公开(公告)号：US09631145B2

公开(公告)日：2017-04-25

申请号：US14593831

申请日：2015-01-09

Applicant: Ensyn Renewables, Inc.

Inventor： Barry A. Freel

IPC: C10B57/12 ,  C10B57/00 ,  C10B49/22 ,  C10B53/02 ,  C10G1/02 ,  C10G9/28 ,  C10K1/04 ,  C10B27/00 ,  F28C3/08

CPC classification number: C10B57/00 ,  C10B27/00 ,  C10B49/22 ,  C10B53/02 ,  C10G1/02 ,  C10G9/28 ,  C10K1/04 ,  F28C3/08 ,  Y02E50/14 ,  Y02P20/145

Abstract: Processes are provided including quenching a hot vapor stream to improve rapid thermal conversion processes for efficiently converting wood, other biomass materials, and other carbonaceous feedstock (including hydrocarbons) into high yields of valuable liquid product, e.g., bio-oil, on a large scale production.

公开(公告)号：US20160102255A1

公开(公告)日：2016-04-14

申请号：US14510497

申请日：2014-10-09

Applicant: Saudi Arabian Oil Company

Inventor： Ali Hoteit ,  Mourad Younes ,  Aqil Jamal

IPC: C10G9/28 ,  F23C10/01 ,  F23C10/04 ,  C10G9/00

CPC classification number: C10G9/28 ,  C10G9/005 ,  C10G9/36 ,  C10G11/04 ,  C10G11/182 ,  C10G51/04 ,  C10G2300/107 ,  C10G2300/4081 ,  C10G2300/708 ,  C10G2400/26 ,  F23C10/01 ,  F23C10/04 ,  Y02E20/346

Abstract: A process for power generation using a chemical looping combustion concept is integrated with heavy liquid fuel coking in a cracking reactor, and is configured such that petcoke deposits on metal oxide particles from the cracking reactor are used as fuel in the chemical looping combustion reaction. The process is also configured such that metal oxide particles provide the heat necessary for the cracking reaction to be initiated in the cracking reactor.

Abstract translation: 使用化学循环燃烧概念的发电过程与裂解反应器中的重液体燃料焦化相结合，并且被配置为使得在化学循环燃烧反应中使用来自裂解反应器的金属氧化物颗粒上的铁屑沉积物作为燃料。 该方法还被配置为使得金属氧化物颗粒提供在裂化反应器中引发裂化反应所需的热量。

公开(公告)号：US08105482B1

公开(公告)日：2012-01-31

申请号：US09958261

申请日：2000-04-07

Applicant: Barry Freel ,  Robert G. Graham

Inventor： Barry Freel ,  Robert G. Graham

IPC: C10G9/28

CPC classification number: C10B55/04 ,  C10G9/32 ,  C10G31/06 ,  C10G2300/302 ,  C10G2300/4006 ,  C10G2300/4025 ,  C10G2300/4081

Abstract: The present invention is directed to the upgrading of heavy hydrocarbon feedstock. The process of the present invention provides for the preparation of a partially upgraded feedstock exhibiting reduced viscosity and increased API gravity. This process reduces the viscosity of the feedstock in order to permit pipeline transport of the upgraded feedstock with little or no addition of diluents. The method for upgrading a heavy hydrocarbon feedstock comprises introducing a particulate heat carrier into an upflow reactor, introducing the heavy hydrocarbon feedstock into the upflow reactor at a location above that of the particulate heat carrier, allowing the heavy hydrocarbon feedstock to interact with the heat carrier to produce a product stream, separating the product stream from the particulate heat carrier, regenerating the particulate heat carrier, and collecting a gaseous and liquid product from the product stream.

Abstract translation: 本发明涉及重质烃原料的升级。 本发明的方法提供了显示出降低的粘度和增加的API重力的部分升级的原料的制备。 该方法降低了原料的粘度，以便允许管道输送少量或不添加稀释剂的升级原料。 用于升级重质烃原料的方法包括将颗粒状热载体引入上流反应器中，将重质烃原料引入到高于微粒热载体的位置的上游反应器中，允许重烃原料与热载体 以产生产物流，将产物流与颗粒状热载体分离，再生颗粒状热载体，以及从产物流收集气态和液态产物。

公开(公告)号：US20090288991A1

公开(公告)日：2009-11-26

申请号：US12533440

申请日：2009-07-31

Applicant: John E. Partanen ,  Stanley W. Ellis ,  Travis F. Ellis

Inventor： John E. Partanen ,  Stanley W. Ellis ,  Travis F. Ellis

IPC: C10G9/28

CPC classification number: C08L95/00 ,  C08K3/04 ,  C08L19/003 ,  C08L2666/08

Abstract: An asphalt mastic is prepared by combining spent activated carbon, that has not been regenerated, with liquid asphalt to achieve a composition that is useful for a variety of applications for which asphalt is used, including aggregate compositions and roofing materials. The activated carbon can also serve as a foaming initiator for the production of foamed asphalt. Still further, the activated carbon can be used as coking unit feedstock and as a quencher for a delayed coking unit.

Abstract translation: 通过将尚未再生的废活性炭与液体沥青组合以获得可用于各种使用沥青的应用的组合物（包括聚集体组合物和屋顶材料）来制备沥青胶泥。 活性炭也可以用作生产发泡沥青的发泡引发剂。 此外，活性炭可以用作焦化单元原料和用作延迟焦化装置的猝灭剂。

公开(公告)号：US5879535A

公开(公告)日：1999-03-09

申请号：US768343

申请日：1996-12-17

Applicant: Willibald Serrand ,  Mitchell Jacobson ,  Michael R. Parrish ,  David G. Hammond

Inventor： Willibald Serrand ,  Mitchell Jacobson ,  Michael R. Parrish ,  David G. Hammond

IPC: C07C4/04 ,  C07C11/04 ,  C07C11/06 ,  C10C1/04 ,  C10C3/06 ,  C10G1/04 ,  C10G7/00 ,  C10G9/32 ,  C10G51/02 ,  C10G53/04 ,  C10G9/28

CPC classification number: C10G51/023 ,  C10G9/32

Abstract: A two-stage process for obtaining a substantial amount of olefinic product from a residua feedstock. The first stage is comprised of a thermal process unit containing a reaction zone comprised of a horizontal moving bed of fluidized hot particles operated at temperatures from about 500.degree. to 600.degree. C. and having a short vapor residence time, and the second stage thermal conversion zone operated at a temperature of about 700.degree. C. to about 1100.degree. C., and also having a short vapor residence time.

Abstract translation: 从残渣原料中获得大量烯烃产物的两阶段方法。 第一阶段包括一个热处理单元，该热处理单元含有一个反应区，该反应区包括在约500℃至600℃的温度下运行的流化热颗粒的水平移动床，并且具有短的蒸气停留时间，而第二级热转化 区域在约700℃至约1100℃的温度下操作，并且还具有短的蒸气停留时间。

公开(公告)号：US4738769A

公开(公告)日：1988-04-19

申请号：US478428

申请日：1983-03-24

Applicant: Christian Busson ,  Jacques Alagy ,  Jean-Paul Euzen ,  Pierre Galtier

Inventor： Christian Busson ,  Jacques Alagy ,  Jean-Paul Euzen ,  Pierre Galtier

IPC: B01J8/12 ,  C10G9/28 ,  C10G47/24

CPC classification number: B01J8/12 ,  C10G2400/20

Abstract: A process for converting liquid or semi-liquid hydrocarbon charges to lighter fractions comprises a first step (a) heating droplets jets of the charge introduced into a pyrolysis chamber by surrounding them with parallel jets of hot solid particles, of relatively large size, of a heat carrier material, not substantially in contact with the droplet jets, so as to maintain a temperature of 700.degree.-1600.degree. C., and introducing a gas so as to obtain a pressure from 1 to 150 bars. A second step involves (b) separating the gaseous fraction from the solid particles. Thereafter (c) at least a portion of the solid particles are heated and fed back to step (a). The gaseous fraction is (d) cooled by means of a cold gas so as to recover light hydrocarbons therefrom.

Abstract translation: 将液体或半液体碳氢化合物装料转化成轻馏分的方法包括第一步骤（a）通过用相当大尺寸的热固体颗粒的平行射流包围引入到热解室中的电荷的液滴射流， 热载体材料，基本上不与液滴射流接触，以保持700〜-1600℃的温度，并引入气体以获得1至150巴的压力。 第二步涉及（b）从固体颗粒中分离气态馏分。 此后（c）将至少一部分固体颗粒加热并反馈到步骤（a）。 气态馏分（d）通过冷气体冷却，以从其中回收轻质烃。

公开(公告)号：US4559132A

公开(公告)日：1985-12-17

申请号：US308339

申请日：1981-10-05

Applicant: Christopher W. Kuehler

Inventor： Christopher W. Kuehler

IPC: B01J8/16 ,  B01J8/22 ,  C10G9/28

CPC classification number: B01J8/16 ,  B01J8/22

Abstract: A gas-liquid or a gas-liquid-solid feed is contacted in a vessel containing a packed bed of contact particles. At least a portion of the feed is passed upwardly through the packed bed and the mass flow rate of the feed is periodically increased sufficiently to cause a portion of the particles within the vessel to form an expanded region within the packed bed.

Abstract translation: 在包含接触颗粒的填充床的容器中接触气液或气液固体进料。 进料的至少一部分向上通过填充床，并且进料的质量流速周期性地增加以使得容器内的一部分颗粒在填充床内形成扩张区域。

公开(公告)号：US4303494A

公开(公告)日：1981-12-01

申请号：US64142

申请日：1979-08-06

Applicant: Darrell D. Whitehurst ,  Tsoung Y. Yan

Inventor： Darrell D. Whitehurst ,  Tsoung Y. Yan

IPC: B01J8/20 ,  C01B39/04 ,  C08F2/06 ,  C08F10/00 ,  C10B55/10 ,  C10G1/04 ,  C10G1/06 ,  C10G9/00 ,  C10G9/28 ,  C10G9/38 ,  C10G1/00

CPC classification number: C10G9/38 ,  B01J8/20 ,  C01B39/04 ,  C08F10/00 ,  C10B55/10 ,  C10G1/042 ,  C10G1/045 ,  C10G1/065 ,  C10G9/005 ,  C10G9/28 ,  B01J2219/1946 ,  Y02P20/582

Abstract: A solid product resulting from the nucleated growth of the product on solid material of either the same or different composition and having a density higher than the reaction medium is formed from one or more liquid phase reactants by a method which comprises tangentially introducing the liquid phase reaction medium into the lower, smaller end of an inverted, frusto-conical reactor-separator, thereby imparting an upward swirling motion to the reaction medium in the reactor-separator, the horizontal velocity at the bottom of the reactor-separator being sufficiently large to cause fluidization of larger, solid product particles and concentration of them in the central lower portion of the reactor-separator and the vertical velocity at the top of the reactor-separator being sufficiently small to avoid carry-over of the smaller solid particles but sufficiently large to concentrate them in the upper portion of the reactor-separator; at least periodically recovering the larger, solid product particles in spherical form from the bottom of the reactor-separator; and recovering fluid products from the top of the reactor-separator. The method described is useful in a variety of reactions wherein a solid product forms by a nucleated growth mechanism. Examples of such reactions include thermal upgrading of petroleum derived feedstocks and coal liquids, synthesis of zeolites and Ziegler-Natta polymerization of olefins.

Abstract translation: 由相同或不同组成的固体材料产生的具有比反应介质高的密度产生的固体产物由一种或多种液相反应物形成，该方法包括切向引入液相反应 介质进入倒立的截头圆锥形反应器分离器的较小的较小端，从而向反应器分离器中的反应介质施加向上旋转运动，反应器分离器底部的水平速度足够大以致 更大的固体产物颗粒的流化和它们在反应器分离器的中心下部的浓度以及反应器分离器顶部的垂直速度足够小以避免较小固体颗粒的滞留，但足够大以至 将它们集中在反应器分离器的上部; 从反应器分离器的底部至少周期性地回收球形的更大的固体产物颗粒; 并从反应器分离器的顶部回收流体产物。 所描述的方法可用于通过有核生长机制形成固体产物的各种反应。 这种反应的实例包括石油衍生的原料和煤液体的热升级，沸石的合成和烯烃的齐格勒 - 纳塔聚合。

公开(公告)号：US4220518A

公开(公告)日：1980-09-02

申请号：US946426

申请日：1978-09-27

Applicant: Seiichi Uchida ,  Yoshihito Satomi ,  Norihiro Kiuchi ,  Takeo Yamagata ,  Susumu Yoshioka ,  Tomohiko Miyamoto ,  Jinichi Tomuro

Inventor： Seiichi Uchida ,  Yoshihito Satomi ,  Norihiro Kiuchi ,  Takeo Yamagata ,  Susumu Yoshioka ,  Tomohiko Miyamoto ,  Jinichi Tomuro

IPC: C10B43/14 ,  C10G9/32 ,  C10G11/18 ,  C10G9/16 ,  B01J37/14 ,  C01B1/09 ,  C10G9/28

CPC classification number: C10B43/14 ,  C10G11/18 ,  C10G9/32 ,  Y10S208/01 ,  Y10S423/16

Abstract: In a reactor for cracking heavy hydrocarbon oil through a fluidized bed of particles of natural ores, coke-like materials are deposited on a top of the reactor or pipe inside surfaces of a transfer line from the reactor to a scrubber. To effectively scour out the deposited coke-like materials, particles of natural ores having a mean diameter of a few hundred .mu.m is made to be contained in an effluent gas from the top of reactor, passing through the transfer line at a concentration of 1 to 40 g/m.sup.3. The particles of natural ores have a good effect of scouring out the deposited coke-like materials and can keep the transfer line efficiently clean even with a small amount of the particles of natural ores, decreasing a pressure drop in the transfer line.

Abstract translation: 在通过天然矿石颗粒的流化床裂解重质烃油的反应器中，焦炭状材料沉积在反应器的顶部或从反应器到洗涤器的输送管线的内表面中。 为了有效地冲出沉积的焦炭状材料，使平均直径为几百微米的天然矿石颗粒被包含在来自反应器顶部的流出气体中，其浓度为1 至40g / m 3。 天然矿石颗粒具有很好的清除沉积的焦炭状物质的效果，并且即使用少量的天然矿石颗粒也能有效地清洁输送管线，从而降低输送管线中的压降。

公开(公告)号：US4180455A

公开(公告)日：1979-12-25

申请号：US864087

申请日：1977-12-23

Applicant: William Taciuk

Inventor： William Taciuk

IPC: B01J8/10 ,  C10C3/00 ,  C10G1/02 ,  C10G9/28 ,  C10G9/20

CPC classification number: C10G1/02 ,  B01J8/10 ,  C10C3/007 ,  C10G9/28 ,  B01J2219/182

Abstract: There is provided an apparatus comprising rotating inner and outer concentric tubes. The inner tube provides a vapor zone and the annular space between the tubes provides a combustion zone. Hot particulate solids, such as sand, are advanced along an endless path through the vapor zone, back through the combustion zone and back into the vapor zone. In the vapor zone, oil is sprayed on the hot solids. The mixture is mixed and cascaded to obtain heat transfer from the solids to the oil, thereby generating hydrocarbon vapors and coke deposition on the solids. The vapors are removed by suction from the vapor zone. The coked solids are transferred into the combustion zone and cascaded and lifted and dropped therein to mix with added oxygen. Coke is burned to heat the solids which are then returned to the vapor zone. The vapors generated in the combustion zone are removed by suction. Segregation of the atmospheres in the two zones is achieved by a combination of maintaining equal pressures in the zones and using the solids, being transferred from one zone to the other, to block gas flow.

Abstract translation: 提供了一种包括旋转内部和外部同心管的装置。 内管提供蒸气区，管之间的环形空间提供燃烧区。 热的颗粒固体，例如砂，沿着环形路径前进通过蒸汽区，通过燃烧区返回到蒸汽区。 在蒸气区，油被喷在热固体上。 将混合物混合并级联以获得从固体到油的热传递​​，从而在固体上产生烃蒸气和焦炭沉积。 通过蒸气区抽吸除去蒸汽。 将焦炭固体转移到燃烧区中并级联并提升并滴入其中以与添加的氧混合。 将焦炭燃烧以加热固体，然后将其返回到蒸气区。 在燃烧区产生的蒸气通过抽吸除去。 通过在区域中保持相等的压力并使用固体从一个区域转移到另一个区域来阻止气体流动的组合来实现两个区域中的气氛的分离。