公开(公告)号：US10011666B2

公开(公告)日：2018-07-03

申请号：US15514871

申请日：2015-09-22

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Pietro Baita ,  Tiziano Dall'Occo ,  Maria Di Diego ,  Dario Liguori ,  Lorella Marturano ,  Gabriele Mei ,  Giampiero Morini ,  Roberta Pica

IPC: C08F110/02 ,  C08F4/649 ,  C08F2/34 ,  C08F2/38 ,  B01J8/24

CPC classification number: C08F110/02 ,  C08F2410/02 ,  C08F2500/12 ,  C08F2500/18 ,  C08F4/6494 ,  C08F4/6493 ,  C08F4/6492 ,  C08F4/6543

Abstract: The present disclosure provides a catalyst system made from or containing: (A) a solid catalyst component made from or containing (i) a titanium compound supported on a magnesium dichloride; (B) an aluminum alkyl compound; and (C) a halogenated organic ester of formula A-COOR, wherein R is a C1-C10 hydrocarbon group and A is a C1-C15 saturated or unsaturated hydrocarbon group in which at least one of the hydrogen atoms is replaced by a chlorine atom. The present disclosure also provides a process for preparing an olefinic polymer, including a polymerization step of polymerizing an olefin in the presence of the catalyst system. The present disclosure also provides an olefinic polymer made therefrom.

公开(公告)号：US20180179371A1

公开(公告)日：2018-06-28

申请号：US15736248

申请日：2016-06-22

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： CLAUDIO CAVALIERI ,  MICHELE GRAZZI ,  ROBERTO PANTALEONI

IPC: C08L23/16

CPC classification number: C08L23/16 ,  C08F210/16 ,  C08L23/12 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2205/03 ,  C08L2205/035 ,  C08L2308/00 ,  C08L2310/00 ,  C08L2314/02 ,  C08L23/06 ,  C08F110/06 ,  C08F4/6492 ,  C08F2/001 ,  C08F210/06 ,  C08F2500/08 ,  C08F2500/12 ,  C08F2500/17

Abstract: Polyolefin composition made from or containing:(A) about 5 to about 35% by weight of a propylene-based polymer containing about 90% by weight or more of propylene units and containing about 10% by weight or less of a fraction soluble in xylene at 25° C. (XSA); (B) about 25 to about 50% by weight, of an ethylene homopolymer containing about 5% by weight or less of a fraction soluble in xylene at 25° C. (XSB) referred to the weight of (B); and (C) about 30 to about 60% by weight, of a copolymer of ethylene and propylene containing from about 25% to about 75% by weight of ethylene units and containing from about 55% to about 95% by weight, of a fraction soluble in xylene at 25° C. (XSC). Following progressive fractionation having first, second, and third dissolution temperatures, the composition has about 20% by weight or less collected at second dissolution temperature.

公开(公告)号：US20180079837A1

公开(公告)日：2018-03-22

申请号：US15826362

申请日：2017-11-29

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： DANIELE EVANGELISTI ,  BENEDETTA GADDI ,  GIANNI COLLINA

IPC: C08F4/649 ,  C08F10/00 ,  C08F4/654 ,  C08F4/651

CPC classification number: C08F4/6494 ,  C08F10/00 ,  C08F4/6545 ,  C08F4/651 ,  C08F110/06 ,  C08F2500/17

Abstract: Solid adducts comprising MgCl2 and an alcohol ROH in which R is a C1-C20 hydrocarbon group, in which the amount of alcohol ranges from higher than 42% to 60% by weight and the porosity determined with Hg method due to pores up to 1 μm and expressed in cm3/g, is such that the value of its ratio with the amount of alcohol in percentage falls above the straight line defined by the equation y=−0.0158x+1.03 in which y is the porosity of the adduct and x is the alcohol percentage by weight.

公开(公告)号：US09914826B2

公开(公告)日：2018-03-13

申请号：US15328845

申请日：2015-06-29

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Monica Galvan ,  Andreas Neumann ,  Sandro Bolognesi ,  Francesca Tisi ,  Giampaolo Pellegatti

IPC: B29D22/00 ,  C08L23/14 ,  B32B1/08 ,  B32B7/12 ,  B32B15/085 ,  B32B27/20 ,  F16L9/12

CPC classification number: C08L23/14 ,  B32B1/08 ,  B32B7/12 ,  B32B15/08 ,  B32B15/085 ,  B32B27/08 ,  B32B27/20 ,  B32B27/304 ,  B32B27/32 ,  B32B2264/10 ,  B32B2264/102 ,  B32B2264/104 ,  B32B2307/702 ,  B32B2307/704 ,  B32B2597/00 ,  C08L23/12 ,  C08L23/142 ,  C08L2203/18 ,  C08L2205/025 ,  F16L9/12

Abstract: A polyolefin composition made from or containing (A) from 90.0 to 99.0 wt % of a first propylene ethylene copolymer wherein (i) the ethylene derived units is between 1.0 and 8.0 wt %; (ii) the melting temperature ranges from 135 to 155° C.; (iii) the melt flow rate (230° C./5 kg ISO 1133) ranges from 0.2 to 3.5 g/10 min; (iv) the xylene solubles at 25° C. ranges from 10.0 to 4.0 wt %; (v) the polydispersity index ranges from 3.0 to 7.0; and (B) from 1.0 to 10.0 wt % of a second propylene ethylene copolymer (i) containing from 8.0 to 20.0 wt % of ethylene derived units; and having a MFR (measured at 190° C. 2.16 kg of load) between 0.5 and 5.0 g/10 min, wherein (a) the resulting polyolefin composition has a melt flow rate (230° C./5 kg ISO 1133) ranging from 0.2 to 4.0 g/10 min and (b) the sum A+B being 100.

公开(公告)号：US20170327603A1

公开(公告)日：2017-11-16

申请号：US15533856

申请日：2015-12-01

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： PIETRO BAITA ,  TIZIANO DALL'OCCO ,  MARIA DI DIEGO ,  DARIO LIGUORI ,  LORELLA MARTURANO ,  ANDREAS MAUS ,  GABRIELE MEI ,  GERHARDUS MEIER ,  GIAMPIERO MORINI ,  ROBERTA PICA ,  ULF SCHUELLER

IPC: C08F2/34 ,  C08F110/02 ,  C08F4/649

CPC classification number: C08F2/34 ,  C08F4/6493 ,  C08F4/6494 ,  C08F110/02 ,  C08F2410/02 ,  C08F2500/12 ,  C08F2500/18 ,  C08F4/6543 ,  C08F210/02

Abstract: The present disclosure provides a gas-phase polymerization process for preparing polyethylene, wherein halogenated alcohols in combination with a Ti based catalyst component and aluminum alkyls as co-catalyst suppress ethane formation or increase polymerization activity.

公开(公告)号：US20170210894A1

公开(公告)日：2017-07-27

申请号：US15328845

申请日：2015-06-29

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： MONICA GALVAN ,  ANDREAS NEUMANN ,  SANDRO BOLOGNESI ,  FRANCESCA TISI ,  GIAMPAOLO PELLEGATTI

IPC: C08L23/14 ,  F16L9/12 ,  B32B15/085 ,  B32B27/20 ,  B32B1/08 ,  B32B7/12

CPC classification number: C08L23/14 ,  B32B1/08 ,  B32B7/12 ,  B32B15/08 ,  B32B15/085 ,  B32B27/08 ,  B32B27/20 ,  B32B27/304 ,  B32B27/32 ,  B32B2264/10 ,  B32B2264/102 ,  B32B2264/104 ,  B32B2307/702 ,  B32B2307/704 ,  B32B2597/00 ,  C08L23/12 ,  C08L23/142 ,  C08L2203/18 ,  C08L2205/025 ,  F16L9/12

Abstract: A polyolefin composition made from or containing (A) from 90.0 to 99.0 wt % of a first propylene ethylene copolymer wherein (i) the ethylene derived units is between 1.0 and 8.0 wt %; (ii) the melting temperature ranges from 135 to 155° C.; (iii) the melt flow rate (230° C./5 kg ISO 1133) ranges from 0.2 to 3.5 g/10 min; (iv) the xylene solubles at 25° C. ranges from 10.0 to 4.0 wt %; (v) the polydispersity index ranges from 3.0 to 7.0; and (B) from 1.0 to 10.0 wt % of a second propylene ethylene copolymer (i) containing from 8.0 to 20.0 wt % of ethylene derived units; and having a MFR (measured at 190° C. 2.16 kg of load) between 0.5 and 5.0 g/10 min, wherein (a) the resulting polyolefin composition has a melt flow rate (230° C./5 kg ISO 1133) ranging from 0.2 to 4.0 g/10 min and (b) the sum A+B being 100.

公开(公告)号：US20170210893A1

公开(公告)日：2017-07-27

申请号：US15325035

申请日：2015-06-29

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： MARCO CIARAFONI ,  PAOLA MASSARI ,  ROBERTO PANTALEONI

IPC: C08L23/12

CPC classification number: C08L23/12 ,  C08L2205/02 ,  C08L2205/03 ,  C08L2207/02 ,  C08L23/16 ,  C08L23/06

Abstract: The present disclosure relates to a polyolefin composition comprising: a propylene homopolymer, a copolymer of ethylene and propylene, and an ethylene homopolymer with enhanced oligomer emission and gloss properties.

公开(公告)号：US09670298B2

公开(公告)日：2017-06-06

申请号：US14432080

申请日：2013-09-23

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： Alessandro Mignogna ,  Davide Balboni ,  Antonio Cristofori ,  Giampiero Morini

IPC: B01J31/00 ,  B01J37/00 ,  B01J27/24 ,  C08F4/02 ,  C08F4/60 ,  C08F4/06 ,  C08F2/00 ,  C08F4/00 ,  C08F4/44 ,  C08F110/06 ,  C08F10/06

CPC classification number: C08F110/06 ,  C08F10/06 ,  C08F4/651 ,  C08F4/6543 ,  C08F2500/12

Abstract: Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor of formula (I) Where R1 and R2, independently, are selected from hydrogen and C1-C15 hydrocarbon groups, optionally contain an heteroatom selected from halogen, P, S, N, O and Si, which can be fused together to form one or more closed cycles and A is a bivalent bridging group.

公开(公告)号：US20170066855A1

公开(公告)日：2017-03-09

申请号：US15309138

申请日：2015-04-28

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： PAOLA MASSARI ,  FABRIZIO PIEMONTESI ,  GIANNI VITALE ,  CAROLINE CATHELIN ,  GIAMPIERO MORINI ,  MARCO CIARAFONI ,  CLAUDIO CAVALIERI ,  TIZIANA CAPUTO

IPC: C08F210/06 ,  C08J5/18

CPC classification number: C08F210/06 ,  C08F210/02 ,  C08F2800/20 ,  C08J5/18 ,  C08J2323/14 ,  C08F210/16 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/26 ,  C08F10/00 ,  C08F4/6492 ,  C08F4/6574

Abstract: The present disclosure relates to a propylene ethylene copolymer comprising: an ethylene content of between 1.8 and 10.0% by weight; a molecular weight distribution (MWD), expressed in terms of Mw/Mn, greater than 4.0; a content of xylene soluble fraction (XS) and ethylene content (C2) that fulfills the following relationship: XS

Abstract translation: 一种丙烯乙烯共聚物，其特征在于以下特征：乙烯含量在1.8至10.0重量％之间; 分子量分布（MWD），以Mw / Mn表示，大于4.0; 二甲苯可溶成分（XS）和乙烯含量（C2）的含量满足下列关系：XS <（C2x2.1）-2.4其中：XS​​ =在25℃下可溶于二甲苯的馏分的重量％ C2 =通过NMR确定的共聚物中乙烯单元的重量％。

公开(公告)号：US20170002108A1

公开(公告)日：2017-01-05

申请号：US15106701

申请日：2014-12-15

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Giuseppina Maria ALGOZZINI ,  Nicolo ARICH DE FINETTI ,  Maria DI DIEGO ,  Anna FAIT ,  Luca RANZANI

IPC: C08F4/02

CPC classification number: C08F4/02 ,  C08F10/00 ,  C08F4/6543 ,  C08F4/6545 ,  C08F4/022 ,  C08F110/06 ,  C08F2500/24

Abstract: The present disclosure relates to a process for preparing a MgCl2-alcohol adduct which comprises (a) forming a mixture of an MgCl2-alcohol adduct in molten form and a liquid which is immiscible with the adduct, (b) subjecting the mixture to a shear stress to obtain an emulsion, and (c) rapidly cooling the emulsion to solidify the disperse phase and collecting the solid adduct particles, the process being characterized by the fact that step (b) is carried out in a device comprising a first outer and second inner cylindrical members that define an annulus between them, wherein at least one of the cylindrical members rotate with respect to the other.

Abstract translation: 本公开涉及一种制备MgCl 2 - 醇加合物的方法，其包括（a）形成熔融形式的MgCl 2 - 醇加合物和与加合物不混溶的液体的混合物，（b）使混合物经受剪切 应力以获得乳液，和（c）快速冷却乳液以固化分散相并收集固体加合物颗粒，该方法的特征在于以下事实：步骤（b）在包括第一外部和第二部分的装置中进行 内圆柱形构件，其在它们之间限定环形空间，其中至少一个圆柱形构件相对于另一个旋转。