摘要:
The present disclosure is concerned with a process for the preparation of carboxylate containing polyurethane and the polymers so produced. Hydroxyl bearing components are reacted with tri- or tetra-carboxylic acid monoanhydrides so as to incorporate free carboxyl groups into the component, a proportion of the carboxyl groups are neutralized to ionic salts and hydroxyl component is then reacted with polyisocyanates and simultaneously or subsequently with chain extending agents. The polymer may be obtained as a dispersion in water and the chain lengthening agent may be water, formaldehyde or water soluble amines or hydrazines.
摘要:
The present invention provides novel nanoscale cellulose particles and also a process for their production. The cellulose-based particles obtained have volume-averaged particle sizes of less than 300 nm. These nanoparticles are produced from amorphous cellulose or by amorphization of cellulose, optional subsequent hydrolysis and by input of energy into a water-containing medium after or during dispersion.
摘要:
The present invention provides novel nanoscale cellulose particles and also a process for their production. The cellulose-based particles obtained have volume-averaged particle sizes of less than 300 run. These nanoparticles are produced from slightly oxidized cellulose and by input of energy into a water-containing medium after or during dispersion.
摘要:
The invention relates to the use of coating compositions to prepare coatings having water vapor permeabilities of at least 2500 g/m.sup.2 per day (DS 2109 TM1 method) containing (A) a polyurethane containing (1) 0.1 to 75 meq/100 g of ionic groups and (2) 11 to 50% by weight of --(CH.sub.2 CH.sub.2 O).sub.n -- units (wherein n is 2 to 25) incorporated into the main chain prepared from reactive components comprising (I) one or more polyisocyanates, (II) one or more polyols having a number average molecular weight of 350 to 5000, with the proviso that if any such polyol is a sulfonated polyether diol having the formula ##STR1## in which R is hydrogen or an organic group having 1 to 8 carbon atoms, m and n are 1 to 10, p is 0, 1, or 2, and M is ammonium or alkali metal cation, then an additional ethoxy-containing polyether polyol must also be present, and (III) one or more chain lengthening agents having a molecular weight of 32 to 349; and (B) 30 to 80% by weight, based on the sum of components (A) and (B), of an aqueous phase.
摘要:
This invention relates to coating compositions containing (A) a polyurethane system containing either a polyurethane containing ionic groups and polyethylene oxide units or a precursor thereof prepared from a blocked isocyanate prepolymer and a cross-linking agent and, optionally, (B) organic solvents. This invention further relates to the use of such coating compositions to prepare coatings that are permeable to water vapor.
摘要:
The present invention relates to polyisocyanate mixtures havinga) an average isocyanate functionality of at least 4.1,b) a (cyclo)aliphatically bound isocyanate group content (calculated as NCO, molecular weight =42) of 12.0 to 20.5% by weight,c) a chemically incorporated carboxyl group content (calculated as COOH, molecular weight =45) of 0.01 to 5.0% by weight andd) an ethylene oxide unit content arranged within terminal or lateral polyether chains of 0 to 10% by weight (calculated as C.sub.2 H.sub.4 O, molecular weight =44).The present invention also relates to a process for the preparation of these polyisocyanate mixtures and to their use as cross-linking agents in aqueous coating compositions containing water soluble or dispersible binders or binder components.
摘要:
The present invention relates to a process for the preparation of a polyurethane coating by coating a substrate with a coating composition containinga) a polyisocyanate component andb) an isocyanate-reactive component containing at least one compound corresponding to the formula ##STR1## wherein X represents an organic group which has a valency of n and is inert towards isocyanate groups at a temperature of 100.degree. C. or less,R.sup.1 and R.sup.2 may be identical or different and represent organic groups which are inert towards isocyanate groups at a temperature of 100.degree. C. or less,R.sup.3 and R.sup.4 may be identical or different and represent hydrogen or organic groups which are inert towards isocyanate groups at a temperature of 100.degree. C. or less andn represents an integer with a value of at least 2, and curing the coating composition at a temperature of 100.degree. C. or less.
摘要:
Disclosed herein is a process for bonding substrates comprising applying a hot-melt adhesive to the surface of at least one of the substrates and contacting the surface of said substrate with the surface of the other substrate, said adhesive containing an ester group-containing polyisocyanate which is a solid below 30.degree. C. and liquid above 100.degree. C., corresponding to formula (I)A(OCO-B-NCO).sub.n (I)in whichn stands for a whole number or a fraction (statistical average) of from 2 to 6,A stands for an n-valent organic group such as is obtained by removal of hydroxyl groups from an n-valent polyhydroxyl compound in the molecular weight (Mn) range of from 800 to 6000 containing ester and/or carbonate groups andB stands for an aliphatic, cycloaliphatic or aromatic hydrocarbon group having up to 18 carbon atoms.
摘要:
The present invention relates to a process for the preparation of a polyurethane coating by coating a substrate with a coating composition containinga) a polyisocyanate component andb) an isocyanate-reactive component containing at least one compound corresponding to the formula ##STR1## wherein X represents an organic group which has a valency of n and is inert towards isocyanate groups at a temperature of 100.degree. C. or less,R.sup.1 and R.sup.2 may be identical or different and represent organic groups which are inert towards isocyanate groups at a temperature of 100.degree. C. or less,R.sup.3 and R.sup.4 may be identical or different and represent hydrogen or organic groups which are inert towards isocyanate groups at a temperature of 100.degree. C. or less andn represents an integer with a value of at least 2,and curing the coating composition at a temperature of 100.degree. C. or less.
摘要:
The present invention therefore relates to a process for the preparation of aqueous solutions or dispersions of polyurethane-polyureas by the reaction in the aqueous phase of prepolymers which contain chemically built-in hydrophilic groups and/or external emulsifiers which are not bound chemically as well as at least two free isocyanate groups with organic compounds containing at least two primary and/or secondary amino groups, characterized in that the isocyanate prepolymer which has been hydrophilically modified and/or contains an external emulsifier is mixed, in the absence of water, with compounds containing at the most one free primary or secondary amino group and at least one blocked group which releases a free primary or secondary amino group in the presence of water and a total of at least two at least partially blocked primary and/or secondary amino groups, and the mixture is subsequently mixed with water.The invention also relates to the dispersions or solutions obtained by this process and to their use for coating flexible and rigid substrates.