Process for the preparation of polyisocyanates addition products
containing carboxylate groups
    31.
    发明授权
    Process for the preparation of polyisocyanates addition products containing carboxylate groups 失效
    制备含羧酸酯基团的多异氰酸酯加成产物的方法

    公开(公告)号:US4172191A

    公开(公告)日:1979-10-23

    申请号:US916403

    申请日:1978-06-16

    摘要: The present disclosure is concerned with a process for the preparation of carboxylate containing polyurethane and the polymers so produced. Hydroxyl bearing components are reacted with tri- or tetra-carboxylic acid monoanhydrides so as to incorporate free carboxyl groups into the component, a proportion of the carboxyl groups are neutralized to ionic salts and hydroxyl component is then reacted with polyisocyanates and simultaneously or subsequently with chain extending agents. The polymer may be obtained as a dispersion in water and the chain lengthening agent may be water, formaldehyde or water soluble amines or hydrazines.

    摘要翻译: 本公开涉及制备含羧酸盐的聚氨酯和如此制备的聚合物的方法。 羟基担载组分与三羧酸或四羧酸单酸酐反应,以将游离羧基引入组分中,一部分羧基被中和成离子盐,然后羟基组分与多异氰酸酯反应,同时或随后与链 扩展代理。 聚合物可以作为水中的分散体获得,并且链延长剂可以是水,甲醛或水溶性胺或肼。

    Process for the production of polyurethane coatings
    37.
    发明授权
    Process for the production of polyurethane coatings 失效
    聚氨酯涂料生产工艺

    公开(公告)号:US5236741A

    公开(公告)日:1993-08-17

    申请号:US877682

    申请日:1992-05-01

    摘要: The present invention relates to a process for the preparation of a polyurethane coating by coating a substrate with a coating composition containinga) a polyisocyanate component andb) an isocyanate-reactive component containing at least one compound corresponding to the formula ##STR1## wherein X represents an organic group which has a valency of n and is inert towards isocyanate groups at a temperature of 100.degree. C. or less,R.sup.1 and R.sup.2 may be identical or different and represent organic groups which are inert towards isocyanate groups at a temperature of 100.degree. C. or less,R.sup.3 and R.sup.4 may be identical or different and represent hydrogen or organic groups which are inert towards isocyanate groups at a temperature of 100.degree. C. or less andn represents an integer with a value of at least 2, and curing the coating composition at a temperature of 100.degree. C. or less.

    摘要翻译: 本发明涉及通过用包含a)多异氰酸酯组分的涂料组合物涂布基材来制备聚氨酯涂料的方法,和b)含有至少一种对应于下式的化合物的异氰酸酯反应性组分(I )其中X表示在100℃或更低的温度下具有n价并且对异氰酸酯基团呈惰性的有机基团,R 1和R 2可以相同或不同,表示在一个或多个基团上对于异氰酸酯基团是惰性的有机基团 温度为100℃以下时,R 3和R 4可以相同或不同,表示在100℃以下的温度下对异氰酸酯基具有惰性的氢或有机基团,n表示至少为 并且在100℃或更低的温度下固化涂料组合物。

    A process for bonding substrates with an ester group-containing hot melt
adhesive
    38.
    发明授权
    A process for bonding substrates with an ester group-containing hot melt adhesive 失效
    使用含钙组合热熔胶粘合基材的方法

    公开(公告)号:US5215618A

    公开(公告)日:1993-06-01

    申请号:US742251

    申请日:1991-08-08

    摘要: Disclosed herein is a process for bonding substrates comprising applying a hot-melt adhesive to the surface of at least one of the substrates and contacting the surface of said substrate with the surface of the other substrate, said adhesive containing an ester group-containing polyisocyanate which is a solid below 30.degree. C. and liquid above 100.degree. C., corresponding to formula (I)A(OCO-B-NCO).sub.n (I)in whichn stands for a whole number or a fraction (statistical average) of from 2 to 6,A stands for an n-valent organic group such as is obtained by removal of hydroxyl groups from an n-valent polyhydroxyl compound in the molecular weight (Mn) range of from 800 to 6000 containing ester and/or carbonate groups andB stands for an aliphatic, cycloaliphatic or aromatic hydrocarbon group having up to 18 carbon atoms.

    摘要翻译: 本文公开了一种用于粘合基材的方法,包括将热熔粘合剂施加到至少一个基材的表面并使所述基材的表面与另一个基材的表面接触,所述粘合剂含有含酯基的多异氰酸酯, 是低于30℃的固体和高于100℃的液体,对应于式(I)A(OCO-B-NCO)n(I),其中n代表整数或分数(统计平均值) 2〜6中,A表示通过从含有酯和/或碳酸酯基的800〜6000的分子量(Mn)范围的n价多羟基化合物除去羟基而得到的n价有机基团 B代表具有至多18个碳原子的脂族,脂环族或芳族烃基。

    Process for the production of polyurethane coatings
    39.
    发明授权
    Process for the production of polyurethane coatings 失效
    聚氨酯涂料生产工艺

    公开(公告)号:US5126170A

    公开(公告)日:1992-06-30

    申请号:US540536

    申请日:1990-06-19

    摘要: The present invention relates to a process for the preparation of a polyurethane coating by coating a substrate with a coating composition containinga) a polyisocyanate component andb) an isocyanate-reactive component containing at least one compound corresponding to the formula ##STR1## wherein X represents an organic group which has a valency of n and is inert towards isocyanate groups at a temperature of 100.degree. C. or less,R.sup.1 and R.sup.2 may be identical or different and represent organic groups which are inert towards isocyanate groups at a temperature of 100.degree. C. or less,R.sup.3 and R.sup.4 may be identical or different and represent hydrogen or organic groups which are inert towards isocyanate groups at a temperature of 100.degree. C. or less andn represents an integer with a value of at least 2,and curing the coating composition at a temperature of 100.degree. C. or less.

    摘要翻译: 本发明涉及通过用包含a)多异氰酸酯组分的涂料组合物涂布基材来制备聚氨酯涂料的方法,和b)含有至少一种对应于下式的化合物的异氰酸酯反应性组分(I )其中X表示在100℃或更低的温度下具有n价并且对异氰酸酯基团呈惰性的有机基团,R 1和R 2可以相同或不同,表示在一个或多个基团上对于异氰酸酯基团是惰性的有机基团 温度为100℃以下时,R 3和R 4可以相同或不同,表示在100℃以下的温度下对异氰酸酯基具有惰性的氢或有机基团,n表示至少为 并且在100℃或更低的温度下固化涂料组合物。

    Process for the preparation of aqueous polyurethane dispersions and
solutions
    40.
    发明授权
    Process for the preparation of aqueous polyurethane dispersions and solutions 失效
    制备水性聚氨酯分散体和溶液的方法

    公开(公告)号:US4829122A

    公开(公告)日:1989-05-09

    申请号:US19902

    申请日:1987-02-27

    摘要: The present invention therefore relates to a process for the preparation of aqueous solutions or dispersions of polyurethane-polyureas by the reaction in the aqueous phase of prepolymers which contain chemically built-in hydrophilic groups and/or external emulsifiers which are not bound chemically as well as at least two free isocyanate groups with organic compounds containing at least two primary and/or secondary amino groups, characterized in that the isocyanate prepolymer which has been hydrophilically modified and/or contains an external emulsifier is mixed, in the absence of water, with compounds containing at the most one free primary or secondary amino group and at least one blocked group which releases a free primary or secondary amino group in the presence of water and a total of at least two at least partially blocked primary and/or secondary amino groups, and the mixture is subsequently mixed with water.The invention also relates to the dispersions or solutions obtained by this process and to their use for coating flexible and rigid substrates.

    摘要翻译: 因此,本发明涉及一种制备聚氨酯 - 聚脲的水溶液或分散体的方法,所述水溶液或分散体是通过在水相中含有化学内置的亲水基团的预聚物和/或外部乳化剂的反应制成的, 至少两个含有至少两个伯和/或仲氨基的有机化合物的游离异氰酸酯基团,其特征在于,在没有水的情况下将已经亲水改性和/或含有外部乳化剂的异氰酸酯预聚物与化合物 含有最多一个游离的伯或仲氨基和至少一个在水存在下释放游离的伯或仲氨基并且总共至少两个至少部分封闭的伯和/或仲氨基的封闭基团, 随后将混合物与水混合。 本发明还涉及通过该方法获得的分散体或溶液及其用于涂覆柔性和刚性基材的用途。