Abstract:
A coating composition is formed from an acid-set coating varnish and a pigment composition. The pigment composition includes a specific organic dyestuff derivative and a specific basic-group-containing resin-type pigment dispersant. The coating composition excels in pigment dispersibility, nonflocculation properties, noncrystallizability and fluidity. When used as a coating, the coating composition has excellent color tone, gloss, hardness, weather resistance, and solvent resistance.
Abstract:
There is described a curable coating composition comprising: (A) a carbamate-functional component that is the reaction product of: (1) a compound having a plurality of hydroxyl groups that is the reaction product of: (a) a compound comprising at least one epoxide group and (b) a compound comprising at least one organic acid group and at least one hydroxyl group, (2) a compound comprising a carbamate group, and (B) a component comprising a plurality of groups that are reactive with the carbamate functional groups on component (A).
Abstract:
A water-based coating composition and methods of making and using the same are disclosed. The composition includes a halogenated resin, a polyol, a surfactant, and an amine. It is suitable for coating a variety of substrates including polyolefinic substrates such as polypropylene, and operates without aromatic organic solvents.
Abstract:
A process for forming an overcoat by the two-coat one-bake method wherein a basecoat composition and a clear coat composition are applied to a substrate wet-on-wet and thereafter cured at the same time by heating, the process being characterized in that the base coat composition is a coating composition consisting primarily of a hydroxyl-containing resin, an amine resin, a pigment and an organic solvent, the clear coat composition being a coating composition comprising:(A) at least one resin selected from the group consisting of (i) a resin having at least one epoxy group and at least one hydroxyl group in the molecue, (ii) a resin mixture of (ii-1) a resin having at least two epoxy groups in the molecule and (ii-2) a resin having at least two hydroxyl groups in the molecule, (iii) a resin having at least two epoxy groups in the molecule, and (iv) any mixture thereof,(B) a crosslinking agent comprising a compound having at least two noncyclic acid anhydride groups and represented by the formula ##STR1## wherein R is a monovalent hydrocarbon group having 2 to 50 carbon atoms, R' is a bivalent hydrocarbon group having 2 to 50 carbon atoms, the hydrocarbon groups R and R' containing or not containing an ether linkage, urethane linkage or ester linkage, and n is an integer of 1 to 500 and (C) a curing catalyst.
Abstract:
Novel carbamyl-methylated aminotriazines and curable compositions comprising these aminotriazines are disclosed. The carbamyl-methylated aminotriazines are substituted with derivatives of monoalkyl ethers and/or monoaryl ethers of alkylene glycols. The curable compositions are particularly useful as film formers in coatings.
Abstract:
A method for forming a coating film by sequentially forming a pigmented base coat and a clear top coat on a substrate. The pigmented base coat composition includes (1) an OH-containing resin, (2) an amino resin, (3) a polyorganosiloxane resin a number average molecule weight of at least 1,000 and having at least two groups per molecule selected from a silanol group and an alkoxysilane group and (4) a flaky metal or a mica powder in (5) an organic solvent. The clear top coat composition includes (1) an OH- and epoxy-containing base resin which additionally contains at least one of a silanol group and a hydrolyzable group bound directly to a silicon atom, (2) a curing catalyst and (3) an organic solvent.
Abstract:
An aqueous based coating composition contains a polymeric film-forming resin and as an additive from about 1 to about 40 percent by weight based on the resin solids of the composition of an oligomeric ester having an acid value of from about 100 to about 500 of the structure: ##STR1## where X is the residue of a polyol containing from 1 to 50 carbon atoms per hydroxyl group after reaction with an acid or an anhydride, R is an organic moiety from the acid or anhydride and A has an average value of about 2 or greater.The coating compositions are particularly advantageous as metallic pigmented coating compositions for automotive basecoat applications because they exhibit excellent resistance to mottling, have good flop and have reduced sensitivity to fluctuations in relative humidity.
Abstract:
Non liquid-crystalline esterphenol-capped liquid polymer and polyol compositions in combination with an amino crosslinking agent endow coating compositions containing them with the ability of providing films having superior properties. The esterphenol-capped polymers and polyols can be prepared by direct esterification of hydroxybenzoic acid without its decarboxylation.
Abstract:
A thermosetting coating composition comprising as essential components:(a) a hydroxyl group-containing base resin,(b) an alicyclic polyepoxide crosslinking agent, and(c) a catalyst selected from the group consisting of a quaternary ammonium hydroxide and a metal chelate.
Abstract:
The present invention provides for amino-crosslinkable coating formulations based on a mixture of a di or polyhydroxy functional polymeric component selected from the group consisting of diesters, polyesters, alkyd polymers, acrylic polymers and polycarbonate polymers, a methylol (alkoxymethyl) amino crosslinking agent and a bis-aromatic polyhydric phenol component having the structure of formula I: ##STR1## wherein X is selected from the group consisting of carbon to carbon covalent bond, oxygen, sulfur, --S--S--, --CO--, --SO--, --SO.sub.2 -- and a divalent organic radical having a molecular weight less than about 400, and wherein Y is independently selected from the group consisting of hydrogen, halogen, C.sub.1 to C.sub.4 alkyl and C.sub.1 to C.sub.4 alkoxy.The crosslinkable compositions of this invention may be used to prepare curable coating and paint formulations, and also may contain other ingredients such as a crosslinking catalyst, fillers, pigments and the like. When cured, the coatings of this invention exhibit improved hardness properties when compared with cured coatings which do not contain the aromatic polyhydric phenol additive. The presence of the additive also serves to eliminate the problem of coating softening when the coated substrate is baked for a prolonged period of time. These cured coatings also have good weatherability, good corrosion resistance and hydrolytic stability, enhanced oxidative and radiation stability, good solvent resistance and good adhesion properties.