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53 条记录 (耗时 0.059 秒)

    Process for the production of chlorinated and/or fluorinated propenes
    31.
    发明授权
    Process for the production of chlorinated and/or fluorinated propenes 有权
    用于生产氯化和/或氟化丙烯的方法

    公开(公告)号：US08581011B2

    公开(公告)日：2013-11-12

    申请号：US12900810

    申请日：2010-10-08

    申请人： Max M. Tirtowidjojo ,  Debashis Chakraborty ,  Juergen Eiffler ,  Kurt F. Hirsekorn ,  William J. Kruper, Jr.

    发明人： Max M. Tirtowidjojo ,  Debashis Chakraborty ,  Juergen Eiffler ,  Kurt F. Hirsekorn ,  William J. Kruper, Jr.

    IPC分类号： C07C21/18

    CPC分类号： C07C17/10 ,  C07C17/202 ,  C07C17/269 ,  C07C21/18 ,  C07C21/04

    摘要： The present invention provides one-step processes for the production of chlorinated and/or fluorinated propenes. The processes provide good product yield with low, e.g., less than about 20%, or even less than 10%, concentrations of residues/by-products. Advantageously, the processes may be conducted at low temperatures than 500° C. so that energy savings are provided, and/or at higher pressures so that high throughputs may also be realized. The use of catalysts or initiators may provide additional enhancements to conversion rates and selectivity, as may adjustments to the molar ratio of the reactants.

    摘要翻译： 本发明提供用于生产氯化和/或氟化丙烯的一步法。 该方法提供良好的产物收率，具有低，例如小于约20％，或甚至低于10％的残余物/副产物浓度。 有利地，该方法可以在低于500℃的低温下进行，从而提供节能和/或在更高的压力下，从而也可以实现高通量。 催化剂或引发剂的使用可以提供对转化率和选择性的额外增强，如可以调节反应物的摩尔比。

    Preparation of catalyst compositions
    33.
    发明授权
    Preparation of catalyst compositions 失效
    催化剂组合物的制备

    公开(公告)号：US06673735B1

    公开(公告)日：2004-01-06

    申请号：US09687395

    申请日：2000-10-13

    申请人： Eugene Y. Chen ,  William J. Kruper, Jr.

    发明人： Eugene Y. Chen ,  William J. Kruper, Jr.

    IPC分类号： B01J3100

    CPC分类号： C08F210/16 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/65927 ,  C08F110/06 ,  C08F4/65908

    摘要： A process for forming a composition useful as a catalyst for the polymerization of addition polymerizable monomers, the steps of the process comprising: a) contacting under exchange reaction conditions a tri(hydrocarbyl)aluminum compound with a tri(fluoroaryl)boron compound; and b) contacting the reaction product from step a) without recovery or isolation thereof, with a neutral Group 3-10 metal complex.

    摘要翻译： 一种用于形成用作聚合可加聚单体的催化剂的组合物的方法，所述方法的步骤包括：a）在交换反应条件下使三（烃基）铝化合物与三（氟化芳基）硼化合物接触; 和b）使来自步骤a）的反应产物与中性的3-10金属络合物进行回收或分离。

    Three coordinate aluminum catalyst activator composition
    35.
    发明授权
    Three coordinate aluminum catalyst activator composition 有权
    三配位铝催化剂活化剂组成

    公开(公告)号：US06528449B1

    公开(公告)日：2003-03-04

    申请号：US09702442

    申请日：2000-10-31

    申请人： Eugene Y. Chen ,  William J. Kruper, Jr. ,  Gordon R. Roof ,  David J. Schwartz ,  Joey W. Storer

    发明人： Eugene Y. Chen ,  William J. Kruper, Jr. ,  Gordon R. Roof ,  David J. Schwartz ,  Joey W. Storer

    IPC分类号： B01J3114

    CPC分类号： C08F10/00 ,  C07F5/062 ,  C07F5/066 ,  C08F4/6592 ,  C08F4/65927 ,  C08F110/06 ,  C08F210/16 ,  Y10S526/943 ,  C08F4/642 ,  C08F4/65912 ,  C08F210/14 ,  C08F2500/12

    摘要： Catalyst compositions useful for olefin polymerizations comprising a Group 3-10 metal complex and a compound corresponding to the formula: AlArfQ1Q2, or a dimer, adduct, or mixture thereof and further mixtures with aluminum compounds of the formula AlArf3, where: Arf is a fluorinated aromatic hydrocarbyl moiety of from 6 to 30 carbon atoms; Q1 is Arf or a C1-20 hydrocarbyl group, optionally substituted with one or more cyclohydrocarbyl, hydrocarbyloxy, hydrocarbylsiloxy, hydrocarbylsilylamino, hydrocarbylsilyl, silylhydrocarbyl, di(hydrocarbylsilyl)amino, hydrocarbylamino, di(hydrocarbyl)amino, di(hydrocarbyl)phosphino, or hydrocarbylsulfido groups having from 1 to 20 atoms other than hydrogen, or, further optionally, such substituents may be covalently linked with each other to form one or more fused rings or ring systems; and Q2 is an aryloxy, arylsulfide or di(hydrocarbyl)amido group, optionally substituted with one or more hydrocarbyl, cyclohydrocarbyl, hydrocarbyloxy, hydrocarbylsiloxy, hydrocarbylsilylamino, hydrocarbylsilyl, silylhydrocarbyl, di(hydrocarbylsilyl)amino, hydrocarbylamino, di(hydrocarbyl)amino, di(hydrocarbyl)phosphino, or hydrocarbylsulfido groups having from 1 to 20 atoms other than hydrogen, or, further optionally such substituents may be covalently linked with each other to form one or more fused rings or ring systems, said Q2 having from 3 to 20 atoms other than hydrogen are useful as activators for olefin polymerizations.

    摘要翻译： 用于烯烃聚合的催化剂组合物，其包含3-10金属络合物和对应于式AlArfQ1Q2的化合物或其二聚体，加合物或其混合物，以及与式AlArf 3的铝化合物的其它混合物，其中：Arf是氟化 6至30个碳原子的芳族烃基部分; Q 1是Arf或C 1-20烃基，任选地被一个或多个环烃基，烃氧基，烃基甲硅烷氧基，烃基甲硅烷基氨基，烃基甲硅烷基，甲硅烷基烃基，二（烃基甲硅烷基）氨基，烃基氨基，二 烃基）氨基，二（烃基）膦基或具有除氢以外的1至20个原子的烃基硫基，或者进一步任选地，这些取代基可以彼此共价连接以形成一个或多个稠环或环系; 环烷氧基，烃基甲硅烷氧基，烃基甲硅烷基氨基，烃基甲硅烷氧基，烃基甲硅烷基氨基，烃基甲硅烷基，甲硅烷基烃基，二（烃基甲硅烷基）氨基，烃基氨基，二（烃基）氨基，二（烃基）氨基， 烃基）膦基或具有除氢之外的1至20个原子的烃基硫基，或者进一步任选地，这些取代基可以彼此共价连接以形成一个或多个稠环或环系，所述Q2具有3至20个原子的其它 氢可用作烯烃聚合的活化剂。

    Ansa group 4 metal bis (.mu.-substituted) aluminum complexes
    38.
    发明授权
    Ansa group 4 metal bis (.mu.-substituted) aluminum complexes 失效
    Ansa组4金属双（μ-取代）铝络合物

    公开(公告)号：US6140521A

    公开(公告)日：2000-10-31

    申请号：US330672

    申请日：1999-06-11

    申请人： Eugene Y. Chen ,  William J. Kruper, Jr. ,  Peter N. Nickias ,  David R. Wilson

    发明人： Eugene Y. Chen ,  William J. Kruper, Jr. ,  Peter N. Nickias ,  David R. Wilson

    IPC分类号： C07F5/06 ,  C07F7/10 ,  C07F7/28 ,  C07F17/00 ,  C07F19/00 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C07F7/00 ,  C08F4/64

    CPC分类号： C08F10/00 ,  C07F17/00 ,  C07F5/066 ,  C08F210/16 ,  C08F4/65908 ,  C08F4/6592 ,  C08F4/65927 ,  Y10S526/943

    摘要： Ansa bis(.mu.-substituted) Group 4 metal and aluminum compounds comprising a single Group 4 metal atom and two aluminum metal atoms corresponding to the formula: ##STR1## wherein: L' is a .pi.-bonded group,M is a Group 4 metal,J is nitrogen or phosphorus;Z is a divalent bridging group causing the complex to have an ansa structure,R' is an inert monovalent ligand;r is one or two;X independently each occurrence is a Lewis basic ligand group able to form a .mu.-bridging ligand group, and optionally the two X groups may be joined together, andA' independently each occurrence is an aluminum containing Lewis acid compound that forms an adduct with the metal complex by means of the .mu.-bridging groups, and optionally two A' groups may be joined together thereby forming a single difunctional Lewis acid containing compound, and a method of preparation comprising contacting a charge-neutral Group IV metal coordination complex having at least two Lewis basic groups with at least two molar equivalents of charge-neutral aluminum coordination complexes having Lewis acidic aluminum atoms such that at least two of the aluminum atoms of the aluminum coordination complexes bond to at least two of the Lewis basic groups of the Group IV coordination complex.

    摘要翻译： Ansa双（μ-取代的）第4族金属和铝化合物，其包含对应于下式的单个第4族金属原子和两个铝金属原子：其中：L'是π键合基团，M是第4族金属，J是 氮或磷; Z是使络合物具有ansa结构的二价桥连基团，R'是惰性单价配体; r是一两个; 独立地，X独立地是能够形成mu-桥接配体基团的路易斯碱性配体基团，并且任选地两个X基团可以连接在一起，并且A'独立地是含铝的路易斯酸化合物，其与 金属络合物，并且任选地两个A'基团可以连接在一起，从而形成单一双官能路易斯酸化合物，以及制备方法，包括使具有至少一个电荷的中性IV族金属配位络合物 两个路易斯碱性基团，其具有至少两摩尔当量的具有路易斯酸性铝原子的电荷 - 中性铝配位络合物，使得铝配位络合物的至少两个铝原子与至少两个第IV族的路易斯碱性基团键合 协调综合体