公开(公告)号：US20120149557A1

公开(公告)日：2012-06-14

申请号：US13402770

申请日：2012-02-22

Applicant: Sho Hoshino ,  Akimasa Hirai ,  Kenichi Taki ,  Keiichi Narita ,  Satoshi Matsueda ,  Asuka Hori ,  Masahiro Kusaka

Inventor： Sho Hoshino ,  Akimasa Hirai ,  Kenichi Taki ,  Keiichi Narita ,  Satoshi Matsueda ,  Asuka Hori ,  Masahiro Kusaka

IPC: B01J27/053 ,  B01J23/02 ,  B01J23/10 ,  B01J23/00 ,  B01J23/58

CPC classification number: B01D53/9422 ,  B01D2255/10 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/2042 ,  B01D2255/2063 ,  B01D2255/2065 ,  B01D2255/908 ,  B01D2257/404 ,  B01J23/002 ,  B01J23/58 ,  B01J23/63 ,  B01J35/002 ,  B01J35/023 ,  B01J35/04 ,  B01J37/0009 ,  B01J37/031 ,  B01J2523/00 ,  F01N3/10 ,  B01J2523/36 ,  B01J2523/3712 ,  B01J2523/48

Abstract: An exhaust gas-purifying catalyst includes first particles of oxygen storage material, second particles of one or more alkaline-earth metal elements and/or compounds thereof interposed between the first particles, and third particles of one or more precious metal elements interposed between the first particles. A spectrum of a first characteristic X-ray intensity for one of the one or more alkaline-earth metal elements and a spectrum of a second characteristic X-ray intensity for one of the one or more precious metal elements that are obtained by performing a line analysis using energy-dispersive X-ray spectrometry along a length of 500 nm have a correlation coefficient σ(AE,PM) of 0.70 or more.

Abstract translation: 废气净化催化剂包括第一颗粒的储氧材料，介于第一颗粒之间的一种或多种碱土金属元素和/或其化合物的第二颗粒和介于第一颗粒之间的一种或多种贵金属元素的第三颗粒 粒子。 一种或多种碱土金属元素之一的第一特征X射线强度的光谱和通过执行线获得的一种或多种贵金属元素之一的第二特征X射线强度的光谱 使用能量色散X射线光谱分析法，沿500nm的长度分析，相关系数（AE，PM）为0.70以上。

公开(公告)号：US20120088655A1

公开(公告)日：2012-04-12

申请号：US13327375

申请日：2011-12-15

Applicant: Yuji Yabuzaki ,  Akimasa Hirai ,  Kenichi Taki ,  Tomohito Mizukami ,  Satoshi Matsueda

Inventor： Yuji Yabuzaki ,  Akimasa Hirai ,  Kenichi Taki ,  Tomohito Mizukami ,  Satoshi Matsueda

IPC: B01J21/04 ,  B01J27/232 ,  B01J27/25 ,  B01J27/053

CPC classification number: B01J23/58 ,  B01D53/945 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/1025 ,  B01D2255/2027 ,  B01D2255/204 ,  B01D2255/2042 ,  B01D2255/2045 ,  B01D2255/2092 ,  B01D2255/407 ,  B01D2255/9022 ,  B01D2255/908 ,  B01J23/63 ,  B01J27/053 ,  B01J35/002 ,  B01J37/0215 ,  B01J37/0244 ,  B01J37/0248 ,  Y02T10/22 ,  Y10T428/24149 ,  Y10T428/24157 ,  Y10T428/24165

Abstract: An exhaust gas-purifying catalyst includes a substrate, and a catalytic layer supported by the substrate. The catalytic layer includes a support made of alumina, an oxygen storage material, an alkaline earth metal and/or a compound of alkaline-earth metal selectively supported by a surface of the support and dispersed on the surface of the support, and a precious metal supported by the surface of the support. A ratio of a number of moles of the alkaline-earth metal in the catalytic layer with respect to a volumetric capacity of the exhaust gas-purifying catalyst falls within a range of 0.0004 mol/L to 0.35 mol/L.

Abstract translation: 废气净化催化剂包括基板和由基板支撑的催化剂层。 催化剂层包括由氧化铝制成的载体，储氧材料，碱土金属和/或由载体表面选择性地分散在载体表面上的碱土金属的化合物和贵金属 由支撑体的表面支撑。 催化剂层中的碱土类金属的摩尔数相对于排气净化催化剂的体积容量的比例在0.0004mol / L〜0.35mol / L的范围内。

公开(公告)号：US20120065058A1

公开(公告)日：2012-03-15

申请号：US13301859

申请日：2011-11-22

Applicant: Satoshi Matsueda ,  Akimasa Hirai ,  Kenichi Taki ,  Yuji Yabuzaki

Inventor： Satoshi Matsueda ,  Akimasa Hirai ,  Kenichi Taki ,  Yuji Yabuzaki

IPC: B01J21/04

CPC classification number: B01J37/0244 ,  B01D53/945 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/1025 ,  B01D2255/2042 ,  B01D2255/2065 ,  B01D2255/20715 ,  B01D2255/407 ,  B01D2255/9022 ,  B01J23/58 ,  B01J37/0219 ,  F01N2370/02 ,  F01N2510/06 ,  F01N2510/0684 ,  Y02T10/22

Abstract: An exhaust gas-purifying catalyst according to the present invention includes a substrate, a first catalytic layer facing the substrate and includes at least one precious metal selected from the group consisting of palladium and platinum, and alumina doped with an alkaline-earth metal element, and a second catalytic layer facing the substrate with the first catalytic layer interposed therebetween or intervening between the substrate and the first catalytic layer, the second catalytic layer includes rhodium and alumina doped with the alkaline-earth metal element.

Abstract translation: 根据本发明的废气净化催化剂包括基材，面向基材的第一催化剂层，并且包括选自钯和铂中的至少一种贵金属和掺杂有碱土金属元素的氧化铝， 以及第二催化剂层，其中所述第一催化剂层位于所述基板之间或介于所述基板和所述第一催化剂层之间，所述第二催化剂层包括掺杂有所述碱土金属元素的铑和氧化铝。

公开(公告)号：US20090099010A1

公开(公告)日：2009-04-16

申请号：US12301011

申请日：2007-05-31

Applicant: Hiroki Nagashima ,  Akiya Chiba ,  Satoshi Matsueda

Inventor： Hiroki Nagashima ,  Akiya Chiba ,  Satoshi Matsueda

IPC: B01J23/38 ,  B01J23/10

CPC classification number: B01J37/08 ,  B01D53/945 ,  B01D2255/206 ,  B01D2255/2092 ,  B01D2255/407 ,  B01J21/10 ,  B01J23/002 ,  B01J23/63 ,  B01J35/002 ,  B01J37/0215 ,  B01J37/0244 ,  B01J37/03 ,  B01J2523/00 ,  Y02T10/22 ,  B01J2523/25 ,  B01J2523/3712 ,  B01J2523/48 ,  B01J2523/828 ,  B01J2523/22 ,  B01J2523/31

Abstract: An exhaust gas-purifying catalyst whose activity is less prone to be decreased even in the case where used in a high-temperature atmosphere containing oxygen at a high concentration can be realized. The catalytic layer of the catalyst includes an oxide particle, a simple oxide of alkaline-earth element or rare-earth element, and alumina and/or aluminum hydroxide. The oxide particle contains an oxide of rare-earth element and/or zirconium, a composite oxide and a precious metal. The composite oxide contains an alkaline-earth element and at least one of the rare-earth element and zirconium. The composite oxide and a part of the precious metal form a solid solution.

Abstract translation: 即使在高浓度氧气的高温气氛中使用的情况下，即使能够实现活性也不易降低的废气净化用催化剂。 催化剂的催化剂层包括氧化物颗粒，碱土金属或稀土元素的简单氧化物，以及氧化铝和/或氢氧化铝。 氧化物颗粒包含稀土元素和/或锆的氧化物，复合氧化物和贵金属。 复合氧化物含有碱土元素和稀土元素和锆中的至少一种。 复合氧化物和贵金属的一部分形成固溶体。

公开(公告)号：US20090036300A1

公开(公告)日：2009-02-05

申请号：US11915317

申请日：2006-06-02

Applicant: Satoshi Matsueda ,  Mareo Kimura ,  Akimasa Hirai ,  Keiichi Narita ,  Hirohisa Tanaka ,  Mari Uenishi ,  Isao Tan ,  Masashi Taniguchi

Inventor： Satoshi Matsueda ,  Mareo Kimura ,  Akimasa Hirai ,  Keiichi Narita ,  Hirohisa Tanaka ,  Mari Uenishi ,  Isao Tan ,  Masashi Taniguchi

IPC: B01J23/10

CPC classification number: B01J23/63 ,  B01D53/9445 ,  B01D53/945 ,  B01D2255/10 ,  B01D2255/204 ,  B01D2255/206 ,  B01D2255/20715 ,  B01J23/002 ,  B01J23/10 ,  B01J35/002 ,  B01J35/1014 ,  B01J37/0009 ,  B01J37/0205 ,  B01J37/03 ,  B01J37/08 ,  B01J2523/00 ,  F01N3/10 ,  Y02T10/22 ,  B01J2523/25 ,  B01J2523/36 ,  B01J2523/3712 ,  B01J2523/48 ,  B01J2523/828 ,  B01J2523/3706 ,  B01J2523/3725

Abstract: An exhaust gas-purifying catalyst (1) contains a rare-earth element, an alkaline-earth element, zirconium and a precious metal, wherein an atomic ratio of the alkaline-earth element with respect to a sum of the rare-earth element and the zirconium is 10 atomic % or more, a part of the rare-earth element and a part of zirconium form a composite oxide with at least a part of the alkaline-earth element, and the composite oxide and a part of the precious metal form a solid solution.

Abstract translation: 废气净化催化剂（1）含有稀土元素，碱土金属元素，锆和贵金属，其中碱土元素相对于稀土元素和 锆为10原子％以上，部分稀土元素和锆的一部分与至少一部分碱土元素形成复合氧化物，复合氧化物和贵金属的一部分形式 一个坚实的解决方案。

公开(公告)号：US20090023580A1

公开(公告)日：2009-01-22

申请号：US11885632

申请日：2006-02-17

Applicant: Hirohisa Tanaka ,  Kiyotomi Mitsumori ,  Isao Tan ,  Ichiro Takahashi ,  Mari Uenishi ,  Nobuhiko Kajita ,  Masashi Taniguchi ,  Kazuya Naito ,  Mareo Kimura ,  Keiichi Narita ,  Akimasa Hirai ,  Hiromasa Suzuki ,  Satoshi Matsueda ,  Hiroki Nagashima ,  Yoshinori Ishii ,  Norihiko Aono

Inventor： Hirohisa Tanaka ,  Kiyotomi Mitsumori ,  Isao Tan ,  Ichiro Takahashi ,  Mari Uenishi ,  Nobuhiko Kajita ,  Masashi Taniguchi ,  Kazuya Naito ,  Mareo Kimura ,  Keiichi Narita ,  Akimasa Hirai ,  Hiromasa Suzuki ,  Satoshi Matsueda ,  Hiroki Nagashima ,  Yoshinori Ishii ,  Norihiko Aono

IPC: B01J23/10 ,  B01J23/40 ,  B01J27/25 ,  B01J27/053 ,  B01J27/232 ,  B01J31/04

CPC classification number: C01G55/002 ,  B01D53/945 ,  B01D2255/1021 ,  B01D2255/1025 ,  B01D2255/402 ,  B01D2258/012 ,  B01D2258/014 ,  B01J23/002 ,  B01J23/10 ,  B01J23/58 ,  B01J23/894 ,  B01J37/033 ,  B01J37/08 ,  B01J2523/00 ,  C01P2002/34 ,  C01P2002/50 ,  F01N3/2803 ,  F01N2370/02 ,  F01N2510/06 ,  Y02T10/22 ,  B01J2523/23 ,  B01J2523/25 ,  B01J2523/31 ,  B01J2523/36 ,  B01J2523/3706 ,  B01J2523/3712 ,  B01J2523/47 ,  B01J2523/48 ,  B01J2523/822 ,  B01J2523/824 ,  B01J2523/828 ,  B01J2523/842 ,  B01J2523/3725 ,  B01J2523/24

Abstract: An object of the present invention is to provide a catalyst composition containing a perovskite-type composite oxide which exhibits a satisfactory catalytic performance over a long time even in a high temperature atmosphere and has a stable quality in which Rh and/or Pt dissolves to form a solid solution at a high rate.To achieve the object described above, in the present invention the catalyst composition is prepared to comprise an Rh-containing perovskite-type composite oxide represented by the following general formula (I) and/or a Pt-containing perovskite-type composite oxide represented by the following general formula (II) and a thermostable oxide optionally containing a noble metal. A1xA2wB11−(y+z)B2yRhzO3±δ  (I) A3rA4sB31−(t+u)B4tPtuO3±δ′  (II)

Abstract translation: 本发明的目的是提供一种含有钙钛矿型复合氧化物的催化剂组合物，即使在高温气氛中也能长时间表现出令人满意的催化性能，并且具有稳定的质量，其中Rh和/或Pt溶解形成 稳固的解决方案。 为了实现上述目的，在本发明中，催化剂组合物被制备为包含由以下通式（I）表示的含Rh的钙钛矿型复合氧化物和/或由以下通式（I）表示的含Pt的钙钛矿型复合氧化物 以下通式（II）和任选含有贵金属的热稳定性氧化物。 <？in-line-formula description =“In-line Formulas”end =“lead”？> A1xA2wB11-（y + z）B2yRhzO3±delta（I）<？in-line-formula description =“In-line Formulas” end =“tail”？> <？in-line-formula description =“In-line Formulas”end =“lead”？> A3rA4sB31-（t + u）B4tPtuO3±delta'（II） description =“内联公式”end =“tail”？>

公开(公告)号：US09364793B2

公开(公告)日：2016-06-14

申请号：US14259933

申请日：2014-04-23

Applicant: Satoshi Matsueda ,  Akimasa Hirai ,  Kenichi Taki ,  Yuji Yabuzaki

Inventor： Satoshi Matsueda ,  Akimasa Hirai ,  Kenichi Taki ,  Yuji Yabuzaki

IPC: B01J27/053 ,  B01J31/26 ,  B01D53/94 ,  B01J23/58 ,  B01J35/02 ,  B01J37/02

CPC classification number: B01D53/944 ,  B01D53/945 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/1025 ,  B01D2255/204 ,  B01D2255/2042 ,  B01D2255/2092 ,  B01D2255/407 ,  B01D2255/9022 ,  B01D2255/908 ,  B01D2255/9202 ,  B01J23/58 ,  B01J27/053 ,  B01J31/26 ,  B01J35/023 ,  B01J37/0215 ,  B01J37/0219 ,  B01J37/0244 ,  F01N2370/02 ,  F01N2510/06 ,  F01N2510/0684 ,  Y02T10/22

Abstract: An exhaust gas-purifying catalyst includes a substrate, and a catalytic layer facing the substrate and including a precious metal, alumina, an oxygen storage material, and a sulfate of an alkaline-earth metal having an average particle diameter falling within a range of 0.01 to 0.70 μm, the average particle diameter being obtained by observation using a scanning electron microscope. Another exhaust gas-purifying catalyst includes a substrate, and a catalytic layer formed on the substrate using slurry containing a precious metal, alumina, an oxygen storage material, and a sulfate of an alkaline-earth metal having an average particle diameter falling within a range of 0.01 to 0.70 μm, the average particle diameter being obtained by observation using a scanning electron microscope.

Abstract translation: 废气净化催化剂包括基材和面向基材的催化剂层，并且包含贵金属，氧化铝，储氧材料和平均粒径在0.01以下的碱土金属的硫酸盐 通过使用扫描型电子显微镜观察得到的平均粒径为0.70μm。 另一种废气净化催化剂包括基材和使用含有贵金属，氧化铝，储氧材料和平均粒径落在一定范围内的碱土金属硫酸盐的浆料在基材上形成的催化剂层 为0.01〜0.70μm，通过使用扫描型电子显微镜观察得到的平均粒径。

公开(公告)号：US09358535B2

公开(公告)日：2016-06-07

申请号：US13356158

申请日：2012-01-23

Applicant: Satoshi Matsueda ,  Akimasa Hirai ,  Kenichi Taki ,  Keiichi Narita ,  Asuka Hori ,  Masahiro Kusaka

Inventor： Satoshi Matsueda ,  Akimasa Hirai ,  Kenichi Taki ,  Keiichi Narita ,  Asuka Hori ,  Masahiro Kusaka

IPC: B01J23/44 ,  B01J35/00 ,  B01D53/94 ,  B01J23/00 ,  B01J23/63 ,  B01J23/652 ,  B01J35/02 ,  B01J37/00 ,  B01J37/02 ,  B01J37/03 ,  B01J23/42

CPC classification number: B01J35/002 ,  B01D53/945 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/2061 ,  B01D2255/2063 ,  B01D2255/20707 ,  B01D2255/20776 ,  B01D2255/30 ,  B01D2255/407 ,  B01D2255/908 ,  B01J23/002 ,  B01J23/42 ,  B01J23/44 ,  B01J23/63 ,  B01J23/6527 ,  B01J35/023 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/03 ,  B01J2523/00 ,  F01N2370/02 ,  Y02T10/22 ,  B01J2523/3712 ,  B01J2523/3725 ,  B01J2523/48 ,  B01J2523/36

Abstract: An exhaust gas-purifying catalyst includes first particles of oxygen storage material, second particles of one or more acidic oxides interposed between the first particles, and third particles of one or more precious metal elements interposed between the first particles, wherein a spectrum of a characteristic X-ray intensity for one of constituent elements of the acidic oxide(s) other than oxygen and a spectrum of a characteristic X-ray intensity for one of the precious metal element(s) that are obtained by performing a line analysis using energy-dispersive X-ray spectrometry along a length of 500 nm have a correlation coefficient of 0.70 or more.

Abstract translation: 废气净化催化剂包括第一颗粒的储氧材料，介于第一颗粒之间的一种或多种酸性氧化物的第二颗粒和介于第一颗粒之间的一种或多种贵金属元素的第三颗粒，其特征在于， 除了氧以外的酸性氧化物的构成成分之一的X射线强度以及通过使用能量线进行线分析而获得的贵金属元素之一的特征X射线强度的光谱， 沿着500nm长度的分散X射线光谱测定具有0.70以上的相关系数。

公开(公告)号：US20120122667A1

公开(公告)日：2012-05-17

申请号：US13356158

申请日：2012-01-23

Applicant: Satoshi Matsueda ,  Akimasa Hirai ,  Kenichi Taki ,  Keiichi Narita ,  Asuka Hori ,  Masahiro Kusaka

Inventor： Satoshi Matsueda ,  Akimasa Hirai ,  Kenichi Taki ,  Keiichi Narita ,  Asuka Hori ,  Masahiro Kusaka

IPC: B01J23/44 ,  B01J23/42 ,  B01J23/30 ,  B01J23/00 ,  B01J21/06

CPC classification number: B01J35/002 ,  B01D53/945 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/2061 ,  B01D2255/2063 ,  B01D2255/20707 ,  B01D2255/20776 ,  B01D2255/30 ,  B01D2255/407 ,  B01D2255/908 ,  B01J23/002 ,  B01J23/42 ,  B01J23/44 ,  B01J23/63 ,  B01J23/6527 ,  B01J35/023 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/03 ,  B01J2523/00 ,  F01N2370/02 ,  Y02T10/22 ,  B01J2523/3712 ,  B01J2523/3725 ,  B01J2523/48 ,  B01J2523/36

Abstract: An exhaust gas-purifying catalyst includes first particles of oxygen storage material, second particles of one or more acidic oxides interposed between the first particles, and third particles of one or more precious metal elements interposed between the first particles, wherein a spectrum of a characteristic X-ray intensity for one of constituent elements of the acidic oxide(s) other than oxygen and a spectrum of a characteristic X-ray intensity for one of the precious metal element(s) that are obtained by performing a line analysis using energy-dispersive X-ray spectrometry along a length of 500 nm have a correlation coefficient of 0.70 or more.

Abstract translation: 废气净化催化剂包括第一颗粒的储氧材料，介于第一颗粒之间的一种或多种酸性氧化物的第二颗粒和介于第一颗粒之间的一种或多种贵金属元素的第三颗粒，其特征在于， 除了氧以外的酸性氧化物的构成成分之一的X射线强度以及通过使用能量线进行线分析而获得的贵金属元素之一的特征X射线强度的光谱， 沿着500nm长度的分散X射线光谱测定具有0.70以上的相关系数。

公开(公告)号：US20120094827A1

公开(公告)日：2012-04-19

申请号：US13273403

申请日：2011-10-14

Applicant: Satoshi Matsueda ,  Akimasa Hirai ,  Kenichi Taki ,  Yuji Yabuzaki ,  Sho Hoshino

Inventor： Satoshi Matsueda ,  Akimasa Hirai ,  Kenichi Taki ,  Yuji Yabuzaki ,  Sho Hoshino

IPC: B01J23/10 ,  B01J23/00

CPC classification number: B01J35/023 ,  B01D53/945 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/1025 ,  B01D2255/2061 ,  B01D2255/2063 ,  B01D2255/2065 ,  B01D2255/2066 ,  B01D2255/2068 ,  B01D2255/20715 ,  B01D2255/40 ,  B01D2255/407 ,  B01D2255/908 ,  B01D2255/9202 ,  B01D2258/014 ,  B01J23/10 ,  B01J23/464 ,  B01J23/63 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/0221 ,  B01J37/04 ,  Y02T10/22

Abstract: The exhaust gas-purifying catalyst includes a first oxide particle with an oxygen storage capacity, one or more second oxide particles partially or entirely covering a surface of the first oxide particle and having an oxygen storage capacity lower than that of the first oxide particle, an average particle diameter Dav of the one or more second oxide particles being smaller than that of the first oxide particle, and precious metal particles supported on at least one of the second oxide particle.

Abstract translation: 废气净化催化剂包括具有储氧能力的第一氧化物颗粒，部分或全部覆盖第一氧化物颗粒的表面并具有低于第一氧化物颗粒的储氧能力的一个或多个第二氧化物颗粒， 一个或多个第二氧化物颗粒的平均粒径Dav小于第一氧化物颗粒的平均粒径Dav，以及负载在至少一个第二氧化物颗粒上的贵金属颗粒。