公开(公告)号：US12161013B2

公开(公告)日：2024-12-03

申请号：US17631522

申请日：2020-09-16

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Jeffrey L. Solomon ,  Henrik B. van Lengerich ,  Bryan V. Hunt ,  Tabitha A Silliman ,  William Blake Kolb ,  Nicholas C. Erickson ,  Stephen M. Menke ,  Derek W. Patzman ,  Justin P Meyer ,  Bert T. Chien ,  Thomas E. Muehle ,  Thomas P. Klun

IPC: H10K50/858 ,  G02B1/04 ,  H10K71/00 ,  H10K71/50 ,  H10K102/00 ,  B82Y20/00 ,  B82Y30/00

Abstract: The present disclosure provides an article including a layer having a nanostructured first surface including nanofeatures and an opposing second surface, and an organic layer including a major surface attached to a portion of the nanofeatures. The nanostructured first surface includes protruding features that are formed of a single composition and/or recessed features. The nanofeatures and the major surface of the second layer together define at least one void. The present disclosure also provides a method of making the article including contacting nanofeatures of a layer having a nanostructured surface with a major surface of an organic layer and reacting at least one material to secure the two layers together. In addition, the present disclosure provides an optical information display and an OLED device including the article. The nanostructured surface of the article is protected from damage and contamination by the organic layer.

公开(公告)号：US12103846B2

公开(公告)日：2024-10-01

申请号：US17603071

申请日：2020-05-04

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： David S. Thompson ,  Chad M. Amb ,  Moses M. David ,  Richard J. Pokorny ,  Thomas P. Klun ,  Jonah Shaver ,  Joan M. Noyola ,  Hannah E. Walsh ,  Jon P. Nietfeld ,  John A. Wheatley ,  Joseph D. Rule ,  Ryan M. Braun ,  Michael A. Johnson

IPC: B82B1/00 ,  B08B17/06 ,  B32B3/30 ,  B32B27/40 ,  B82Y30/00 ,  B82Y40/00 ,  G02B1/18 ,  G02B27/00

CPC classification number: B82B1/005 ,  B08B17/065 ,  B32B3/30 ,  B32B27/40 ,  B82Y30/00 ,  B82Y40/00 ,  G02B1/18 ,  G02B27/0006 ,  B32B2255/10 ,  B32B2307/21 ,  B32B2307/412 ,  B32B2307/712 ,  B32B2307/73 ,  B32B2307/754 ,  B32B2375/00

Abstract: A nanostructured article includes a substrate; a plurality of first nanostructures disposed on, and extending away from, the substrate; and a covalently crosslinked fluorinated polymeric layer disposed on the plurality of first nanostructures. The plurality of first nanostructures includes polyurethane. The polymeric layer at least partially fills spaces between the first nanostructures to an average minimum height above the substrate of at least 30 nm such that the polymeric layer has a nanostructured surface defined by, and facing away from, the plurality of first nanostructures.

公开(公告)号：US11807795B2

公开(公告)日：2023-11-07

申请号：US17804726

申请日：2022-05-31

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Bryan V. Hunt ,  Brandt K. Carter ,  Maureen C. Nelson ,  Thomas P. Klun ,  Jason S. Petaja ,  Yizhong Wang ,  Joel D. Oxman

IPC: C08F220/34 ,  C09K3/16 ,  C08F222/10

CPC classification number: C09K3/16 ,  C08F220/34 ,  C08F222/104 ,  Y10T428/3154 ,  Y10T428/31544 ,  Y10T428/31663 ,  C08F220/34 ,  C08F222/104 ,  C08F220/24 ,  C08F222/104 ,  C08F220/34 ,  C08F230/08

Abstract: Optical devices comprising at least one optical layer and at least one antistatic layer disposed on at least one surface of the optical layer wherein the antistatic layer comprises the reaction product of: (a) at least one polymerizable onium salt; and (b) at least one polymerizable, non-onium, silicone or perfluoropolyether moiety-containing monomer, oligomer, or polymer.

公开(公告)号：US11691248B2

公开(公告)日：2023-07-04

申请号：US16955592

申请日：2018-12-19

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Lan Hong Liu ,  Thomas P. Klun ,  Jing Chen ,  Thomas W. Floyd ,  Bathsheba E. Chong Conklin ,  Adriana C. Gorgan

IPC: B24D18/00 ,  B24D3/28 ,  B24D11/02 ,  B24D3/34

CPC classification number: B24D18/0072 ,  B24D3/28 ,  B24D3/346 ,  B24D11/02

Abstract: The present disclosure relates to an abrasive article construction containing an anti-loading composition which significantly reduces loading, is coatable, is durable, and is relatively inexpensive to manufacture. In particular, the use of the anti-loading compositions of the present disclosure as a size coat at least reduces if not eliminates the need for a supersize coat, while offering comparable if not superior performance and durability. In one aspect, the present disclosure provides an abrasive article including a backing with a first major surface and an opposing second major surface, an abrasive layer bonded to at least a portion of the first major surface, with the abrasive layer comprising abrasive particles retained in a make coat. The abrasive article further includes an anti-loading size layer comprising a size coat binder and wax at least partially disposed on the abrasive layer.

公开(公告)号：US20230151149A1

公开(公告)日：2023-05-18

申请号：US17912947

申请日：2021-04-26

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Thomas P. Klun ,  Brandon R. Pietz ,  Paul J. Homnick ,  Christopher S. Lyons ,  Chad M. Amb ,  Jonathan M. Ryss

IPC: C08G65/00 ,  C08J5/18

CPC classification number: C08G65/007 ,  C08J5/18 ,  C08J2371/02

Abstract: A polymerizable composition is described comprising a fluorinated monomer, oligomer, or mixture thereof; and a coupling agent comprising a (meth)acryl terminal group, a terminal silane comprising hydrolysable groups and a perfluorooxyalkylene or perfluorooxyalkyl moiety. Also described are compounds and methods.

公开(公告)号：US20230127519A1

公开(公告)日：2023-04-27

申请号：US17915534

申请日：2021-04-13

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Jeffrey L. Solomon ,  Stephen M. Menke ,  Nicholas C. Erickson ,  Daniel W. Hennen ,  Derek W. Patzman ,  Thomas P. Klun

IPC: G02B1/14 ,  H10K50/858

Abstract: The present disclosure provides an article including either at least two layers each having at least one enclosed void that is defined in part by nanostructured surfaces, or a layer having at least one enclosed void that is defined by two nanostructured surfaces in contact with each other. In addition, the present disclosure provides an optical information display and an OLED device including the article. The nanostructured surface of the article is protected from damage and contamination by the presence of another layer.

公开(公告)号：US11447657B2

公开(公告)日：2022-09-20

申请号：US16757578

申请日：2018-12-06

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Thomas P. Klun ,  Chunjie Zhang ,  Richard J. Pokorny ,  Benjamin R. Coonce ,  Benjamin G. Sonnek ,  Gregg A. Ambur ,  Jung-Sheng Wu

IPC: C09D175/14 ,  C08K3/22 ,  C08G18/62 ,  C08G18/78 ,  C08G18/79

Abstract: A curable composition comprises: a) 91 to 98.2 weight percent of: (i) at least one polymerizable compound containing at least one carbamylene group; or (ii) at least one polyurethane precursor system; and b) 0.2 to 9 weight percent of alpha alumina particles having a particle size distribution with a Dv50 of from 0.1 to 1 micron, wherein the weight percentages of a) and b) are based upon the total amount of a) and b). Cured compositions and their use in thermoforming are also disclosed.

公开(公告)号：US20220177303A1

公开(公告)日：2022-06-09

申请号：US17603071

申请日：2020-05-03

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： David S. Thompson ,  Chad M. Amb ,  Moses M. David ,  Richard J. Pokorny ,  Thomas P. Klun ,  Jonah Shaver ,  Joan M. Noyola ,  Hannah E. Walsh ,  Jon P. Nietfeld ,  John A. Wheatley ,  Joseph D. Rule ,  Ryan M. Braun ,  Michael A. Johnson

IPC: B82B1/00

Abstract: A nanostructured article includes a substrate; a plurality of first nanostructures disposed on, and extending away from, the substrate; and a covalently crosslinked fluorinated polymeric layer disposed on the plurality of first nanostructures. The plurality of first nanostructures includes polyurethane. The polymeric layer at least partially fills spaces between the first nanostructures to an average minimum height above the substrate of at least 30 nm such that the polymeric layer has a nanostructured surface defined by, and facing away from, the plurality of first nanostructures.

公开(公告)号：US11225535B2

公开(公告)日：2022-01-18

申请号：US17042243

申请日：2019-05-21

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Thomas P. Klun ,  Zeba Parkar ,  John M. Riedesel ,  Richard J. Pokorny ,  Chad M. Amb ,  Benjamin R. Coonce ,  Robert S. Clough ,  Tianyu Wu ,  Saswata Chakraborty ,  Yongshang Lu ,  Benjamin C. MacMurray ,  Ian Dailey ,  David B. Olson

IPC: C08F2/46 ,  C08F2/50 ,  C08G61/04 ,  C08F220/18 ,  C08F2/44 ,  C08F290/06 ,  C08G18/44 ,  B33Y70/00 ,  C08K5/00 ,  C08K5/3437 ,  B29C64/129 ,  B33Y10/00 ,  B33Y30/00 ,  C08G18/67

Abstract: The present disclosure provides a photopolymerizable composition. The photopolymerizable composition includes a) 40-60 parts by weight of a monofunctional (meth)acrylate monomer, per 100 parts of the total photopolymerizable composition; b) a photoinitiator; and c) a polymerization reaction product of components. A cured homopolymer of the monofunctional (meth)acrylate monomer has a glass transition temperature of 125 degrees Celsius or greater. The polymerization reaction product of components includes i) a diisocyanate; ii) a hydroxy functional methacrylate; iii) a polycarbonate diol; and iv) a catalyst. The polymerization reaction product includes a polyurethane methacrylate polymer. Often, the polycarbonate diol has a number average molecular weight of greater than 1,000 grams per mole (g/mol) or a weighted average of all polycarbonate diols present in the components has a Mn of greater than 1,000 g/mol; alternatively, the polyurethane methacrylate polymer has a weight average molecular weight of 8,000 g/mol or greater. An article is also provided including the photopolymerizable composition reaction product. Further, the present disclosure provides articles and methods of making articles. Methods are additionally provided, including receiving, by a manufacturing device having one or more processors, a digital object comprising data specifying an article; and generating, with the manufacturing device by an additive manufacturing process, the article based on the digital object. A system is also provided, including a display that displays a 3D model of an article; and one or more processors that, in response to the 3D model selected by a user, cause a 3D printer to create a physical object of an article.

公开(公告)号：US11208576B2

公开(公告)日：2021-12-28

申请号：US16486533

申请日：2018-02-27

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Lan Hong Liu ,  Jianhui Xia ,  Thomas P. Klun ,  David A. Kowitz ,  Audrey A. Sherman

IPC: C09J4/06 ,  B32B7/12 ,  C09J129/14 ,  C09J175/14 ,  B32B17/10

Abstract: The present invention is an optically clear, curable adhesive including a polyvinylbutyral, a polyurethane (meth)acrylate, and a photoinitiator. The polyvinylbutyral has a dynamic viscosity of between about 9 and about 13 mPa·s and a polyvinyl alcohol weight percent of less than about 18%. The polyurethane (meth)acrylate includes the reaction product of a diol, at least one diisocyanate, and a hydroxyfunctional (meth)acrylate or an isocyanatofunctional (meth)acrylate. When the optically clear, curable adhesive is placed between two transparent substrates and made into a laminate, the laminate has a haze of less than about 6%, a transmission of greater than about 88% and an optical clarity of greater than about 98% when cured. The optically clear, curable adhesive also has a peel adhesion of at least about 100 g/cm based on ASTM 3330 when cured.