公开(公告)号：US20140234206A1

公开(公告)日：2014-08-21

申请号：US14217806

申请日：2014-03-18

Applicant: BASF SE

Inventor： Natalia Trukhan ,  Ulrich Müller ,  Ivor Bull

IPC: B01J29/76 ,  B01D53/94

CPC classification number: B01J29/763 ,  B01D53/9418 ,  B01D2251/2062 ,  B01D2255/2063 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2255/9202 ,  B01D2255/9207 ,  B01D2257/402 ,  B01D2257/404 ,  B01D2257/406 ,  B01D2258/012 ,  B01J29/072 ,  B01J29/7065 ,  B01J35/04 ,  B01J37/0215 ,  B01J37/036 ,  B01J37/038 ,  B01J37/30 ,  C01B37/00 ,  C01B39/06 ,  C01B39/48 ,  Y02C20/10 ,  Y02P20/153

Abstract: A process for the preparation of a copper containing zeolitic material having CHA framework structure and a composition comprising the molar ratio (n YO2):X2O3 wherein X is a trivalent element, preferably Al, Y is a tetravalent element, preferably Si, and wherein n is preferably at least 20, the process comprising the preparation of an phosphor-free aqueous solution containing at least one source for X2O3 and at least one source for YO2, at least one structure directing agent suitable for the preparation of a zeolitic material having CHA framework structure, and at least one Cu source, and the process further comprising the hydrothermal crystallization of said aqueous solution obtaining a suspension containing the copper containing zeolitic material having CHA framework structure.

Abstract translation: 一种制备具有CHA骨架结构的含铜沸石材料和包含摩尔比（n YO 2）：X 2 O 3的组合物的方法，其中X是三价元素，优选Al，Y是四价元素，优选Si，其中n 优选至少为20，该方法包括制备含有至少一种X 2 O 3源和至少一种YO源的无磷水溶液，至少一种适于制备具有CHA骨架的沸石材料的结构导向剂 结构和至少一个Cu源，并且所述方法还包括所述水溶液的水热结晶，得到含有具有CHA骨架结构的含铜沸石材料的悬浮液。

公开(公告)号：US20140128622A1

公开(公告)日：2014-05-08

申请号：US14072179

申请日：2013-11-05

Applicant: BASF SE

Inventor： Nicolas Vautravers ,  Joaquim Henrique Teles ,  Andrei-Nicolae Parvulescu ,  Ulrich Müller

IPC: C07B41/06 ,  C07C51/285 ,  C07D309/30 ,  C07C45/29 ,  C07D313/04 ,  C07D315/00

CPC classification number: C07D313/04 ,  B01J23/00 ,  C07C45/54 ,  C07C51/285 ,  C07D309/30 ,  C07D313/00 ,  C07C47/21 ,  C07C57/03

Abstract: A process for the oxidation of an organic carbonyl compound comprising reacting the organic carbonyl compound, optionally in the presence of a solvent, with hydrogen peroxide in the presence of a catalyst comprising a tin-containing zeolitic material having an MWW-type framework structure.

Abstract translation: 一种有机羰基化合物的氧化方法，包括有机羰基化合物，任选在溶剂存在下，在含有具有MWW型骨架结构的含锡沸石材料的催化剂存在下，与过氧化氢反应。

公开(公告)号：US20140097100A1

公开(公告)日：2014-04-10

申请号：US14048358

申请日：2013-10-08

Applicant: BASF SE

Inventor： Mathias Weickert ,  Stefan Marx ,  Ulrich Müller ,  Peter Renze

IPC: F17C11/00

CPC classification number: F17C11/005 ,  F17C11/00 ,  F17C11/007

Abstract: Described is a method of charging a sorption store with a gas. The sorption store comprises a closed container and a feed device which has a passage through the container wall, through which the gas can flow into the container, and the container has at least two parallel, channel-shaped subchambers which are located in its interior and are each at least partly filled with an adsorption medium and whose channel walls are coolable. The method comprises, in a first step, feeding in a gas in such an amount that a pressure in the store of at least 30% of a predetermined final pressure is reached as quickly as possible and, in a second step, subsequently varying the amount of gas fed in in such a way that the course of the pressure in the store approximates the adsorption kinetics of the adsorption medium until the predetermined final pressure in the store is reached after a predetermined period of time.

Abstract translation: 描述了一种用气体对吸附物料进行充电的方法。 吸附储存器包括密封容器和进料装置，其具有通过容器壁的通道，气体可以通过该通道流入容器中，并且容器具有位于其内部的至少两个平行的通道形子室， 各自至少部分地填充有吸附介质，并且其通道壁是可冷却的。 该方法包括在第一步骤中，将气体供给量使得储存器中的压力达到尽可能快的至少30％的预定最终压力，并且在第二步骤中随后改变量 以这样的方式供给气体，使得商店中的压力过程接近吸附介质的吸附动力学，直到在预定时间段之后达到储存器中的预定最终压力。

公开(公告)号：US20130129611A1

公开(公告)日：2013-05-23

申请号：US13673661

申请日：2012-11-09

Applicant: BASF SE

Inventor： Stefan Maurer ,  Hanpeng Jin ,  Jeff Yang ,  Ulrich Müller

IPC: C01B39/02

CPC classification number: C01B39/02 ,  B01J29/7015 ,  C01B39/026 ,  C01B39/46

Abstract: The present invention relates to an organotemplate-free synthetic process for the production of a zeolitic material having a CHA-type framework structure comprising YO2, X2O3, and optionally comprising Z2O5, wherein said process comprises the steps of: (1) providing a mixture comprising one or more sources for YO2, one or more sources for X2O3, and seed crystals having a CHA framework structure, wherein the CHA framework structure of the seed crystals comprises YO2, X2O3, and optionally comprises Z2O5; and (2) crystallizing the mixture obtained in step (1); wherein Y is a tetravalent element, X is a trivalent element, and Z is a pentavalent element, wherein optionally one or more sources for Z2O5 are further provided in step (1), and wherein if the CHA framework of the seed crystals does not contain Z2O5, the seed crystals then have a YO2:X2O3 molar ratio of 5 or greater than 5.

Abstract translation: 本发明涉及一种用于生产具有包含YO 2，X 2 O 3和任选地包含Z 2 O 5的CHA型骨架结构的沸石材料的有机模板合成方法，其中所述方法包括以下步骤：（1）提供包含 YO2的一种或多种来源，X 2 O 3的一种或多种来源和具有CHA骨架结构的晶种，其中晶种的CHA骨架结构包含YO 2，X 2 O 3，并且任选包含Z 2 O 5; 和（2）使步骤（1）中获得的混合物结晶; 其中Y是四价元素，X是三价元素，Z是五价元素，其中在步骤（1）中还可以任选地提供一种或多种Z2O5源，并且其中如果晶种的CHA骨架不包含 Z2O5，然后晶种的YO 2：X 2 O 3摩尔比为5或大于5。

公开(公告)号：US10315924B2

公开(公告)日：2019-06-11

申请号：US15315636

申请日：2015-06-03

Applicant: BASF SE

Inventor： Mathias Feyen ,  Jeff Yang ,  Roger Ruetz ,  Ulrich Müller

IPC: C01B39/48 ,  B01J29/70 ,  B01J37/02 ,  B01J29/76 ,  B01J35/00 ,  B01J35/02 ,  B01J20/18 ,  B01J20/30 ,  B01J37/00 ,  B01J39/02 ,  B01J39/14 ,  B01J29/72

Abstract: The present invention relates to a process for the preparation of a zeolitic material having a CHA-type framework structure comprising YO2 and X2O3, wherein said process comprises the steps of: (1) providing a mixture comprising one or more sources for YO2, one or more sources for X2O3, one or more tetraalkylammonium cation R1R2R3R4N+-containing compounds, and one or more tetraalkylammonium cation R5R6R7R8N+-containing compounds as structure directing agent; (2) crystallizing the mixture obtained in step (1) for obtaining a zeolitic material having a CHA-type framework structure; wherein Y is a tetravalent element and X is a trivalent element, wherein R1, R2, R3, R4, R5, R6, and R7 independently from one another stand for alkyl, and wherein R8 stands for cycloalkyl, as well as to zeolitic materials which may be obtained according to the inventive process and to their use.

公开(公告)号：US10150750B2

公开(公告)日：2018-12-11

申请号：US15034249

申请日：2014-11-05

Applicant: BASF SE

Inventor： Nicolas Vautravers ,  Joaquim H. Teles ,  Andrei-Nicolae Parvulescu ,  Ulrich Müller

IPC: B01J29/06 ,  B01J21/16 ,  C07C49/00 ,  C07D313/04 ,  B01J27/18 ,  B01J29/70 ,  B01J31/02 ,  C07B41/12

Abstract: A process for the oxidation of an organic carbonyl compound comprising reacting the compound, optionally in the presence of a solvent, with hydrogen peroxide in the presence of a catalyst comprising a tin-containing zeolitic material and at least one potassium salt.

公开(公告)号：US09999878B2

公开(公告)日：2018-06-19

申请号：US15033824

申请日：2014-11-05

Applicant: BASF SE

Inventor： Andrei-Nicolae Parvulescu ,  Ulrich Müller ,  Joaquim H. Teles ,  Nicolas Vautravers ,  Georg Uhl ,  Ive Hermans ,  Patrick Wolf ,  Ceri Hammond

IPC: C01B39/06 ,  C01B39/46 ,  B01J29/06 ,  B01J29/89 ,  B01J29/70 ,  C07D313/04 ,  B01J35/00 ,  B01J35/10 ,  B01J37/10 ,  B01J37/30 ,  B01J29/40 ,  C01B39/38 ,  C01B39/02

CPC classification number: B01J29/7057 ,  B01J29/06 ,  B01J29/40 ,  B01J29/7007 ,  B01J29/7015 ,  B01J29/7038 ,  B01J29/7065 ,  B01J29/7088 ,  B01J29/89 ,  B01J35/002 ,  B01J35/1019 ,  B01J37/10 ,  B01J37/30 ,  B01J2229/183 ,  B01J2229/186 ,  C01B39/026 ,  C01B39/06 ,  C01B39/38 ,  C01B39/46 ,  C01P2002/82 ,  C07D313/04

Abstract: A process for preparing a tin-containing zeolitic material having a BEA framework structure comprising providing a zeolitic material having a BEA framework structure having vacant tetrahedral framework sites, providing a tin-ion source in solid form, incorporating tin into the zeolitic material via solid-state ion exchange, calcining the zeolitic material, and treating the calcined zeolitic material with an aqueous solution having a pH of at most 5.

公开(公告)号：US09878965B2

公开(公告)日：2018-01-30

申请号：US14897379

申请日：2014-06-13

Applicant: BASF SE

Inventor： Kirsten Spannhoff ,  Andrei-Nicolae Parvulescu ,  Armin Lange de Oliveira ,  Stefan Marx ,  Mathias Feyen ,  Ulrich Müller ,  Ekkehard Schwab

IPC: C07C1/24 ,  C07C1/20 ,  B01J29/89 ,  B01J37/00 ,  C01B39/02 ,  C01B39/08 ,  C01B39/12 ,  C07C1/207

CPC classification number: C07C1/20 ,  B01J29/89 ,  B01J37/0045 ,  B01J2229/183 ,  B01J2229/37 ,  B01J2229/62 ,  C01B39/026 ,  C01B39/08 ,  C01B39/085 ,  C01B39/12 ,  C01P2006/12 ,  C07C1/2076 ,  C07C2529/70 ,  C07C2529/78 ,  C07C2529/86 ,  C07C2529/89 ,  C07C11/167

Abstract: The present invention relates to a gas-phase process for the preparation of butadiene comprising (i) providing a gas stream G-1 comprising ethanol; (ii) contacting the gas stream G-1 comprising ethanol with a catalyst, thereby obtaining a gas stream G-2 comprising butadiene, wherein the catalyst comprises a zeolitic material having a framework structure comprising YO2, Y standing for one or more tetravalent elements, wherein at least a portion of Y comprised in the framework structure is isomorphously substituted by one or more elements X, as well as to a zeolitic material having a framework structure comprising YO2, Y standing for one or more tetravalent elements, wherein at least a portion of Y comprised in the framework structure is isomorphously substituted by one or more elements X, wherein the zeolitic material displays a specific X-ray powder diffraction pattern, and to its use.

公开(公告)号：US09636668B2

公开(公告)日：2017-05-02

申请号：US14076651

申请日：2013-11-11

Applicant: BASF SE

Inventor： Manuela Gaab ,  Ulrich Müller ,  Milan Kostur ,  Kirsten Spannhoff ,  Kerem Bay ,  Andrei-Nicolae Parvulescu

IPC: B01J29/40 ,  B01J37/02 ,  B01J29/70 ,  B01J23/02 ,  B01J37/00 ,  C07C1/20

CPC classification number: B01J29/7038 ,  B01J23/02 ,  B01J29/40 ,  B01J29/7034 ,  B01J37/0009 ,  B01J37/0201 ,  C07C1/20 ,  C07C2523/02 ,  C07C2529/035 ,  C07C2529/40 ,  C07C2529/70 ,  Y02P20/52 ,  C07C11/06 ,  C07C11/08

Abstract: Described is a process for the production of a zeolitic material having an MFI, MEL, and/or MWW-type framework structure comprising YO2 and X2O3. The process comprises (1) preparing a mixture comprising one or more sources for YO2, one or more sources for X2O3, and one or more solvents; (2) crystallizing the mixture obtained in step (1) to obtain a zeolitic material having an MFI, MEL and/or MWW-type framework structure; and (3) impregnating the zeolitic material obtained in step (2) with one or more elements selected from the group of alkaline earth metals. Y is a tetravalent element, and X is a trivalent element. The mixture crystallized in step (2) contains 3 wt.-% or less of one or more elements M based on 100 wt-% of YO2, wherein M stands for sodium.

公开(公告)号：US09561995B2

公开(公告)日：2017-02-07

申请号：US15022960

申请日：2014-09-22

Applicant: BASF SE

Inventor： Stefan Maurer ,  Hendrick Mattenheimer ,  Ulrich Müller

IPC: C07C51/00 ,  C07C51/487 ,  B01D11/02 ,  B01J20/22 ,  B01J20/30

CPC classification number: C07C51/487 ,  B01D11/02 ,  B01J20/226 ,  B01J20/3085 ,  C07C51/47 ,  C07C63/331 ,  C07C63/307 ,  C07C63/26 ,  C07C57/15

Abstract: The present invention relates to a process for the recovery of an at least bidentate organic compound comprised in a porous metal-organic framework material, the material comprising the at least bidentate organic compound coordinated to at least one metal ion, the process comprising the steps of (a) treating the metal-organic framework material with an acidic or alkaline liquid; (b) optionally separating off solid residue; and (c) isolating the at least bidentate organic compound.

Abstract translation: 本发明涉及回收包含在多孔金属 - 有机骨架材料中的至少二齿有机化合物的方法，所述材料包含与至少一种金属离子配位的至少二齿有机化合物，该方法包括以下步骤： （a）用酸性或碱性液体处理金属 - 有机骨架材料; （b）任选分离固体残余物; 和（c）分离出至少二齿有机化合物。