公开(公告)号：US08222470B2

公开(公告)日：2012-07-17

申请号：US12360231

申请日：2009-01-27

Applicant: Vincent Coupard ,  Alexandra Chaumonnot ,  Laurent Simon

Inventor： Vincent Coupard ,  Alexandra Chaumonnot ,  Laurent Simon

IPC: C07C2/10 ,  B01J21/12

CPC classification number: C07C2/10 ,  C10G50/00 ,  C10G2300/1081 ,  C10G2300/1088 ,  C10G2300/1092 ,  C10G2400/22

Abstract: A process for oligomerizing an olefinic hydrocarbon feed is described which consists of bringing said feed into contact with a catalyst comprising a silica-alumina, the silica content of said catalyst being in the range 5% to 95% by weight, said catalyst being prepared using a process comprising at least: a) mixing at least one alumina compound which is partially soluble in an acid medium with either at least one silica compound which is completely soluble in the reaction mixture or a combination formed by at least one silica compound and at least one alumina compound, said silica and alumina compounds being completely soluble in the reaction mixture, in order to form a solid precursor of said catalyst; b) hydrothermal treatment of the solid derived from step a) by calcining in moist air for a period in the range 4 to 7 hours.

Abstract translation: 描述了一种使烯烃进料低聚的方法，其包括使所述进料与包含二氧化硅 - 氧化铝的催化剂接触，所述催化剂的二氧化硅含量在5重量％至95重量％的范围内，所述催化剂使用 一种方法至少包括：a）将至少一种部分可溶于酸性介质的氧化铝化合物与至少一种完全可溶于反应混合物的二氧化硅化合物或由至少一种二氧化硅化合物形成的组合物和至少 一种氧化铝化合物，所述二氧化硅和氧化铝化合物完全溶于反应混合物中，以形成所述催化剂的固体前体; b）通过在潮湿空气中煅烧4至7小时的时间段对来自步骤a）的固体进行水热处理。

公开(公告)号：US20110087059A1

公开(公告)日：2011-04-14

申请号：US12903690

申请日：2010-10-13

Applicant: Laurent SIMON ,  Antoine DAUDIN

Inventor： Laurent SIMON ,  Antoine DAUDIN

IPC: C10G1/00

CPC classification number: B01J29/166 ,  B01J23/883 ,  B01J29/084 ,  B01J29/72 ,  B01J29/7261 ,  B01J29/78 ,  B01J29/7861 ,  B01J37/20 ,  B01J2229/16 ,  B01J2229/20 ,  B01J2229/32 ,  B01J2229/42 ,  C10G3/46 ,  C10G3/47 ,  C10G3/50 ,  C10G3/54 ,  C10G45/64 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/4018 ,  C10G2400/06 ,  C10G2400/08 ,  Y02P30/20

Abstract: This invention describes a process for treatment of feedstocks obtained from a renewable source implementing a catalyst that comprises at least one hydro-dehydrogenating metal that is selected from the group that is formed by the metals of group VIB and group VIII of the periodic table and a substrate that comprises at least one zeolite that has at least one series of channels whose opening is defined by a ring with 8 oxygen atoms modified by a) at least one stage for introducing at least one alkaline cation that belongs to group IA or IIA of the periodic table, b) a stage for treating said zeolite in the presence of at least one molecular compound that contains at least one silicon atom, c) at least one stage of partial exchange of said alkaline cations by NH4+ cations, and d) at least one heat treatment stage.

Abstract translation: 本发明描述了一种处理从可再生原料获得的原料的方法，该方法包括至少一种选自由元素周期表第ⅥB族和Ⅷ族金属形成的基团的至少一种氢化脱氢金属的催化剂，以及 底物，其包含至少一种沸石，其具有至少一个通道系列，其开口由具有8个氧原子的环限定，所述环具有由a）至少一个阶段修饰，用于引入至少一种碱性阳离子，所述碱性阳离子属于 周期表，b）在至少一种含有至少一个硅原子的分子化合物存在下处理所述沸石的阶段，c）至少一个阶段由NH 4 +阳离子部分交换所述碱性阳离子，和d）至少 一个热处理阶段。

公开(公告)号：US20060122446A1

公开(公告)日：2006-06-08

申请号：US11269883

申请日：2005-11-09

Applicant: Sylvain Louret ,  Patrice Font ,  Sylvie Lacombe ,  Eric Sanchez ,  Laurent Simon

Inventor： Sylvain Louret ,  Patrice Font ,  Sylvie Lacombe ,  Eric Sanchez ,  Laurent Simon

IPC: C07C2/06 ,  B01J8/18

CPC classification number: B01J8/125 ,  B01J8/085 ,  B01J8/087 ,  C10G50/00 ,  C10G2300/1088 ,  C10G2300/4018 ,  C10G2400/04

Abstract: A reaction device with staged zones making it possible to implement strongly endothermic or exothermic reactions. The device reduces the differences in catalytic activity between these zones using an addition of fresh or regenerated catalyst at the inlet of each reaction zone and provides an integrated heat exchanger. A process of chemical conversion employs the device for gas-phase and/or liquid-phase exothermic or endothermic reactions, and in particular for the oligomerization reaction of C2 to C12 fractions for the purpose of producing a diesel fraction.

Abstract translation: 具有分段区域的反应装置可以实现强烈的吸热或放热反应。 该装置通过在每个反应区的入口处添加新鲜或再生的催化剂来减少这些区域之间的催化活性的差异，并提供集成的热交换器。 化学转化的方法使用该装置进行气相和/或液相放热或吸热反应，特别是为了制备柴油馏分的C2至C12馏分的低聚反应。

公开(公告)号：US20060115387A1

公开(公告)日：2006-06-01

申请号：US11267570

申请日：2005-11-07

Applicant: Sylvain Louret ,  Patrice Font ,  Sylvie Lacombe ,  Eric Sanchez ,  Laurent Simon

Inventor： Sylvain Louret ,  Patrice Font ,  Sylvie Lacombe ,  Eric Sanchez ,  Laurent Simon

IPC: B01J8/18

CPC classification number: B01J8/125 ,  B01J8/0453 ,  B01J8/0492 ,  B01J8/0496 ,  B01J8/085 ,  B01J8/087 ,  B01J2208/00168 ,  B01J2208/00203 ,  C10G50/00 ,  C10G2300/1088 ,  C10G2400/04

Abstract: This invention relates to a staged-zone reactor of the axial-flow type that makes it possible to implement strongly endothermic or exothermic reactions. The reactor comprises a constriction of the catalytic bed between an upper zone (3a) and a lower zone (3b), making it possible to house in the reactor a heat exchanger for the intermediate heating or cooling of the effluents. Process of chemical conversion using this reactor for exothermic or endothermic reactions in the gas and/or liquid phase, and in particular for the oligomerization reaction of C2 to C12 fractions for the purpose of producing a diesel fraction.

Abstract translation: 本发明涉及一种能够实现强吸热或放热反应的轴流式分级反应器。 反应器包括上部区域（3a）和下部区域（3b）之间的催化床的收缩部，使得可以在反应器中容纳用于中间加热或冷却流出物的热交换器。 用于在气体和/或液相中使用该反应器进行放热或吸热反应的化学转化方法，特别是用于生产柴油馏分的C2至C12馏分的低聚反应的方法。

公开(公告)号：US06921524B2

公开(公告)日：2005-07-26

申请号：US10792914

申请日：2004-03-05

Applicant: Yannick Mathieu ,  Jean-Louis Paillaud ,  Philippe Caullet ,  Nicolas Bats ,  Laurent Simon

Inventor： Yannick Mathieu ,  Jean-Louis Paillaud ,  Philippe Caullet ,  Nicolas Bats ,  Laurent Simon

IPC: C01B39/46 ,  C01B37/00 ,  C01B39/06 ,  C01B39/48

CPC classification number: C01B37/005 ,  C01B39/06

Abstract: The invention concerns a crystalline solid, designated IM-10, which has the X ray diffraction diagram given below. Said solid has a chemical composition, expressed as the anhydrous base, in terms of moles of oxides, in accordance with the formula XO2:mYO2:pZ2O3:qR2/nO:sF, in which R represents one or more cation(s) with valency n, X represents one or more tetravalent element(s) other than germanium, Y represents germanium, Z represents at least one trivalent element and F is fluorine.

Abstract translation: 本发明涉及一种称为IM-10的结晶固体，其具有以下给出的X射线衍射图。 所述固体具有以氧化物的摩尔数表示的无水碱的化学组成，根据式XO 2：mYO 2：pZ 2 其中R表示一个或多个具有化合价n的阳离子，X表示一个或多个四价基团 除锗以外的元素，Y表示锗，Z表示至少一个三价元素，F表示氟。

公开(公告)号：US20050058596A1

公开(公告)日：2005-03-17

申请号：US10902425

申请日：2004-07-30

Applicant: Bogdan Harbuzaru ,  Jean-Louis Paillaud ,  Joel Patarin ,  Nicolas Bats ,  Laurent Simon ,  Catherine Laroche

Inventor： Bogdan Harbuzaru ,  Jean-Louis Paillaud ,  Joel Patarin ,  Nicolas Bats ,  Laurent Simon ,  Catherine Laroche

IPC: C07D498/08 ,  B01J20/06 ,  B01J20/10 ,  B01J20/18 ,  C01B37/00 ,  C01B39/48 ,  C01F7/00 ,  C01B33/36 ,  C01B39/00

CPC classification number: B01J20/10 ,  B01J20/06 ,  C01B37/005 ,  Y10S423/24

Abstract: The invention concerns a IM-11 crystalline solid with structure type LTA, with a neutral framework, having a chemical composition expressed as the anhydrous base in terms of moles of oxide defined by the general formula XO2: mYO2:qR: sF, in which R represents one or more nitrogen-containing organic compounds, X represents one or more tetravalent elements other than germanium, Y represents germanium, F is fluorine, m, q, s represent the number of moles of YO2, R and F respectively, m is in the range 0.1 to 4, and q and s are in the range 0 to 1.

Abstract translation: 本发明涉及结构类型为LTA的IM-11结晶固体，具有中性骨架，其化学组成以无水碱表示，以通式XO2：mYO2：qR：sF所定义的氧化物的摩尔数表示，其中R 表示一种或多种含氮有机化合物，X表示一种或多种除锗以外的四价元素，Y表示锗，F表示氟，m，q表示分别为YO 2，R和F的摩尔数，m为 范围为0.1〜4，q和s为0〜1。

公开(公告)号：US06854785B2

公开(公告)日：2005-02-15

申请号：US10275644

申请日：2001-05-04

Applicant: Laurent Simon ,  Jean-Pierre Eustache

Inventor： Laurent Simon ,  Jean-Pierre Eustache

IPC: B60R16/02 ,  B60J5/00 ,  B60J5/04 ,  B60J5/10 ,  B60Q3/02 ,  B60S1/56

CPC classification number: B60J5/0416

Abstract: The invention concerns an equipment module (22) for a motor vehicle opening panel (12) comprising in particular an interior door trim element (42) and an outer cladding (14) comprising a structural element (20) whereon are directly mounted accessories internal to the opening panel (12), characterized in that the structural element (20) consists of the inner door trim (42).

Abstract translation: 本发明涉及一种用于机动车辆开放面板（12）的设备模块（22），特别地包括内部门装饰元件（42）和外部包层（14），该外部包层（14）包括直接安装在内部的附件 所述开口面板（12）的特征在于，所述结构元件（20）由所述内门装饰件（42）组成。

公开(公告)号：US06637801B1

公开(公告)日：2003-10-28

申请号：US10048376

申请日：2002-01-28

Applicant: Jean-Pierre Eustache ,  Laurent Simon ,  Vincent Izabel

Inventor： Jean-Pierre Eustache ,  Laurent Simon ,  Vincent Izabel

IPC: B62D2506

CPC classification number: B60J5/107 ,  B60J5/10 ,  B60Q1/302 ,  B60S1/0416 ,  B60S1/0419 ,  B60S1/0438 ,  B60S1/583

Abstract: A motor vehicle rear transverse part includes a generally vertically oriented element defining a frame closed by a rear window and an internal support structure and an external fitting panel and also including an equipment module directly mounted on the element and a wiper system for the rear window and a flashing light. The equipment module is received in a housing matching the element wherein it is mounted from outside.

Abstract translation: 机动车辆后横向部分包括大致竖直定向的元件，其限定由后窗封闭的框架和内部支撑结构和外部配件面板，并且还包括直接安装在元件上的设备模块和用于后窗的刮水器系统，以及 闪烁的光芒 设备模块被容纳在与外部匹配的外壳中的外壳中。

公开(公告)号：US11351529B2

公开(公告)日：2022-06-07

申请号：US14005936

申请日：2012-02-10

Applicant: Bertrand Guichard ,  Laurent Simon ,  Valentina De Grandi ,  Delphine Minoux ,  Jean-Pierre Dath

Inventor： Bertrand Guichard ,  Laurent Simon ,  Valentina De Grandi ,  Delphine Minoux ,  Jean-Pierre Dath

IPC: B01J31/34 ,  B01J31/02 ,  B01J38/52 ,  C10G45/04 ,  B01J37/20 ,  C10G47/12 ,  B01J23/882 ,  B01J23/94 ,  B01J35/00 ,  B01J31/04 ,  B01J38/62 ,  C10G45/08 ,  C10G45/50 ,  B01J23/883 ,  B01J37/02 ,  B01J23/85 ,  C10G45/06 ,  C10G45/68 ,  C10G45/10 ,  C10G45/12 ,  C10G45/54 ,  C10G47/14 ,  C10G47/18 ,  B01J21/04 ,  B01J37/00 ,  B01J21/12

Abstract: A catalyst which comprises an amorphous support based on alumina, a C1-C4 dialkyl succinate, citric acid and optionally acetic acid, phosphorus and a hydrodehydrogenating function comprising at least one element from group VIII and at least one element from group VIB; the most intense bands comprised in the Raman spectrum of the catalyst are characteristic of Keggin heteropolyanions (974 and/or 990 cm−1), C1-C4 dialkyl succinate and citric acid (in particular 785 and 956 cm−1). Also a process for preparing said catalyst in which a catalytic precursor in the dried, calcined or regenerated state containing the elements of the hydrodehydrogenating function, and optionally phosphorus, is impregnated with an impregnation solution comprising at least one C1-C4 dialkyl succinate, citric acid and optionally at least one compound of phosphorus and optionally acetic acid, and is then dried. Further, the use of said catalyst in any hydrotreatment process.

公开(公告)号：US09914113B2

公开(公告)日：2018-03-13

申请号：US13345041

申请日：2012-01-06

Applicant: Jeremy Francis ,  Laurent Simon ,  Emmanuelle Guillon ,  Nicolas Bats ,  Avelino Corma ,  Christophe Pichon

Inventor： Jeremy Francis ,  Laurent Simon ,  Emmanuelle Guillon ,  Nicolas Bats ,  Avelino Corma ,  Christophe Pichon

IPC: C10G45/12 ,  C10G47/06 ,  C10G65/12 ,  B01J29/04 ,  B01J29/14 ,  B01J29/16 ,  B01J35/00 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  B01J37/20 ,  C10G49/08

CPC classification number: B01J29/146 ,  B01J29/166 ,  B01J35/002 ,  B01J35/0066 ,  B01J35/109 ,  B01J37/0009 ,  B01J37/0205 ,  B01J37/20 ,  B01J2229/14 ,  B01J2229/16 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/38 ,  B01J2229/42 ,  C10G49/08 ,  C10G2300/301 ,  C10G2300/4018

Abstract: Process for hydrocracking and/or hydrotreatment of hydrocarbon feeds utilizing a catalyst comprising at least one hydro-dehydrogenating element of group VIB and of non-precious group VIII used alone or mixed, and a support comprising at least one porous mineral matrix and at least one dealuminated USY zeolite having an overall silicon-to-aluminium atomic ratio comprised between 2.5 and 10, a fraction by weight of extra-network aluminium atom greater than 10% relative to the total mass of the aluminium present in the zeolite, a mesopore volume measured by nitrogen porosimetry greater than 0.07 ml.g−1, and a crystal parameter a0 of the elemental mesh greater than 24.28 Å, in which a quantity of the element nickel comprised between 0.5 and 3% by weight relative to the total mass of the zeolite is deposited on said USY zeolite and in which said catalyst is in the sulphide form.