摘要:
A method for the direct synthesis of a crystalline material with the AEI zeolithic structure containing iron-species and being essentially free of alkali ions, comprising the following steps: (i) preparation of a mixture containing water, a high-silica zeolite as a main source of silica and alumina, an alkyl-substituted cyclic ammonium cation as organic structure directing agent (OSDA), a source of iron, and a source of an alkali metal ion [Alk], to obtain a final synthesis mixture having the following molar composition: SiO2:aAl2O3:bFe:cOSDA:dAlk:eH2O wherein a is in the range from 0.001 to 0.2; wherein b is in the range from 0.001 to 0.2; wherein c is in the range from 0.01 to 2; wherein d is in the range from 0.001 to 2; wherein e is in the range from 1 to 200; (ii) crystallization of the mixture achieved in (i); (iii) recovery of the crystalline material achieved in (ii); (iv) calcination of the crystalline material from step (iii); and (v) removal of the alkali metal cation, present in the calcined crystalline material after step (iv) to obtain a final molar composition: SiO2:oAl2O3:pFe:qAlk wherein o is in the range from 0.001 to 0.2, p is in the range from 0.001 to 0.2 and q is below 0.02.
摘要:
A method of utilizing a catalyst for the sterilization, disinfection and purification of indoor air. The catalyst carrier is made of inorganic porous material such as Silica, Zeolite, Diatomite, Sepiolite, Montmoroillonite, and Aluminum oxide. The catalyst carrier can also be made of Cordierite, or Mullite ceramic honeycomb. After dipping into stabilized sodium hypochlorite solution or stabilized chlorine dioxide solution, the catalyst is produced after dehydration. The catalyst is irradiated with ultraviolet lamp to generate gas-phase free radicals including reactive particles such as .OH, .ClO2, .HO2, .O, thereby sterilizing microbial air pollutants such as viruses, bacteria, fungi and other microorganisms, and remove chemical air pollutants such as formaldehyde.
摘要:
A composition and method for producing the same are provided. The composition includes transition metal oxides adhered to a surface of a cerium oxide support, and can additionally include alkali metal or alkaline earth metal promotors. The method includes incipient wetness impregnation of the support with metal salt in solution, and can include impregnation with a metal chelator salt. The composition can be useful as a catalyst for the reduction of noxious gases in combustion exhaust streams. The composition can be of particular use as a component of an automobile catalytic converter, for the specific catalytic reduction of nitrogen oxides to nitrogen gas.
摘要:
Both a system and a method for scrubbing a contaminated gas stream with a glycerol solution are disclosed. The system includes a contaminated gas stream in need of purification, along with a column which receives the contaminated gas stream. A glycerol solution is also received by the column and is used to scrub the contaminated gas stream in the column. The glycerol solution is used to reduce at least three contaminants from the gas stream, and includes greater than 50% glycerol and less than 98% glycerol. In one embodiment, the glycerol solution includes between 0.5% to 10% salts, wherein the salts are sodium based, potassium based or a combination thereof. The salts act catalytically to convert glycerol and carbon dioxide to glycerol carbonate.
摘要:
A high-temperature NOx occlusion reduction type catalyst in which an NOx occlusion material containing an alkali metal is supported, and a low-temperature NOx occlusion reduction type catalyst in which an NOx occlusion material containing an alkaline earth metal is supported, are disposed in series on an upstream side and a downstream side, respectively, of an exhaust gas purification system. An oxidation catalyst is disposed on an upstream side of the high-temperature NOx occlusion reduction type catalyst. The desulfurization of the NOx occlusion reduction type catalysts is facilitated, and the NOx reduction efficiency is improved by the partial oxidation of hydrocarbons in the exhaust gas, while a wide NOx active temperature window is achieved.
摘要:
An embodiment relates to a photocatalytic composite material comprising (a) a first component that generates a photoexcited electron and has at least a certain minimum bandgap to absorb visible light and a structure that substantially prevents the recombination of the photoexcited electron and a hole; (b) a second component that adsorbs/absorbs an oxide of carbon; and (c) a third component that splits the oxide of carbon into carbon and oxygen using the photoexcited electron.
摘要:
The present invention relates to an oxidation catalyst, a method for preparing the same, and a filter for exhaust gas purification comprising the same and, more specifically, to an oxidation catalyst, a method for preparing the same, and a filter for exhaust gas purification comprising the same, the oxidation catalyst being formed by comprising an amorphous metal alloy powder, thereby being preparable at a low cost, being capable of enhancing purification efficiency for exhaust gas when applied to the filter for exhaust gas purification, and being capable of deriving reliability enhancement for operation of an exhaust gas purifier having the filter for exhaust gas purification mounted therein. To this end, the present invention provides an oxidation catalyst, a method for preparing the same, and a filter for exhaust gas purification comprising the same, the oxidation catalyst characterized by being coated onto the carrier surface of the filter for exhaust gas purification and being formed by comprising an amorphous metal alloy powder.
摘要:
The present invention relates to an application of polyoxometalates with good water solubility in the preparation of disinfectant for sterilizing or removing formaldehyde. The present invention provides a sterilizing and disinfecting system utilizing oxygen in the air as an oxidizing agent, killing microorganisms via catalysis and oxidation, and particularly suitable for an air purification system. If the air is constantly introduced in, the disinfectant of the present invention can be used for a long time, without need of anti-viral drugs or peroxides having potential safety hazard, and without use of irritant substances containing halogen and alcohol having explosive hazard. Without using precious metals, the disinfectant system is easy to prepare and has low cost, dose not cause secondary pollution, and has a good application prospect.
摘要:
Described is a copper containing ZSM-34, OFF and/or ERI zeolitic material having a silica to alumina mole ratio ranging from about 4 to about 50 and a copper content, reported as CuO, ranging from about 1 to about 10 wt.-%, based on the total weight of the calcined zeolitic material, and having an alkali metal content, reported as metal oxide, ranging from about 1.5 to about 12 wt.-%.
摘要:
A sorbent composition that is useful for injection into a flue gas stream of a coal burning furnace to efficiently remove mercury from the flue gas stream. The sorbent composition may include a sorbent with an associated ancillary catalyst component that is a catalytic metal, a precursor to a catalytic metal, a catalytic metal compound or a precursor to a catalytic metal compound. Alternatively, a catalytic metal or metal compound, or their precursors, may be admixed with the coal feedstock prior to or during combustion in the furnace, or may be independently injected into a flue gas stream. A catalytic promoter may also be used to enhance the performance of the catalytic metal or metal compound.