公开(公告)号：US09458327B2

公开(公告)日：2016-10-04

申请号：US14243049

申请日：2014-04-02

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Kevin M. Lewandowski ,  Larry R. Krepski ,  Yizhong Wang ,  Joel D. Oxman ,  Peiwang Zhu ,  Brian N. Holmes ,  Thomas P. Klun ,  Bryan V. Hunt

IPC: C09D4/00 ,  C08F22/22 ,  C08F222/22 ,  C07C219/06 ,  C07C229/16 ,  C07C271/16 ,  C07D233/60 ,  C08F222/10

CPC classification number: C09D4/00 ,  C07C219/06 ,  C07C229/16 ,  C07C271/16 ,  C07D233/60 ,  C08F22/22 ,  C08F222/1006 ,  C08F222/22

Abstract: A multifunctional polymerizable ionic liquid is described comprising an anion and a cationic group having at least two ethylenically unsaturated polymerizable groups, each bonded to the cationic group via a divalent non-alkyl linking group. The multifunctional linking groups independently comprise a heteroatom such as oxygen or nitrogen. The linking groups may independently comprise one or more linkages such as an amide, urea, and more typically a urethane or ester linkage. The ethylenically unsaturated polymerizable groups are typically (meth)acrylate groups. Coatings and coated articles are also described.

Abstract translation: 描述了一种多功能可聚合离子液体，其包含具有至少两个烯属不饱和可聚合基团的阴离子和阳离子基团，各自通过二价非烷基连接基团与阳离子基团键合。 多官能连接基团独立地包含杂原子如氧或氮。 连接基团可以独立地包含一个或多个键，例如酰胺，脲，更典型的是氨基甲酸酯或酯键。 烯键式不饱和可聚合基团通常为（甲基）丙烯酸酯基团。 还描述了涂层和涂层制品。

公开(公告)号：US09414996B2

公开(公告)日：2016-08-16

申请号：US14437200

申请日：2013-10-31

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Guy D. Joly ,  Ahmed S. Abuelyaman ,  Ann R. Fornof ,  Bradley D. Craig ,  Larry R. Krepski ,  William H. Moser ,  Serkan Yurt ,  Joel D. Oxman ,  Afshin Falsafi

IPC: A61K6/083 ,  A61K6/00 ,  C09J133/14

CPC classification number: A61K6/083 ,  A61K6/0023 ,  A61K6/0088 ,  A61K6/0835 ,  C09J133/14 ,  C08L33/10

Abstract: A curable dental composition comprising an addition-fragmentation agent and a curable dental resin is disclosed.

Abstract translation: 公开了一种包含加成碎裂剂和可固化牙科用树脂的可固化牙科用组合物。

公开(公告)号：US09403966B2

公开(公告)日：2016-08-02

申请号：US14674666

申请日：2015-03-31

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Guy D. Joly ,  Larry R. Krepski ,  Ann R. Fornof ,  Serkan Yurt ,  Babu N. Gaddam ,  Ahmed S. Abuelyaman

IPC: C07C67/00 ,  C08K5/205 ,  C07C69/593 ,  C07C271/16 ,  C07C67/14 ,  C07C67/26 ,  A61K6/083 ,  C08K3/22 ,  C08K3/36 ,  C08K5/11 ,  C08K5/12 ,  C09D133/08

CPC classification number: C08K5/205 ,  A61K6/083 ,  C07C67/14 ,  C07C67/26 ,  C07C69/593 ,  C07C271/16 ,  C08K3/22 ,  C08K3/36 ,  C08K5/11 ,  C08K5/12 ,  C09D133/08 ,  C08L33/10 ,  C08L33/08

Abstract: Addition-fragmentation agents of the formula are disclosed: wherein R1, R2 and R3 are each independently Z-Q-, a (hetero)alkyl group or a (hetero)aryl group with the proviso that at least one of R1, R2 and R3 is Zm-Q-, Q is a linking group have a valence of m+1; Z is an ethylenically unsaturated polymerizable group, m is 1 to 6; each X1 is independently —O— or —NR4—, where R4 is H or C1-C4 alkyl, and n is 0 or 1.

Abstract translation: 公开了下式的加成碎裂剂：其中R1，R2和R3各自独立地为ZQ-，（杂）烷基或（杂）芳基，条件是R1，R2和R3中的至少一个为Zm -Q-，Q为连接基团，其价数为m + 1; Z为烯键式不饱和可聚合基团，m为1至6; 每个X1独立地是-O-或-NR4-，其中R4是H或C1-C4烷基，n是0或1。

公开(公告)号：US09243172B2

公开(公告)日：2016-01-26

申请号：US14619141

申请日：2015-02-11

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Larry R. Krepski ,  Babu N. Gaddam ,  Marie Aloshyna ep Lesuffleur ,  Arlin L. Weikel ,  Kathleen S. Shafer

IPC: C08F2/46 ,  C08F2/50 ,  C08G61/04 ,  C09J133/08 ,  C09J133/06 ,  C09J133/10 ,  C08K5/07 ,  C08K5/08 ,  C08K5/45

CPC classification number: C09J133/08 ,  C08K5/07 ,  C08K5/08 ,  C08K5/45 ,  C08L2312/06 ,  C09J133/06 ,  C09J133/10

Abstract: The present disclosure provides a method of providing an adhesive composition comprising the steps of combining crosslinkable composition including: a) a (meth)acryloyl monomer mixture with the b) photocrosslinking agent mixture, and irradiating with UVC radiation to polymerize and crosslink the composition.

公开(公告)号：US20150238389A1

公开(公告)日：2015-08-27

申请号：US14707096

申请日：2015-05-08

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： William H. Moser ,  Guy D. Joly ,  Larry R. Krepski ,  Babu N. Gaddam ,  Ahmed S. Abuelyaman ,  Bradley D. Craig ,  Timothy D. Dunbar ,  Chuntao Cao ,  Joel D. Oxman ,  Afshin Falsafi ,  Hoa T. Bui

IPC: A61K6/083 ,  A61K6/00

CPC classification number: A61K6/083 ,  A61K6/0023 ,  A61K6/0029 ,  A61K6/005 ,  C08L33/10

Abstract: Dental compositions are described comprising an addition-fragmentation agent of the formula: wherein R1, R2 and R3 are each independently Zm-Q-, a (hetero)alkyl group or a (hetero)aryl group with the proviso that at least one of R1, R2 and R3 is Zm-Q-; Q is a linking group have a valence of m+1; Z is an ethylenically unsaturated polymerizable group; m is 1 to 6; each X1 is independently —O— or —NR4—, where R4 is H or C1-C4 alkyl; and n is 0 or 1. Also described are dental articles prepared from a dental composition comprising an addition-fragmentation agent and methods of treating a tooth surface.

Abstract translation: 描述了牙科组合物，其包含下式的加成断裂剂：其中R 1，R 2和R 3各自独立地为Zm-Q-，（杂）烷基或（杂）芳基，条件是R 1 ，R2和R3是Zm-Q-; Q是连接基团，其价态为m + 1; Z是烯属不饱和可聚合基团; m为1〜6; 每个X 1独立地是-O-或-NR 4 - ，其中R 4是H或C 1 -C 4烷基; 并且n为0或1.还描述了由包含加成碎裂剂的牙科组合物制备的牙科用品和治疗牙齿表面的方法。

公开(公告)号：US20140194628A1

公开(公告)日：2014-07-10

申请号：US14205114

申请日：2014-03-11

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Larry R. Krepski ,  Joseph F. Dellaria, Jr. ,  Daniel E. Duffy ,  Matthew R. Radmer ,  David T. Amos

IPC: C07D471/04

CPC classification number: C07D471/04 ,  C07D213/74 ,  C07D255/02 ,  C07D471/14

Abstract: Imidazo ring systems substituted at the 1-position, pharmaceutical compositions containing the compounds, intermediates, methods of making the compounds, and methods of use of these compounds as immunomodulators, for inducing cytokine biosynthesis in animals and in the treatment of diseases including viral and neoplastic diseases are disclosed.

Abstract translation: 在1位置取代的咪唑环体系，含有化合物的药物组合物，中间体，制备化合物的方法，以及这些化合物作为免疫调节剂的使用方法，用于诱导动物中的细胞因子生物合成和治疗包括病毒和肿瘤的疾病 疾病被披露。

公开(公告)号：US20130196153A1

公开(公告)日：2013-08-01

申请号：US13798884

申请日：2013-03-13

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Arlin L. Weikel ,  Larry R. Krepski ,  Jason D. Clapper ,  Wayne S. Mahoney ,  Babu N. Gaddam

IPC: C09J133/10 ,  C09J7/02 ,  C08F224/00

CPC classification number: C09J133/10 ,  C08F220/32 ,  C08F224/00 ,  C08L63/10 ,  C09D4/06 ,  C09J7/38 ,  C09J133/062 ,  Y10T428/2809 ,  Y10T428/2852 ,  Y10T428/287 ,  Y10T428/2891

Abstract: A pre-adhesive composition is described comprising an acid- and epoxy-functional (meth)acryloyl copolymer, which when crosslinked with or without using an ionic photoacid generator (PAG) provides a pressure-sensitive adhesive and pressure-sensitive adhesive articles having desirable properties.

Abstract translation: 描述了一种预粘合剂组合物，其包含酸和环氧官能的（甲基）丙烯酰基共聚物，当与或不使用离子光酸产生剂（PAG）交联时，提供具有期望性质的压敏粘合剂和压敏粘合剂制品 。

公开(公告)号：US20200048392A1

公开(公告)日：2020-02-13

申请号：US16485576

申请日：2018-02-13

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Stefan H. Gryska ,  Joon Chatterjee ,  Deepti Gopalakrishnan ,  George W. Griesgraber ,  Larry R. Krepski ,  Babu N. Gaddam

IPC: C08F297/02 ,  C08L33/08 ,  C08L33/12 ,  C08F20/06

Abstract: Described is a polymerizable polymer composition compri a) a copolymerizable macromer, b) a (meth)acrylate ester monomer; and c) a polyfunctional type I photoinitiator.

公开(公告)号：US10195119B2

公开(公告)日：2019-02-05

申请号：US14778191

申请日：2014-03-13

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： William H. Moser ,  Guy D. Joly ,  Ann R. Fornof ,  Ahmed S. Abuelyaman ,  Afshin Falsafi ,  Larry R. Krepski

IPC: C07C69/00 ,  A61K6/00 ,  C07C271/28 ,  C07C69/76 ,  C08F222/10 ,  A61K6/083 ,  C08F222/20 ,  C08K9/00 ,  C09D4/00 ,  C09J4/00 ,  C09J5/00

Abstract: Addition-fragmentation agents having the following functional groups: 1) a labile addition-fragmentation group that can cleave and reform to relieve strain, 2) at least one high refractive index group, and 3) at least one ethylenically unsaturated, polymerizable group are described.

公开(公告)号：US09890304B2

公开(公告)日：2018-02-13

申请号：US14437214

申请日：2013-11-26

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Serkan Yurt ,  Jason D. Clapper ,  Ross E. Behling ,  Christopher J. Campbell ,  Mark F. Ellis ,  Larry R. Krepski ,  Ann R. Fornof ,  Babu N. Gaddam ,  James P. DiZio

IPC: C09J133/08 ,  C09J4/00 ,  C09J133/06 ,  C09J133/14 ,  C09J143/04 ,  C09J7/02 ,  C08F220/20 ,  C08F220/18 ,  C08F220/34

CPC classification number: C09J133/08 ,  C08F220/20 ,  C08F2220/1891 ,  C08F2220/343 ,  C08L2312/00 ,  C09J4/00 ,  C09J7/20 ,  C09J133/066 ,  C09J133/14 ,  C09J143/04 ,  C09J2433/00 ,  Y10T428/2891

Abstract: The disclosure describes a curable composition comprising a first oligomer having a plurality of polymerizable groups; a second component comprising alkylene oxide repeat units and terminal polymerizable groups, a solvent monomer component; and a photoinitiator. The curable composition may be used as an adhesive in optical applications.