组分(A)上的官能团。

    Process for forming overcoat
    24.
    发明授权
    Process for forming overcoat 失效
    成型外套的工艺

    公开(公告)号:US5609960A

    公开(公告)日:1997-03-11

    申请号:US553398

    申请日:1995-11-21

    Abstract: A process for forming an overcoat by the two-coat one-bake method wherein a basecoat composition and a clear coat composition are applied to a substrate wet-on-wet and thereafter cured at the same time by heating, the process being characterized in that the base coat composition is a coating composition consisting primarily of a hydroxyl-containing resin, an amine resin, a pigment and an organic solvent, the clear coat composition being a coating composition comprising:(A) at least one resin selected from the group consisting of (i) a resin having at least one epoxy group and at least one hydroxyl group in the molecue, (ii) a resin mixture of (ii-1) a resin having at least two epoxy groups in the molecule and (ii-2) a resin having at least two hydroxyl groups in the molecule, (iii) a resin having at least two epoxy groups in the molecule, and (iv) any mixture thereof,(B) a crosslinking agent comprising a compound having at least two noncyclic acid anhydride groups and represented by the formula ##STR1## wherein R is a monovalent hydrocarbon group having 2 to 50 carbon atoms, R' is a bivalent hydrocarbon group having 2 to 50 carbon atoms, the hydrocarbon groups R and R' containing or not containing an ether linkage, urethane linkage or ester linkage, and n is an integer of 1 to 500 and (C) a curing catalyst.

    Abstract translation: PCT No.PCT / JP93 / 00669 Sec。 371日期:1995年11月21日 102(e)日期1995年11月21日PCT提交1993年5月21日PCT公布。 公开号WO94 / 27740 日期1994年12月8日一种通过双层单烘烤法形成外涂层的方法,其中将底涂层组合物和透明涂层组合物施加到湿润基板上,然后通过加热同时固化, 方法的特征在于,底涂层组合物是主要由含羟基树脂,胺树脂,颜料和有机溶剂组成的涂料组合物,透明涂料组合物是涂料组合物,其包含:(A)至少一种树脂 选自(i)在分子中具有至少一个环氧基和至少一个羟基的树脂,(ii)(ii-1)在分子中具有至少两个环氧基的树脂的树脂混合物 和(ii-2)在分子中具有至少两个羟基的树脂,(iii)分子中具有至少两个环氧基的树脂,和(iv)其任何混合物,(B)包含化合物 具有至少两个非环酸酐基团a d由下式表示:其中R是具有2至50个碳原子的一价烃基,R'是具有2至50个碳原子的二价烃基,烃基R和R'含有或不含有醚键 氨基甲酸酯键或酯键,n为1〜500的整数,(C)固化催化剂。

    Aqueous based coating compositions having improved metallic pigment
orientation
    27.
    发明授权
    Aqueous based coating compositions having improved metallic pigment orientation 失效
    具有改进的金属颜料取向的水性涂料组合物

    公开(公告)号:US5356973A

    公开(公告)日:1994-10-18

    申请号:US938912

    申请日:1992-08-31

    CPC classification number: C08F283/008 C09D5/024 C09D5/38

    Abstract: An aqueous based coating composition contains a polymeric film-forming resin and as an additive from about 1 to about 40 percent by weight based on the resin solids of the composition of an oligomeric ester having an acid value of from about 100 to about 500 of the structure: ##STR1## where X is the residue of a polyol containing from 1 to 50 carbon atoms per hydroxyl group after reaction with an acid or an anhydride, R is an organic moiety from the acid or anhydride and A has an average value of about 2 or greater.The coating compositions are particularly advantageous as metallic pigmented coating compositions for automotive basecoat applications because they exhibit excellent resistance to mottling, have good flop and have reduced sensitivity to fluctuations in relative humidity.

    Abstract translation: 水基涂料组合物含有聚合物成膜树脂和约1至约40重量%的添加剂,基于组合物的树脂固体,其酸值为约100至约500的低聚酯 结构:其中X是与酸或酸酐反应后,每个羟基含有1至50个碳原子的多元醇的残基,R是酸或酸酐的有机部分,A的平均值约为 2以上。 涂料组合物作为用于汽车底涂层应用的金属着色涂料组合物是特别有利的,因为它们表现出优异的斑驳性,具有良好的翻转性并且降低了对相对湿度波动的敏感性。

    Thermoset coating composition having improved hardness
    30.
    发明授权
    Thermoset coating composition having improved hardness 失效
    具有改进硬度的热固性涂料组合物

    公开(公告)号:US5166289A

    公开(公告)日:1992-11-24

    申请号:US630298

    申请日:1990-12-19

    CPC classification number: C09D167/00 C09D133/06 C09D169/00 C08L61/32

    Abstract: The present invention provides for amino-crosslinkable coating formulations based on a mixture of a di or polyhydroxy functional polymeric component selected from the group consisting of diesters, polyesters, alkyd polymers, acrylic polymers and polycarbonate polymers, a methylol (alkoxymethyl) amino crosslinking agent and a bis-aromatic polyhydric phenol component having the structure of formula I: ##STR1## wherein X is selected from the group consisting of carbon to carbon covalent bond, oxygen, sulfur, --S--S--, --CO--, --SO--, --SO.sub.2 -- and a divalent organic radical having a molecular weight less than about 400, and wherein Y is independently selected from the group consisting of hydrogen, halogen, C.sub.1 to C.sub.4 alkyl and C.sub.1 to C.sub.4 alkoxy.The crosslinkable compositions of this invention may be used to prepare curable coating and paint formulations, and also may contain other ingredients such as a crosslinking catalyst, fillers, pigments and the like. When cured, the coatings of this invention exhibit improved hardness properties when compared with cured coatings which do not contain the aromatic polyhydric phenol additive. The presence of the additive also serves to eliminate the problem of coating softening when the coated substrate is baked for a prolonged period of time. These cured coatings also have good weatherability, good corrosion resistance and hydrolytic stability, enhanced oxidative and radiation stability, good solvent resistance and good adhesion properties.

    Abstract translation: 本发明提供了基于选自二酯,聚酯,醇酸聚合物,丙烯酸聚合物和聚碳酸酯聚合物的二或多羟基官能聚合物组分,羟甲基(烷氧基甲基)氨基交联剂和羟甲基(烷氧基甲基)氨基交联剂的混合物的氨基可交联涂料配方, 具有式I结构的双芳族多元酚组分:其中X选自碳 - 碳共价键,氧,硫,-SS - , - CO - , - SO-, -SO 2 - 和分子量小于约400的二价有机基团,其中Y独立地选自氢,卤素,C 1至C 4烷基和C 1至C 4烷氧基。 本发明的可交联组合物可用于制备可固化涂料和涂料制剂,并且还可以含有其它成分如交联催化剂,填料,颜料等。 当固化时,与不含芳族多元酚添加剂的固化涂层相比,本发明的涂层表现出改善的硬度性能。 当涂覆的基材长时间烘烤时,添加剂的存在也用于消除涂布软化的问题。 这些固化涂层也具有良好的耐候性,良好的耐腐蚀性和水解稳定性,增强的氧化和辐射稳定性,良好的耐溶剂性和良好的粘合性能。

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